CN103711011B - 一种微交联型聚甲基丙烯酰氧乙基三甲基氯化铵改性固色剂及其制备方法 - Google Patents
一种微交联型聚甲基丙烯酰氧乙基三甲基氯化铵改性固色剂及其制备方法 Download PDFInfo
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- CN103711011B CN103711011B CN201310734018.XA CN201310734018A CN103711011B CN 103711011 B CN103711011 B CN 103711011B CN 201310734018 A CN201310734018 A CN 201310734018A CN 103711011 B CN103711011 B CN 103711011B
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- ammonium chloride
- trimethyl ammonium
- fixing agent
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- kilograms
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 40
- -1 poly(methacryloxyethyltrimethyl ammonium chloride) Polymers 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000004132 cross linking Methods 0.000 title abstract 4
- 239000004593 Epoxy Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 239000003999 initiator Substances 0.000 claims abstract description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 34
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 32
- YXYZMHGSOKYZAF-UHFFFAOYSA-M [Cl-].C(C(=C)C)(=O)OCC[N+](C(C)(C)C)(C)C Chemical compound [Cl-].C(C(=C)C)(=O)OCC[N+](C(C)(C)C)(C)C YXYZMHGSOKYZAF-UHFFFAOYSA-M 0.000 claims description 24
- 230000004048 modification Effects 0.000 claims description 23
- 238000012986 modification Methods 0.000 claims description 23
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 22
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 17
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 235000019394 potassium persulphate Nutrition 0.000 claims description 12
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000012423 maintenance Methods 0.000 claims description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims description 8
- 150000002924 oxiranes Chemical class 0.000 claims description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 claims description 5
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 4
- 238000005406 washing Methods 0.000 abstract description 7
- 239000004753 textile Substances 0.000 abstract description 6
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 abstract 2
- 239000004744 fabric Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 10
- 239000000975 dye Substances 0.000 description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000985 reactive dye Substances 0.000 description 6
- 239000003643 water by type Substances 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000002605 large molecules Chemical class 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- BFFCQDPRXVYDIA-UHFFFAOYSA-L disodium 6-(2,3-dibromopropanoylamino)-3-[[5-(2,3-dibromopropanoylamino)-2-sulfonatophenyl]diazenyl]-4-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Oc1c(N=Nc2cc(NC(=O)C(Br)CBr)ccc2S([O-])(=O)=O)c(cc2ccc(NC(=O)C(Br)CBr)cc12)S([O-])(=O)=O BFFCQDPRXVYDIA-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
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CN201510340023.1A CN104892832B (zh) | 2013-12-27 | 2013-12-27 | 一种微交联型聚甲基丙烯酰氧乙基三甲基氯化铵改性固色剂的制备方法 |
CN201310734018.XA CN103711011B (zh) | 2013-12-27 | 2013-12-27 | 一种微交联型聚甲基丙烯酰氧乙基三甲基氯化铵改性固色剂及其制备方法 |
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CN103711011B true CN103711011B (zh) | 2015-07-01 |
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CN201310734018.XA Active CN103711011B (zh) | 2013-12-27 | 2013-12-27 | 一种微交联型聚甲基丙烯酰氧乙基三甲基氯化铵改性固色剂及其制备方法 |
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Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105648803A (zh) * | 2016-04-01 | 2016-06-08 | 吴江市泽旺纺织有限公司 | 一种耐碱型固色剂及其制备方法 |
CN105862476B (zh) * | 2016-05-20 | 2017-12-22 | 刘剑锋 | 一种无甲醛活性染料固色剂及其制备方法 |
CN110382775B (zh) * | 2017-04-14 | 2022-09-09 | 日东纺绩株式会社 | 纤维素系纤维用湿摩擦坚牢度提高剂,使用其的染色纤维素纤维的制造方法,及其用途 |
CN107385916A (zh) * | 2017-06-28 | 2017-11-24 | 常州新之雅装饰材料有限公司 | 一种湿摩擦牢度提升剂 |
CN107325213B (zh) * | 2017-08-09 | 2019-09-10 | 江苏富淼科技股份有限公司 | 一种分子量可调节的甲基丙烯酰氧乙基三甲基氯化铵聚合物制备方法 |
CN108797163A (zh) * | 2018-07-06 | 2018-11-13 | 李美琴 | 一种织物固色剂及其制备方法 |
CN112142921A (zh) * | 2020-09-25 | 2020-12-29 | 苏州联胜化学有限公司 | 固色剂及其制备方法 |
CN113584912B (zh) * | 2021-09-09 | 2023-04-07 | 苏州联胜化学有限公司 | 一种浸渍用多功能色牢度提升剂及其制备方法 |
CN115584649B (zh) * | 2021-12-29 | 2023-11-28 | 清远市宏图助剂有限公司 | 一种阳离子高分子无甲醛的固色剂、制备方法及其应用 |
CN114953075B (zh) * | 2022-05-09 | 2023-08-08 | 浙江升华云峰新材股份有限公司 | 一种高色牢度重组装饰单板的制备方法 |
CN115748271A (zh) * | 2022-10-26 | 2023-03-07 | 浙江海联新材料科技有限公司 | 一种活性染料用三元共聚高效无醛固色剂及其制备方法 |
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CN101705632A (zh) * | 2009-11-30 | 2010-05-12 | 建德市白沙化工有限公司 | 一种阳离子高分子低温自交联无甲醛的固色剂及制备方法 |
CN101891854A (zh) * | 2010-07-05 | 2010-11-24 | 南京理工大学 | 相对分子质量受控聚季铵盐固色剂及其合成方法 |
CN102127873A (zh) * | 2010-01-20 | 2011-07-20 | 崔伟 | 一种用于织物的高分子型去污固色剂 |
CN102409568A (zh) * | 2011-11-17 | 2012-04-11 | 烟台大学 | 一种亲水性阳离子型无醛固色剂的制备方法 |
CN102504102A (zh) * | 2011-11-21 | 2012-06-20 | 南京理工大学 | 含3-羟杂氮环丁烷基反应性基团聚二甲基二烯丙基氯化铵改性固色剂及其合成方法 |
CN102797170A (zh) * | 2012-09-06 | 2012-11-28 | 苏州联胜化学有限公司 | 一种无醛固色剂及其制备方法 |
CN102887989A (zh) * | 2011-07-18 | 2013-01-23 | 杨海翔 | 一种新型无甲醛固色剂 |
CN103015239A (zh) * | 2012-12-29 | 2013-04-03 | 福建清源科技有限公司 | 一种聚二甲基二烯丙基氯化铵改性固色剂及其制备方法 |
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CN101684621B (zh) * | 2009-06-09 | 2012-05-09 | 陕西科技大学 | 一种树状阳离子皮革固色剂及其制备方法 |
CN102863582B (zh) * | 2011-07-04 | 2014-05-07 | 中国石油化工股份有限公司 | 一种超高分子量阳离子型聚丙烯酰胺的制备方法 |
CN102504103A (zh) * | 2011-11-21 | 2012-06-20 | 南京理工大学 | 微交联型聚二甲基二烯丙基氯化铵改性固色剂及其合成方法 |
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- 2013-12-27 CN CN201510340023.1A patent/CN104892832B/zh not_active Expired - Fee Related
- 2013-12-27 CN CN201310734018.XA patent/CN103711011B/zh active Active
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CN101705632A (zh) * | 2009-11-30 | 2010-05-12 | 建德市白沙化工有限公司 | 一种阳离子高分子低温自交联无甲醛的固色剂及制备方法 |
CN102127873A (zh) * | 2010-01-20 | 2011-07-20 | 崔伟 | 一种用于织物的高分子型去污固色剂 |
CN101891854A (zh) * | 2010-07-05 | 2010-11-24 | 南京理工大学 | 相对分子质量受控聚季铵盐固色剂及其合成方法 |
CN102887989A (zh) * | 2011-07-18 | 2013-01-23 | 杨海翔 | 一种新型无甲醛固色剂 |
CN102409568A (zh) * | 2011-11-17 | 2012-04-11 | 烟台大学 | 一种亲水性阳离子型无醛固色剂的制备方法 |
CN102504102A (zh) * | 2011-11-21 | 2012-06-20 | 南京理工大学 | 含3-羟杂氮环丁烷基反应性基团聚二甲基二烯丙基氯化铵改性固色剂及其合成方法 |
CN102797170A (zh) * | 2012-09-06 | 2012-11-28 | 苏州联胜化学有限公司 | 一种无醛固色剂及其制备方法 |
CN103015239A (zh) * | 2012-12-29 | 2013-04-03 | 福建清源科技有限公司 | 一种聚二甲基二烯丙基氯化铵改性固色剂及其制备方法 |
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CN104892832B (zh) | 2017-03-01 |
CN103711011A (zh) | 2014-04-09 |
CN104892832A (zh) | 2015-09-09 |
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Denomination of invention: Micro-crosslinking type poly(methacryloxyethyltrimethyl ammonium chloride) modified color fixing agent and preparation method thereof Effective date of registration: 20161108 Granted publication date: 20150701 Pledgee: Agricultural Bank of China Limited by Share Ltd Shishi branch Pledgor: Fujian Qingyuan Technology Co., Ltd. Registration number: 2016350000127 |
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Denomination of invention: Micro-crosslinking type poly(methacryloxyethyltrimethyl ammonium chloride) modified color fixing agent and preparation method thereof Effective date of registration: 20180719 Granted publication date: 20150701 Pledgee: Agricultural Bank of China Limited by Share Ltd Shishi branch Pledgor: Fujian Qingyuan Technology Co., Ltd. Registration number: 2018350000066 |
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Denomination of invention: A micro crosslinking color fixing agent modified by poly (methacryloxyethyl trimethylammonium chloride) and its preparation method Effective date of registration: 20210617 Granted publication date: 20150701 Pledgee: Agricultural Bank of China Limited by Share Ltd. Shishi branch Pledgor: FUJIAN QINGYUAN TECHNOLOGY Co.,Ltd. Registration number: Y2021350000060 |