WO2016147998A1 - 抗菌用繊維 - Google Patents
抗菌用繊維 Download PDFInfo
- Publication number
- WO2016147998A1 WO2016147998A1 PCT/JP2016/057513 JP2016057513W WO2016147998A1 WO 2016147998 A1 WO2016147998 A1 WO 2016147998A1 JP 2016057513 W JP2016057513 W JP 2016057513W WO 2016147998 A1 WO2016147998 A1 WO 2016147998A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fiber
- group
- polyacetal copolymer
- antibacterial
- polyacetal
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/08—Filter cloth, i.e. woven, knitted or interlaced material
- B01D39/083—Filter cloth, i.e. woven, knitted or interlaced material of organic material
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1615—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of natural origin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
- B01D39/163—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin sintered or bonded
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2003—Glass or glassy material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2003—Glass or glassy material
- B01D39/2017—Glass or glassy material the material being filamentary or fibrous
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D39/2055—Carbonaceous material
- B01D39/2065—Carbonaceous material the material being fibrous
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/18—Copolymerisation of aldehydes or ketones
- C08G2/22—Copolymerisation of aldehydes or ketones with epoxy compounds
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- C—CHEMISTRY; METALLURGY
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- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
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- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
- D10B2503/06—Bed linen
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/04—Filters
Definitions
- the present invention relates to an antibacterial fiber having a polyacetal copolymer on its surface.
- the present invention also relates to a nonwoven fabric, knitted fabric, woven fabric, felt, and web using the antibacterial fiber.
- the present invention relates to a garment, bedding, or interior equipment using any one or more selected from the group consisting of a filter using the nonwoven fabric, the knitted fabric, the woven fabric, the felt, and the web.
- Polyacetal is an engineering plastic with excellent mechanical properties, heat resistance, chemical resistance, and electrical characteristics, and is widely used in fields such as electrical machinery, automobiles, machinery, and building materials. In addition, since it is easy to mold, it is also used as a fiber, non-woven fabric, or filter (see, for example, Patent Documents 1 to 3).
- plastics are required to have resistance to bacteria (antibacterial properties) in addition to the above physical properties.
- plastic has the property of being a dielectric material or electrical insulating material, so it easily adsorbs dust and bacteria in the air, and when the conditions of temperature and humidity are met, bacteria tend to grow on the surface. is there. Bacterial growth causes deterioration of the appearance and generation of malodor, and also causes contamination of the contact.
- Moraxella is known as a cause of generation of 4-methyl-3-hexenoic acid having a rag-like odor generated in clothes after washing.
- Plastics include inorganic antibacterial agents such as 2- (4-thiazolyl) -benzimidazole (thiabendazole), or substances containing metal ions such as silver, copper, and zinc ions.
- inorganic antibacterial agents such as 2- (4-thiazolyl) -benzimidazole (thiabendazole)
- metal ions such as silver, copper, and zinc ions.
- Patent Document 4 discloses a resin composition obtained by melt-kneading a substance containing metal ions such as zinc benzoate, zinc sulfate, and zinc oxide in polyacetal.
- Patent Document 5 discloses a resin composition in which polyacetal is melt-kneaded with a poly- ⁇ -alanine polymer and an inorganic antibacterial agent zeolite.
- Patent Document 6 discloses melt kneading a specific hindered amine-based material such as dimethyl succinate / 1- (2-hydroxyethyl) -4-hydroxy-2,2,6,6-tetramethylpiperidine polycondensate into polyacetal.
- a resin composition is disclosed.
- organic antibacterial agents often have problems in terms of appearance, heat resistance, safety (for example, carcinogenicity and atopy), and resin affinity.
- the thiabendazole is very easy to bleed even when mixed with a plastic, and therefore a continuous antibacterial effect (antibacterial property) cannot be expected.
- the surface of the molded product is whitened by bleed and the surface of the molded product is sticky.
- organic antibacterial agents also have a problem that they are easily decomposed by heat when melt-kneaded with a plastic material (see, for example, Patent Document 4).
- an inorganic antibacterial agent when used, a large amount of addition to the plastic (for example, 1 to 2% by weight) is necessary to impart an antibacterial effect. Inferior to water, elution due to contact with water or solvent.
- a fiber having a polyacetal copolymer containing a specific amount of oxyalkylene groups on the surface has excellent antibacterial properties, and that the antibacterial properties continue even after repeated washing.
- the headline and the present invention were completed.
- R 0 and R 0 ′ may be the same or different, and each represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an organic group having an alkyl group having 1 to 8 carbon atoms, a phenyl group, and (It is selected from organic groups having a phenyl group, and m is an integer of 2 to 6.)
- the antibacterial fiber according to (1) or (2), wherein the fiber having the polyacetal copolymer (X) on the surface is a single-layer fiber of the polyacetal copolymer (X).
- the antibacterial fiber according to (1) or (2), wherein the fiber having the polyacetal copolymer (X) on the surface is a multilayer fiber obtained by coating a fiber made of a thermoplastic resin with the polyacetal copolymer (X).
- the antibacterial fiber according to (1) or (2), wherein the fiber having the polyacetal copolymer (X) on the surface is a composite fiber having the polyacetal copolymer (X) on the surface of a fiber made of a thermoplastic resin. .
- the thermoplastic resin is one kind selected from polyacetal homopolymer, polyacetal copolymer other than polyacetal copolymer (X), polyolefin resin, polylactic acid resin, nylon resin, polyester resin, polyvinyl resin, and elastomers thereof
- the antibacterial fiber according to (4) or (5) which is two or more types.
- (11) A felt using the antibacterial fiber according to any one of (1) to (6).
- a garment using at least one selected from the group consisting of the knitted fabric, woven fabric, felt, and web according to (9) to (12).
- a bedding using at least one selected from the group consisting of the knitted fabric, woven fabric, felt, and web according to (9) to (12).
- An interior tool using any one or more selected from the group consisting of the knitted fabric, woven fabric, felt, and web according to (9) to (12).
- the antibacterial fiber of the present invention can be processed into a nonwoven fabric, a knitted fabric, a woven fabric, a felt, and a web excellent in antibacterial properties, and can provide a filter, clothing, bedding, and interior tools excellent in antibacterial properties using these. .
- the present invention is a fiber having a polyacetal copolymer (X) having an oxymethylene group and an oxyalkylene group represented by the general formula (1) described later on the surface, the mole of the oxyalkylene group in the polyacetal copolymer (X).
- the antibacterial fiber has an amount of 0.2 to 5 mol% based on the total value of the molar amount of the oxymethylene group and the molar amount of the oxyalkylene group.
- the antibacterial fiber of the present invention has an oxyalkylene group represented by the general formula (1) described later in an amount of 0.2 to 5 mol relative to the total value of the molar amount of the oxymethylene group and the molar amount of the oxyalkylene group.
- the antibacterial fiber of the present invention is a fiber having the polyacetal copolymer (X) on the surface.
- the form of the fiber having the polyacetal copolymer (X) on the surface is not particularly limited.
- [A] the form of a single-layer fiber of the polyacetal copolymer (X), and [B] the fiber made of a thermoplastic resin is converted into the polyacetal copolymer (X ),
- the form of the single layer fiber of [A] polyacetal copolymer (X) described above is a fiber made of polyacetal copolymer (X).
- the single-layer fiber is obtained by melt spinning the polyacetal copolymer (X), and can be obtained by further stretching as necessary.
- thermoplastic resin As the core portion in the form of the multilayer fiber whose surface is coated with the polyacetal copolymer (X), fibers made of a thermoplastic resin can be used.
- the type of the thermoplastic resin is not particularly limited.
- the polyacetal copolymer other than the polyacetal homopolymer and the polyacetal copolymer (X) for example, the content of the oxyalkylene group represented by the general formula (1) is an oxymethylene group.
- polyacetal copolymer exceeding 5 mol% with respect to the total of the molar amount of oxyalkylene group and the total amount of oxyalkylene groups
- polyolefin resin polylactic acid resin, nylon resin, polyester resin, polyvinyl resin, and elastomers thereof.
- thermoplastic resins can be used singly or in a combination of two or more.
- the “coating” referred to in the present invention refers to a form in which all or part of the surface parallel to the fiber direction of the core fiber is covered.
- the ratio of the coating on the surface is not particularly limited, but a higher ratio is preferable because of superior antibacterial properties.
- Such a multilayer fiber can be obtained by melt spinning the polyacetal copolymer (X) and the above-described thermoplastic resin, and can be obtained by further stretching as necessary.
- the form of the obtained multilayer fiber has a core-sheath structure in which the whole or a part of the fiber made of the thermoplastic resin as the core fiber is covered with the polyacetal copolymer (X).
- thermoplastic resin in the form of the composite fiber having the polyacetal copolymer (X) on the surface of the fiber made of the thermoplastic resin is not particularly limited, and is the same as the thermoplastic resin in the form of the multilayer fiber described above. Can be used. These thermoplastic resins can be used singly or in a combination of two or more.
- the composite fiber having the polyacetal copolymer (X) on the surface of the fiber made of the thermoplastic resin is obtained by melt spinning the mixture of the polyacetal copolymer (X) and the above-mentioned thermoplastic resin, and further stretched as necessary. Obtainable.
- the form of the obtained composite fiber may be a state in which the polyacetal copolymer (X) is in a state compatible with the thermoplastic resin and is exposed on the fiber surface at the polymer molecule level, and is a sea-island structure or a dispersion derived therefrom.
- the exposure ratio of the polyacetal copolymer (X) on the surface of the composite fiber is not particularly limited, but a higher ratio is preferable because of superior antibacterial properties.
- the orientation degree of the polyacetal copolymer (X) in the antibacterial fiber of the present invention is not particularly limited, but is preferably 60% or more, more preferably 70% or more, and particularly preferably 80% or more. This is because the higher the degree of orientation of the polyacetal copolymer (X), the better the antibacterial properties. As will be described later, the antibacterial property of the polyacetal copolymer (X) has a correlation with the oxyalkylene group content of the copolymer, and the polyacetal copolymer (X) having a high oxyalkylene group content tends to have a low antibacterial property.
- the polyacetal copolymer (X) having a higher oxyalkylene group content has a feature that the influence of the orientation degree on the antibacterial property is larger. Therefore, the polyacetal copolymer (X) having a higher oxyalkylene group content has a higher orientation degree. Excellent antibacterial properties.
- the degree of orientation of the polyacetal copolymer (X) can be efficiently increased by drawing a melt-spun fiber.
- the degree of orientation of the antibacterial fiber can be determined using a wide-angle X-ray diffractometer as described in the examples of this specification.
- the fineness of the antibacterial fiber of the present invention is not particularly limited because the allowable value varies depending on the application, but when used as a filter, it is necessary to increase the filtration accuracy while reducing the pressure loss with respect to the fluid. : Decitex) or less.
- the antibacterial fiber of the present invention is a Staphylococcus aureus whose bacteriostatic activity value obtained by an antibacterial test compliant with JIS L 1902 (antibacterial test method and antibacterial effect of textile products) is known as a causative agent of food poisoning Usually, it is 2.2 or more, preferably 2.4 or more, particularly preferably 2.7 or more. This figure satisfies the certification of antibacterial and deodorant processing established by the Japan Textile Evaluation Technology Council.
- the antibacterial fiber of the present invention is characterized by an excellent bactericidal activity value for Staphylococcus aureus. Furthermore, compared with the antibacterial fiber obtained by kneading an antibacterial substance in polyacetal fiber, it has an excellent feature that the antibacterial property is maintained even after repeated washing.
- the antibacterial fiber of the present invention exhibits a high bacteriostatic activity value even in Moraxella that causes malodor.
- the bacteriostatic activity value in Moraxella is usually 1.8 or more, preferably 2.0 or more, and particularly preferably 2.2 or more.
- the antibacterial fiber of the present invention is characterized by an excellent bactericidal activity value against Moraxella bacteria. Furthermore, compared with the antibacterial fiber obtained by kneading an antibacterial substance into polyacetal fiber, it has an excellent feature that the antibacterial property is maintained even after repeated washing.
- the antibacterial fiber of the present invention can be produced according to a conventionally known fiber production method.
- it can be produced by, for example, melt spinning a pellet of polyacetal copolymer (X).
- X polyacetal copolymer
- the stretching process can also be performed by a conventionally known method and conditions.
- the draw ratio is preferably 3 times or more from the viewpoint of the degree of orientation.
- the upper limit of the draw ratio is not limited in terms of the degree of orientation, but is 15 times from the viewpoint of stability during production (prevention of yarn breakage) and prevention of excessive fibrillation.
- the melt spinning and stretching apparatus can be performed using a conventionally known apparatus.
- the polyacetal copolymer (X) present on the surface of the antibacterial fiber of the present invention has an oxyalkylene group having a structure represented by the following general formula (1) in addition to the oxymethylene group (—CH 2 —O—) in the molecule.
- R 0 and R 0 ′ may be the same or different and are each a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an organic group having an alkyl group having 1 to 8 carbon atoms, a phenyl group, and a phenyl group It is selected from organic groups having groups.
- M is an integer of 2 to 6.
- R 0 and R 0 ′ may be the same or different and are each selected from a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a phenyl group, and a benzyl group, m is an integer of 2 to 4. More preferably, R 0 and R 0 ′ are selected from a hydrogen atom and an alkyl group having 1 to 4 carbon atoms, and m is 2.
- Examples of the alkyl group having 1 to 8 carbon atoms include methyl group, ethyl group, propyl group, isopropyl group, butyl group, isobutyl group, pentyl group, hexyl group, and cyclohexyl group.
- Examples of the organic group having an alkyl group having 1 to 8 carbon atoms include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, and a butoxy group.
- Examples of the organic group having a phenyl group include a benzyl group and a phenethyl group.
- an oxyethylene group, an oxypropylene group, and an oxybutylene group are preferable, and an oxyethylene group is particularly preferable.
- the above-mentioned oxyalkylene group may be contained in the polyacetal copolymer (X) by one type or two or more types. That is, the polyacetal copolymer (X) of the present invention includes not only a binary copolymer but also a multi-component copolymer.
- the polyacetal copolymer (X) of the present invention may be a polyacetal copolymer further having a block structure other than oxymethylene groups and oxyalkylene groups, or may be a polyacetal copolymer further having a branched structure in the molecule.
- these polyacetal copolymers for example, the structure of the chain transfer agent at the terminal obtained by using a thermoplastic resin or oligomer having a functional group having an active hydrogen such as a hydroxyl group in the molecular terminal or in the molecule as the chain transfer agent.
- the polyacetal copolymer (X) of the present invention may be produced using an epoxy compound such as glycidyl ether or allyl ether as a termonomer, and has a structure derived from these compounds in the polyacetal copolymer. Some are included.
- the content of oxyalkylene groups in the polyacetal copolymer is in a wide range of 0.01 to 20 mol% with respect to the total of the molar amount of oxymethylene groups and the molar amount of oxyalkylene groups.
- the content of the oxyalkylene group (molar amount of the oxyalkylene group) in the polyacetal copolymer (X) of the present invention is usually 0 with respect to the total value of the molar amount of the oxymethylene group and the molar amount of the oxyalkylene group.
- the content of the oxyalkylene group is 0.2 mol% or more and 5 mol% or less, the antibacterial property is excellent, the bacteriostatic activity value indicating the antibacterial property is high, and the bacteriostatic activity value decreases even after repeated washing. Hateful.
- the content of the oxyalkylene group is 0.2 mol% or more and 3.0 mol% or less, the antibacterial property is more excellent and the bacteriostatic activity value indicating the antibacterial property is higher. Bacterial activity value is less likely to decrease.
- the polyacetal copolymer (X) of the present invention may be used alone or in combination of two or more polyacetal copolymers having different types of oxyalkylene groups, and the polyacetal copolymers having different oxyalkylene group contents. May be used in combination of two or more. When two or more types of polyacetal copolymers having different types of oxyalkylene groups or different oxyalkylene group contents are used in combination, these polyacetal copolymers may be in a compatible state, and the sea-island structure or a dispersed state derived therefrom It may be in a state of being side by side.
- Polyacetal copolymer of the present invention is preferably MVR in conformity with ISO1133 (Melt Volume Rate) is less than 100 cm 3/10 min. Although MVR value is suitable for obtaining thin fibers in higher melt spinning greater, equal to or less than 100 cm 3/10 min, fibers having excellent mechanical properties (especially toughness) is obtained.
- the production method of the polyacetal copolymer (X) of the present invention is arbitrary, and may be produced by any conventionally known method.
- an oxymethylene group such as formaldehyde trimer (trioxane) or tetramer (tetraoxane) is used.
- a cyclic acetal containing an oxyalkylene group having 2 to 4 carbon atoms such as ethylene oxide, 1,3-dioxolane, 1,3,6-trioxocane, 1,3-dioxepane, and the like.
- the polyacetal copolymer (X) of the present invention is preferably a copolymer of a cyclic acetal such as trioxane or tetraoxane and ethylene oxide or 1,3-dioxolane, and in particular, a copolymer of trioxane and 1,3-dioxolane.
- a polymer is particularly preferred.
- the polyacetal copolymer (X) of the present invention is a method in which a cyclic acetal of an oxymethylene group and a cyclic acetal containing an oxyalkylene group having 2 to 4 carbon atoms as a comonomer are subjected to bulk polymerization using a polymerization catalyst.
- a reaction terminator may be used as necessary for the deactivation treatment of the polymerization catalyst and the polymerization growth terminal.
- the type and amount of the polymerization catalyst, reaction terminator, and molecular weight regulator that can be used in the production of the polyacetal copolymer (X) of the present invention are not particularly limited as long as the effects of the present invention are not impaired. Any known polymerization catalyst, reaction terminator, and molecular weight regulator can be appropriately used.
- the polymerization catalyst is not particularly limited, and examples thereof include boron trifluoride, tin tetrachloride, titanium tetrachloride, phosphorus pentachloride, phosphorus pentafluoride, arsenic pentafluoride, and antimony pentafluoride.
- Examples thereof include Lewis acids, and complex compounds or salt compounds of these Lewis acids.
- Protonic acids such as trifluoromethanesulfonic acid and perchloric acid
- Protic acid esters such as perchloric acid and lower aliphatic alcohol ester
- Protic acid anhydrides such as mixed anhydride of perchloric acid and lower aliphatic carboxylic acid And so on.
- triethyloxonium hexafluorophosphate triphenylmethylhexafluoroarsenate, acetylhexafluoroborate, heteropolyacid or acid salt thereof, isopolyacid or acid salt thereof, perfluoroalkylsulfonic acid or acid salt thereof, etc.
- compounds containing boron trifluoride are preferable, and boron trifluoride diethyl etherate and boron trifluoride dibutyl etherate, which are coordination complexes with ethers, are particularly preferable.
- the amount of the polymerization catalyst used is not particularly limited, but is usually 1.0 ⁇ 10 ⁇ 8 to 2.0 ⁇ 10 ⁇ 3 mol with respect to 1 mol of the total monomer of trioxane and comonomer, preferably Is in the range of 5.0 ⁇ 10 ⁇ 8 to 8.0 ⁇ 10 ⁇ 4 mol, particularly preferably 5.0 ⁇ 10 ⁇ 8 to 1.0 ⁇ 10 ⁇ 4 mol.
- the reaction terminator is not particularly limited, and examples thereof include trivalent organic phosphorus compounds, amine compounds, alkali metal or alkaline earth metal hydroxides. These reaction terminators can be used individually by 1 type or in combination of 2 or more types. Of these, trivalent organic phosphorus compounds, tertiary amines, and hindered amines are preferable.
- the amount of the reaction terminator used is not particularly limited as long as it is sufficient to deactivate the polymerization catalyst.
- the molar ratio with respect to the polymerization catalyst is usually 1.0 ⁇ 10 ⁇ 1 to 1.0 ⁇ 10 10. 1 range.
- the molecular weight regulator is not particularly limited, and examples thereof include methylal, methoxymethylal, dimethoxymethylal, trimethoxymethylal, oxymethylene di-n-butyl ether and the like. Of these, methylal is preferable.
- the amount of these molecular weight regulators used is appropriately determined according to the target molecular weight. Usually, the addition amount is adjusted in the range of 0 to 0.1% by mass with respect to all monomers.
- the polyacetal copolymer (X) of the present invention includes hindered phenol compounds, hindered amine compounds, amino-substituted triazine compounds, phosphorus stabilizers, alkali metals within the range that does not impair the original purpose. And a metal-containing compound represented by the group consisting of an alkaline earth metal hydroxide, a fatty acid salt, an inorganic acid salt, or an alkoxide.
- hindered amine compound hindered amine compound, amino-substituted triazine compound, phosphorus stabilizer, alkali metal and alkaline earth metal hydroxide, fatty acid salt, inorganic acid salt, or alkoxide.
- metal-containing compound represented by the group may be referred to as “optional component”.
- a conventionally well-known thing can be used as these arbitrary components.
- the polyacetal copolymer (X) of the present invention includes a stabilizer, a nucleating agent, a release agent, if necessary, in addition to the optional components described above, within a range not impairing the original purpose.
- Various additives such as molds, fillers, pigments, dyes, lubricants, plasticizers, antistatic agents, oil agents, sizing agents, UV absorbers, flame retardants, flame retardant aids, antifungal agents, antiviral agents, etc. These resins, elastomers and the like may be added as appropriate.
- stabilizer nucleating agent, release agent, filler, pigment, dye, lubricant, plasticizer, antistatic agent, oil agent, sizing agent, ultraviolet absorber, flame retardant, difficulty
- additives such as fuel aids, antifungal agents, antiviral agents, other resins, elastomers, etc.” are sometimes referred to as “other components”.
- fillers minerals such as glass fiber, glass flakes, glass beads, wollastonite, mica, talc, boron nitride, calcium carbonate, kaolin, silicon dioxide, clay, asbestos, silica, diatomaceous earth, graphite, molybdenum disulfide
- examples include fillers and inorganic fibers such as glass fibers, middle fibers, potassium titanate fibers, and poron fibers, organic fibers such as carbon fibers and aramid fibers, potassium titanate whiskers, and carbon black and pigments. it can.
- the method for adding the above-mentioned optional components and other components to the polyacetal copolymer (X) is not particularly limited.
- the above-described polyacetal copolymer (X) and optional components added as necessary and / or Or it can manufacture by mixing and kneading
- the conditions such as mixing and kneading temperature and pressure may be appropriately selected according to a conventionally known method for producing a polyacetal copolymer.
- the kneading may be performed at a temperature equal to or higher than the melting temperature of the polyacetal copolymer, and is usually preferably performed at 180 ° C. or higher and 260 ° C. or lower.
- An apparatus for producing the polyacetal copolymer is not particularly limited, and a mixing and kneading apparatus conventionally used for producing this kind of polyacetal copolymer can be used.
- the antibacterial fiber of the present invention can be processed into a non-woven fabric, a woven fabric, a knitted fabric, a felt, a web, or the like depending on the application.
- a form suitable for taking advantage of antibacterial properties is a filter made of a nonwoven fabric.
- These nonwoven fabrics, woven fabrics, knitted fabrics, felts, and webs also have the same antibacterial properties as the antibacterial fibers of the present invention, and have the excellent feature that the antibacterial properties persist even after repeated washing.
- the nonwoven fabric of the present invention can be suitably used as a filter.
- This filter also has an antibacterial property equivalent to that of the antibacterial fiber of the present invention, and has an excellent feature that the antibacterial property continues even after repeated washing.
- the woven fabric, knitted fabric, felt and web of the present invention are underwear, shirt, sportswear, apron, socks, stockings, tights, pantyhose, tabi, Japanese clothing, tie, handkerchief, scarf, hat, gloves, mask, Clothes such as diapers, pillowcases, towels, sheets, bedding such as cotton in the futon, curtains, carpets, mats, rugs, wall hangings, wall coverings, tablecloths, moquettes, and other interior items, towels, towels, scourers, It can be suitably used for miscellaneous goods such as mops and stuffed toys.
- These clothing, bedding, interior goods, and sundries also have the same antibacterial properties as the antibacterial fibers of the present invention, and have excellent characteristics that the antibacterial properties persist even after repeated washing.
- the antibacterial fiber of the present invention when used to process into a non-woven fabric, woven fabric, knitted fabric, felt, web, or the like, it may be processed using only the antibacterial fiber of the present invention, but nylon, polyester, polyurethane Can be combined with synthetic fibers such as cotton, silk, and other natural fibers, carbon fibers, glass fibers, etc., and processed into forms such as non-woven fabrics, woven fabrics, knitted fabrics, felts, and webs as twisted yarns, covering yarns, braids Often blended with and blended with synthetic fibers such as nylon, polyester and polyurethane, natural fibers such as cotton and silk, carbon fibers and glass fibers, and processed into non-woven fabrics, woven fabrics, knitted fabrics, felts, webs, etc.
- synthetic fibers such as cotton, silk, and other natural fibers, carbon fibers, glass fibers, etc.
- the method for producing the nonwoven fabric having antibacterial properties of the present invention is not particularly limited, and conventionally known dry methods, wet methods, spunbond methods, melt blow methods, and the like can be used. At this time, it is preferable to suppress the dropping of the fibers by sufficiently bonding or entwining the fibers. Examples of such methods include the thermal bond method, chemical bond method, needle punch method, spunlace method (hydrodynamic entanglement method), stitch bond method, steam jet method, etc. Among them, the thermal bond method provides sufficient bonding. This is preferable because it can be achieved.
- the polyacetal copolymer (X) is used for the frame member that supports the above-described non-woven fabric filter, so that the product has excellent antibacterial and recyclability properties.
- polyacetal copolymer used in Examples and Comparative Examples is as follows.
- content (molar amount of oxyethylene group) of the oxyethylene group in polyacetal copolymer (X) is a value with respect to the total value of the molar amount of oxymethylene group and the molar amount of oxyethylene group.
- POM-1 A polyacetal copolymer having an oxyethylene group content of 0.4 mol% and an MVR of 8.
- POM-2 a polyacetal copolymer having an oxyethylene group content of 1.6 mol% and an MVR of 8.
- POM-3 a polyacetal copolymer having an oxyethylene group content of 3.0 mol% and an MVR of 8.
- POM-4 a polyacetal copolymer having an oxyethylene group content of 4.7 mol% and an MVR of 8.
- POM-5 a polyacetal copolymer having an oxyethylene group content of 5.7 mol% and an MVR of 8.
- PLA polylactic acid resin
- Terramac registered trademark
- PET polyethylene terephthalate resin
- a multifilament having a single fineness of 2 dtex was used as it was.
- the fineness [dtex (decitex)] of the fiber is obtained by measuring the fine diameter of a single fiber using an optical microscope, calculating the fineness with a density of 1.40 g / cm 3 , and calculating the average value of 50 fibers as the fineness of the fiber. did.
- ⁇ Creation of fiber sample> The temperature of the cylinder and the nozzle part was heated to 200 ° C., and the molten resin was discharged at a rate of 1.2 kg / h from a nozzle provided with 48 holes having a diameter of 0.6 mm.
- the discharge rate from the nozzle was 0.6 kg / h for both the core component resin and the sheath component resin.
- the undrawn fiber was continuously collected with the take-up speed fixed at 100 m / min, and the obtained undrawn fiber was continuously guided to the heating and drawing step, followed by drawing at a roll temperature of 120 to 140 ° C. Fiber samples were made.
- ⁇ Antimicrobial test (bacteriostatic activity value, bactericidal activity value, bacteriostatic activity retention after 10 washings, bactericidal activity retention after 10 washings)> Based on JIS L 1902 (antibacterial test method and antibacterial effect of textile products), it was evaluated by a quantitative test (bacterial solution absorption method).
- a fiber sample of a standard cotton fabric, 0.4 g of a fiber sample of an example or a comparative example (hereinafter referred to as a measurement sample) are placed in separate vials, inoculated with 0.2 ml of a test bacterial solution, and 18 ⁇ at 37 ⁇ 2 ° C.
- the bacteriostatic activity value was calculated according to the following formula (2). The greater the bacteriostatic activity value, the better the antibacterial properties. Moreover, if the bacteriostatic activity value with respect to Staphylococcus aureus is 2.2 or more, it corresponds to the SEK mark (blue: antibacterial deodorization processing) which the general corporate judicial person textile evaluation technology meeting certifies. Moreover, the bactericidal activity value was computed according to following formula (3).
- the bacteriostatic activity retention rate and the bactericidal activity retention rate after 10 washes were determined as follows. The washing method conformed to JIS L 0217 No. 103, and the detergent used was a JAFET standard combination detergent. After the washing treatment was repeated 10 times, the same antibacterial test was performed as described above, and the bacteriostatic activity retention rate [unit:%] after 10 washing was calculated according to the following formula (4). Moreover, according to the following formula (5), the bactericidal activity retention [unit:%] after 10 washings was calculated.
- Table 1 shows a single layer fiber of a polyacetal copolymer having an oxyethylene group content within a predetermined range, a multilayer fiber of a polyacetal copolymer having an oxyethylene group content within a predetermined range, and an oxyethylene group content within a predetermined range. Examples of multilayer fibers of polyacetal copolymer and PLA, and comparison examples of polyester fibers and polyacetal copolymer single layer fibers having an oxyethylene group content exceeding a predetermined range are shown.
- Examples 1 to 6 and Comparative Examples 1 and 2 when the amount of oxyethylene in the polyacetal copolymer is 0.2 to 5 mol%, the bacteriostatic activity value, the bactericidal activity value, and the bactericidal activity retention after washing are excellent. I understand that. Further, Examples 4 to 6 show that when the degree of orientation of the polyacetal copolymer in the fiber is high, the bacteriostatic activity value, the bactericidal activity value, and the bactericidal activity retention after washing are further improved.
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Abstract
Description
(1)オキシメチレン基と下記一般式(1)で表されるオキシアルキレン基を有するポリアセタールコポリマー(X)を表面に有する繊維であって、ポリアセタールコポリマー(X)中のオキシアルキレン基のモル量が、オキシメチレン基のモル量とオキシアルキレン基のモル量の合計値に対して0.2~5mol%である、抗菌用繊維。
(式中、R0及びR0’は、同一又は異なってもよく、それぞれ、水素原子、炭素数1~8のアルキル基、炭素数1~8のアルキル基を有する有機基、フェニル基、及びフェニル基を有する有機基から選択され、mは、2~6の整数である。)
(2)前記ポリアセタールコポリマー(X)の配向度が60%以上である、(1)に記載の抗菌用繊維。
(3)前記ポリアセタールコポリマー(X)を表面に有する繊維が、ポリアセタールコポリマー(X)の単層繊維である、(1)又は(2)に記載の抗菌用繊維。
(4)前記ポリアセタールコポリマー(X)を表面に有する繊維が、熱可塑性樹脂からなる繊維をポリアセタールコポリマー(X)で被覆した多層繊維である、(1)又は(2)に記載の抗菌用繊維。
(5)前記ポリアセタールコポリマー(X)を表面に有する繊維が、熱可塑性樹脂からなる繊維の表面にポリアセタールコポリマー(X)を有する複合繊維である、(1)又は(2)に記載の抗菌用繊維。
(6)前記熱可塑性樹脂が、ポリアセタールホモポリマー、ポリアセタールコポリマー(X)以外のポリアセタールコポリマー、ポリオレフィン樹脂、ポリ乳酸樹脂、ナイロン樹脂、ポリエステル樹脂、ポリビニル樹脂、及びこれらのエラストマーから選択される1種類又は2種類以上である、(4)又は(5)に記載の抗菌用繊維。
(7)(1)~(6)のいずれか一項に記載の抗菌用繊維を用いた不織布。
(8)(7)に記載の不織布を用いたフィルター。
(9)(1)~(6)のいずれか一項に記載の抗菌用繊維を用いた編物。
(10)(1)~(6)のいずれか一項に記載の抗菌用繊維を用いた織物。
(11)(1)~(6)のいずれか一項に記載の抗菌用繊維を用いたフェルト。
(12)(1)~(6)のいずれか一項に記載の抗菌用繊維を用いたウェブ。
(13)(9)~(12)に記載の編物、織物、フェルト、及びウェブからなる群より選択されるいずれか1種以上を用いた衣料。
(14)(9)~(12)に記載の編物、織物、フェルト、及びウェブからなる群より選択されるいずれか1種以上を用いた寝具。
(15)(9)~(12)に記載の編物、織物、フェルト、及びウェブからなる群より選択されるいずれか1種以上を用いたインテリア具。
以下、本発明について詳細に説明する。本発明は、オキシメチレン基と後述する一般式(1)で表されるオキシアルキレン基を有するポリアセタールコポリマー(X)を表面に有する繊維であって、ポリアセタールコポリマー(X)中のオキシアルキレン基のモル量が、オキシメチレン基のモル量とオキシアルキレン基のモル量の合計値に対して0.2~5mol%である、抗菌用繊維である。すなわち、本発明の抗菌用繊維は、後述する一般式(1)で表されるオキシアルキレン基を、オキシメチレン基のモル量とオキシアルキレン基のモル量の合計値に対して0.2~5mol%有するポリアセタールコポリマー(X)を、繊維の表面に有することを特徴とする。
本発明の抗菌用繊維は、従来公知の繊維の製造方法にしたがって製造できる。例えば、例えば、ポリアセタールコポリマー(X)のペレットを溶融紡糸して製造できる。その際、上述した配向度を高くできる点から、溶融紡糸した繊維を更に延伸加工するのが好ましい。延伸加工の条件も従来公知の方法、条件で行うことができる。延伸倍率は、配向度の観点から3倍以上であるのが好ましい。延伸倍率の上限は配向度の点で限定されるものではないが、生産時の安定性(糸切れ防止)や過度なフィブリル化防止の点から15倍である。なお、溶融紡糸、延伸加工の装置は、従来公知の装置を用いて行うことができる。
本発明の抗菌用繊維の表面に存在するポリアセタールコポリマー(X)は、分子中にオキシメチレン基(-CH2-O-)以外に、下記一般式(1)で表される構造のオキシアルキレン基を有する。
式中、R0及びR0’は、同一又は異なってもよく、それぞれ、水素原子、炭素数1~8のアルキル基、炭素数1~8のアルキル基を有する有機基、フェニル基、及びフェニル基を有する有機基から選択される。また、mは、2~6の整数である。好ましくは、R0及びR0’は、同一又は異なってもよく、それぞれ、水素原子、炭素数1~4のアルキル基、炭素数1~4のアルコキシ基、フェニル基及びベンジル基から選択され、mは、2~4の整数である。より好ましくは、R0及びR0’は、水素原子及び炭素数1~4のアルキル基から選択され、mは、2である。
本発明のポリアセタールコポリマー(X)の製造方法は任意であり、従来公知の任意の方法によって製造すればよい。例えば、オキシメチレン基と、炭素数2以上4以下のオキシアルキレン基を構成単位とするポリアセタール樹脂の製造方法としては、ホルムアルデヒドの3量体(トリオキサン)や4量体(テトラオキサン)等のオキシメチレン基の環状アセタールと、エチレンオキシド、1,3-ジオキソラン、1,3,6-トリオキソカン、1,3-ジオキセパン等の炭素数2以上4以下のオキシアルキレン基を含む環状アセタールとを共重合することによって製造することができる。中でも本発明のポリアセタールコポリマー(X)としては、トリオキサンやテトラオキサン等の環状アセタールと、エチレンオキシド又は1,3-ジオキソランとの共重合体であることが好ましく、中でもトリオキサンと1,3-ジオキソランとの共重合体であることが特に好ましい。
また、本発明を実施するとき、本発明のポリアセタールコポリマー(X)には、本来の目的を損なわない範囲内で、ヒンダードフェノール化合物、ヒンダードアミン化合物、アミノ置換トリアジン化合物、リン系安定剤、アルカリ金属及びアルカリ土類金属の水酸化物、脂肪酸塩、無機酸塩、又はアルコキシドからなる群で示される金属含有化合物を添加することができる。以下、本明細書では、上述した「ヒンダードフェノール化合物、ヒンダードアミン化合物、アミノ置換トリアジン化合物、リン系安定剤、アルカリ金属及びアルカリ土類金属の水酸化物、脂肪酸塩、無機酸塩、又はアルコキシドからなる群で示される金属含有化合物」のことを「任意成分」ということもある。これらの任意成分としては、従来公知のものを使用することができる。
本発明の抗菌用繊維は、用途に応じて不織布、織物、編物、フェルト、ウェブなどの形態に加工することができる。特に抗菌性を活かすために好適な形態は、不織布からなるフィルターである。これら不織布、織物、編物、フェルト、ウェブも本発明の抗菌用繊維と同等の抗菌性を有し、洗濯を繰り返しても抗菌性が持続するという優れた特徴を有する。また、従来の有機系抗菌剤や無機系抗菌剤を有する抗菌用繊維に比べて、加工時の耐熱性や変色などの問題がなく、安全性に優れるため、幅広い用途において好適に用いることができる。特に、本発明の不織布は、フィルターとして好適に使用することができる。このフィルターも本発明の抗菌用繊維と同等の抗菌性を有し、洗濯を繰り返しても抗菌性が持続するという優れた特徴を有する。また、本発明の織物、編物、フェルト、及びウェブは、肌着、シャツ、スポーツウェア、エプロン、ソックス、ストッキング、タイツ、パンティストッキング、足袋、和装品、ネクタイ、ハンカチ、スカーフ、帽子、手袋、マスク、おむつなどの衣料、枕カバー、タオルケット、シーツ、布団中わたなどの寝具、カーテン、カーぺット、マット、ラグ、壁掛け、壁張り、テーブルクロス、モケットなどのインテリア具、タオル、ふきん、たわし、モップ、ぬいぐるみの中わたなどの雑貨などに好適に使用することができる。これらの衣料、寝具、インテリア具、及び雑貨も本発明の抗菌用繊維と同等の抗菌性を有し、洗濯を繰り返しても抗菌性が持続するという優れた特徴を有する。
実施例及び比較例で用いたポリアセタールコポリマーは、以下のとおりである。なお、ポリアセタールコポリマー(X)中のオキシエチレン基の含有量(オキシエチレン基のモル量)は、オキシメチレン基のモル量とオキシエチレン基のモル量の合計値に対する値である。
POM-1:オキシエチレン基の含有量が0.4mol%であり、MVRが8であるポリアセタールコポリマー。
POM-2:オキシエチレン基の含有量が1.6mol%であり、MVRが8であるポリアセタールコポリマー。
POM-3:オキシエチレン基の含有量が3.0mol%であり、MVRが8であるポリアセタールコポリマー。
POM-4:オキシエチレン基の含有量が4.7mol%であり、MVRが8であるポリアセタールコポリマー。
POM-5:オキシエチレン基の含有量が5.7mol%であり、MVRが8であるポリアセタールコポリマー。
PLA(ポリ乳酸樹脂):ユニチカ株式会社製テラマック(登録商標)TE2000をそのまま用いた。
PET(ポリエチレンテレフタレート樹脂):単繊度2デシテックスのマルチフィラメントをそのまま用いた。
ポリアセタールコポリマーのMVR(cm3/10分)は、ISO1133に従って測定した。
実施例及び比較例で用いたポリアセタールコポリマーをヘキサフルオロイソプロパノール(d2)に溶解させて、NMR測定試料を作製し、この測定試料についてNMRスペクトルを測定して、ポリアセタールコポリマー中のオキシエチレン基の含有量を測定した。
繊維の繊度[dtex(デシテックス)]は、光学顕微鏡を用いて単繊維の繊径を測定し、密度1.40g/cm3として繊度を算出し、測定本数50本の平均値を繊維の繊度とした。
広角X線回折装置(株式会社島津製作所製 DP-D1)を用い、CuKα(Niフイルターを使用)を線源として測定した(出力45KV、40mA)。配向度(fc)は、2θ=22.2°付近に観察される(100)面について、円周方向にスキャンして得られる回折強度の分布曲線(方位角分布曲線)の半値幅FWHM(°)から、下記の式(1)を用いて求めた。
シリンダー、ノズル部の温度を200℃に加温し、直径が0.6mmのホールを48個備えたノズルから1.2kg/hの速度で、溶融樹脂を吐出した。なお、芯鞘複合繊維の場合は、ノズルからの吐出速度は、芯成分の樹脂、鞘成分の樹脂ともに0.6kg/hとした。この時、引取り速度を100m/分に固定して連続的に未延伸繊維を採取し、得られた未延伸繊維を引き続き加熱延伸工程へ導き、ロール温度120~140℃で延伸処理を行って繊維試料を作成した。
上記延伸繊維に捲縮処理を施した後、51mm長にカットした。これをカード機(株式会社京和機材製作所製)でウェブとし、ニードルパンチ装置(有限会社大和機工社製)で交絡させてニードルパンチ不織布とした。
JIS L 1902(繊維製品の抗菌性試験方法及び抗菌効果)に準拠し、定量試験(菌液吸収法)により評価した。標準綿布の繊維試料、実施例又は比較例の繊維試料(以下、測定試料という)0.4gをそれぞれ別々のバイアル瓶に入れ、試験菌液0.2mlを接種し、37±2℃で18±1時間培養した後、非イオン界面活性剤0.2%を含む生理食塩水20mlを加えて試料から菌を洗い出し、洗い出し液中の菌数を混釈平板培養法(コロニー法)により測定し、下記の式(2)に従い静菌活性値を算出した。静菌活性値の数値が大きいほど、抗菌性に優れる。また、黄色ブドウ球菌に対する静菌活性値が2.2以上であれば、一般社団法人繊維評価技術協議会が認証するSEKマーク(青:抗菌防臭加工)に該当する。また、下記の式(3)に従って殺菌活性値を算出した。殺菌活性値が大きいほど抗菌性に優れ、0より大きいと抗菌性試験の前後で菌が減少することを意味する。
洗濯10回後の静菌活性保持率と殺菌活性保持率は、次のようにして求めた。洗濯方法は、JIS L 0217の103号に準拠し、洗剤はJAFET標準配合洗剤を用いた。10回繰り返し洗濯処理を行った後に上述と同じ抗菌性試験を行い、下記の式(4)に従い、洗濯10回後の静菌活性保持率[単位:%]を算出した。また、下記の式(5)に従い、洗濯10回後の殺菌活性保持率[単位:%]を算出した。いずれも、数値が100%に近いほど、抗菌性に優れる。
上記、静菌活性値、殺菌活性値、及び洗濯10回後の静菌活性保持率、殺菌活性保持率は、黄色ブドウ球菌とモラクセラ菌について測定した。
表1に、オキシエチレン基含有量が所定範囲内であるポリアセタールコポリマーの単層繊維、オキシエチレン基含有量が所定範囲内であるポリアセタールコポリマーの多層繊維、オキシエチレン基含有量が所定範囲内であるポリアセタールコポリマーとPLAの多層繊維の実施例、並びにポリエステル繊維、オキシエチレン基含有量が所定範囲よりも多いポリアセタールコポリマー単層繊維の比較例を示した。
それぞれの例につき、ポリアセタールコポリマー中のオキシエチレン含有量、単繊度、配向度と、上述の抗菌性試験における培養後の静菌数(単位:個)、抗菌性試験前後の増加比、静菌活性値、洗濯10回後の静菌活性保持率、殺菌活性値、洗濯10回後の殺菌活性維持率を示した。
Claims (15)
- 前記ポリアセタールコポリマー(X)の配向度が60%以上である、請求項1に記載の抗菌用繊維。
- 前記ポリアセタールコポリマー(X)を表面に有する繊維が、ポリアセタールコポリマー(X)の単層繊維である、請求項1又は2に記載の抗菌用繊維。
- 前記ポリアセタールコポリマー(X)を表面に有する繊維が、熱可塑性樹脂からなる繊維をポリアセタールコポリマー(X)で被覆した多層繊維である、請求項1又は2に記載の抗菌用繊維。
- 前記ポリアセタールコポリマー(X)を表面に有する繊維が、熱可塑性樹脂からなる繊維の表面にポリアセタールコポリマー(X)を有する複合繊維である、請求項1又は2に記載の抗菌用繊維。
- 前記熱可塑性樹脂が、ポリアセタールホモポリマー、ポリアセタールコポリマー(X)以外のポリアセタールコポリマー、ポリオレフィン樹脂、ポリ乳酸樹脂、ナイロン樹脂、ポリエステル樹脂、ポリビニル樹脂、及びこれらのエラストマーから選択される1種類又は2種類以上である、請求項4又は5に記載の抗菌用繊維。
- 請求項1~6のいずれか一項に記載の抗菌用繊維を用いた不織布。
- 請求項7に記載の不織布を用いたフィルター。
- 請求項1~6のいずれか一項に記載の抗菌用繊維を用いた編物。
- 請求項1~6のいずれか一項に記載の抗菌用繊維を用いた織物。
- 請求項1~6のいずれか一項に記載の抗菌用繊維を用いたフェルト。
- 請求項1~6のいずれか一項に記載の抗菌用繊維を用いたウェブ。
- 請求項9~12に記載の編物、織物、フェルト、及びウェブからなる群より選択されるいずれか1種以上を用いた衣料。
- 請求項9~12に記載の編物、織物、フェルト、及びウェブからなる群より選択されるいずれか1種以上を用いた寝具。
- 請求項9~12に記載の編物、織物、フェルト、及びウェブからなる群より選択されるいずれか1種以上を用いたインテリア具。
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US10538863B2 (en) | 2015-09-18 | 2020-01-21 | Mitsubishi Gas Chemical Company, Inc. | Cloth having excellent contact cold sensation and colorfastness |
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KR20200029512A (ko) * | 2017-07-14 | 2020-03-18 | 미츠비시 가스 가가쿠 가부시키가이샤 | 폴리아세탈 섬유의 제조 방법 |
JPWO2019012877A1 (ja) * | 2017-07-14 | 2020-05-21 | 三菱瓦斯化学株式会社 | ポリアセタール繊維の製造方法 |
TWI774794B (zh) * | 2017-07-14 | 2022-08-21 | 日商三菱瓦斯化學股份有限公司 | 聚縮醛纖維的製造方法 |
US11441242B2 (en) | 2017-07-14 | 2022-09-13 | Mitsubishi Gas Chemical Company, Inc. | Method for manufacturing polyacetal fiber |
KR102494183B1 (ko) | 2017-07-14 | 2023-01-31 | 미츠비시 가스 가가쿠 가부시키가이샤 | 폴리아세탈 섬유의 제조 방법 |
JP7310603B2 (ja) | 2017-07-14 | 2023-07-19 | 三菱瓦斯化学株式会社 | ポリアセタール繊維の製造方法 |
Also Published As
Publication number | Publication date |
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US11767423B2 (en) | 2023-09-26 |
US20200002853A1 (en) | 2020-01-02 |
JP6787309B2 (ja) | 2020-11-18 |
TW201638412A (zh) | 2016-11-01 |
EP3272917A1 (en) | 2018-01-24 |
CN107407010B (zh) | 2020-10-20 |
US20180080149A1 (en) | 2018-03-22 |
JPWO2016147998A1 (ja) | 2017-12-28 |
KR20170129156A (ko) | 2017-11-24 |
EP3272917A4 (en) | 2018-10-24 |
TWI704259B (zh) | 2020-09-11 |
CN107407010A (zh) | 2017-11-28 |
KR102551954B1 (ko) | 2023-07-05 |
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