CA1124917A - Melanges elastoplastiques de caoutchouc d'olefine vulcanise et de resine de polyolefines - Google Patents

Melanges elastoplastiques de caoutchouc d'olefine vulcanise et de resine de polyolefines

Info

Publication number: CA1124917A
Authority: CA; Canada
Prior art keywords: rubber; composition; weight; parts; cured
Prior art date: 1977-11-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA314,541A

Other languages

English (en)

Inventor

Michael A. Fath

Sabet Abdou-Sabet

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Monsanto Co

Original Assignee

Monsanto Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-11-09

Filing date

1978-10-27

Publication date

1982-06-01

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25306493&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1124917(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1978-10-27 Application filed by Monsanto Co filed Critical Monsanto Co

1982-06-01 Application granted granted Critical

1982-06-01 Publication of CA1124917A publication Critical patent/CA1124917A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 298
239000005060 rubber Substances 0.000 title claims abstract description 226
229920001971 elastomer Polymers 0.000 title claims abstract description 223
229920005672 polyolefin resin Polymers 0.000 title claims abstract description 83
150000001336 alkenes Chemical class 0.000 title abstract description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 139
229920001169 thermoplastic Polymers 0.000 claims abstract description 25
239000004416 thermosoftening plastic Substances 0.000 claims abstract description 25
229920002943 EPDM rubber Polymers 0.000 claims description 102
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 98
229920005989 resin Polymers 0.000 claims description 96
239000011347 resin Substances 0.000 claims description 96
-1 polypropylene Polymers 0.000 claims description 88
239000004743 Polypropylene Substances 0.000 claims description 59
229920001155 polypropylene Polymers 0.000 claims description 57
239000012190 activator Substances 0.000 claims description 52
239000011787 zinc oxide Substances 0.000 claims description 49
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 47
239000008096 xylene Substances 0.000 claims description 47
238000009835 boiling Methods 0.000 claims description 44
239000004606 Fillers/Extenders Substances 0.000 claims description 37
239000006229 carbon black Substances 0.000 claims description 25
238000000034 method Methods 0.000 claims description 25
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 23
229920000642 polymer Polymers 0.000 claims description 18
239000000945 filler Substances 0.000 claims description 16
239000002245 particle Substances 0.000 claims description 15
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims description 14
239000003795 chemical substances by application Substances 0.000 claims description 14
230000008569 process Effects 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 9
229920002681 hypalon Polymers 0.000 claims description 9
229920001897 terpolymer Polymers 0.000 claims description 9
239000004698 Polyethylene Substances 0.000 claims description 8
229920000573 polyethylene Polymers 0.000 claims description 8
229910044991 metal oxide Inorganic materials 0.000 claims description 7
150000004706 metal oxides Chemical class 0.000 claims description 7
229920000098 polyolefin Polymers 0.000 claims description 5
OPFTUNCRGUEPRZ-QLFBSQMISA-N Cyclohexane Natural products CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 claims description 4
230000006872 improvement Effects 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
239000004927 clay Substances 0.000 claims description 3
229920006124 polyolefin elastomer Polymers 0.000 claims description 3
239000012463 white pigment Substances 0.000 claims description 3
229910001507 metal halide Inorganic materials 0.000 claims 8
150000005309 metal halides Chemical group 0.000 claims 8
JFMWXIQWCXVKNO-UHFFFAOYSA-N 2,3-bis(hydroxymethyl)-4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C(CO)=C1CO JFMWXIQWCXVKNO-UHFFFAOYSA-N 0.000 claims 3
239000008240 homogeneous mixture Substances 0.000 claims 3
230000006835 compression Effects 0.000 abstract description 21
238000007906 compression Methods 0.000 abstract description 21
238000000465 moulding Methods 0.000 abstract description 2
238000001723 curing Methods 0.000 description 76
239000003921 oil Substances 0.000 description 54
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 18
229910052717 sulfur Inorganic materials 0.000 description 18
239000011593 sulfur Substances 0.000 description 18
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 16
239000012632 extractable Substances 0.000 description 14
235000021355 Stearic acid Nutrition 0.000 description 13
239000004615 ingredient Substances 0.000 description 13
238000002156 mixing Methods 0.000 description 13
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 13
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 13
239000008117 stearic acid Substances 0.000 description 13
229920000578 graft copolymer Polymers 0.000 description 9
229910052736 halogen Inorganic materials 0.000 description 9
150000002367 halogens Chemical class 0.000 description 9
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
239000005977 Ethylene Substances 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
150000001993 dienes Chemical class 0.000 description 8
239000000047 product Substances 0.000 description 8
238000007792 addition Methods 0.000 description 7
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 7
239000000391 magnesium silicate Substances 0.000 description 7
229910052919 magnesium silicate Inorganic materials 0.000 description 7
235000019792 magnesium silicate Nutrition 0.000 description 7
239000000463 material Substances 0.000 description 7
150000005673 monoalkenes Chemical class 0.000 description 7
239000005011 phenolic resin Substances 0.000 description 7
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 6
229910021626 Tin(II) chloride Inorganic materials 0.000 description 6
238000001125 extrusion Methods 0.000 description 6
229920001568 phenolic resin Polymers 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
235000011150 stannous chloride Nutrition 0.000 description 6
229920001187 thermosetting polymer Polymers 0.000 description 6
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 5
241001441571 Hiodontidae Species 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
230000000694 effects Effects 0.000 description 5
150000002989 phenols Chemical class 0.000 description 5
239000000049 pigment Substances 0.000 description 5
230000009257 reactivity Effects 0.000 description 5
239000001119 stannous chloride Substances 0.000 description 5
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 4
ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 4
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
239000004594 Masterbatch (MB) Substances 0.000 description 4
238000012937 correction Methods 0.000 description 4
238000004132 cross linking Methods 0.000 description 4
239000000155 melt Substances 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 3
238000001746 injection moulding Methods 0.000 description 3
239000004014 plasticizer Substances 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
JKYOLVWIBWJSTQ-UHFFFAOYSA-N 2,3-bis(hydroxymethyl)-4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C(CO)=C1CO JKYOLVWIBWJSTQ-UHFFFAOYSA-N 0.000 description 2
LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 2
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
238000013329 compounding Methods 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
238000001879 gelation Methods 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
239000000178 monomer Substances 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
238000010298 pulverizing process Methods 0.000 description 2
239000002195 soluble material Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
229920002397 thermoplastic olefin Polymers 0.000 description 2
229920005992 thermoplastic resin Polymers 0.000 description 2
239000010409 thin film Substances 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
HOEFIGOFJSMARD-FUOWLQLWSA-N (1z,5z)-1-methylcycloocta-1,5-diene Chemical compound C\C1=C\CC\C=C/CC1 HOEFIGOFJSMARD-FUOWLQLWSA-N 0.000 description 1
TVEFFNLPYIEDLS-VQHVLOKHSA-N (4e)-deca-1,4,9-triene Chemical compound C=CCCC\C=C\CC=C TVEFFNLPYIEDLS-VQHVLOKHSA-N 0.000 description 1
UJNVTDGCOKFBKM-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)hexane Chemical compound CCCCCC(OOC(C)(C)C)OOC(C)(C)C UJNVTDGCOKFBKM-UHFFFAOYSA-N 0.000 description 1
KTRQRAQRHBLCSQ-UHFFFAOYSA-N 1,2,4-tris(ethenyl)cyclohexane Chemical compound C=CC1CCC(C=C)C(C=C)C1 KTRQRAQRHBLCSQ-UHFFFAOYSA-N 0.000 description 1
UHHCYAAVGADGGP-UHFFFAOYSA-N 1,2-bis(ethenyl)cyclobutane Chemical compound C=CC1CCC1C=C UHHCYAAVGADGGP-UHFFFAOYSA-N 0.000 description 1
RCJMVGJKROQDCB-UHFFFAOYSA-N 1,3-dimethyl-1,3-butadiene Natural products CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 1
HQGYGGZHZWXFSI-UHFFFAOYSA-N 1,4-cycloheptadiene Chemical compound C1CC=CCC=C1 HQGYGGZHZWXFSI-UHFFFAOYSA-N 0.000 description 1
VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
239000004912 1,5-cyclooctadiene Substances 0.000 description 1
FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical compound CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
UHBUPDFDZHLGCC-UHFFFAOYSA-N 2-[7-(2-hydroxyphenyl)heptyl]propane-1,3-diol Chemical compound OCC(CO)CCCCCCCC1=CC=CC=C1O UHBUPDFDZHLGCC-UHFFFAOYSA-N 0.000 description 1
DRWYRROCDFQZQF-UHFFFAOYSA-N 2-methylpenta-1,4-diene Chemical compound CC(=C)CC=C DRWYRROCDFQZQF-UHFFFAOYSA-N 0.000 description 1
PKXHXOTZMFCXSH-UHFFFAOYSA-N 3,3-dimethylbut-1-ene Chemical compound CC(C)(C)C=C PKXHXOTZMFCXSH-UHFFFAOYSA-N 0.000 description 1
OGJJVYFQXFXJKU-UHFFFAOYSA-N 3-methylbicyclo[2.2.1]hepta-2,5-diene Chemical compound C1C2C(C)=CC1C=C2 OGJJVYFQXFXJKU-UHFFFAOYSA-N 0.000 description 1
RITONZMLZWYPHW-UHFFFAOYSA-N 3-methylhex-1-ene Chemical compound CCCC(C)C=C RITONZMLZWYPHW-UHFFFAOYSA-N 0.000 description 1
BYBCLLCZZCTRLI-UHFFFAOYSA-N 3a,4-dimethyl-1,4,7,7a-tetrahydroindene Chemical compound CC1C=CCC2CC=CC12C BYBCLLCZZCTRLI-UHFFFAOYSA-N 0.000 description 1
BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
OPMUAJRVOWSBTP-UHFFFAOYSA-N 4-ethyl-1-hexene Chemical compound CCC(CC)CC=C OPMUAJRVOWSBTP-UHFFFAOYSA-N 0.000 description 1
YVLGRGCYQOZGCO-UHFFFAOYSA-N 4-methyl-3a,4,7,7a-tetrahydro-1h-indene Chemical compound CC1C=CCC2CC=CC12 YVLGRGCYQOZGCO-UHFFFAOYSA-N 0.000 description 1
OJOWICOBYCXEKR-UHFFFAOYSA-N 5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CC)CC1C=C2 OJOWICOBYCXEKR-UHFFFAOYSA-N 0.000 description 1
JIUFYGIESXPUPL-UHFFFAOYSA-N 5-methylhex-1-ene Chemical compound CC(C)CCC=C JIUFYGIESXPUPL-UHFFFAOYSA-N 0.000 description 1
WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
229920003043 Cellulose fiber Polymers 0.000 description 1
239000004709 Chlorinated polyethylene Substances 0.000 description 1
HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
229940123457 Free radical scavenger Drugs 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 1
125000002619 bicyclic group Chemical group 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
230000008859 change Effects 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000000779 depleting effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000010408 film Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
238000005184 irreversible process Methods 0.000 description 1
238000009940 knitting Methods 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
235000012245 magnesium oxide Nutrition 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
OFHMODDLBXETIK-UHFFFAOYSA-N methyl 2,3-dichloropropanoate Chemical compound COC(=O)C(Cl)CCl OFHMODDLBXETIK-UHFFFAOYSA-N 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
150000004291 polyenes Chemical class 0.000 description 1
239000002952 polymeric resin Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000010791 quenching Methods 0.000 description 1
239000002516 radical scavenger Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000012265 solid product Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000003856 thermoforming Methods 0.000 description 1
229920002725 thermoplastic elastomer Polymers 0.000 description 1
AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
238000004073 vulcanization Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1
239000002023 wood Substances 0.000 description 1
DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/04—Crosslinking with phenolic resin
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA314,541A 1977-11-09 1978-10-27 Melanges elastoplastiques de caoutchouc d'olefine vulcanise et de resine de polyolefines Expired CA1124917A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US84977377A	1977-11-09	1977-11-09
US849,773		1977-11-09

Publications (1)

Publication Number	Publication Date
CA1124917A true CA1124917A (fr)	1982-06-01

Family

ID=25306493

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA314,541A Expired CA1124917A (fr)	1977-11-09	1978-10-27	Melanges elastoplastiques de caoutchouc d'olefine vulcanise et de resine de polyolefines

Country Status (18)

Country	Link
JP (1)	JPS5846138B2 (fr)
AR (1)	AR219136A1 (fr)
AU (1)	AU523072B2 (fr)
BG (1)	BG36637A3 (fr)
BR (1)	BR7807351A (fr)
CA (1)	CA1124917A (fr)
DE (1)	DE2848448C2 (fr)
ES (1)	ES474870A1 (fr)
FR (1)	FR2408632B1 (fr)
GB (1)	GB2007683B (fr)
IL (1)	IL55902A (fr)
IN (1)	IN150497B (fr)
IT (1)	IT1100929B (fr)
MX (2)	MX4142E (fr)
NL (1)	NL186641C (fr)
PL (1)	PL126439B1 (fr)
SU (2)	SU1531860A3 (fr)
ZA (1)	ZA786298B (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1193549B (it) *	1980-08-19	1988-07-08	Montedison Spa	Procedimento per la preparazione di composizioni plasto-elastomeriche poliolefiniche,mediante vulcanizzazione dinamica
US4594390A (en) *	1982-08-23	1986-06-10	Monsanto Company	Process for the preparation of thermoplastic elastomers
EP0215959B1 (fr)	1985-04-16	1993-01-13	Mitsui Petrochemical Industries, Ltd.	Copolymere amorphe reticule, particulaire, son procede de production et son utilisation
IT1207498B (it) *	1985-05-31	1989-05-25	Himont Inc	Procedimento per la preparazione di composizioni plasto-elastomeriche poliolefiniche, mediante vulcanizzazione dinamica.
US5073597A (en) *	1989-05-26	1991-12-17	Advanced Elastomer Systems, L. P.	Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix
DE4113063A1 (de)	1991-04-22	1992-10-29	Continental Ag	Thermoplastische elastomere und verfahren zu deren herstellung
MY117913A (en) *	1996-07-12	2004-08-30	Dow Global Technologies Inc	Elastomers, processes for their manufacture, and articles made from these elastomers
ZA976110B (en)	1996-07-12	1999-01-11	Dow Chemical Co	Elastomers processes for their manufacture and articles made from these elastomers
ATE214409T1 (de)	1996-11-14	2002-03-15	Phoenix Ag	Verfahren zur herstellung einer thermoplastischen elastomermasse
JP3704948B2 (ja)	1997-09-30	2005-10-12	三井化学株式会社	熱可塑性エラストマーおよび製造方法
ATE444333T1 (de)	1999-02-15	2009-10-15	Polyone Corp	Verfahren zur herstellung eines thermoplastischen vulkanisats
US6872784B2 (en) *	2000-12-29	2005-03-29	Kimberly-Clark Worldwide, Inc.	Modified rubber-based adhesives
JP4231357B2 (ja) *	2003-07-17	2009-02-25	リケンテクノス株式会社	熱可塑性エラストマー組成物
JP4949019B2 (ja)	2004-04-19	2012-06-06	三井化学株式会社	α−オレフィン系重合体組成物、該組成物からなる成形体、新規重合体
JP5104059B2 (ja) *	2006-07-04	2012-12-19	住友化学株式会社	熱可塑性エラストマー組成物の製造方法および熱可塑性エラストマー組成物
JP2008031445A (ja) *	2006-07-04	2008-02-14	Sumitomo Chemical Co Ltd	熱可塑性エラストマー組成物とその製造方法
JP2009013428A (ja) *	2008-10-22	2009-01-22	Riken Technos Corp	熱可塑性エラストマー組成物
RU2012132909A (ru) *	2010-02-01	2014-03-10	Джонсонайт Инк.	Плинтус и состав для его изготовления
US8557906B2 (en) *	2010-09-03	2013-10-15	Exxonmobil Chemical Patents Inc.	Flame resistant polyolefin compositions and methods for making the same
WO2018181062A1 (fr)	2017-03-29	2018-10-04	株式会社イノアックコーポレーション	Procédé de fabrication d'une composition de résine thermoplastique et composition de résine thermoplastique
JP7007881B2 (ja)	2017-03-29	2022-01-25	株式会社イノアックコーポレーション	熱可塑性樹脂組成物の製造方法
KR102574542B1 (ko)	2019-02-22	2023-09-04	미쓰이 가가쿠 가부시키가이샤	올레핀계 중합체 조성물 및 그의 성형체
BE1027627B1 (fr) *	2020-04-14	2021-04-30	Soc Ind Liegeoise Des Oxydes	Composition activatrice de vulcanisation
JP7100933B1 (ja) *	2022-03-03	2022-07-14	株式会社Tbm	積層シート及び食品包装容器

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3037954A (en) *	1958-12-15	1962-06-05	Exxon Research Engineering Co	Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber
NL134120C (fr) *	1961-11-24	1900-01-01
NL300146A (fr) *	1962-11-08	1900-01-01
DE1271980B (de) *	1963-07-11	1968-07-04	Huels Chemische Werke Ag	Teilvulkanisierte Formmassen auf Basis von Polypropylen
NL6402820A (fr) *	1963-07-11	1965-01-12
NL6708183A (fr) *	1966-06-14	1967-12-15
US3534119A (en) *	1967-04-11	1970-10-13	Uniroyal Inc	Crosslinking epdm rubber with dimethylol phenol
US3909463A (en) *	1968-11-29	1975-09-30	Allied Chem	Grafted block copolymers of synthetic rubbers and polyolefins
US3741924A (en) *	1969-03-08	1973-06-26	Taoka Dyestuffs Mfg Co Ltd	Rubber composition
US3709848A (en) *	1971-01-29	1973-01-09	Exxon Research Engineering Co	High temperature cure systems for ethylene propylene diene monomers
US3806558A (en) *	1971-08-12	1974-04-23	Uniroyal Inc	Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic
US3957919A (en) *	1974-09-24	1976-05-18	Copolymer Rubber & Chemical Corporation	Thermoplastic elastomer composition and method for preparation
US4130535A (en) *	1975-07-21	1978-12-19	Monsanto Company	Thermoplastic vulcanizates of olefin rubber and polyolefin resin
NL160591B (nl) *	1975-07-21	1979-06-15	Monsanto Co	Werkwijze voor de bereiding van elastomere preparaten.
US4311628A (en) *	1977-11-09	1982-01-19	Monsanto Company	Thermoplastic elastomeric blends of olefin rubber and polyolefin resin

1978
- 1978-10-27 CA CA314,541A patent/CA1124917A/fr not_active Expired
- 1978-11-04 SU SU782684153A patent/SU1531860A3/ru active
- 1978-11-07 ES ES474870A patent/ES474870A1/es not_active Expired
- 1978-11-07 NL NLAANVRAGE7811054,A patent/NL186641C/xx not_active IP Right Cessation
- 1978-11-08 BR BR7807351A patent/BR7807351A/pt unknown
- 1978-11-08 ZA ZA00786298A patent/ZA786298B/xx unknown
- 1978-11-08 IN IN1210/CAL/78A patent/IN150497B/en unknown
- 1978-11-08 AU AU41425/78A patent/AU523072B2/en not_active Expired
- 1978-11-08 FR FR7831626A patent/FR2408632B1/fr not_active Expired
- 1978-11-08 IT IT29593/78A patent/IT1100929B/it active
- 1978-11-08 PL PL1978210789A patent/PL126439B1/pl unknown
- 1978-11-08 BG BG7841321A patent/BG36637A3/xx unknown
- 1978-11-08 GB GB7843621A patent/GB2007683B/en not_active Expired
- 1978-11-08 JP JP53138391A patent/JPS5846138B2/ja not_active Expired
- 1978-11-08 DE DE2848448A patent/DE2848448C2/de not_active Expired - Lifetime
- 1978-11-08 AR AR274379A patent/AR219136A1/es active
- 1978-11-08 IL IL55902A patent/IL55902A/xx unknown
- 1978-11-09 MX MX787526U patent/MX4142E/es unknown
- 1978-11-09 MX MX175545A patent/MX149404A/es unknown
1979
- 1979-08-02 SU SU792790704A patent/SU1105119A3/ru active

Also Published As

Publication number	Publication date
JPS5846138B2 (ja)	1983-10-14
JPS5499156A (en)	1979-08-04
BR7807351A (pt)	1979-07-24
MX4142E (es)	1982-01-06
PL210789A1 (pl)	1979-08-13
AR219136A1 (es)	1980-07-31
ZA786298B (en)	1979-10-31
BG36637A3 (en)	1984-12-16
FR2408632B1 (fr)	1985-10-18
DE2848448C3 (de)	1994-07-14
DE2848448A1 (de)	1979-05-10
DE2848448C2 (de)	1994-07-14
IN150497B (fr)	1982-10-23
ES474870A1 (es)	1980-04-01
IT1100929B (it)	1985-09-28
NL186641B (nl)	1990-08-16
MX149404A (es)	1983-11-03
NL186641C (nl)	1993-08-16
PL126439B1 (en)	1983-08-31
AU4142578A (en)	1979-05-17
IT7829593A0 (it)	1978-11-08
GB2007683A (en)	1979-05-23
AU523072B2 (en)	1982-07-08
SU1105119A3 (ru)	1984-07-23
FR2408632A1 (fr)	1979-06-08
NL7811054A (nl)	1979-05-11
GB2007683B (en)	1982-05-12
IL55902A0 (en)	1979-01-31
SU1531860A3 (ru)	1989-12-23
IL55902A (en)	1982-04-30

Legal Events

Date	Code	Title	Description
1999-06-01	MKEX	Expiry
2023-05-26	MKEX	Expiry	Effective date: 19990601

Publication	Publication Date	Title
CA1124917A (fr)	1982-06-01	Melanges elastoplastiques de caoutchouc d'olefine vulcanise et de resine de polyolefines
US4311628A (en)	1982-01-19	Thermoplastic elastomeric blends of olefin rubber and polyolefin resin
CA1248262A (fr)	1989-01-03	Polymere d'olefine thermoplastique durci par voie dynamique
US4130535A (en)	1978-12-19	Thermoplastic vulcanizates of olefin rubber and polyolefin resin
CA1258934A (fr)	1989-08-29	Polymeres thermoplastiques d'olefine vulcanises par voie dynamique
EP0468947B1 (fr)	1996-03-06	Mélanges dynamiquement vulcanisés à base d'un copolymère d'éthylène modifié
CA1096986A (fr)	1981-03-03	Substances elastoplastiques a base de caoutchouc butylique et de resines de polyolefines
EP0428153B1 (fr)	1995-03-22	Elastomère thermoplastique à base de matériau de polymère de propylène et éthylène-propylène caoutchouc reticulé
EP0473703B1 (fr)	1997-11-12	Alliages dynamiquement vulcanises comportant deux copolymeres dans la phase reticulee ainsi qu'une matrice cristalline
US5266626A (en)	1993-11-30	Thermoplastic elastomer based on an ethylene/α-olefin copolymer and on polynorbornene
CA1285093C (fr)	1991-06-18	Composition d'olefine thermoplastique thermoretricissable
USRE35398E (en)	1996-12-10	Thermoplastic olefin compositions of EPDM rubber and ethylene copolymer resin
CA1265883A (fr)	1990-02-13	Composition thermoplastique elastomere
US5086121A (en)	1992-02-04	Dynamically cured thermoplastic olefin polymers
US5021500A (en)	1991-06-04	Dynamically vulcanized alloys of crystalline polyolefin resin and halobutyl rubber material
CA1129140A (fr)	1982-08-03	Substances thermoplastiques du type caoutchouc csm - resine de polyolefine
EP0404351A2 (fr)	1990-12-27	Mélanges vulcanisés dynamiquement présentant un équilibre entre rigidité et résistance au choc
CA1101578A (fr)	1981-05-19	Traduction non-disponible
EP0320001A2 (fr)	1989-06-14	Composition élastomères thermoplastiques et procédé pour leur préparation
EP0393993A2 (fr)	1990-10-24	Elastomère thermoplastique de copolymère d'éthylène-hexène ou d'éthylène-butène et de caoutchouc
CA2152106A1 (fr)	1995-12-21	Compositions a base de polyolefine, convenant a l'obtention de feuilles et de pellicules scellables par radio-frequence
NO158878B (no)	1988-08-01	Fremgangsmaate ved fremstilling av plastisk-elastomere materialer ved dynamisk vulkanisering av en blanding av et polyolefin og en elastomer terpolymer.
US4960830A (en)	1990-10-02	Dynamically cured thermoplastic olefin polymers
AU731226B2 (en)	2001-03-29	Thermoplastic elastomer vulcanizate
EP0379779B1 (fr)	1996-12-27	Mélanges de polyoléfine cristalline et caoutchouc halobutyl vulcanisées dynamiquement