CH566420B5 - Bis-stilbene compds for use as optical brighteners - Google Patents

Bis-stilbene compds for use as optical brighteners

Info

Publication number
CH566420B5
CH566420B5 CH700070A CH700070A CH566420B5 CH 566420 B5 CH566420 B5 CH 566420B5 CH 700070 A CH700070 A CH 700070A CH 700070 A CH700070 A CH 700070A CH 566420 B5 CH566420 B5 CH 566420B5
Authority
CH
Switzerland
Prior art keywords
compds
stilbene
bis
optical brighteners
groups
Prior art date
Application number
CH700070A
Other languages
German (de)
English (en)
Other versions
CH700070A4 (de
Inventor
Kurt Dr Weber
Peter Dr Liechti
Hans Rudolf Dr Meyer
Adolf Emil Dr Siegrist
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Priority to CH700070A priority Critical patent/CH566420B5/xx
Publication of CH700070A4 publication Critical patent/CH700070A4/xx
Publication of CH566420B5 publication Critical patent/CH566420B5/xx

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182Radicals derived from carboxylic acids
    • C07D295/192Radicals derived from carboxylic acids from aromatic carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/324Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a phosphorus atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/26Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/26Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/32Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by introduction of halogenated alkyl groups into ring compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24Halogenated aromatic hydrocarbons with unsaturated side chains
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01Sulfonic acids
    • C07C309/28Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01Sulfonic acids
    • C07C309/28Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/39Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing halogen atoms bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63Esters of sulfonic acids
    • C07C309/72Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/73Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78Halides of sulfonic acids
    • C07C309/86Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78Halides of sulfonic acids
    • C07C309/86Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/87Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/15Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/15Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
    • C07C311/17Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • CCHEMISTRY; METALLURGY
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02Sulfinic acids; Derivatives thereof
    • C07C313/04Sulfinic acids; Esters thereof
    • CCHEMISTRY; METALLURGY
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/44Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reduction and hydrolysis of nitriles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/52Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/546Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings polycyclic
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/52Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/55Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/42Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/64Acyl halides
    • C07C57/72Acyl halides containing six-membered aromatic rings
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/66Polycyclic acids with unsaturation outside the aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/26Sulfur atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/30Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32Esters thereof
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/30Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32Esters thereof
    • C07F9/3205Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3241Esters of arylalkanephosphinic acids
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4003Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4056Esters of arylalkanephosphonic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/535Organo-phosphoranes
    • C07F9/5352Phosphoranes containing the structure P=C-
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/54Quaternary phosphonium compounds
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/54Quaternary phosphonium compounds
    • C07F9/5456Arylalkanephosphonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041Optical brightening agents, organic pigments
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14Styryl dyes
    • C09B23/141Bis styryl dyes containing two radicals C6H5-CH=CH-
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14Styryl dyes
    • C09B23/148Stilbene dyes containing the moiety -C6H5-CH=CH-C6H5
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60Optical bleaching or brightening

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Paper (AREA)
CH700070A 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners CH566420B5 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CH700070A CH566420B5 (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1380667A CH513785A (de) 1967-10-03 1967-10-03 Verfahren zur Herstellung von neuen Bis-stilbenverbindungen
CH700070A CH566420B5 (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners

Publications (2)

Publication Number Publication Date
CH700070A4 CH700070A4 (de) 1975-01-31
CH566420B5 true CH566420B5 (en) 1975-09-15

Family

ID=4395511

Family Applications (4)

Application Number Title Priority Date Filing Date
CH700170A CH532106A (de) 1967-10-03 1967-10-03 Verwendung von Bis-stilbenverbindungen als optische Aufhellmittel ausserhalb der Textilindustrie
CH700070A CH566420B5 (en) 1967-10-03 1967-10-03 Bis-stilbene compds for use as optical brighteners
CH1380667A CH513785A (de) 1967-10-03 1967-10-03 Verfahren zur Herstellung von neuen Bis-stilbenverbindungen
CH1251168A CH554821A (de) 1967-10-03 1968-08-20 Verfahren zur herstellung von bis-stilbenverbindungen.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CH700170A CH532106A (de) 1967-10-03 1967-10-03 Verwendung von Bis-stilbenverbindungen als optische Aufhellmittel ausserhalb der Textilindustrie

Family Applications After (2)

Application Number Title Priority Date Filing Date
CH1380667A CH513785A (de) 1967-10-03 1967-10-03 Verfahren zur Herstellung von neuen Bis-stilbenverbindungen
CH1251168A CH554821A (de) 1967-10-03 1968-08-20 Verfahren zur herstellung von bis-stilbenverbindungen.

Country Status (22)

Country Link
JP (1) JPS54929B1 (xx)
AT (2) AT288306B (xx)
BE (1) BE721754A (xx)
BR (1) BR6802828D0 (xx)
CH (4) CH532106A (xx)
CS (2) CS174800B2 (xx)
DE (1) DE1793482C3 (xx)
DK (1) DK139845B (xx)
ES (2) ES358737A1 (xx)
FI (1) FI50238C (xx)
FR (1) FR1583595A (xx)
GB (1) GB1247934A (xx)
HK (1) HK53076A (xx)
IE (1) IE32388B1 (xx)
IL (1) IL30776A (xx)
NL (1) NL145531B (xx)
NO (1) NO131456C (xx)
PL (1) PL79354B1 (xx)
RO (1) RO55806A (xx)
SE (1) SE367399B (xx)
SU (2) SU476748A3 (xx)
YU (1) YU35093B (xx)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054511A2 (de) * 1980-12-12 1982-06-23 Ciba-Geigy Ag 4-Styryl-4'-vinylbiphenyle, Verfahren zu deren Herstellung und deren Verwendung als optische Aufheller
WO2005085189A2 (en) * 2004-03-08 2005-09-15 Medical Research Council Analogues of congo red and evaluation of their anti-prion activity

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH540233A (de) * 1969-06-05 1973-08-15 Ciba Geigy Ag Verfahren zur Herstellung neuer Di-Styrylbenzol-Derivate
US3880841A (en) * 1971-03-18 1975-04-29 Sandoz Ltd Triazolyl ethenyl phenylene derivatives
CH1917171A4 (xx) * 1971-12-30 1975-04-30
FR2168210A2 (en) * 1972-01-20 1973-08-31 Ciba Geigy Ag Bis-stilbene cpds - as optical brighteners
DE2326467B2 (de) * 1972-06-01 1979-02-22 Colgate-Palmolive Co., New York, N.Y. (V.St.A.) Flüssiges Grobwaschmittel
CH569043A5 (xx) * 1973-01-23 1975-11-14 Ciba Geigy Ag
CH630215B (de) * 1976-07-09 Ciba Geigy Ag Aufhellmittel und dessen verwendung zum aufhellen von textilien.
ZA802160B (en) * 1979-04-11 1981-04-29 Ciba Geigy Ag Distyrylbiphenyls
ZA802159B (en) * 1979-04-11 1981-04-29 Ciba Geigy Ag Distyrylbenzenes
US4339393A (en) * 1979-04-11 1982-07-13 Ciba-Geigy Corporation Distyrylbiphenyls
US4925595A (en) * 1987-07-03 1990-05-15 Ciba-Geigy Corporation Liquid detergent compositions containing disulfonated fluorescent whitening agents: di-styryl-biphenyl or di-styryl-benzene derivatives
EP0364403B1 (de) * 1988-10-13 1993-03-24 Ciba-Geigy Ag Distyrylbiphenylverbindungen
DE4019309A1 (de) * 1990-06-16 1991-12-19 Bayer Ag Neue lichtpolarisierende filme oder folien und farbstoffe zu ihrer herstellung
MY109837A (en) * 1992-06-30 1997-08-30 Ciba Specialty Chemicals Holding Inc Hydrates of the disodium salt or dipotassium salt of 4, 4''-bis (2-sulfostyryl)bipheny]
TW229199B (xx) * 1992-09-03 1994-09-01 Ciba Geigy
GB2277749B (en) * 1993-05-08 1996-12-04 Ciba Geigy Ag Fluorescent whitening of paper
US6168776B1 (en) 1994-07-19 2001-01-02 University Of Pittsburgh Alkyl, alkenyl and alkynyl Chrysamine G derivatives for the antemortem diagnosis of Alzheimer's disease and in vivo imaging and prevention of amyloid deposition
GB9422280D0 (en) * 1994-11-04 1994-12-21 Ciba Geigy Ag Fluorescent whitening agent formulation
GB9718353D0 (en) * 1997-08-30 1997-11-05 Ciba Geigy Ag Sulphonated distyryl - Biphenyl compounds
WO1999047495A1 (en) * 1998-03-19 1999-09-23 Ciba Speciality Chemicals Holding Inc. Process for the preparation of sulphonated distyryl-biphenyl compounds
KR100274871B1 (ko) * 1998-11-12 2000-12-15 김순택 발광 화합물 및 이를 발색 재료로서 채용하고 있는 표시소자2
DE10334046A1 (de) * 2003-07-25 2005-02-10 Clariant Gmbh Verfahren zur Herstellung von granulierten Acyloxybenzolsulfonaten oder Acyloxybenzolcarbonsäuren und deren Salze
EP3020768B1 (en) * 2010-05-18 2018-04-25 Milliken & Company Optical brighteners and compositions comprising the same
EP2571973B1 (en) 2010-05-18 2020-04-01 Milliken & Company Optical brighteners and compositions comprising the same
CN109912465B (zh) * 2019-04-17 2021-08-24 沈阳新纪化学有限公司 一种微蓝色调的二苯乙烯联苯类荧光增白剂的合成方法
US11292957B2 (en) 2020-01-21 2022-04-05 King Fahd University Of Petroleum And Minerals Gemini surfactants containing an arylene linker for clay swelling inhibition
CN114230509A (zh) * 2021-04-19 2022-03-25 闽都创新实验室 一种含有氟取代联苯的二苯乙烯衍生物及其制备方法、应用
JP2023056635A (ja) * 2021-10-08 2023-04-20 セイコーエプソン株式会社 結合材および成形体の製造方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054511A2 (de) * 1980-12-12 1982-06-23 Ciba-Geigy Ag 4-Styryl-4'-vinylbiphenyle, Verfahren zu deren Herstellung und deren Verwendung als optische Aufheller
WO2005085189A2 (en) * 2004-03-08 2005-09-15 Medical Research Council Analogues of congo red and evaluation of their anti-prion activity
WO2005085189A3 (en) * 2004-03-08 2005-12-29 Medical Res Council Analogues of congo red and evaluation of their anti-prion activity

Also Published As

Publication number Publication date
SU391781A3 (xx) 1973-07-25
SE367399B (xx) 1974-05-27
IL30776A0 (en) 1968-11-27
NO131456C (xx) 1975-06-11
IE32388B1 (en) 1973-07-11
YU226368A (en) 1980-03-15
NL6814089A (xx) 1969-04-09
CS174800B2 (cs) 1977-04-29
SU476748A3 (ru) 1975-07-05
CH554821A (de) 1974-10-15
NL145531B (nl) 1975-04-15
YU35093B (en) 1980-09-25
DE1793482C3 (de) 1975-09-25
FR1583595A (xx) 1969-11-14
RO55806A (xx) 1974-01-03
NO131456B (xx) 1975-02-24
DE1793482B2 (de) 1975-02-20
CH532106A (de) 1972-12-31
DK139845B (da) 1979-04-30
GB1247934A (en) 1971-09-29
DE1793482A1 (de) 1972-03-09
AT288306B (de) 1971-02-25
DK139845C (xx) 1979-10-08
BR6802828D0 (pt) 1973-04-17
JPS54929B1 (xx) 1979-01-18
CH700070A4 (de) 1975-01-31
FI50238C (fi) 1976-01-12
IL30776A (en) 1974-06-30
CH513785A (de) 1971-10-15
AT299171B (de) 1972-06-12
ES378656A1 (es) 1973-02-01
IE32388L (en) 1969-04-03
ES358737A1 (es) 1970-10-16
FI50238B (xx) 1975-09-30
HK53076A (en) 1976-09-03
BE721754A (xx) 1969-04-02
CS174763B2 (xx) 1977-04-29
PL79354B1 (en) 1975-06-30

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