BR112014031920A2 - copolímeros de etileno, película e processo de polimerização - Google Patents

copolímeros de etileno, película e processo de polimerização

Info

Publication number
BR112014031920A2
BR112014031920A2 BR112014031920A BR112014031920A BR112014031920A2 BR 112014031920 A2 BR112014031920 A2 BR 112014031920A2 BR 112014031920 A BR112014031920 A BR 112014031920A BR 112014031920 A BR112014031920 A BR 112014031920A BR 112014031920 A2 BR112014031920 A2 BR 112014031920A2
Authority
BR
Brazil
Prior art keywords
film
ethylene copolymers
polymerization process
copolymers
good
Prior art date
Application number
BR112014031920A
Other languages
English (en)
Other versions
BR112014031920B1 (pt
Inventor
Ashton Garret Carter Charles
J Morrison Darryl
Lam Patrick
Phung Minh Hoang Peter
Ker Victoria
Jiang Yan
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CA 2780508 external-priority patent/CA2780508A1/en
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of BR112014031920A2 publication Critical patent/BR112014031920A2/pt
Publication of BR112014031920B1 publication Critical patent/BR112014031920B1/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02Anti-static agent incorporated into the catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/04Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

resumo “copolímeros de etileno, película e processo de polimerização” copolímeros de etileno tendo uma razão de fluxo de fusão relativamente alta e um perfil multimodal em um lote de fracionamento por eluição com aumento de temperatura (tref) são divulgados. os copolímeros podem ser feitos em película tendo bons valores de impacto por dardo e boas propriedades de rigidez sob pres-sões de extrusão diminuídas.
BR112014031920-0A 2012-06-21 2013-05-24 processo de polimerização de olefina para produzir um copolímero de etileno, copolímero de etileno e copolímero de etileno que não é uma blenda BR112014031920B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CA2780508 2012-06-21
CA 2780508 CA2780508A1 (en) 2012-06-21 2012-06-21 Polyethylene composition, film and polymerization process
CA2798855 2012-12-14
CA2798855A CA2798855C (en) 2012-06-21 2012-12-14 Ethylene copolymers having reverse comonomer incorporation
PCT/CA2013/000498 WO2013188950A1 (en) 2012-06-21 2013-05-24 Ethylene copolymers, film and polymerization process

Publications (2)

Publication Number Publication Date
BR112014031920A2 true BR112014031920A2 (pt) 2017-06-27
BR112014031920B1 BR112014031920B1 (pt) 2021-04-20

Family

ID=49767962

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014031920-0A BR112014031920B1 (pt) 2012-06-21 2013-05-24 processo de polimerização de olefina para produzir um copolímero de etileno, copolímero de etileno e copolímero de etileno que não é uma blenda

Country Status (10)

Country Link
US (2) US9079991B2 (pt)
EP (1) EP2864369B1 (pt)
JP (1) JP6211073B2 (pt)
KR (1) KR102104302B1 (pt)
CN (1) CN104470955B (pt)
BR (1) BR112014031920B1 (pt)
CA (1) CA2798855C (pt)
ES (1) ES2712684T3 (pt)
MX (1) MX367637B (pt)
WO (1) WO2013188950A1 (pt)

Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
CA2797620C (en) * 2012-12-03 2019-08-27 Nova Chemicals Corporation Controlling resin properties in a gas phase polymerization process
KR102121298B1 (ko) * 2012-12-14 2020-06-11 노바 케미컬즈 (인터내셔널) 소시에테 아노님 에틸렌 공중합체 조성물, 필름 및 중합 방법
CN104822716B (zh) 2012-12-21 2017-11-14 埃克森美孚化学专利公司 具有改进的加工性的支化聚乙烯及由其制成的高抗撕裂性膜
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
EP2978783B1 (en) * 2013-03-28 2017-05-17 Dow Global Technologies LLC An ethylene/alpha-olefin interpolymer composition
CA2820501C (en) 2013-06-27 2021-01-26 Nova Chemicals Corporation Synthesis of phosphinimide coordination compounds
US9181370B2 (en) 2013-11-06 2015-11-10 Chevron Phillips Chemical Company Lp Low density polyolefin resins with low molecular weight and high molecular weight components, and films made therefrom
KR101549209B1 (ko) * 2013-11-18 2015-09-02 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
BR112016019327B1 (pt) * 2014-02-11 2021-09-21 Univation Technologies, Llc Método para polimerizar olefinas para produzir um polímero de poliolefina com uma distribuição de composição multimodal
TWI557140B (zh) * 2014-08-19 2016-11-11 努發化工(國際)公司 使用單活性中心催化劑產生之乙烯共聚物
KR101617870B1 (ko) 2014-09-05 2016-05-03 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
US9441063B2 (en) * 2014-10-09 2016-09-13 Chevron Phillips Chemical Company Lp Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports
CA2871463A1 (en) * 2014-11-19 2016-05-19 Nova Chemicals Corporation Passivated supports: catalyst, process and product
KR101747396B1 (ko) * 2014-12-15 2017-06-14 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
EP3286233B1 (en) 2015-04-23 2022-09-14 Univation Technologies, LLC Polyethylene copolymers having a particular comonomer distribution
CA2900772C (en) * 2015-08-20 2022-07-12 Nova Chemicals Corporation Method for altering melt flow ratio of ethylene polymers
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
EP3344665A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS FOR POLYOLEFINREACTIONS
EP3344385A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS ON SOUND
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9975973B2 (en) 2015-10-02 2018-05-22 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
US9994657B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9982076B2 (en) 2015-10-02 2018-05-29 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metals complexes, production and use thereof
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US10414887B2 (en) 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
CA2914166C (en) * 2015-12-08 2022-07-26 Nova Chemicals Corporation High density rotomolding resin
KR101889598B1 (ko) 2015-12-08 2018-08-17 주식회사 엘지화학 올레핀계 중합체
KR101924198B1 (ko) * 2015-12-23 2018-11-30 주식회사 엘지화학 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
EP3214116B1 (en) * 2016-03-03 2021-06-23 Dow Global Technologies LLC Breathable films and method of making the same
CN107554292B (zh) * 2016-06-30 2020-11-27 宁波高发汽车控制***股份有限公司 电子油门踏板总成
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
KR102086055B1 (ko) 2016-09-23 2020-03-06 주식회사 엘지화학 폴리프로필렌계 수지 조성물
KR102083001B1 (ko) 2016-09-23 2020-02-28 주식회사 엘지화학 올레핀계 공중합체 및 이의 제조 방법
KR102086056B1 (ko) 2016-09-23 2020-03-06 주식회사 엘지화학 폴리프로필렌계 수지 조성물
JP7475139B2 (ja) * 2016-09-28 2024-04-26 ダウ グローバル テクノロジーズ エルエルシー 特性が改善されたインフレーションフィルム
WO2018105852A1 (ko) * 2016-12-05 2018-06-14 주식회사 엘지화학 혼성 담지 촉매
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
US9963529B1 (en) * 2017-04-19 2018-05-08 Nova Chemicals (International) S.A. Multi reactor solution polymerization
AR112359A1 (es) * 2017-06-30 2019-10-23 Dow Global Technologies Llc Laminados de polietileno para usar en materiales de embalaje flexibles
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
US10435527B2 (en) * 2017-09-26 2019-10-08 Chevron Phillips Chemical Company Lp Dual component LLDPE copolymers with improved impact and tear resistance
WO2019099577A1 (en) 2017-11-15 2019-05-23 Exxonmobil Chemical Patents Inc. Polymerization processes
EP3710501A2 (en) 2017-11-15 2020-09-23 ExxonMobil Chemical Patents Inc. Polymerization processes
CN111356706B (zh) 2017-11-15 2022-04-15 埃克森美孚化学专利公司 聚合方法
KR102013170B1 (ko) * 2018-04-05 2019-08-22 대림산업 주식회사 폴리올레핀 수지 조성물 및 이의 제조방법
CA3011038A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having a good permeability, stiffness and sealability
CA3011041A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film
JP7254404B2 (ja) * 2018-12-21 2023-04-10 エルジー・ケム・リミテッド ポリオレフィン
US11427703B2 (en) 2019-03-25 2022-08-30 Chevran Phillips Chemical Company LP Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation
US11028258B2 (en) * 2019-08-19 2021-06-08 Chevron Phillips Chemical Company Lp Metallocene catalyst system for producing LLDPE copolymers with tear resistance and low haze
CN114364533A (zh) * 2019-09-03 2022-04-15 Sabic环球技术有限责任公司 包含双向取向聚乙烯膜的包装
KR102616697B1 (ko) * 2019-10-11 2023-12-21 주식회사 엘지화학 폴리에틸렌 및 이의 제조방법
KR20220056859A (ko) * 2019-11-23 2022-05-06 릴라이언스 인더스트리즈 리미티드 촉매 구성 및 촉매 제조 과정
KR102525719B1 (ko) 2019-11-28 2023-04-26 한화솔루션 주식회사 올레핀계 중합체 필름 및 그 제조방법
US11492429B2 (en) * 2020-06-05 2022-11-08 Formosa Plastics Corporation, U.S.A. Long-chain branched ethylene copolymer with novel composition distribution and films formed from the same
WO2022114710A1 (ko) * 2020-11-24 2022-06-02 주식회사 엘지화학 유무기 하이브리드 폴리올레핀 복합체 및 그의 제조 방법
JP7329720B1 (ja) * 2021-12-23 2023-08-18 ポリプラスチックス株式会社 環状オレフィン共重合体の製造方法及び触媒組成物
WO2024030619A1 (en) * 2022-08-05 2024-02-08 Dow Global Technologies Llc Symmetrical hafnium metallocene for making polymers with broad-orthogonal composition distributions

Family Cites Families (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US4242241A (en) 1977-10-31 1980-12-30 The Celotex Corporation Method for making a slurry containing particulate matter and fibers for a preformed insulation product
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
JPS5964604A (ja) 1982-10-06 1984-04-12 Sumitomo Chem Co Ltd ポリオレフインの製造方法
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4613484A (en) 1984-11-30 1986-09-23 Phillips Petroleum Company Loop reactor settling leg system for separation of solid polymers and liquid diluent
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5026795A (en) 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
US4937301A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US4935397A (en) 1988-09-28 1990-06-19 Exxon Chemical Patents Inc. Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
US5382631A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
US5382630A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution
EP0955322A3 (en) 1988-12-26 1999-12-08 Mitsui Chemicals, Inc. Olefin copolymers and processes for preparing same
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2660926B1 (fr) 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
PL166690B1 (pl) 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
US5231151A (en) 1991-01-18 1993-07-27 The Dow Chemical Company Silica supported transition metal catalyst
CA2113627A1 (en) 1991-07-18 1993-02-18 Prasadarao Meka Heat sealed article
US5281679A (en) 1991-11-07 1994-01-25 Exxon Chemical Patents Inc. Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof
US5206075A (en) 1991-12-19 1993-04-27 Exxon Chemical Patents Inc. Sealable polyolefin films containing very low density ethylene copolymers
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US6143854A (en) 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5420220A (en) 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
AU682821B2 (en) 1993-04-26 1997-10-23 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
FI96216C (fi) 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
NO315857B1 (no) 1995-03-28 2003-11-03 Japan Polyolefines Co Ltd Etylen-<alfa>-olefin-kopolymer, blanding, film, laminert material, elektrisk isolerende material og strömkabel inneholdende denne
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US6066588A (en) 1995-11-22 2000-05-23 Fina Research, S.A. Bridged metallocenes catalyst for polymerization of olefins
JPH09183816A (ja) 1995-12-28 1997-07-15 Mitsui Petrochem Ind Ltd エチレン・α−オレフィン共重合体およびこの共重合体から得られるフィルム
DE19615953A1 (de) 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
CO4990981A1 (es) 1996-05-17 2000-12-26 Dow Chemical Co Composicion de poliolefina en donde se presenta el maximo peso molecular en la parte de la composicion que tiene el contenido de comonomero mas alto
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
KR20000067941A (ko) 1996-07-22 2000-11-25 그래햄 이. 테일러 가교결합된 비방향족 음이온 디에닐기를 함유하는 금속 착화합물
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
US6420507B1 (en) 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
CA2210131C (en) 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
US6319989B1 (en) 1997-07-21 2001-11-20 The Dow Chemical Company Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
US6441116B1 (en) 1997-09-03 2002-08-27 Idemitsu Kosan Co., Ltd. Ethylenic copolymer, composition containing said copolymer, and ethylenic copolymer film
TR200000691T2 (tr) 1997-09-19 2002-04-22 The Dow Chemical Company Dar MWD,bileşim olarak optimize edilmiş etilen interpolimer bileşimi, bunun elde edilmesi için işlem ve bundan imal edilen ürün.
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US7354880B2 (en) 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
CA2245375C (en) * 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
ATE276279T1 (de) 1999-05-07 2004-10-15 Bp Chem Int Ltd Verfahren zur gasphasen (co-)polymerisation von olefinen in einem fliessbettreaktor
CA2277259C (en) * 1999-07-09 2009-09-15 Nova Chemicals Corporation Heavy duty packaging film
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6932592B2 (en) 2000-06-22 2005-08-23 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes
GB0016153D0 (en) 2000-06-30 2000-08-23 Borealis Tech Oy Process
WO2002088196A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
EP1399491B1 (en) 2001-04-30 2006-08-23 W.R. Grace &amp; Co.-Conn. Supported dual transition metal catalyst systems
WO2002088199A1 (en) 2001-04-30 2002-11-07 W. R. Grace & Co.-Conn. Chromium support-agglomerate-transition metal polymerization catalysts and processes utilizing same
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
WO2004000919A1 (en) 2001-07-19 2003-12-31 Univation Technologies, Llc Polyethylene films with improved physical properties
US6828394B2 (en) * 2001-07-19 2004-12-07 Univation Technologies, Llc Mixed metallocene catalyst systems containing a poor comonomer incorporator and a good comonomer incorporator
ATE503776T1 (de) 2002-12-20 2011-04-15 Basell Polyolefine Gmbh Copolymere mit alpha-olefinen
US7064096B1 (en) * 2004-12-07 2006-06-20 Nova Chemicals (International) Sa Dual catalyst on a single support
US7531602B2 (en) * 2005-10-05 2009-05-12 Nova Chemicals (International) S.A. Polymer blends
GB0610667D0 (en) 2006-05-30 2006-07-05 Nova Chem Int Sa Supported polymerization catalysts
GB0610668D0 (en) 2006-05-30 2006-07-12 Nova Chem Int Sa Supported antistatic polymerization catalysts
AU2007265645B2 (en) 2006-06-27 2012-06-21 Univation Technologies, Llc Improved polymerization processes using metallocene catalysts, their polymer products and end uses
KR101299375B1 (ko) 2006-06-27 2013-08-22 유니베이션 테크놀로지즈, 엘엘씨 에틸렌-알파 올레핀 공중합체 및 이의 중합 제조 방법
EP1935909A1 (en) * 2006-12-21 2008-06-25 Ineos Europe Limited Copolymers and films thereof
WO2009023111A1 (en) 2007-08-16 2009-02-19 Univation Technologies, Llc Continuity additives and their use in polymerization processes
GB2458160A (en) 2008-03-07 2009-09-09 Exxonmobil Chem Patents Inc High MIR linear polyethylene, in co-extruded films
US20110212315A1 (en) 2008-09-25 2011-09-01 Basell Polyolefine Gmbh Impact Resistant LLDPE Composition and Films Made Thereof
US8114946B2 (en) * 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
CA2716772C (en) 2009-10-20 2017-09-05 Nova Chemicals Corporation Improved reactor continuity
US8383754B2 (en) * 2010-04-19 2013-02-26 Chevron Phillips Chemical Company Lp Catalyst compositions for producing high Mz/Mw polyolefins
CA2734167C (en) * 2011-03-15 2018-03-27 Nova Chemicals Corporation Polyethylene film
CA2742454C (en) * 2011-06-09 2018-06-12 Nova Chemicals Corporation Methods for controlling ethylene copolymer properties
CA2742461C (en) * 2011-06-09 2018-06-12 Nova Chemicals Corporation Modified phosphinimine catalysts for olefin polymerization
KR102121298B1 (ko) * 2012-12-14 2020-06-11 노바 케미컬즈 (인터내셔널) 소시에테 아노님 에틸렌 공중합체 조성물, 필름 및 중합 방법

Also Published As

Publication number Publication date
EP2864369A4 (en) 2016-03-30
WO2013188950A1 (en) 2013-12-27
EP2864369B1 (en) 2018-12-05
EP2864369A1 (en) 2015-04-29
US20150252159A1 (en) 2015-09-10
US20130345377A1 (en) 2013-12-26
CA2798855A1 (en) 2013-12-21
MX367637B (es) 2019-08-29
CN104470955B (zh) 2016-08-24
US9079991B2 (en) 2015-07-14
JP2015520276A (ja) 2015-07-16
BR112014031920B1 (pt) 2021-04-20
CN104470955A (zh) 2015-03-25
CA2798855C (en) 2021-01-26
KR20150027235A (ko) 2015-03-11
KR102104302B1 (ko) 2020-04-27
ES2712684T3 (es) 2019-05-14
US9382394B2 (en) 2016-07-05
MX2014014715A (es) 2015-03-04
JP6211073B2 (ja) 2017-10-11

Similar Documents

Publication Publication Date Title
BR112014031920A2 (pt) copolímeros de etileno, película e processo de polimerização
BR112015014121A2 (pt) composições de copolímero de etileno, película e processos de polimerização
BR112016029163B8 (pt) Película soprada, artigo e película espumada
BR112016029269A2 (pt) filamento de grama artificial, grama artificial e preparação dos mesmos
RU2017133753A (ru) Промежуточная пленка для ламинированного стекла и ламинированное стекло
BR112015015290A2 (pt) composições de misturas de polietileno e filme
BR112016029258A2 (pt) filmes fundidos com tenacidade melhorada
CL2018001049A1 (es) Polímeros termoplásticos y composiciones para la fabricación aditiva
BR112018002933A2 (pt) composição de poliolefina compreendendo microesferas vítreas ocas
BR112014009065A2 (pt) polímeros de arquitetura controlada
MX2015002703A (es) Polimeros a base de etileno y articulos elaborados a partir de los mismos.
ATE543871T1 (de) Zusammensetzung mit einem halogenierten vinylpolymer und einem copolymer mit assoziativen gruppen
WO2012061211A3 (en) Reflective articles and methods of making the same
BR112017010898A2 (pt) laminado elástico, artigo contendo o mesmo, artigo laminado elástico alongado e artigo contendo o laminado
MX2012014835A (es) Composiciones de polimero a base de etileno para utilizarse como un componente de combinacion en aplicaciones de pelicula de contraccion.
BR112017019006A2 (pt) composição reticulável por radiação ultravioleta que compreende um polímero acrílico tendo um sítio reticulável por radiação ultravioleta
SG11201809285YA (en) Polymer, composition, molded article, cured product, and laminate
BR112015019865A2 (pt) composições de copolímero de alfa-olefina de alta viscosidade e métodos de preparação e uso das mesmas
TW201712056A (en) Crosslinked coating film having scratch resistance and flexibility, and resin composition
BR112016028635A2 (pt) artigo absorvente com adesivo isento de agente de pegajosidade
WO2014130275A3 (en) High performance polymer composition with improved flow properties
ATE388175T1 (de) Polyethylenfilm mit verbesserter verarbeitbarkeit und verbesserten mechanischen eigenschaften
BR112014014572A2 (pt) composição bioativa
WO2015069384A3 (en) High refractive index silicone nanocomposites
ES2524909T3 (es) Una composición termoplástica, un método para producir la misma y artículos preparados a partir de ella

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06I Publication of requirement cancelled [chapter 6.9 patent gazette]

Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA.

B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/05/2013, OBSERVADAS AS CONDICOES LEGAIS.