WO2014162965A1 - 高炉操業方法及びランス - Google Patents
高炉操業方法及びランス Download PDFInfo
- Publication number
- WO2014162965A1 WO2014162965A1 PCT/JP2014/058797 JP2014058797W WO2014162965A1 WO 2014162965 A1 WO2014162965 A1 WO 2014162965A1 JP 2014058797 W JP2014058797 W JP 2014058797W WO 2014162965 A1 WO2014162965 A1 WO 2014162965A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- lance
- blowing
- pipe
- reducing material
- combustion
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000007664 blowing Methods 0.000 claims abstract description 71
- 239000007787 solid Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims description 66
- 238000011017 operating method Methods 0.000 claims description 10
- 238000002485 combustion reaction Methods 0.000 abstract description 38
- 239000003245 coal Substances 0.000 abstract description 34
- 239000003638 chemical reducing agent Substances 0.000 abstract description 9
- 238000001816 cooling Methods 0.000 abstract description 9
- 239000007789 gas Substances 0.000 description 52
- 239000003949 liquefied natural gas Substances 0.000 description 25
- 229910052760 oxygen Inorganic materials 0.000 description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 20
- 239000001301 oxygen Substances 0.000 description 20
- 238000002474 experimental method Methods 0.000 description 10
- 239000000571 coke Substances 0.000 description 9
- 230000009467 reduction Effects 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000009423 ventilation Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910000805 Pig iron Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003034 coal gas Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
- C21B7/163—Blowpipe assembly
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/02—Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
- F27B1/16—Arrangements of tuyeres
Definitions
- a flammable gas reducing material such as LNG (Liquefied Natural Gas) or a combustion-supporting gas is blown into the furnace from the blast furnace tuyere into the furnace, together with a solid reducing material such as pulverized coal.
- LNG Liquified Natural Gas
- the present invention relates to a blast furnace operating method that is effective in improving productivity and reducing the reducing material basic unit by raising the temperature, and a lance used in implementing this method.
- the ratio of low reducing agent ratio (low RAR: Abbreviation for Reduction Agent Ratio) is the total amount of reducing material blown from the tuyere and coke charged from the top of the furnace per ton of pig iron. ) Operations are being promoted. Blast furnaces mainly use coke and pulverized coal as reducing materials, and in order to achieve a low reducing material ratio, and thus carbon dioxide emission control, coke etc. have a high hydrogen content such as waste plastic, LNG, heavy oil, etc. A method of replacing with a reducing material is effective.
- Patent Document 1 promotes the temperature rise of the solid reducing material in the combustion field of the gas reducing material by simultaneously blowing the solid reducing material, the gas reducing material, and the combustion-supporting gas using a plurality of lances. It is a method to make it.
- the combustion rate of the solid reducing material is improved, the generation of unburned powder and coke powder is suppressed, the ventilation is improved, and the reducing material ratio can be reduced.
- the lance is a heavy pipe type, for example, a solid reducing material is blown from the inner pipe, a combustion-supporting gas is blown from the gap between the inner pipe and the middle pipe, and the middle pipe and the outer pipe are blown.
- Patent Document 3 discloses a structure in which a plurality of small-diameter pipes are arranged in parallel around the lance main pipe.
- Patent Document 1 The blast furnace operating method disclosed in Patent Document 1 is more effective in raising the combustion temperature at the tuyere and reducing the reducing material basic unit than the method of blowing only pulverized coal from the tuyere, The effect is not sufficient only by adjusting the blowing position. Further, in the case of the heavy tube type lance described in Patent Document 2, it is necessary to increase the outside blowing speed in order to ensure the cooling ability of the lance. For this purpose, the gap between the inner pipe and the outer pipe must be extremely narrow, and due to equipment limitations, a predetermined amount of gas cannot be flowed, and there is a possibility that the effect of improving combustibility may not be obtained. .
- An object of the present invention is to propose a blast furnace operating method capable of overcoming the above-described problems of the prior art and a lance used for this operation.
- a blast furnace operating method capable of improving both cooling performance and improving combustibility without excessively increasing the lance diameter, and enabling reduction in reducing material basic unit. And the purpose of proposing lances.
- the blast furnace operating method according to the present invention developed to solve the above problems is an independent blast furnace operating method in which a solid reducing material, a gas reducing material and a combustion-supporting gas are blown into a blast furnace from a tuyere through a lance.
- a solid reducing material, a gas reducing material and a combustion-supporting gas are blown into a blast furnace from a tuyere through a lance.
- parallel lances in which individual blow tubes are bundled in parallel and bundled and accommodated in the outer lance tube, either one or two of the gas reducing material and the combustion-supporting gas and solid reduction are provided from each blow tube.
- the solid reducing material blowing pipe and the gas reducing material blowing pipe are positioned above the combustion-supporting gas blowing pipe when blowing from the parallel lance. It is a blast furnace operating method.
- the present invention provides a lance for injecting a solid reducing material, a gas reducing material, and a combustion-supporting gas from a tuyere into a blast furnace, and any one or two of the gas reducing material and the combustion-supporting gas is used as the solid reducing material.
- three independent blowing pipes are arranged in parallel and bundled and accommodated in the outer lance pipe so as to be integrated, and the positional relationship of the respective blowing pipes is determined by the solid reducing material blowing pipes and
- the lance is characterized in that the blowing pipe for the gas reducing material is disposed so as to be positioned above the combustion-supporting gas blowing pipe.
- an angle formed by a plane passing through the center of the solid reducing material blowing pipe and the outer contact of the lance outer pipe and a radial vertical plane of the lance inserted into the blow pipe is ⁇ 90.
- Placing a solid reducing material blowing tube, a gas reducing material blowing tube and a combustion-supporting gas blowing tube so as to be within ⁇ (2)
- Each blowing tube is a tube having an inner diameter of 6 mm or more and 30 mm or less, Is a more preferable solution.
- the parallel lances in which the respective blowing paths are bundled in parallel and bundled with the outer lance tube are bundled in parallel and bundled with the outer lance tube.
- FIG. 1 is a schematic diagram of a blast furnace to which a blast furnace operating method according to the present invention is applied.
- the blast furnace 1 is provided with a plurality of tuyere in the furnace circumferential direction.
- the tuyere 3 is connected to a blow pipe (blower pipe) 2 for blowing hot air, and the blow pipe 2 has a lance 4 that is mainly inserted obliquely from above toward the center in the tube axis direction. Installed.
- a combustion space called a raceway 5 that is also a coke deposit layer is formed in front of the tuyere 3 where hot air is blown (inside the furnace). In this combustion space, iron ore is mainly reduced, and molten iron is generated. Generate.
- FIG. 2 shows a combustion state when only pulverized coal 6 is blown from the lance 4.
- the pulverized coal 6 passing from the lance 4 through the tuyere 3 and blown into the raceway 5 and the lump coke 7 charged from the top of the furnace are burned here.
- the speed of the hot air in the forward direction of the hot air blown into the furnace from the tuyere 3 is about 200 m / sec, and the region where O 2 exists in the raceway 5 from the tip of the lance 4 is about 0.3-0. Therefore, it is necessary to improve the heating efficiency of pulverized coal particles and the contact efficiency (dispersibility) with oxygen (O 2 ) which is a combustion-supporting gas at a level of 1/1000 second. Become.
- FIG. 3 is an explanatory diagram of a combustion mechanism when only pulverized coal (PC: Pulverized Coal) 6 that is a solid reducing material is blown into the blow pipe 2 from the lance 4.
- PC Pulverized Coal
- the pulverized coal 6 blown into the raceway 5 from the tuyere 3 is heated by the radiant heat transfer from the flame in the raceway 5, and the temperature of the pulverized coal 6 is rapidly increased by the radiant heat transfer and conduction heat transfer.
- Pyrolysis starts when the temperature is raised to 300 ° C. or more, and the volatile matter is ignited to form a flame.
- the combustion temperature particle temperature
- the above-described char 8 is obtained. Since the char 8 is mainly constant carbon, a reaction called a carbon dissolution reaction occurs along with a combustion reaction.
- FIG. 4 shows that LNG, which is a preferred example of a flammable gas reducing material, and oxygen (not shown), which is a preferred example of a combustion-supporting gas, are blown into the blow pipe 2 from the lance 4.
- LNG which is a preferred example of a flammable gas reducing material
- oxygen which is a preferred example of a combustion-supporting gas
- Fig. 5a shows a conventional heavy tube type lance used conventionally.
- FIG. 5b shows the parallel lance proposed in the present invention.
- the heavy tube type lance is a concentric triple tube of an inner tube I, a middle tube M, and an outer tube O in which stainless steel tubes are used, and the dimensions are as shown in the figure.
- the gap between the inner pipe I and the middle pipe M is 1.15 mm, and the gap between the middle pipe M and the outer pipe O is 0.65 mm.
- the solid reducing material blowing tube 21, the gas reducing material blowing tube 22, and the combustion supporting gas blowing tube 23 such as oxygen are arranged in parallel. These are bundled, accommodated in the outer lance tube and integrated, and the dimensions of each blow tube are as shown in the figure.
- Fig. 6 shows the results of a comparative measurement of pressure loss between the heavy tube type lance and the parallel type lance.
- the parallel type lance has less pressure loss than the heavy tube type lance.
- the ventilation resistance is reduced by relatively increasing the blowing space (the volume of the blowing pipe).
- FIG. 7 shows a comparison of cooling capacity for each lance (heavy tube type, parallel type).
- the parallel lance has a higher cooling capacity at the same pressure loss than the heavy tube lance. This is thought to be because the flow rate that can be flowed at the same pressure loss is large because the in-tube ventilation resistance is small.
- FIG. 8 focuses on the outer diameter of the lance.
- FIG. 8a shows the outer diameter of the non-water-cooled type and
- FIG. 8b shows the outer diameter of the water-cooled type lance.
- the outer diameter of the lance is smaller than that of the heavy tube type lance. This is presumably because the parallel lance can reduce the flow path, the thickness of the pipe, and the cross-sectional area of the water-cooled portion as compared with the heavy tube lance.
- the experimental furnace 11 is filled with lump coke, and the inside of the raceway 15 can be observed from the viewing window.
- a lance 14 is inserted into the blow pipe (blower pipe) 12 so that hot air generated in the combustion burner 13 can be blown into the experimental furnace 11 with a predetermined amount of blown air.
- this ventilation pipe 12 it is also possible to adjust the oxygen enrichment amount of ventilation.
- the lance 14 can blow any one or more of pulverized coal, LNG, and oxygen into the blower pipe 12.
- the exhaust gas generated in the experimental furnace 11 is separated into exhaust gas and dust by a separation device 16 called a cyclone, the exhaust gas is sent to an exhaust gas treatment facility such as an auxiliary combustion furnace, and the dust is collected in a collection box 17. .
- a two-color thermometer is a radiation thermometer that measures temperature using thermal radiation (electromagnetic wave movement from a high-temperature object to a low-temperature object). Focusing on the shift, it is one of the wavelength distribution types to obtain the temperature by measuring the temperature change of the wavelength distribution, and in order to capture the wavelength distribution among them, the radiant energy at two wavelengths is measured and the ratio The temperature is measured from
- pulverized coal is blown from the parallel lance solid reducing agent blowing pipe 21
- LNG is blown from the gas reducing material blowing pipe 22
- combustion supporting gas is injected.
- Oxygen was blown in from the blow-in pipe 23.
- the blowing pipe for solid reducing material and the gas reducing material are used for blowing from the parallel lance.
- the operation is performed in such a manner that the blow-in pipe is positioned above the combustion-supporting gas blow-in pipe. That is, the positional relationship among the fine powder, LNG, and oxygen blown into the blow pipe is such that oxygen is blown to the lower side of the blow pipe near the center of the tube axis, and fine coal and LNG are blown above it.
- Such a positional relationship is such that the parallel lances are in a state where the blowing attitude passes through the tube axis center of the solid reducing material blowing pipe and the outer contact of the lance, and the radial vertical plane of the lance inserted into the blow pipe.
- the lance arrangement is such that the angle between the two and the blow pipes is in a positional relationship of ⁇ 90 °. That is, when the position corresponding to the outer diameter of the lance is the point A on the outer peripheral surface of the blowing pipe 21 into which the pulverized coal is blown, the point A is 0 ° when the point A is at the top, and the point A is the axis of the lance.
- the combustion temperature was measured by a two-color thermometer at a position rotated around 60 ° in the clockwise direction and at a position rotated around 180 ° of point A.
- the insertion length of each lance into the blow pipe was 50 mm.
- the specifications of pulverized coal as the solid reducing material are 71.3% of fixed carbon (FC), 19.6% of volatile matter (VM), 9.1% of ash (Ash), and blown.
- the condition was 50.0 kg / h (corresponding to 158 kg / t per pig iron unit).
- the LNG blowing conditions were 3.6 kg / h (5.0 Nm 3 / h, equivalent to 11 kg / t per pig iron unit).
- the coke used was 150 15 DI83 according to the test method described in JISK2151.
- blowing conditions are as follows: blowing temperature 1100 ° C., flow rate 350 Nm 3 / h, flow rate 80 m / s, O 2 enrichment +3.7 (oxygen concentration 24.7%, air oxygen concentration 21%, 3.7% wealth) ).
- FIG. 11 shows the result of the combustion temperature by the combustion experiment.
- the position of the first pipe of the parallel pipe lance that is, the pulverized coal blowing pipe is changed to 0 °, 60 °, 180 ° around the axis of the lance, 60 °
- the combustion temperature is highest when the pulverized coal and LNG blowing pipes are above the oxygen blowing pipe. This is because the combustion field of LNG is adjacent to pulverized coal, the temperature of pulverized coal is raised, and oxygen is located below LNG and pulverized coal, so that oxygen is efficiently mixed into both LNG and pulverized coal. Therefore, it is considered that combustion was promoted.
- LNG is used as the flammable gas reducing material.
- city gas can also be used, and other gas reducing materials include propane gas, hydrogen, as well as city gas and LNG.
- converter gas, blast furnace gas, and coke oven gas generated at an ironworks can also be used.
- shale gas can be used as equivalent to LNG.
- Shale gas is a natural gas extracted from the shale layer, and is produced from a place other than the conventional gas field, so it is called an unconventional natural gas resource.
- 1 is a blast furnace
- 2 is a blow pipe
- 3 is a tuyere
- 4 is a lance
- 5 is a raceway
- 6 is pulverized coal (solid reducing material)
- 7 is coke
- 8 is char
- 9 is LNG (flammable reducing material) )
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Manufacture Of Iron (AREA)
- Blast Furnaces (AREA)
Abstract
Description
特に、本発明では、ランス径を極端に大きくすることなく、冷却能を高めることと、燃焼性の向上との両立を図ることができると共に、還元材原単位の低減を可能にする高炉操業方法及びランスを提案することを目的とする。
(1)前記並列型ランスは、固体還元材用吹き込み管の中心とランス外管との外接点とを通る面と、ブローパイプに差し込まれたランスの半径方向鉛直面とのなす角度が±90°以内となるように、固体還元材用吹き込み管、気体還元材用吹き込み管および支燃性ガス用吹込み管を配置すること、
(2)前記各吹き込み管は、内径が6mm以上30mm以下の管であること、
が、より好ましい解決手段である。
この燃焼実験では、ランス14として、単管ランス、三重管ランス(以下、重管型ランスとも記す)、3本の吹き込み管を並列かつ束ねて一体化とした並列型ランスの3種を用いた。そして、単管ランスから微粉炭のみを吹き込んだ場合をベースとして、重管型ランスについては内管から微粉炭を吹き込み、内管と中管の隙間から酸素を吹き込み、中管と外管の隙間からLNGを吹き込んだ。一方、並列型ランスについては、束ねられてはいるが、それぞれ独立している吹き込み管からは、微粉炭、LNGおよび酸素を吹き込んだ。これらの吹き込み位置を、ランスの軸周りに変化させた場合について、二色温度計による燃焼温度、ランス内圧力損失、ランス表面温度、並びにランスの外径を測定した。二色温度計は、周知のように、熱放射(高温物体から低温物体への電磁波の移動)を利用して温度計測を行う放射温度計であり、温度が高くなると波長分布が短波長側にずれていくことに着目して、波長分布の温度の変化を計測することで温度を求める波長分布形の一つであり、中でも波長分布を捉えるため、二つの波長における放射エネルギーを計測し、比率から温度を測定するものである。
Claims (5)
- 羽口から高炉内に固体還元材、気体還元材及び支燃性ガスをランスを介して吹き込む高炉操業方法において、独立した3個の吹き込み管が並列かつ束ねられてランス外管内に収容されて一体化した並列型ランスを用い、それぞれの吹き込み管からは、気体還元材及び支燃性ガスのいずれか1又は2と固体還元材とを同時に吹き込むと共に、この並列型ランスからの吹き込みに際しては、固体還元材用吹き込み管及び気体還元材用吹き込み管が支燃性ガス吹き込み管よりも上方に位置する態勢にして行なうことを特徴とする高炉操業方法。
- 前記並列型ランスは、固体還元材用吹き込み管の中心とランス外管との外接点とを通る面と、ブローパイプに差し込まれたランスの半径方向鉛直面とのなす角度が±90°以内となるように、固体還元材用吹き込み管、気体還元材用吹き込み管および支燃性ガス用吹込み管を配置することを特徴とする請求項1に記載の高炉操業方法。
- 羽口から高炉内に固体還元材、気体還元材及び支燃性ガスを吹き込むためのランスにおいて、気体還元材および支燃性ガスのいずれか1又は2を固体還元材と同時に吹き込む際に、独立した3個の吹き込み管が並列かつ束ねられてランス外管内に収容されて一体化した構造を有し、かつそれぞれの吹き込み管の位置関係を、固体還元材用吹き込み管及び気体還元材用吹き込み管を支燃性ガス吹き込み管よりも上方に位置する関係となるように配設したものであることを特徴とするランス。
- 前記並列型ランスの吹き込み姿勢は、固体還元材用吹き込み管の中心とランス外管との外接点とを通る面と、ブローパイプに差し込まれたランスの半径方向鉛直面とのなす角度が±90°以内となるようなランス配置としたことを特徴とする請求項3に記載のランス。
- 前記各吹き込み管は、内径が6mm以上30mm以下の管であることを特徴とする請求項3または4に記載のランス。
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014527377A JP5652575B1 (ja) | 2013-04-03 | 2014-03-27 | 高炉操業方法及びランス |
CN201480019172.1A CN105074014A (zh) | 2013-04-03 | 2014-03-27 | 高炉操作方法及喷枪 |
KR1020157027225A KR101675710B1 (ko) | 2013-04-03 | 2014-03-27 | 고로 조업 방법 및 랜스 |
RU2015147170A RU2674454C2 (ru) | 2013-04-03 | 2014-03-27 | Способ работы доменной печи и копье |
AU2014250568A AU2014250568B2 (en) | 2013-04-03 | 2014-03-27 | Blast furnace operation method and lance |
CA2907833A CA2907833C (en) | 2013-04-03 | 2014-03-27 | Blast furnace operation method and lance |
EP14780034.6A EP2982768B1 (en) | 2013-04-03 | 2014-03-27 | Blast furnace operation method and lance |
US14/781,698 US9945001B2 (en) | 2013-04-03 | 2014-03-27 | Blast furnace operation method and lance |
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JP2013-077523 | 2013-04-03 | ||
JP2013077523 | 2013-04-03 |
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US (1) | US9945001B2 (ja) |
EP (1) | EP2982768B1 (ja) |
JP (1) | JP5652575B1 (ja) |
KR (1) | KR101675710B1 (ja) |
CN (1) | CN105074014A (ja) |
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US9938593B2 (en) * | 2013-04-03 | 2018-04-10 | Jfe Steel Corporation | Blast furnace operation method |
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EP2982768A1 (en) | 2016-02-10 |
AU2014250568A1 (en) | 2015-10-15 |
US9945001B2 (en) | 2018-04-17 |
JP5652575B1 (ja) | 2015-01-14 |
KR101675710B1 (ko) | 2016-11-11 |
CA2907833A1 (en) | 2014-10-09 |
KR20150123920A (ko) | 2015-11-04 |
EP2982768A4 (en) | 2016-03-30 |
EP2982768B1 (en) | 2017-05-24 |
CA2907833C (en) | 2017-01-24 |
JPWO2014162965A1 (ja) | 2017-02-16 |
US20160040261A1 (en) | 2016-02-11 |
CN105074014A (zh) | 2015-11-18 |
AU2014250568B2 (en) | 2016-09-15 |
RU2015147170A (ru) | 2017-05-12 |
RU2674454C2 (ru) | 2018-12-10 |
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