CN106245215A - A kind of production method of alginate fibre Rachael blanket - Google Patents
A kind of production method of alginate fibre Rachael blanket Download PDFInfo
- Publication number
- CN106245215A CN106245215A CN201610683939.1A CN201610683939A CN106245215A CN 106245215 A CN106245215 A CN 106245215A CN 201610683939 A CN201610683939 A CN 201610683939A CN 106245215 A CN106245215 A CN 106245215A
- Authority
- CN
- China
- Prior art keywords
- alginate fibre
- rachael blanket
- finished product
- fibre rachael
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 185
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 title claims abstract description 158
- 229940072056 alginate Drugs 0.000 title claims abstract description 158
- 235000010443 alginic acid Nutrition 0.000 title claims abstract description 158
- 229920000615 alginic acid Polymers 0.000 title claims abstract description 158
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 239000011265 semifinished product Substances 0.000 claims abstract description 67
- 238000004043 dyeing Methods 0.000 claims abstract description 50
- 239000000047 product Substances 0.000 claims abstract description 44
- 230000009467 reduction Effects 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 35
- 206010053615 Thermal burn Diseases 0.000 claims abstract description 32
- 238000004140 cleaning Methods 0.000 claims abstract description 30
- 230000008569 process Effects 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 26
- 210000004209 hair Anatomy 0.000 claims abstract description 20
- 239000004744 fabric Substances 0.000 claims abstract description 19
- 238000004513 sizing Methods 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 15
- 238000010025 steaming Methods 0.000 claims abstract description 13
- 241000628997 Flos Species 0.000 claims abstract description 8
- 238000009941 weaving Methods 0.000 claims abstract description 8
- 238000005520 cutting process Methods 0.000 claims abstract description 7
- 238000007689 inspection Methods 0.000 claims abstract description 7
- 238000004806 packaging method and process Methods 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims description 92
- 241000195474 Sargassum Species 0.000 claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000000243 solution Substances 0.000 claims description 40
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 35
- 239000000787 lecithin Substances 0.000 claims description 32
- 235000010445 lecithin Nutrition 0.000 claims description 32
- 229940067606 lecithin Drugs 0.000 claims description 32
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000001913 cellulose Substances 0.000 claims description 26
- 229920002678 cellulose Polymers 0.000 claims description 26
- 229920000728 polyester Polymers 0.000 claims description 26
- 239000012530 fluid Substances 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 24
- 238000007493 shaping process Methods 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 22
- 238000010009 beating Methods 0.000 claims description 20
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 17
- 229960004756 ethanol Drugs 0.000 claims description 16
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 15
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 15
- 241001330002 Bambuseae Species 0.000 claims description 15
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 15
- 239000011425 bamboo Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 238000011049 filling Methods 0.000 claims description 12
- 238000010008 shearing Methods 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 238000009987 spinning Methods 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 11
- 239000004310 lactic acid Substances 0.000 claims description 10
- 235000014655 lactic acid Nutrition 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 10
- 239000000376 reactant Substances 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 9
- 229930182490 saponin Natural products 0.000 claims description 9
- 150000007949 saponins Chemical class 0.000 claims description 9
- 238000001291 vacuum drying Methods 0.000 claims description 9
- 238000009954 braiding Methods 0.000 claims description 7
- 238000005470 impregnation Methods 0.000 claims description 7
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 7
- 235000013824 polyphenols Nutrition 0.000 claims description 7
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- 229920002101 Chitin Polymers 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 6
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 230000001680 brushing effect Effects 0.000 claims description 6
- 239000003599 detergent Substances 0.000 claims description 6
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- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 230000000149 penetrating effect Effects 0.000 claims description 6
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 6
- 229920000136 polysorbate Polymers 0.000 claims description 6
- 229920000053 polysorbate 80 Polymers 0.000 claims description 6
- 239000000661 sodium alginate Substances 0.000 claims description 6
- 235000010413 sodium alginate Nutrition 0.000 claims description 6
- 229940005550 sodium alginate Drugs 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- DSCFFEYYQKSRSV-FEPQRWDDSA-N (1s,2s,4s,5r)-6-methoxycyclohexane-1,2,3,4,5-pentol Chemical compound COC1[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H]1O DSCFFEYYQKSRSV-FEPQRWDDSA-N 0.000 claims description 5
- 241000195493 Cryptophyta Species 0.000 claims description 5
- 239000000648 calcium alginate Substances 0.000 claims description 5
- 229960002681 calcium alginate Drugs 0.000 claims description 5
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 5
- 238000006073 displacement reaction Methods 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 239000000017 hydrogel Substances 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 239000002608 ionic liquid Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000002000 scavenging effect Effects 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000640 hydroxylating effect Effects 0.000 claims description 2
- 238000002074 melt spinning Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 244000269722 Thea sinensis Species 0.000 claims 2
- 238000007598 dipping method Methods 0.000 claims 1
- 239000000052 vinegar Substances 0.000 claims 1
- 235000021419 vinegar Nutrition 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 17
- 230000036541 health Effects 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 238000003795 desorption Methods 0.000 abstract description 5
- 230000003115 biocidal effect Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 3
- 241001122767 Theaceae Species 0.000 description 12
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 241001474374 Blennius Species 0.000 description 9
- 238000011161 development Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 102000002322 Egg Proteins Human genes 0.000 description 4
- 108010000912 Egg Proteins Proteins 0.000 description 4
- 210000004681 ovum Anatomy 0.000 description 4
- 150000003904 phospholipids Chemical class 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
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- 230000008901 benefit Effects 0.000 description 3
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- 230000000694 effects Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000283898 Ovis Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000001461 cytolytic effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003814 hair luster Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
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- 229910052760 oxygen Inorganic materials 0.000 description 1
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- 230000035515 penetration Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
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- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/02—Pile fabrics or articles having similar surface features
- D04B21/04—Pile fabrics or articles having similar surface features characterised by thread material
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/02—Bed linen; Blankets; Counterpanes
- A47G9/0207—Blankets; Duvets
- A47G9/0223—Blankets
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C11/00—Teasing, napping or otherwise roughening or raising pile of textile fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C13/00—Shearing, clipping or cropping surfaces of textile fabrics; Pile cutting; Trimming seamed edges
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C15/00—Calendering, pressing, ironing, glossing or glazing textile fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/024—Material containing basic nitrogen using dispersed dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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Abstract
The present invention relates to woollen blanket preparation field, disclose the production method of a kind of alginate fibre Rachael blanket, including: 1), weaving: to plush yarn and wire gauze successively warping, weave, cut open floss, prepare alginate fibre Rachael blanket semi-finished product；2), prefinishing: by fabric sizing, bristle, hot light, clot；3), dyeing and finishing: by textile dyeing, then to its reduction cleaning, be then passed through acetum and neutralize, wash out cylinder, drying, steaming and color fixing, flexible smooth process, the most again dry；4), Final finishing: fabric drying sizing, front hot light, front bristle, front are scalded cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front scald cut, the back side scald cut, cutting stitching；5), product inspection, packaging warehouse-in.The alginate fibre Rachael blanket fine hair of the present invention is submissive, stand upright, good springiness, fabric skin-friendly, moisture absorption and desorption property, good permeability, and has the feature of antibiotic health care, environmental protection.
Description
Technical field
The present invention relates to woollen blanket preparation field, particularly relate to the production method of a kind of alginate fibre Rachael blanket.
Background technology
Along with the raising of people's material and culture level, the requirement of textile is also being improved, is not requiring nothing more than warming, beautiful by people
See, and more focus on comfortableness and functional.Functional textile becomes one of following developing trend of textile industry, will be with
Fine count fiber textile, non-woven fabrics, composite, ep-type material etc. collectively form the big tendency of following textile.Section now
The exploitation developing into functional textile of skill provides guarantee, the most also for textile enterprise's development and product restructuring, rises
To bigger facilitation the added value that improves textile.Study and produce the ecological and healthy function that is beneficial to man
Property textile product, have become as the world today development trend.
In general, the functionalization of textile is mainly realized by two approach: one is the functional treatment by fabric
Realizing, this is also the main path of current functional textile exploitation；Two is the functionalization of textile fabric.Along with science and technology
Development and the gradually enhancing of people's environmental protection consciousness, the limitation of fabric functional Final finishing processing method is increasingly subject to people
Concern, do not only exist the durability of function, the comfortableness of use and safety by the method functional product of obtaining of processing
Defect in terms of property, and inevitable to environment in arranging the course of processing.Merit is processed by functional fiber
Energy property textile then can overcome many drawbacks of fabric functional Final finishing, is the development trend obtaining functional textile.
Hosiery industry, under the leading of new and high technology, is actively adjusted the product mix, and payes attention to new raw material and the exploitation of new product,
Particularly fibre in differentiation and the exploitation of functional fiber kind, greatly promote the development of hosiery industry.At Rachael blanket
Field, along with exploitation and utilization and the progress of technology of novel material, the most constantly widens its product scope.Except conventional
Outside Rachael blanket, develop high in technological content Rachael blanket and become an important developing direction.The each big authority in the world spins
The research of loom structure shows, the development trend in textile product field is to pursue comfortableization and multifunction.
Present consumer does not require nothing more than Rachael blanket and has warmth retention property, has that matte is plentiful, soft comfortable, plain height
Expensive, slim and graceful feel style and fabric good permeability, moisture absorption and desorption property are good, and have antibiotic health care, green ring to woollen blanket
The multifunctionalities such as guarantor have had demand.But on market, Rachael blanket, typically based on acrylon and terylene woollen blanket, also has at home
Least a portion of cotton and Pilus Caprae seu Ovis Rachael blanket, quality scale is relatively low or expensive, it is impossible to meets the market demand, therefore develops
Disclosure satisfy that the Rachael blanket of consumer demand becomes a kind of trend.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides the production method of a kind of alginate fibre Rachael blanket.This
The alginate fibre Rachael blanket of invention has that fine hair is submissive, stands upright, good springiness, fabric skin-friendly, moisture absorption and desorption property, breathability
Good advantage, additionally has the feature such as antibiotic health care, environmental protection.
The concrete technical scheme of the present invention is: the production method of a kind of alginate fibre Rachael blanket, long with alginate fibre
Silk, as plush yarn raw material, using polyester drawn yarns as wire gauze raw material, comprises the steps:
1), weaving: on tricot machine, plush yarn and wire gauze are successively carried out warping, weaves, cut open floss, prepare alginate fibre La Sheer
Woollen blanket semi-finished product.
2), prefinishing: carry out described alginate fibre Rachael blanket semi-finished product shaping, bristle, hot light, clot.
3), dyeing and finishing: the alginate fibre Rachael blanket semi-finished product after prefinishing are positioned in dyeing liquor and dye, connect
, with reduction cleaning liquid, the alginate fibre Rachael blanket semi-finished product after dyeing are carried out reduction cleaning, warp after elder generation after reduction cleaning
Peracetic acid solution neutralizes, washes out cylinder, drying, steaming and color fixing, uses flexible smooth agent that alginate fibre is drawn house after steaming and color fixing
You carry out flexible smooth process by woollen blanket semi-finished product, the most again dry.
4), Final finishing: the alginate fibre Rachael blanket semi-finished product after dyeing and finishing carry out drying and shaping successively, front is scalded
Light, front bristle, front scald cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front boiling hot are cut, the back side
Scald cut, cutting sew up, obtain alginate fibre Rachael blanket finished product.
5), product inspection, packaging warehouse-in.
The inventive method is according to the feature of alginate fibre long filament, in conjunction with the performance of HDR5DPLM30 raschel machine, if
Count out the upper machine tissue meeting its characteristic.Prefinishing technique is formulated according to alginate fibre long filament performance；To cuing open the grey cloth after floss
First carrying out pre-setting and hot light process, make the carpet surface fine hair crimpness before dyeing reduce, pieces dissipates pine and is conducive at dyeing, softness
Reason and Final finishing processing.
The preparation method of described alginate fibre long filament is as follows: by melted after polyester slice, Sargassum functional agglomerate being blended
Spinning-drawing machine carries out spinning, prepares alginate fibre long filament；Wherein said Sargassum functional agglomerate accounts for the 3-of alginate fibre long filament gross mass
5%。
The present invention selects alginate fibre as Rachael blanket plush yarn, contains Sargassum extract in Sargassum functional agglomerate,
For natural material, there is antibacterial, the feature of good hygroscopicity, harmless, good to the affinity of skin.The present invention is to use sea
Algae fiber is as raw material, and this fiber is a kind of novel plants antimicrobial fiber.By organizational structure reasonable in design for this raw material, ingenious
In conjunction with chaining, latitude substrate cloth raw material, by the research to key technologies such as warp knit weaving, prefinishing, printing and dyeing and Final finishing productions
With exploitation, thus improve quality and the added value of product, make woollen blanket keep soft, fine and smooth, smooth on the basis of, more have antibacterial
Health care, the feature such as ventilative nice and cool.Product in use, along with the continuous CONTACT WITH FRICTION of human body skin Yu fiber, by Sargassum
Effective component in fiber constantly discharges from fiber, and is absorbed by human body, and the successful development of this project meets Green Textile Base
The needs of product, i.e. ensure that the characteristic of the comfortable softness of Rachael blanket, more outstanding natural, green, healthy concept.
As preferably, tricot machine described in step 1) is HDR5DPLM30 type raschel machine, and braiding speed is 420r/
Min, L1 and L5 sley bar uses inlaid thread filling inlaid thread, L2 Yu L4 sley bar uses inlaid thread filling chaining, and L3 wool yarn sley bar uses through flat
Braiding, form of entrying is for completely to wear；Wherein, the specification of described alginate fibre long filament is 150D/72F, and the specification of polyester drawn yarns is
150D/36F。
As preferably, step 2) sizing time, alginate fibre Rachael blanket semi-finished product are at room temperature immersed in treatment fluid,
Treatment fluid to 50 DEG C, is then incubated 45min with the ramp of 2 DEG C/min, is cooled to sea after room temperature with the speed of 3 DEG C/min
Algae fiber raschel blanket semi-finished product take out washing, containing following material in treatment fluid: sodium silicate 0.2g/L, Matrii Sulfas Exsiccatus 2g/L,
Aluminium silicate 0.22g/L, chitin 1.5g/L and penetrating agent 0.5g/L, bath raio 1:20.
As preferably, before carrying out dyeing and finishing, the alginate fibre Rachael blanket semi-finished product after prefinishing are carried out pretreatment:
Alginate fibre Rachael blanket semi-finished product submergence carries out impregnation process in ethanol, and wherein alginate fibre Rachael blanket half becomes
Product are 1:(2-4 with the mass ratio of ethanol), dip time is 20-40min.
Owing to fiber surface has one layer of oil film, therefore when dyeing, due to the obstruct of oil film, dyestuff not easily penetrate into into
Fibrous inside, causes Color poor.And before dyeing, fabric is carried out in ethanol impregnation process, it is possible to dissolve part oil
Film so that it is lower thickness, it is simple to dyestuff penetration enters fibrous inside, increases color fastness.However it is necessary that control dip time and second
Alcohol consumption, it is to avoid oil film excessive dissolution and cause fibre-fibre friction, finally affect glossiness and the smoothness of fiber surface.
As preferably, when step 3) dyes, high-temperature and high pressure dyeing process is selected to dye: to prepare dying easily at normal temperatures
Liquid, the pH of described dye liquor controls at 5.6-6.8；Then alginate fibre Rachael blanket semi-finished product are immersed in dye liquor, Sargassum
Fiber raschel blanket semi-finished product are 1:10 with the mass ratio of dye liquor；Then dye liquor is carried out heat temperature raising: first by dye liquor with
The speed of 1.5 DEG C/min is warming up to 90 DEG C, then with the speed of 1 DEG C/min, dye liquor is warming up to 125-135 DEG C, last fixation
60min；Dye wherein uses during dark product Palanilp nonionic dye；Mibct keton is used during dye light-coloured prods
Polyester dispersion dyestuff.
In the present invention, according to alginate fibre morphosis, aggregated structure, physical and mechanical properties, to chemical agent
Sensitivity, the performance such as fibrillation formulate suitable dyeing and finishing technology.Alginate fibre is a kind of polyester-based fibers, and molten point is relatively low, no
High temperature resistant, especially sensitive to alkali, it is easy to hydrolysis damage；In acid bath, fiber also can occur significantly to hydrolyze damage, in order to
Ensure affinity, dye-uptake, dyeing speed and the level-dyeing property of alginate fibre La Er woollen blanket, select low temperature, alkali-free, the dye of low acid
Color processing conditions；In dye during dark color, select PalanilP nonionic dye；During dye light-coloured prods, Mibct keton is selected to gather
Ester disperse dyes, are dyeed by SYC-300 high-temperature pressure dyeing, it is possible to reduce environmental pollution.
As preferably, reduction cleaning liquid described in step 3) includes the synthesis detergent of 1.5-2.5g/L, 1.0-1.5g/L
Tea saponin, the sodium alginate of 10-15g/L Sargassum powder and 1.0-2.0g/L and water, bath raio 1:25, temperature 50-55 DEG C, clean
Time 25-35min；During the dark product of dye, described reduction cleaning liquid also includes the sodium carbonate of 1-2g/L, the sodium hydrosulfite of 2g/L, 5-
The tea polyphenols of 10g/L and the nano titanium oxide of 0.3-0.5g/L；After reduction cleaning, the concentration of acetum used is 0.5wt%；
When flexible smooth processes, carry out arranging the 2-3 second to fabric with flexible smooth agent；Described flexible smooth agent includes lecithin, puts down
Lubrication prescription, tween 80 and water, the weight of wherein said lecithin is the 2.5-3% of water weight, and the weight of smooth agent is the 1.5-of water weight
2%, the weight of tween is the 0.5-1% of water weight.
In the present invention, owing to alginate fibre is the most alkaline-resisting, low-temperature neutral bath time at softness, is used to process, soft in reduction cleaning
During supple-settlement, after cleanout fluid cleans, softness is smooth, gloss is beautiful to make alginate fibre Rachael blanket have, clear in reduction
Adding Sargassum powder in washing liquid is to make it form a tunic to protect woollen blanket at carpeted surface, having anti-oxidation function；Tea
Saponin is a kind of nonionic surfactant, therefore, it is possible to use as abluent, and tea saponin and common abluent simultaneously
Compare, the water environment of various hardness has preferable stability, it is possible to give full play to the surface activity of himself.In addition tea
Saponin also has certain color fixative blast, increases the effect of color fastness, when after Woollen blanket printing fixation, it is possible to promote outside it fiber
See vividness.Na is added when dye is dark3CO3And sodium hydrosulfite, more effectively remove the loose colour of fiber surface；Add tea polyphenols and receive
Rice titanium dioxide, then be to improve the anti-oxidation function of woollen blanket and anti-microbial property.
Lecithin is oily matter, has good lubricant effect, it is possible to absorbed by fiber, thus promotes the toughness of fiber
And feel so that the fine hair of woollen blanket has good anti-pressure ability.In addition lecithin is harmless to health, for green material.Tell
Temperature has good emulsification, also is able to increase the dissolubility of lecithin simultaneously.
As preferably, described lecithin is through modification: mixed with the lactic acid solution that concentration is 50-60wt% by lecithin
Closing the stirring of uniform post-heating, wherein said lecithin is 100:(4-6 with the mass ratio of lactic acid solution), heating-up temperature is 70-80
DEG C, heat time heating time 40-60min；Being gradually added into quality to reactant liquor during heated and stirred is described lecithin 20-25%
Concentration is the hydrogen peroxide solution of 30wt%；To reactant liquor dropping sodium hydroxide solution to neutral, the most very after heated and stirred terminates
Empty dried prepared hydroxylating modified lecithin.
The mobility of common lecithin is poor, and viscosity is higher, is unfavorable for being absorbed by fiber and in fiber surface film forming,
The mobility of modified lecithin is therefore greatly increased, and is easier to be absorbed and in fiber surface film forming by fiber.
As preferably, in step 4) Final finishing, drying and shaping uses FIR4 drying and setting machine, inverse hair to enter machine, patent door width
158-162cm, temperature 110-120 DEG C, speed 17-20m/min of shaping；Bristle uses the double roller brushing machine of MB211E type, speed 3-
4m/min, enters machine along hair, and bristle spaces 2.5mm；Hot light uses SME473H type list roller secondary to scald shearing machine, hot light temperature 120-130
DEG C, speed 7-10m/min；Scalding to cut uses MB322E type high-speed and high-efficiency to scald shearing machine, carries out alginate fibre Rachael blanket front
Scald and cut, temperature 120-130 DEG C, speed 8-10m/min；Fluffing uses ME331E raising machine, anti-to alginate fibre Rachael blanket
Fluff in face, speed 8-10m/min.
As preferably, the preparation method of described Sargassum functional agglomerate is as follows: takes bamboo powder and adds to its 8-12 times of quality
Concentration is in the sodium hydroxide solution of 8-12wt%, and after being uniformly dispersed, heating under reduced pressure is to 110-130 DEG C, and 6-8h is discongested in insulation；Dredge
It is filtrated to get bamboo powder after solution, then bamboo powder is added to the ethanol solution that concentration is 70-80wt% of its 8-12 times of quality, heating
Being incubated 3-5h after 80-90 DEG C, again filter, add water insoluble matter and pull an oar, making beating to slurry beating degree is 14-
16 ° of SR, then carry out defibrination, and defibrination is 18-22 ° of SR to slurry beating degree, wash and obtain after distillation of reducing pressure after making beating
Cellulose；Cellulose is added to the ionic liquid of its 18-22 times of quality, obtains cellulose solution；In cellulose solution
Add the seaweed extracted liquor of its volume 0.4-0.6 times, be uniformly mixing to obtain mixed solution, then the body such as interpolation in mixed solution
The long-pending calcium chloride solution that concentration is 2-4wt%, after cross-linking 1-2h at 40-50 DEG C, ice in a low temperature of shifting-18 DEG C to-22 DEG C
Freeze 1-2 days, then take out frost thing, thaw with flowing water, prepare cellulose-calcium alginate hydrogel, then carry out with dehydrated alcohol
Solvent is replaced, and after eventually passing vacuum drying and grinding, prepares Sargassum functional agglomerate.
Common alginate fibre be by spinning after fiber impregnation process in seaweed extracted liquor, thus it is fine to prepare Sargassum
Dimension；But the alginate fibre prepared in this way can gradually drop after repeatedly washing.Another kind of alginate fibre preparation side
Method is directly to carry out spinning after blended to seaweed extracted liquor and spinning liquid, the insufficient strength reason of the alginate fibre that this method prepares
Think, and seaweed extracted liquor and spinning liquid that dispersibility is blended is undesirable.
The alginate fibre of the present invention is that Sargassum functional agglomerate and polyester slice are together carried out melt spinning.Wherein, Sargassum
In the preparation process of functional agglomerate, first preparing cellulose, cellulolytic activity prepared by the inventive method is high, easily cross-links.Then
Cellulose is blended with seaweed extracted liquor, adds cross-linking agent calcium chloride solution, make the partial cross-linked solidification of seaweed extracted liquor, then warp
Cross freezing, make cellulose crosslinked sizing, thaw and after solvent displacement, prepare Sargassum functional agglomerate, this Sargassum functional agglomerate
The aeroge that actually solidfied material of Sargassum extract is compound with cellulose, the solidfied material of Sargassum extract is mutual with cellulose
Staggered crosslinking, and cellulose is preferable with the compatibility of spinning liquid, the alginate fibre intensity that spinning obtains is higher, Sargassum active substance
Load fastness high.Additionally, this Sargassum functional agglomerate has higher specific surface area so that it is have moisture absorption and desorption property, breathability
Good advantage.
The solid content of described seaweed extracted liquor is 25-35wt%, and the particle diameter of described Sargassum functional agglomerate is 1-20 micron.Sea
The usual prior art of algae extract is extracted and is obtained.
It is compared with the prior art, the invention has the beneficial effects as follows: the alginate fibre Rachael blanket of the present invention has fine hair
Color and luster is good, submissive, stand upright, good springiness, fabric skin-friendly, moisture absorption and desorption property, the advantage of good permeability and antibiotic health care, green
The feature of environmental protection.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
The production method of a kind of alginate fibre Rachael blanket, using alginate fibre long filament as plush yarn raw material, with drafted polyester
Silk, as wire gauze raw material, comprises the steps:
1), weaving: on tricot machine, plush yarn and wire gauze are successively carried out warping, weaves, cut open floss, prepare alginate fibre La Sheer
Woollen blanket semi-finished product.Wherein said tricot machine is HDR5DPLM30 type raschel machine, and braiding speed is 420r/min, L1 and L5
Sley bar uses inlaid thread filling inlaid thread, L2 Yu L4 sley bar uses inlaid thread filling chaining, and L3 wool yarn sley bar uses and knits through flat sennit, shape of entrying
Formula is for completely to wear；Wherein, the specification of described alginate fibre long filament is 150D/72F, and the specification of polyester drawn yarns is 150D/36F.
2), prefinishing: carry out described alginate fibre Rachael blanket semi-finished product shaping, bristle, hot light, clot.Sizing
Time, alginate fibre Rachael blanket semi-finished product are at room temperature immersed in treatment fluid, treatment fluid is with the ramp of 2 DEG C/min extremely
50 DEG C, then it is incubated 45min, after being cooled to room temperature with the speed of 3 DEG C/min, alginate fibre Rachael blanket semi-finished product is taken out
Washing, containing following material in treatment fluid: sodium silicate 0.2g/L, Matrii Sulfas Exsiccatus 2g/L, aluminium silicate 0.22g/L, chitin 1.5g/L
With penetrating agent 0.5g/L, bath raio 1:20.
3), dyeing and finishing: the alginate fibre Rachael blanket semi-finished product after prefinishing are positioned in dyeing liquor and dye, connect
, with reduction cleaning liquid, the alginate fibre Rachael blanket semi-finished product after dyeing are carried out reduction cleaning, warp after elder generation after reduction cleaning
Peracetic acid solution neutralizes, washes out cylinder, drying, steaming and color fixing, uses flexible smooth agent that alginate fibre is drawn house after steaming and color fixing
You carry out flexible smooth process by woollen blanket semi-finished product, the most again dry.
When dyeing, high-temperature and high pressure dyeing process is selected to dye: to prepare dye liquor at normal temperatures, the pH control of described dye liquor
System is about 6.2；Then being immersed in dye liquor by alginate fibre Rachael blanket semi-finished product, alginate fibre Rachael blanket half becomes
Product are 1:10 with the mass ratio of dye liquor；Then dye liquor is carried out heat temperature raising: first heated up with the speed of 1.5 DEG C/min by dye liquor
To 90 DEG C, then dye liquor is warming up to 130 DEG C with the speed of 1 DEG C/min, last fixation 60min；Wherein in dye during dark product
Use Palanilp nonionic dye；Mibct keton polyester dispersion dyestuff is used during dye light-coloured prods.
Described reduction cleaning liquid include 2g/L synthesis detergent, the tea saponin of 1.25g/L, 12.5g/L Sargassum powder with
The sodium alginate of 1.5g/L and water, bath raio 1:25, temperature 52 DEG C, scavenging period 30min；During the dark product of dye, described reduction is clear
Washing liquid also includes the sodium carbonate of 1.5g/L, the sodium hydrosulfite of 2g/L, the tea polyphenols of 7.5g/L and the nano titanium oxide of 0.4g/L.
After reduction cleaning, the concentration of acetum used is 0.5wt%.
When flexible smooth processes, carry out arranging the 2-3 second to fabric with flexible smooth agent；Described flexible smooth agent includes ovum
Phospholipid, smooth agent, tween 80 and water, the weight of wherein said lecithin is the 2.75% of water weight, and the weight of smooth agent is water weight
1.75%, the weight of tween is the 0.75% of water weight.
4), Final finishing: the alginate fibre Rachael blanket semi-finished product after dyeing and finishing carry out drying and shaping successively, front is scalded
Light, front bristle, front scald cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front boiling hot are cut, the back side
Scald cut, cutting sew up, obtain alginate fibre Rachael blanket finished product.Wherein, drying and shaping uses FIR4 drying and setting machine, inverse hair
Enter machine, patent door width 158-162cm, temperature 115 DEG C, speed 18m/min of shaping；Bristle uses the double roller brushing machine of MB211E type,
Speed 3.5m/min, enters machine along hair, and bristle spaces 2.5mm；Hot light uses SME473H type list roller secondary to scald shearing machine, hot light temperature
125 DEG C, speed 8m/min；Scalding to cut uses MB322E type high-speed and high-efficiency to scald shearing machine, carries out alginate fibre Rachael blanket front
Scald and cut, temperature 125 DEG C, speed 9m/min；Fluffing uses ME331E raising machine, has carried out alginate fibre Rachael blanket reverse side
Hair, speed 9m/min.
5), product inspection, packaging warehouse-in.
The preparation method of described alginate fibre long filament is as follows: by melted after polyester slice, Sargassum functional agglomerate being blended
Spinning-drawing machine carries out spinning, prepares alginate fibre long filament；Wherein said Sargassum functional agglomerate accounts for the 4% of alginate fibre long filament gross mass.
Embodiment 2
The production method of a kind of alginate fibre Rachael blanket, using alginate fibre long filament as plush yarn raw material, with drafted polyester
Silk, as wire gauze raw material, comprises the steps:
1), weaving: on tricot machine, plush yarn and wire gauze are successively carried out warping, weaves, cut open floss, prepare alginate fibre La Sheer
Woollen blanket semi-finished product.Wherein said tricot machine is HDR5DPLM30 type raschel machine, and braiding speed is 420r/min, L1 and L5
Sley bar uses inlaid thread filling inlaid thread, L2 Yu L4 sley bar uses inlaid thread filling chaining, and L3 wool yarn sley bar uses and knits through flat sennit, shape of entrying
Formula is for completely to wear；Wherein, the specification of described alginate fibre long filament is 150D/72F, and the specification of polyester drawn yarns is 150D/36F.
2), prefinishing: carry out described alginate fibre Rachael blanket semi-finished product shaping, bristle, hot light, clot.Sizing
Time, alginate fibre Rachael blanket semi-finished product are at room temperature immersed in treatment fluid, treatment fluid is with the ramp of 2 DEG C/min extremely
50 DEG C, then it is incubated 45min, after being cooled to room temperature with the speed of 3 DEG C/min, alginate fibre Rachael blanket semi-finished product is taken out
Washing, containing following material in treatment fluid: sodium silicate 0.2g/L, Matrii Sulfas Exsiccatus 2g/L, aluminium silicate 0.22g/L, chitin 1.5g/L
With penetrating agent 0.5g/L, bath raio 1:20.
3), dyeing and finishing: before carrying out dyeing and finishing, the alginate fibre Rachael blanket semi-finished product after prefinishing are carried out pretreatment:
Alginate fibre Rachael blanket semi-finished product submergence carries out impregnation process in ethanol, and wherein alginate fibre Rachael blanket half becomes
Product are 1:3 with the mass ratio of ethanol, and dip time is 30min.
Pretreated alginate fibre Rachael blanket semi-finished product are positioned in dyeing liquor and dye, then with reduction
Cleanout fluid carries out reduction cleaning to the alginate fibre Rachael blanket semi-finished product after dyeing, the most molten through peracetic acid after reduction cleaning
Liquid neutralizes, washes out cylinder, drying, steaming and color fixing, uses flexible smooth agent to alginate fibre Rachael blanket half after steaming and color fixing
Finished product carries out flexible smooth process, the most again dries.
When dyeing, high-temperature and high pressure dyeing process is selected to dye: to prepare dye liquor at normal temperatures, the pH control of described dye liquor
System is 6.8；Then alginate fibre Rachael blanket semi-finished product are immersed in dye liquor, alginate fibre Rachael blanket semi-finished product with
The mass ratio of dye liquor is 1:10；Then dye liquor is carried out heat temperature raising: first dye liquor is warming up to 90 with the speed of 1.5 DEG C/min
DEG C, then dye liquor is warming up to 130 DEG C with the speed of 1 DEG C/min, last fixation 60min；Wherein dye uses during dark product
Palanilp nonionic dye；Mibct keton polyester dispersion dyestuff is used during dye light-coloured prods.
Described reduction cleaning liquid include 2g/L synthesis detergent, the tea saponin of 1.25g/L, 12.5g/L Sargassum powder with
The sodium alginate of 1.5g/L and water, bath raio 1:25, temperature 52 DEG C, scavenging period 30min；During the dark product of dye, described reduction is clear
Washing liquid also includes the sodium carbonate of 1.5g/L, the sodium hydrosulfite of 2g/L, the tea polyphenols of 7.5g/L and the nano titanium oxide of 0.4g/L.
After reduction cleaning, the concentration of acetum used is 0.5wt%.
When flexible smooth processes, carry out arranging the 2-3 second to fabric with flexible smooth agent；Described flexible smooth agent includes ovum
Phospholipid, smooth agent, tween 80 and water, the weight of wherein said lecithin is the 2.8% of water weight, and the weight of smooth agent is water weight
1.8%, the weight of tween is the 0.7% of water weight.
Wherein said lecithin is through modification: after being mixed homogeneously with the lactic acid solution that concentration is 55wt% by lecithin
Heated and stirred, wherein said lecithin is 100:5 with the mass ratio of lactic acid solution, and heating-up temperature is 75 DEG C, heat time heating time
50min；Being gradually added into, to reactant liquor, the concentration that quality is described lecithin 22.5% during heated and stirred is the double of 30wt%
Oxygen aqueous solution；To reactant liquor dropping sodium hydroxide solution to neutral after heated and stirred terminates, finally after vacuum drying, prepare hydroxyl
Base modified lecithin.
4), Final finishing: the alginate fibre Rachael blanket semi-finished product after dyeing and finishing carry out drying and shaping successively, front is scalded
Light, front bristle, front scald cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front boiling hot are cut, the back side
Scald cut, cutting sew up, obtain alginate fibre Rachael blanket finished product.Wherein, drying and shaping uses FIR4 drying and setting machine, inverse hair
Enter machine, patent door width 158-162cm, temperature 115 DEG C, speed 19m/min of shaping；Bristle uses the double roller brushing machine of MB211E type,
Speed 3.5m/min, enters machine along hair, and bristle spaces 2.5mm；Hot light uses SME473H type list roller secondary to scald shearing machine, hot light temperature
125 DEG C, speed 8m/min；Scalding to cut uses MB322E type high-speed and high-efficiency to scald shearing machine, carries out alginate fibre Rachael blanket front
Scald and cut, temperature 125 DEG C, speed 9m/min；Fluffing uses ME331E raising machine, has carried out alginate fibre Rachael blanket reverse side
Hair, speed 9m/min.
5), product inspection, packaging warehouse-in.
The preparation method of described alginate fibre long filament is as follows: by melted after polyester slice, Sargassum functional agglomerate being blended
Spinning-drawing machine carries out spinning, prepares alginate fibre long filament；Wherein said Sargassum functional agglomerate accounts for the 3% of alginate fibre long filament gross mass.
In the present embodiment, the preparation method of described Sargassum functional agglomerate is as follows: takes bamboo powder and adds to its 10 times of quality
The sodium hydroxide solution that concentration is 10wt% in, after being uniformly dispersed, heating under reduced pressure to 120 DEG C, insulation discongest 7h；Mistake after discongesting
Filter obtains bamboo powder, then is added to the ethanol solution that concentration is 75wt% of its 10 times of quality by bamboo powder, is incubated after being heated to 85 DEG C
4h, filters again, adds water insoluble matter and pulls an oar, and making beating is 15 ° of SR to slurry beating degree, then carries out defibrination, mill
Slurry is 20 ° of SR to slurry beating degree, washes and obtain cellulose after distillation of reducing pressure after making beating；By cellulose add to its 20
In the ionic liquid of times quality, obtain cellulose solution；The solid content adding its volume 0.5 times in cellulose solution is
The seaweed extracted liquor of 30wt%, is uniformly mixing to obtain mixed solution, and then adding isopyknic concentration in mixed solution is 3wt%
Calcium chloride solution, cross-link after 1.5h at 45 DEG C, freeze 1.5 days in a low temperature of shift-20 DEG C, then take out frost thing, use
Flowing water thaws, and prepares cellulose-calcium alginate hydrogel, then carries out solvent displacement with dehydrated alcohol, eventually passes vacuum drying
After grinding, prepared particle diameter is the Sargassum functional agglomerate of 1-20 micron.
Embodiment 3
The production method of a kind of alginate fibre Rachael blanket, using alginate fibre long filament as plush yarn raw material, with drafted polyester
Silk, as wire gauze raw material, comprises the steps:
1), weaving: on tricot machine, plush yarn and wire gauze are successively carried out warping, weaves, cut open floss, prepare alginate fibre La Sheer
Woollen blanket semi-finished product.Wherein said tricot machine is HDR5DPLM30 type raschel machine, and braiding speed is 420r/min, L1 and L5
Sley bar uses inlaid thread filling inlaid thread, L2 Yu L4 sley bar uses inlaid thread filling chaining, and L3 wool yarn sley bar uses and knits through flat sennit, shape of entrying
Formula is for completely to wear；Wherein, the specification of described alginate fibre long filament is 150D/72F, and the specification of polyester drawn yarns is 150D/36F.
2), prefinishing: carry out described alginate fibre Rachael blanket semi-finished product shaping, bristle, hot light, clot.Sizing
Time, alginate fibre Rachael blanket semi-finished product are at room temperature immersed in treatment fluid, treatment fluid is with the ramp of 2 DEG C/min extremely
50 DEG C, then it is incubated 45min, after being cooled to room temperature with the speed of 3 DEG C/min, alginate fibre Rachael blanket semi-finished product is taken out
Washing, containing following material in treatment fluid: sodium silicate 0.2g/L, Matrii Sulfas Exsiccatus 2g/L, aluminium silicate 0.22g/L, chitin 1.5g/L
With penetrating agent 0.5g/L, bath raio 1:20.
3), dyeing and finishing: before carrying out dyeing and finishing, the alginate fibre Rachael blanket semi-finished product after prefinishing are carried out pretreatment:
Alginate fibre Rachael blanket semi-finished product submergence carries out impregnation process in ethanol, and wherein alginate fibre Rachael blanket half becomes
Product are 1:2 with the mass ratio of ethanol, and dip time is 40min.
Pretreated alginate fibre Rachael blanket semi-finished product are positioned in dyeing liquor and dye, then with reduction
Cleanout fluid carries out reduction cleaning to the alginate fibre Rachael blanket semi-finished product after dyeing, the most molten through peracetic acid after reduction cleaning
Liquid neutralizes, washes out cylinder, drying, steaming and color fixing, uses flexible smooth agent to alginate fibre Rachael blanket half after steaming and color fixing
Finished product carries out flexible smooth process, the most again dries.
When dyeing, high-temperature and high pressure dyeing process is selected to dye: to prepare dye liquor at normal temperatures, the pH control of described dye liquor
System is about 5.6；Then being immersed in dye liquor by alginate fibre Rachael blanket semi-finished product, alginate fibre Rachael blanket half becomes
Product are 1:10 with the mass ratio of dye liquor；Then dye liquor is carried out heat temperature raising: first heated up with the speed of 1.5 DEG C/min by dye liquor
To 90 DEG C, then dye liquor is warming up to 125 DEG C with the speed of 1 DEG C/min, last fixation 60min；Wherein in dye during dark product
Use Palanilp nonionic dye；Mibct keton polyester dispersion dyestuff is used during dye light-coloured prods.
Described reduction cleaning liquid include 1.5g/L synthesis detergent, the tea saponin of 1.0g/L, 10g/L Sargassum powder with
The sodium alginate of 1.0g/L and water, bath raio 1:25, temperature 50 C, scavenging period 35min；During the dark product of dye, described reduction is clear
Washing liquid also includes the sodium carbonate of 1g/L, the sodium hydrosulfite of 2g/L, the tea polyphenols of 5g/L and the nano titanium oxide of 0.3g/L.
After reduction cleaning, the concentration of acetum used is 0.5wt%.
When flexible smooth processes, carry out arranging the 2-3 second to fabric with flexible smooth agent；Described flexible smooth agent includes ovum
Phospholipid, smooth agent, tween 80 and water, the weight of wherein said lecithin is the 2.5% of water weight, and the weight of smooth agent is water weight
1.5%, the weight of tween is the 0.5% of water weight.
Wherein said lecithin is through modification: after being mixed homogeneously with the lactic acid solution that concentration is 50wt% by lecithin
Heated and stirred, wherein said lecithin is 100:4 with the mass ratio of lactic acid solution, and heating-up temperature is 70 DEG C, heat time heating time
60min；It is gradually added into, to reactant liquor, the dioxygen that concentration is 30wt% that quality is described lecithin 20% during heated and stirred
Aqueous solution；To reactant liquor dropping sodium hydroxide solution to neutral after heated and stirred terminates, finally after vacuum drying, prepare hydroxyl
Change modified lecithin.
4), Final finishing: the alginate fibre Rachael blanket semi-finished product after dyeing and finishing carry out drying and shaping successively, front is scalded
Light, front bristle, front scald cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front boiling hot are cut, the back side
Scald cut, cutting sew up, obtain alginate fibre Rachael blanket finished product.Wherein, drying and shaping uses FIR4 drying and setting machine, inverse hair
Enter machine, patent door width 158-162cm, temperature 110 DEG C, speed 17m/min of shaping；Bristle uses the double roller brushing machine of MB211E type,
Speed 3m/min, enters machine along hair, and bristle spaces 2.5mm；Hot light uses SME473H type list roller secondary to scald shearing machine, hot light temperature 120
DEG C, speed 7m/min；Scalding to cut uses MB322E type high-speed and high-efficiency to scald shearing machine, scalds alginate fibre Rachael blanket front
Cut, temperature 120 DEG C, speed 8m/min；Fluffing uses ME331E raising machine, has carried out alginate fibre Rachael blanket reverse side
Hair, speed 8m/min.
5), product inspection, packaging warehouse-in.
The preparation method of described alginate fibre long filament is as follows: by melted after polyester slice, Sargassum functional agglomerate being blended
Spinning-drawing machine carries out spinning, prepares alginate fibre long filament；Wherein said Sargassum functional agglomerate accounts for the 5% of alginate fibre long filament gross mass.
In the present embodiment, the preparation method of described Sargassum functional agglomerate is as follows: takes bamboo powder and adds to its 8 times of quality
Concentration is in the sodium hydroxide solution of 8wt%, and after being uniformly dispersed, heating under reduced pressure to 110 DEG C, 8h is discongested in insulation；Filter after discongesting
To bamboo powder, then bamboo powder is added to the ethanol solution that concentration is 70wt% of its 8 times of quality, after being heated to 80 DEG C, be incubated 5h, then
Secondary filtering, add water insoluble matter and pull an oar, making beating is 14 ° of SR to slurry beating degree, then carries out defibrination, and defibrination is to slurry
Material beating degree is 18 ° of SR, washes and obtain cellulose after distillation of reducing pressure after making beating；Cellulose is added to its 18 times of quality
Ionic liquid in, obtain cellulose solution；The sea that solid content is 25wt% of its volume 0.4 times is added in cellulose solution
Algae extracting solution, is uniformly mixing to obtain mixed solution, then adds the calcium chloride that isopyknic concentration is 2wt% in mixed solution
Solution, after cross-linking 2h, freezes 2 days in a low temperature of shifting-18 DEG C, then takes out frost thing, thaw with flowing water, prepare at 40 DEG C
Cellulose-calcium alginate hydrogel, then carry out solvent displacement with dehydrated alcohol, after eventually passing vacuum drying and grinding, prepare
Particle diameter is the Sargassum functional agglomerate of 1-20 micron.
Embodiment 4
The production method of a kind of alginate fibre Rachael blanket, using alginate fibre long filament as plush yarn raw material, with drafted polyester
Silk, as wire gauze raw material, comprises the steps:
1), weaving: on tricot machine, plush yarn and wire gauze are successively carried out warping, weaves, cut open floss, prepare alginate fibre La Sheer
Woollen blanket semi-finished product.Wherein said tricot machine is HDR5DPLM30 type raschel machine, and braiding speed is 420r/min, L1 and L5
Sley bar uses inlaid thread filling inlaid thread, L2 Yu L4 sley bar uses inlaid thread filling chaining, and L3 wool yarn sley bar uses and knits through flat sennit, shape of entrying
Formula is for completely to wear；Wherein, the specification of described alginate fibre long filament is 150D/72F, and the specification of polyester drawn yarns is 150D/36F.
2), prefinishing: carry out described alginate fibre Rachael blanket semi-finished product shaping, bristle, hot light, clot.Sizing
Time, alginate fibre Rachael blanket semi-finished product are at room temperature immersed in treatment fluid, treatment fluid is with the ramp of 2 DEG C/min extremely
50 DEG C, then it is incubated 45min, after being cooled to room temperature with the speed of 3 DEG C/min, alginate fibre Rachael blanket semi-finished product is taken out
Washing, containing following material in treatment fluid: sodium silicate 0.2g/L, Matrii Sulfas Exsiccatus 2g/L, aluminium silicate 0.22g/L, chitin 1.5g/L
With penetrating agent 0.5g/L, bath raio 1:20.
3), dyeing and finishing: before carrying out dyeing and finishing, the alginate fibre Rachael blanket semi-finished product after prefinishing are carried out pretreatment:
Alginate fibre Rachael blanket semi-finished product submergence carries out impregnation process in ethanol, and wherein alginate fibre Rachael blanket half becomes
Product are 1:4 with the mass ratio of ethanol, and dip time is 20min.
Pretreated alginate fibre Rachael blanket semi-finished product are positioned in dyeing liquor and dye, then with reduction
Cleanout fluid carries out reduction cleaning to the alginate fibre Rachael blanket semi-finished product after dyeing, the most molten through peracetic acid after reduction cleaning
Liquid neutralizes, washes out cylinder, drying, steaming and color fixing, uses flexible smooth agent to alginate fibre Rachael blanket half after steaming and color fixing
Finished product carries out flexible smooth process, the most again dries.
When dyeing, high-temperature and high pressure dyeing process is selected to dye: to prepare dye liquor at normal temperatures, the pH control of described dye liquor
System is about 6；Then alginate fibre Rachael blanket semi-finished product are immersed in dye liquor, alginate fibre Rachael blanket semi-finished product
It is 1:10 with the mass ratio of dye liquor；Then dye liquor is carried out heat temperature raising: be first warming up to the speed of 1.5 DEG C/min by dye liquor
90 DEG C, then dye liquor is warming up to 135 DEG C with the speed of 1 DEG C/min, last fixation 60min；Wherein dye makes during dark product
Use Palanilp nonionic dye；Mibct keton polyester dispersion dyestuff is used during dye light-coloured prods.
Described reduction cleaning liquid include 2.5g/L synthesis detergent, the tea saponin of 1.5g/L, 15g/L Sargassum powder with
The sodium alginate of 2.0g/L and water, bath raio 1:25, temperature 55 DEG C, scavenging period 25-35min；During the dark product of dye, described reduction
Cleanout fluid also includes the sodium carbonate of 2g/L, the sodium hydrosulfite of 2g/L, the tea polyphenols of 10g/L and the nano titanium oxide of 0.5g/L.
After reduction cleaning, the concentration of acetum used is 0.5wt%.
When flexible smooth processes, carry out arranging the 2-3 second to fabric with flexible smooth agent；Described flexible smooth agent includes ovum
Phospholipid, smooth agent, tween 80 and water, the weight of wherein said lecithin is the 3% of water weight, and the weight of smooth agent is water weight
2%, the weight of tween is the 1% of water weight.
Wherein said lecithin is through modification: after being mixed homogeneously with the lactic acid solution that concentration is 60wt% by lecithin
Heated and stirred, wherein said lecithin is 100:6 with the mass ratio of lactic acid solution, and heating-up temperature is 80 DEG C, heat time heating time
60min；It is gradually added into, to reactant liquor, the dioxygen that concentration is 30wt% that quality is described lecithin 25% during heated and stirred
Aqueous solution；To reactant liquor dropping sodium hydroxide solution to neutral after heated and stirred terminates, finally after vacuum drying, prepare hydroxyl
Change modified lecithin.
4), Final finishing: the alginate fibre Rachael blanket semi-finished product after dyeing and finishing carry out drying and shaping successively, front is scalded
Light, front bristle, front scald cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front boiling hot are cut, the back side
Scald cut, cutting sew up, obtain alginate fibre Rachael blanket finished product.Wherein, drying and shaping uses FIR4 drying and setting machine, inverse hair
Enter machine, patent door width 158-162cm, temperature 120 DEG C, speed 20m/min of shaping；Bristle uses the double roller brushing machine of MB211E type,
Speed 4m/min, enters machine along hair, and bristle spaces 2.5mm；Hot light uses SME473H type list roller secondary to scald shearing machine, hot light temperature 130
DEG C, speed 10m/min；Scalding to cut uses MB322E type high-speed and high-efficiency to scald shearing machine, scalds alginate fibre Rachael blanket front
Cut, temperature 130 DEG C, speed 10m/min；Fluffing uses ME331E raising machine, has carried out alginate fibre Rachael blanket reverse side
Hair, speed 10m/min.
5), product inspection, packaging warehouse-in.
The preparation method of described alginate fibre long filament is as follows: by melted after polyester slice, Sargassum functional agglomerate being blended
Spinning-drawing machine carries out spinning, prepares alginate fibre long filament；Wherein said Sargassum functional agglomerate accounts for the 5% of alginate fibre long filament gross mass.
In the present embodiment, the preparation method of described Sargassum functional agglomerate is as follows: takes bamboo powder and adds to its 12 times of quality
The sodium hydroxide solution that concentration is 12wt% in, after being uniformly dispersed, heating under reduced pressure to 130 DEG C, insulation discongest 6h；Mistake after discongesting
Filter obtains bamboo powder, then is added to the ethanol solution that concentration is 80wt% of its 12 times of quality by bamboo powder, is incubated after being heated to 0 DEG C
3h, filters again, adds water insoluble matter and pulls an oar, and making beating is 16 ° of SR to slurry beating degree, then carries out defibrination, mill
Slurry is 22 ° of SR to slurry beating degree, washes and obtain cellulose after distillation of reducing pressure after making beating；By cellulose add to its 22
In the ionic liquid of times quality, obtain cellulose solution；The solid content adding its volume 0.6 times in cellulose solution is
The seaweed extracted liquor of 35wt%, is uniformly mixing to obtain mixed solution, and then adding isopyknic concentration in mixed solution is 4wt%
Calcium chloride solution, cross-link after 1h at 50 DEG C, in a low temperature of shift-22 DEG C, frost 1 day, then takes out frost thing, uses flowing water
Thaw, prepare cellulose-calcium alginate hydrogel, then carry out solvent displacement with dehydrated alcohol, eventually pass vacuum drying and grind
After mill, prepared particle diameter is the Sargassum functional agglomerate of 1-20 micron.
Raw materials used, equipment in the present invention, unless otherwise noted, is the conventional raw material of this area, equipment；In the present invention
Method therefor, unless otherwise noted, is the conventional method of this area.
The above, be only presently preferred embodiments of the present invention, not impose any restrictions the present invention, every according to the present invention
Any simple modification, change and the equivalent transformation that above example is made by technical spirit, all still falls within the technology of the present invention side
The protection domain of case.
Claims (10)
1. the production method of an alginate fibre Rachael blanket, it is characterised in that former using alginate fibre long filament as plush yarn
Material, using polyester drawn yarns as wire gauze raw material, comprises the steps:
1), weaving: on tricot machine, plush yarn and wire gauze are successively carried out warping, weaves, cut open floss, prepare alginate fibre La Sheer
Woollen blanket semi-finished product；
2), prefinishing: carry out described alginate fibre Rachael blanket semi-finished product shaping, bristle, hot light, clot；
3), dyeing and finishing: the alginate fibre Rachael blanket semi-finished product after prefinishing are positioned in dyeing liquor and dye, then use
Reduction cleaning liquid carries out reduction cleaning to the alginate fibre Rachael blanket semi-finished product after dyeing, successively through vinegar after reduction cleaning
Acid solution neutralizes, washes out cylinder, drying, steaming and color fixing, uses flexible smooth agent to alginate fibre La Sheermao after steaming and color fixing
Blanket semi-finished product carry out flexible smooth process, the most again dry；
4), Final finishing: the alginate fibre Rachael blanket semi-finished product after dyeing and finishing are carried out successively drying and shaping, front hot light, just
Face bristle, front scald cut, back side fluffing, back side bristle, back side hot light, the back side grab cut, multiple sizing, front scald cut, the back side boiling hot is cut,
Cutting is sewed up, and obtains alginate fibre Rachael blanket finished product；
5), product inspection, packaging warehouse-in；
The preparation method of described alginate fibre long filament is as follows: pass through melt spinning after polyester slice, Sargassum functional agglomerate being blended
Machine carries out spinning, prepares alginate fibre long filament；Wherein said Sargassum functional agglomerate accounts for the 3-5% of alginate fibre long filament gross mass.
2. the production method of alginate fibre Rachael blanket as claimed in claim 1, it is characterised in that warp described in step 1)
Volume machine is HDR5DPLM30 type raschel machine, and braiding speed is that 420r/min, L1 and L5 sley bar uses inlaid thread filling inlaid thread,
L2 Yu L4 sley bar uses inlaid thread filling chaining, and L3 wool yarn sley bar uses and knits through flat sennit, and form of entrying is for completely to wear；Wherein, described sea
The specification of algae fiber filament is 150D/72F, and the specification of polyester drawn yarns is 150D/36F.
3. the production method of alginate fibre Rachael blanket as claimed in claim 1, it is characterised in that step 2) sizing time,
Alginate fibre Rachael blanket semi-finished product are at room temperature immersed in treatment fluid, treatment fluid with the ramp of 2 DEG C/min to 50
DEG C, then it is incubated 45min, after being cooled to room temperature with the speed of 3 DEG C/min, alginate fibre Rachael blanket semi-finished product is taken out water
Wash, containing following material in treatment fluid: sodium silicate 0.2g/L, Matrii Sulfas Exsiccatus 2g/L, aluminium silicate 0.22g/L, chitin 1.5g/L with
Penetrating agent 0.5g/L, bath raio 1:20.
4. the production method of alginate fibre Rachael blanket as claimed in claim 1, it is characterised in that before carrying out dyeing and finishing,
Alginate fibre Rachael blanket semi-finished product after prefinishing are carried out pretreatment: by alginate fibre Rachael blanket semi-finished product submergence
Carrying out impregnation process in ethanol, wherein alginate fibre Rachael blanket semi-finished product are 1:(2-4 with the mass ratio of ethanol), dipping
Time is 20-40min.
5. the production method of alginate fibre Rachael blanket as claimed in claim 1, it is characterised in that the dye in step 3)
During color, high-temperature and high pressure dyeing process is selected to dye: preparing dye liquor at normal temperatures, the pH of described dye liquor controls at 5.6-6.8；
Then alginate fibre Rachael blanket semi-finished product are immersed in dye liquor, alginate fibre Rachael blanket semi-finished product and the matter of dye liquor
Amount ratio is 1:10；Then dye liquor is carried out heat temperature raising: first dye liquor is warming up to 90 DEG C with the speed of 1.5 DEG C/min, then
Dye liquor is warming up to 125-135 DEG C with the speed of 1 DEG C/min, last fixation 60min；Wherein dye uses during dark product
Palanilp nonionic dye；Mibct keton polyester dispersion dyestuff is used during dye light-coloured prods.
6. the production method of alginate fibre Rachael blanket as claimed in claim 1, it is characterised in that described in step 3) also
Former cleanout fluid include the synthesis detergent of 1.5-2.5g/L, the tea saponin of 1.0-1.5g/L, 10-15g/L Sargassum powder with 1.0-
The sodium alginate of 2.0g/L and water, bath raio 1:25, temperature 50-55 DEG C, scavenging period 25-35min；During the dark product of dye, described
Reduction cleaning liquid also includes the sodium carbonate of 1-2g/L, the sodium hydrosulfite of 2g/L, the tea polyphenols of 5-10g/L and the nanometer of 0.3-0.5g/L
Titanium dioxide；After reduction cleaning, the concentration of acetum used is 0.5wt%；When flexible smooth processes, with flexible smooth agent pair
Fabric carries out arranging the 2-3 second；Described flexible smooth agent includes lecithin, smooth agent, tween 80 and water, wherein said lecithin
Weight be water weight 2.5-3%, the weight of smooth agent be water weight 1.5-2%, the weight of tween be water weight 0.5-1%.
7. the production method of alginate fibre Rachael blanket as claimed in claim 6, it is characterised in that described lecithin passes through
Modification: post-heating of being mixed homogeneously with the lactic acid solution that concentration is 50-60wt% by lecithin stirs, wherein said lecithin
Be 100:(4-6 with the mass ratio of lactic acid solution), heating-up temperature is 70-80 DEG C, heat time heating time 40-60min；In heated and stirred mistake
Journey is gradually added into, to reactant liquor, the hydrogen peroxide solution that concentration is 30wt% that quality is described lecithin 20-25%；Stir in heating
Mix end backward reactant liquor dropping sodium hydroxide solution the most neutral, finally after vacuum drying, prepare hydroxylating modified lecithin.
8. the production method of alginate fibre Rachael blanket as claimed in claim 1, it is characterised in that step 4) Final finishing
In, drying and shaping uses FIR4 drying and setting machine, inverse hair to enter machine, patent door width 158-162cm, temperature 110-120 DEG C, sizing speed
Degree 17-20m/min；Bristle uses the double roller brushing machine of MB211E type, speed 3-4m/min, enters machine along hair, and bristle spaces 2.5mm；
Hot light uses SME473H type list roller secondary to scald shearing machine, hot light temperature 120-130 DEG C, speed 7-10m/min；Scald and cut employing
MB322E type high-speed and high-efficiency scalds shearing machine, carries out alginate fibre Rachael blanket front scalding and cuts, temperature 120-130 DEG C, speed 8-
10m/min；Fluffing uses ME331E raising machine, fluffs alginate fibre Rachael blanket reverse side, speed 8-10m/min.
9. the production method of the alginate fibre Rachael blanket as described in claim 1-8 is arbitrary, it is characterised in that described Sargassum
The preparation method of functional agglomerate is as follows: takes bamboo powder and adds to the sodium hydroxide that concentration is 8-12wt% of its 8-12 times of quality molten
In liquid, after being uniformly dispersed, heating under reduced pressure is to 110-130 DEG C, and 6-8h is discongested in insulation；Bamboo powder it is filtrated to get after discongesting, then by bamboo powder
Add to the ethanol solution that concentration is 70-80wt% of its 8-12 times of quality, be incubated 3-5h after being heated to 80-90 DEG C, again enter
Row filters, and adds water insoluble matter and pulls an oar, and making beating is 14-16 ° of SR to slurry beating degree, then carries out defibrination, and defibrination is to slurry
Material beating degree is 18-22 ° of SR, washes and obtain cellulose after distillation of reducing pressure after making beating；Cellulose is added to its 18-22
In the ionic liquid of times quality, obtain cellulose solution；The Sargassum adding its volume 0.4-0.6 times in cellulose solution is extracted
Liquid, is uniformly mixing to obtain mixed solution, then adds the calcium chloride solution that isopyknic concentration is 2-4wt% in mixed solution,
After cross-linking 1-2h at 40-50 DEG C, freeze 1-2 days in a low temperature of shifting-18 DEG C to-22 DEG C, then take out frost thing, use flowing water
Thaw, prepare cellulose-calcium alginate hydrogel, then carry out solvent displacement with dehydrated alcohol, eventually pass vacuum drying and grind
After mill, prepare Sargassum functional agglomerate.
10. the production method of alginate fibre Rachael blanket as claimed in claim 9, it is characterised in that described Sargassum is extracted
The solid content of liquid is 25-35wt%, and the particle diameter of described Sargassum functional agglomerate is 1-20 micron.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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