WO2002066894A1 - Dispositif de combustion catalytique et procede de fabrication d'une partie de chassis du dispositif - Google Patents
Dispositif de combustion catalytique et procede de fabrication d'une partie de chassis du dispositif Download PDFInfo
- Publication number
- WO2002066894A1 WO2002066894A1 PCT/JP2002/001442 JP0201442W WO02066894A1 WO 2002066894 A1 WO2002066894 A1 WO 2002066894A1 JP 0201442 W JP0201442 W JP 0201442W WO 02066894 A1 WO02066894 A1 WO 02066894A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- section
- catalytic combustion
- heat
- heat exchange
- combustion
- Prior art date
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 57
- 239000003054 catalyst Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims description 6
- 239000000446 fuel Substances 0.000 claims abstract description 50
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 35
- 230000005855 radiation Effects 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000000567 combustion gas Substances 0.000 claims abstract description 6
- 238000007084 catalytic combustion reaction Methods 0.000 claims description 143
- 238000005192 partition Methods 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 17
- 230000001629 suppression Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 230000008016 vaporization Effects 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000003973 paint Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 230000005070 ripening Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 12
- 239000007789 gas Substances 0.000 description 10
- 239000000919 ceramic Substances 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- 238000009834 vaporization Methods 0.000 description 6
- 239000003566 sealing material Substances 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000006200 vaporizer Substances 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/12—Radiant burners
- F23D14/18—Radiant burners using catalysis for flameless combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/0027—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters using fluid fuel
- F24H1/0045—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters using fluid fuel with catalytic combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/22—Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating
- F24H1/40—Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating with water tube or tubes
- F24H1/41—Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating with water tube or tubes in serpentine form
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2213/00—Burner manufacture specifications
Definitions
- the present invention relates to a catalytic combustion device having a low cost, high mass productivity, and easy maintenance.
- the radiant heat receiving section 3 is arranged parallel to the flow of the combustion gas, but the flow path 4 supporting it is perpendicular to the flow. Under such a configuration, it is necessary to form the radiation heat receiving portion 3 and the flow path 4 supporting the radiation heat receiving portion 3 as separate parts, and then press-fit or braze the radiation heat receiving portion 3 into the flow path 4.
- An object of the present invention is to solve the problems of such a conventional catalytic combustion device.
- a first invention (corresponding to the invention according to claim 1) includes a combustion chamber having a fuel supply section and a combustion air supply section upstream and a combustion gas exhaust port downstream, and installed in the combustion chamber.
- a catalytic combustion unit in which an upstream surface and a downstream surface are substantially parallel to each other, a catalytic combustion device that reacts a mixture of fuel and air supplied into the combustion chamber to generate heat,
- a heat exchange unit that forms part of the wall of the combustion chamber
- a fin-type radiant heat receiving unit that protrudes into the combustion chamber from the heat exchange unit and is provided near the catalytic combustion unit
- At least the surface of the fin-type radiation heat receiving portion and the surface of the heat exchange portion are catalytic combustion devices that face the same direction.
- the second present invention (corresponding to the second aspect of the present invention) is further provided so as to protrude from the heat exchange section into the combustion chamber according to a downstream law of the catalytic combustion section, and 1 is a first embodiment of the catalytic combustion device of the present invention provided with a convection heat transfer portion having surfaces oriented in substantially the same direction.
- the heat exchange section, the radiant heat receiving section and the convective heat transfer section are integrally formed by extrusion molding.
- 2 is a catalytic combustion device according to a second invention.
- a fourth aspect of the present invention (corresponding to the invention according to claim 4) is that the surface of the catalyst supporting portion that supports the catalytic combustion portion on the side of the catalytic combustion portion faces in substantially the same direction as the surface of the radiation heat receiving portion.
- 1 is a catalytic combustion device according to the first or second aspect of the present invention.
- a fifth aspect of the present invention is any one of the first to fourth aspects of the present invention, wherein the surface of the catalytic combustion unit is also oriented in the same direction as the surface of the radiation heat receiving unit. This is a catalytic combustion device.
- a sixth aspect of the present invention (corresponding to the invention according to claim 6) further includes a heat medium flow path through which the heat medium flows, and a heat medium flow path support portion that supports the heat medium flow path,
- the first to the heat medium passage support portions are provided on the heat exchange portion such that the flow direction of the heat medium in the heat medium passage is substantially parallel to the surface of the catalytic combustion portion.
- 5 is a catalytic combustion device according to any one of the present invention.
- a seventh invention is a method according to the first to sixth inventions, wherein the surface of the heat exchange section on the side of the catalyst combustion section is coated with a heat-resistant paint having an emissivity of about 1.
- the catalytic combustion device according to any one of the inventions.
- the eighth invention (corresponding to the invention according to claim 8) further comprises a vaporizing section for vaporizing a liquid fuel, and wherein the radiant heat receiving section is disposed downstream of the catalytic combustion section and thereafter. Any one of the catalytic combustion apparatuses according to the present invention.
- a ninth aspect of the present invention (corresponding to the ninth aspect of the present invention) is that, upstream of the catalytic combustion section, a surface of the heat exchange section on the side of the catalytic combustion section is heated by a base material of the heat exchange section.
- An eighth aspect of the catalytic combustion apparatus according to the present invention in which a tar suppression plate made of a material having a low conductivity is installed.
- the tar suppressing plate and the heat exchanging part are partially disposed between the tar suppressing plate and the heat exchanging unit.
- a ninth embodiment of the catalytic combustion device of the present invention provided with a tar suppression plate support portion that comes into contact with the catalytic combustion device.
- the eleventh invention (corresponding to the invention according to claim 11) includes, among the walls forming the combustion chamber, at least one of two walls substantially perpendicular to a surface of the radiant heat receiving portion.
- the wall is the catalytic combustion device according to any one of the first to tenth aspects of the present invention, which is detachable.
- a twenty-second aspect of the present invention is the eleventh aspect of the eleventh aspect of the invention, wherein at least one of the walls is made of a metal or coated with a metal oxide film. It is a catalytic combustion device.
- the thirteenth invention (corresponding to the invention according to claim 13) is directed to a first to a twelfth book in which a flow path partition plate substantially parallel to an upstream surface of the catalytic combustion part is provided. Invention! /, Without This is a catalytic combustion device.
- a fifteenth invention is the catalyst combustion apparatus according to the thirteenth invention, wherein the flow path partition plate and the wall are integrated.
- a fifteenth invention (corresponding to the invention according to claim 15) includes a combustion chamber having a fuel supply section and a combustion air supply section upstream and a combustion gas exhaust port downstream, A method for producing a frame portion in a catalytic combustion device installed, wherein an upstream surface and a downstream surface are substantially parallel to each other, and a mixture of fuel and air supplied into the combustion chamber reacts to generate heat.
- a heat exchange unit that forms part of the wall of the combustion chamber
- a fin-type radiant heat receiving unit that protrudes into the combustion chamber from the heat exchange unit and is provided near the catalytic combustion unit;
- a convection heat transfer section provided on the downstream side of the catalytic combustion section so as to protrude from the heat exchange section into the combustion chamber and having a surface oriented substantially in the same direction as the surface of the radiant heat reception section;
- the surface of the fin-type radiation heat receiving portion, the surface of the heat exchange portion, and the surface of the convection heat transfer portion face in the same direction, respectively.
- FIG. 1 is a perspective view of a catalytic combustion device according to a first embodiment of the present invention.
- FIG. 2 is a perspective view of a catalytic combustion device according to a second embodiment of the present invention.
- FIG. 3 is a perspective view of a catalytic combustion device according to a third embodiment of the present invention.
- a catalytic combustion section having an air permeability and an acid activity for various fuels, an ignition device, A flow control device, a fuel-air mixer, or a liquid fuel vaporizer, a temperature detection device, and a drive device are required as necessary.
- the catalytic combustion section use a metal or ceramic honeycomb carrier, or a ceramic fiber braided body, porous sintered body, etc. carrying an active component mainly composed of a precious metal such as platinum or palladium. be able to.
- a manual needle valve or electric solenoid pulp is used for controlling the flow rate of air or gaseous fuel, and an electromagnetic pump is used for liquid fuel.
- Other drive parts can be operated by manual lever operation, automatic control motor drive, etc., and an electric heater or discharge igniter can be used as the ignition device.
- FIG. 1 is a perspective view of a first embodiment of the catalytic combustion device according to the present invention.
- 1 is a fuel supply path
- 2 is an air supply path
- 3 is a heat exchange section
- 4 is an exhaust port.
- Reference numeral 5 denotes a catalytic combustion unit in which a platinum group metal is supported on a gas-permeable ceramic honeycomb
- reference numeral 6 denotes a catalyst support unit. The position of the catalytic combustion unit 5 is fixed by the catalyst support unit 6.
- Reference numeral 7 denotes a heat medium flow path
- 8 denotes a heat medium flow path support portion
- the heat medium flow path 7 is installed in contact with the heat medium flow path support portion 8.
- heat exchange unit 3 9 protruding inside the heat exchange section 3 is a fin-shaped radiation heat receiving section, and 10 is a convection heat transfer section.
- reference numeral 11 denotes a heat exchange unit side plate, which is detachable from an end face of the heat exchange unit 3.
- the combustion chamber 200 is mainly constituted by the heat exchange unit 3 and the heat exchange unit side plate 11.
- the fuel supplied via the fuel supply path 1 (here, city gas is used) is mixed with the air via the air supply path 2 and then supplied into the heat exchange section 3.
- the air-fuel mixture is supplied to the catalytic combustion section 5, where an oxidation reaction is performed.
- This reaction heat Accordingly, the upstream temperature of the catalytic combustion section 5 is controlled to 600 ° C. or more, which has good combustion exhaust gas characteristics, and 900 ° C. or less, which is the heat resistance limit of the catalyst material. At this time, the downstream temperature changes from 350 ° C to 65 ° C.
- the radiant heat from the upstream and downstream sides of the catalytic combustion section 5 is received by the radiant heat receiving section 9, then conducts in the heat exchange section 3, passes through the heat medium flow path support section 8, The heat is transmitted to the heat medium flowing through the medium flow path 7. Further, the combustion exhaust gas after the oxidation reaction repeats contact with the convection heat transfer section 10 to perform heat exchange, and from 50 ° C to 200 ° C, and finally from the exhaust port 4. Is discharged.
- the surface of the radiation heat receiving unit 9, the surface of the heat exchange unit 3, the surface of the catalyst support unit 6, and the surface of the heat medium flow path support unit 8 face in the same direction.
- the same direction here does not necessarily mean a parallel relationship, but any direction perpendicular to the upstream and downstream surfaces of the catalytic combustion section 5 and perpendicular to the flow direction of the heat medium in the heat medium flow path 7.
- the sections of the catalytic combustion section 5, the radiant heat receiving section 9, the heat exchange section 3, and the heat medium flow path 7 always have the same shape.
- the radiation heat receiving section 9, the heat exchange section 3, the catalyst support section 6, and the heat medium flow path support section 8 can be integrally manufactured by extrusion molding.
- the radiant heat receiving section 9, the heat exchange section 3, the catalyst support section 6, and the heat medium flow path support section 8 constitute a frame of the present invention.
- the catalyst support section 6 for fixing the position of the catalyst combustion section 5 is provided, the positioning of the catalyst combustion section 5 is easy, and the seal configuration between the heat exchange section 3 and the catalyst combustion section 5 is simple. As a result, it is possible to increase production efficiency during manufacturing. Therefore, it is possible to realize a low-cost and highly mass-produced catalytic combustion device.
- the configuration of the scenery between the heat exchange section 3 and the catalytic combustion section 5 is as shown in FIG. 1B.
- the scenery 100 contributes to tightening and also has the effect of suppressing heat conduction.
- the upstream and downstream surfaces of the catalytic combustion unit 5 are perpendicular to each other.
- the removable heat exchange section side plate 11 is provided on one surface perpendicular to the direction of flow of the heat medium in the heat medium flow path 7, abnormal conditions such as deterioration and cracking of the catalytic combustion section 5 can be prevented.
- the heat exchange section side plate 11 can be attached and detached, and only the catalytic combustion section 5 can be replaced.
- the fin surface of the fin-type radiant heat-receiving part be parallel to the gas flow, with emphasis on convection, but radiant heat is mainly used like a catalytic combustion device.
- the apparatus that performs the above, there is no problem even if the upstream surface and the downstream surface of the catalytic combustion unit 5 and the surface of the radiation heat receiving unit 9 are parallel to each other, as described above.
- a catalytic combustion device that is easy to maintain can be realized. Further, it becomes possible to recover the platinum group noble metal from the exchanged catalytic combustion section 5, thereby realizing a catalytic combustion apparatus excellent in recyclability. Furthermore, since the heat medium flow path 7 is installed in contact with the heat medium flow path support section 8 and is not directly brazed to the heat exchange section 3, it is easy to separate the heat medium flow path 7 from the heat exchange section 3. Even when the material of the medium flow path 7 is different, a catalytic combustion device excellent in recyclability can be realized.
- the heat medium flow path 7 is provided in contact with the heat medium flow path support section 8 formed in a direction parallel to the upstream surface and the downstream surface of the catalytic combustion section 5, and has the following advantages. There is. That is, as shown in FIG. 1, considering the phenomenon of heating at the ceiling of the catalytic combustion section 5, in the first embodiment, the temperature difference of the heating medium heated on the ceiling is It is relatively small as compared with the case where the flow path support portion 8 is formed in a direction perpendicular to the upstream surface and the downstream surface of the catalytic combustion portion 5.
- the heat medium flow passage 7 may cross the longitudinal direction of the ceiling surface many times. After all, the temperature difference of the heat medium is large. It will be sharp.
- gaseous fuel is used.
- liquid fuel may be used, and the same effect as described above can be obtained.
- the heat medium flow path 7 may be embedded inside the heat exchange section 3 disposed outside the heat exchange section 3 or may be disposed inside the heat exchange section 3, and the same effects as above can be obtained. is there.
- the catalytic combustion unit 5 is disposed via the heat exchange unit 3 and a ceramic sealing material having expandability in a high temperature range.
- a ceramic sealing material having expandability in a high temperature range.
- the configuration is such that the catalytic combustion unit 5 can be positioned, There is no need to use a separate sealing material, and even if the shape of the catalyst support section 6 is made to be in linear contact with the catalyst combustion section 5 in order to suppress heat conduction to the heat exchange section 3, the same effect as described above is obtained. Is obtained.
- the support surface of the catalyst support section 6 is formed in an M shape so that the catalyst support section 6 does not come into surface contact with the catalyst combustion section 5. do it.
- the heat exchange section side plate 11 is made of a metal material having a high heat ray reflectance, or when the inner surface of the heat exchange section 3 is covered with a heat-resistant black paint having a heat ray absorption rate of about 1
- a catalytic combustion device with higher heat exchange efficiency.
- a second embodiment of the present invention will be described.
- the basic configuration of the second embodiment is the same as that of the first embodiment except that the flow direction of the air-fuel mixture is substantially parallel to the upstream surface and the downstream surface of the catalytic combustion section 5.
- the difference is that a road partition plate is arranged. Therefore, this difference will be mainly described.
- FIG. 2 is a perspective view of the present embodiment.
- reference numeral 12 denotes a first flow path partition plate
- reference numeral 13 denotes a second flow path partition plate, which are disposed so as to be substantially parallel to the upstream surface and the downstream surface of the catalytic combustion section 5.
- Reference numeral 14 denotes an opening of the first flow path partition plate
- 15 denotes an opening of the second flow path partition plate.
- the air-fuel mixture collides with the first flow path partition plate 12 to form a parallel flow in the fin-type radiant heat receiving section 9, and from the first flow path partition plate opening 14 (before the drawing), 1 flows into the space between the partition plate 12 and the catalytic combustion section 5.
- a part of the air-fuel mixture passes through the catalyst combustion section 5 and then collides with the second flow path partition plate 13 to form a parallel flow in the second flow path partition plate 13.
- a part of the flow passes through the catalytic combustion section 5 after forming a flow parallel to the radiation heat receiving section 9.
- the upstream temperature of the catalytic combustion section 5 is from 600 ° C to 900 ° C, and the downstream temperature is
- Most of the radiant heat from the downstream side of the catalytic combustion section 5 is received by the second flow path partition plate 13 disposed in the vicinity, and then the heat exchange section is received in the same manner as when the heat is received by the radiant heat receiving section 9.
- the heat is transmitted through the heat medium flow path 7 to the heat medium flowing through the heat medium flow path 7 via the heat medium flow path support portion 8.
- the combustion exhaust gas flows into the space downstream of the second flow path partition plate 13 from the opening 15 of the second flow path partition plate (in the back of the drawing), and flows parallel to the convection heat transfer section 10.
- heat exchange is performed by repeating contact with the convection heat transfer section 10, and the temperature is reduced from 50 ° C. to 200 ° C., and finally discharged from the exhaust port 4.
- the flow direction of the air-fuel mixture is determined by the upstream surface and the downstream surface of the catalytic combustion unit 5, that is, the surface of the radiation heat receiving unit 9, the convection heat transfer unit.
- the heat exchange unit 3 can be manufactured by extrusion as in the first embodiment.
- the convection heat transfer section 10 also on the most downstream surface of the heat exchange section 3, and the heat transfer area is increased. For this reason, it is possible to realize a low-cost, high-mass productivity, and high heat exchange efficiency catalytic combustion device.
- the second flow path partition plate 13 integrated with the heat exchange section 3 near the downstream surface of the catalytic combustion section 5, in addition to heat transfer by convection, radiation from the downstream side is achieved. Since most of the radiated heat can be received, a catalytic combustion device with high heat exchange efficiency can be realized.
- liquid fuel may be used if a vaporizer for liquid fuel is provided, and the same effect as described above can be obtained.
- the heat medium flow path 7 may be embedded inside the heat exchange unit 3 and may be disposed outside or inside the heat exchange unit 3 to obtain the same effect as above. Is something that can be done.
- the catalytic combustion unit 5 is disposed via the heat exchange unit 3 and a ceramic sealing material having expandability in a high temperature range.
- a ceramic sealing material having expandability in a high temperature range.
- the heat exchange section side plate 11 is made of a metal material having a high heat ray reflectance, or when the inner surface of the heat exchange section 3 is covered with a heat-resistant black paint having a heat ray absorption rate of about 1
- a catalytic combustion device with higher heat exchange efficiency.
- a third embodiment of the present invention will be described.
- the basic configuration is Same as Embodiment 1, except that a vaporization section for liquid fuel is installed upstream of the catalytic combustion section 5, and heat is applied to the inner surface of the heat exchange section 3 between the catalytic combustion section 5 and the vaporization section.
- the difference is that a tar suppression plate made of a material having a small thermal conductivity is installed in the exchange unit 3. Therefore, the description will focus on this difference.
- FIG. 3 is a perspective view of the third embodiment.
- 16 is a liquid fuel vaporization section
- 17 is a tar suppression plate, which is made of a material having a lower thermal conductivity than the base material of the heat exchange section 3.
- Reference numeral 18 denotes a current plate.
- the fuel here, kerosene is used
- the fuel jetted to the vaporizer 16 where it is vaporized. Further, it collides with the current plate 18, is mixed with air, and is supplied to the catalytic combustion section 5.
- the upstream temperature of the catalytic combustion section 5 changes from 600 ° C. to 900 ° C.
- the downstream temperature changes from 350 ° C. to 65 ° C.
- radiant heat is received on the upstream side of the catalytic combustion section 5.
- the temperature at this tip is about 60 ° C, and the vaporized liquid fuel is re-condensed, which is a condition in which tar easily adheres.
- the surface temperature is 160 °. It rises to the vicinity of C, and it becomes possible to suppress the adhesion of tar.
- a tar suppression plate support 171 which protrudes toward the heat exchange unit 3, is installed on the tar suppression plate 17, and the tar suppression plate 17 and the heat exchange unit 3 are connected to each other. Or, by using the line contact, the surface temperature of the tar suppressing plate 17 can be further increased, and the tar can be made harder to adhere.
- the inner surface of the heat exchange section 3 between the catalytic combustion section 5 and the gasification section 16 also has By installing a tar suppression plate 17 made of a material with a lower thermal conductivity than the base material of the heat exchange section 3 It is possible to provide a catalytic combustion device excellent in comfort and safety without fear of generating odor due to tar adhesion or ignition due to accumulated tar.
- the heat medium flow path 7 is embedded inside the heat exchange section 3, but may be arranged outside or inside the heat exchange section 3, and the same as above. An effect can be obtained.
- the catalyst support section 6 is formed in a line contact with the catalyst combustion section 5 and is sealed at the line contact section. It may be arranged via the replacement part 3 and a ceramic sealing material having expandability in a high temperature range, and the same effect as described above can be obtained.
- the present invention has been described with respect to the example in which the present invention is applied to the catalytic combustion apparatus for gas and liquid fuel.
- the present invention is not limited to this. That is, the following cases are also included in the present invention.
- gas fuel supplied to a pipe or liquid fuel such as kerosene can be used.
- gas fuel supplied at a high pressure such as liquefied gas fuel supplied from a fuel tank
- an air supply means such as a blower fan.
- a means for sucking and introducing air by using is added.
- a means for vaporizing the liquid fuel is added.
- a ceramic honeycomb is used for the carrier of the catalytic combustion section
- the material and the shape are not limited as long as it has a plurality of communication holes through which a mixture can flow.
- Sintered metal, metal honeycomb, metal non-woven fabric, braided ceramic fiber, etc. can be used.
- the shape is not limited to a flat plate, but depends on the workability and application of the material, such as a curved shape, a tubular shape, or a corrugated shape. Can be set arbitrarily.
- a noble metal such as platinum, palladium, and rhodium is generally used, but a mixture of these metals, another metal, an oxidized product thereof, and a mixed composition thereof are also used. Well, it is possible to select the active ingredient according to the fuel type and use conditions.
- the frame can be manufactured by extrusion molding.
- the catalyst combustion section can be easily positioned, and the seal configuration between the heat exchange section and the catalytic combustion section can be simple. Therefore, it is possible to increase the production efficiency during manufacturing. Therefore, it is possible to realize a catalytic combustion device with low mass production and high productivity.
- the end face of the heat exchange section has a detachable heat exchange section side plate, if an abnormal state such as deterioration or cracking of the catalytic combustion section is detected, the heat exchange section side plate is attached and detached. Only the catalytic combustion section can be replaced. For this reason, it is possible to realize a catalytic combustion device that is easy to maintain. Furthermore, it is also possible to recover platinum group noble metals from the replaced catalytic combustion section, which can realize a catalytic combustion apparatus with excellent recyclability.
- the first flow path partition plate and the second flow path partition are arranged such that the flow direction of the air-fuel mixture is substantially parallel to the upstream and downstream surfaces of the catalytic combustion section, that is, the radiant heat receiving section and the convective heat transfer section.
- the plates are arranged, the amount of heat transferred to the radiant heat receiving portion and the convective heat transfer portion is increased, and the heat exchange portion can be manufactured by extrusion.
- the second flow path partition plate integrated with the heat exchange section is located near the downstream surface of the catalytic combustion section. In the case of being placed nearby, in addition to heat transfer by convection, most of the radiant heat from the downstream side can be received, so that a catalytic combustion device with high heat exchange efficiency can be realized. In addition, since the mechanical strength of the heat exchange part is also increased, the strength against impacts such as dropping during transportation is improved, and the yield during mass production can be expected to be improved. Therefore, it is possible to realize a catalytic combustion device having high mass productivity.
- the heat conductivity between the catalytic combustion section and the gaseous section inside the heat exchange section is higher than that of the base material of the heat exchange section.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Spray-Type Burners (AREA)
- Gas Burners (AREA)
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/258,366 US6669469B2 (en) | 2001-02-21 | 2002-02-20 | Catalyst combustion device and method of producing frame body portion thereof |
JP2002566174A JPWO2002066894A1 (ja) | 2001-02-21 | 2002-02-20 | 触媒燃焼装置およびその枠体部分の製造方法 |
EP02703854A EP1367322A1 (en) | 2001-02-21 | 2002-02-20 | Catalyst combustion device and method of producing frame body portion thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001044727 | 2001-02-21 | ||
JP2001-44727 | 2001-02-21 |
Publications (1)
Publication Number | Publication Date |
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WO2002066894A1 true WO2002066894A1 (fr) | 2002-08-29 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/001442 WO2002066894A1 (fr) | 2001-02-21 | 2002-02-20 | Dispositif de combustion catalytique et procede de fabrication d'une partie de chassis du dispositif |
Country Status (6)
Country | Link |
---|---|
US (1) | US6669469B2 (ja) |
EP (1) | EP1367322A1 (ja) |
JP (1) | JPWO2002066894A1 (ja) |
KR (1) | KR100541489B1 (ja) |
CN (1) | CN1217127C (ja) |
WO (1) | WO2002066894A1 (ja) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100570291B1 (ko) * | 2004-10-13 | 2006-04-11 | 주식회사 경동보일러 | 보일러/급탕기용 공용열교환기 |
WO2007123776A2 (en) * | 2006-03-31 | 2007-11-01 | The Trustees Of Columbia University In The City Of New York | Methods and systems for gasifying a process stream |
WO2008101483A1 (de) * | 2007-02-21 | 2008-08-28 | Cella, Fred | Wärmetauscheranordnung |
WO2011002714A1 (en) * | 2009-06-29 | 2011-01-06 | W.C. Bradley Co. | Single cavity radiant cooking apparatus |
KR101883502B1 (ko) | 2011-11-22 | 2018-07-30 | 엘지전자 주식회사 | 횡류팬 및 공기 조화기 |
US9768458B2 (en) * | 2012-08-31 | 2017-09-19 | Toyota Jidosha Kabushiki Kaisha | Control device of fuel cell, fuel cell system and control method of fuel cell |
CN105782962A (zh) * | 2016-03-04 | 2016-07-20 | 常州市蓝博净化科技有限公司 | 一种催化燃烧节能供热*** |
JP6972754B2 (ja) * | 2017-08-10 | 2021-11-24 | スズキ株式会社 | 内燃機関の排気構造 |
Citations (5)
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JPS57101207A (en) * | 1980-12-12 | 1982-06-23 | Matsushita Electric Ind Co Ltd | Catalytic combustion type hot air fan |
JPS62299610A (ja) * | 1986-06-20 | 1987-12-26 | Saamomitsuku:Kk | 赤外線複合放射スト−ブ |
JPH07190646A (ja) * | 1993-12-27 | 1995-07-28 | Showa Alum Corp | 冷暖房装置用熱交換器 |
EP0716263A2 (en) * | 1994-12-06 | 1996-06-12 | Matsushita Electric Industrial Co., Ltd. | Combustion apparatus |
JPH09280517A (ja) * | 1996-04-17 | 1997-10-31 | Matsushita Electric Ind Co Ltd | 触媒燃焼装置 |
Family Cites Families (14)
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JPS5747119A (en) * | 1980-09-05 | 1982-03-17 | Matsushita Electric Ind Co Ltd | Catalytic combustor |
JPS59167616A (ja) * | 1983-03-15 | 1984-09-21 | Matsushita Electric Ind Co Ltd | 気化式灯油燃焼装置 |
JPS59180209A (ja) * | 1983-03-29 | 1984-10-13 | Matsushita Electric Ind Co Ltd | 気化式灯油燃焼装置 |
JPS6066005A (ja) * | 1983-09-21 | 1985-04-16 | Matsushita Electric Ind Co Ltd | 気化式液体燃料燃焼装置 |
JPH05306808A (ja) * | 1990-05-10 | 1993-11-19 | Toshiba Corp | 触媒燃焼装置 |
JPH06221513A (ja) * | 1993-01-29 | 1994-08-09 | Matsushita Electric Ind Co Ltd | 触媒燃焼装置 |
JPH08100908A (ja) | 1994-09-30 | 1996-04-16 | Toshiba Corp | 触媒燃焼装置 |
DE4438356C2 (de) * | 1994-10-27 | 1997-04-30 | Ruhrgas Ag | Verfahren und Vorrichtung zur zweistufigen Verbrennung von gas- oder dampfförmigem Brennstoff |
JP3657675B2 (ja) | 1994-12-06 | 2005-06-08 | 松下電器産業株式会社 | 燃焼装置 |
EP0798512B1 (en) * | 1996-03-25 | 2005-02-16 | Matsushita Electric Industrial Co., Ltd. | Combustion apparatus |
JPH1151333A (ja) * | 1997-08-01 | 1999-02-26 | Matsushita Electric Ind Co Ltd | 触媒燃焼装置 |
JPH11182869A (ja) | 1997-12-22 | 1999-07-06 | Matsushita Electric Ind Co Ltd | 触媒燃焼装置 |
JP2000146298A (ja) | 1998-11-13 | 2000-05-26 | Matsushita Electric Ind Co Ltd | 触媒燃焼装置 |
JP3466103B2 (ja) * | 1999-03-16 | 2003-11-10 | 松下電器産業株式会社 | 触媒燃焼装置 |
-
2002
- 2002-02-20 CN CN028003667A patent/CN1217127C/zh not_active Expired - Fee Related
- 2002-02-20 JP JP2002566174A patent/JPWO2002066894A1/ja active Pending
- 2002-02-20 WO PCT/JP2002/001442 patent/WO2002066894A1/ja not_active Application Discontinuation
- 2002-02-20 KR KR1020027014108A patent/KR100541489B1/ko not_active IP Right Cessation
- 2002-02-20 EP EP02703854A patent/EP1367322A1/en not_active Withdrawn
- 2002-02-20 US US10/258,366 patent/US6669469B2/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57101207A (en) * | 1980-12-12 | 1982-06-23 | Matsushita Electric Ind Co Ltd | Catalytic combustion type hot air fan |
JPS62299610A (ja) * | 1986-06-20 | 1987-12-26 | Saamomitsuku:Kk | 赤外線複合放射スト−ブ |
JPH07190646A (ja) * | 1993-12-27 | 1995-07-28 | Showa Alum Corp | 冷暖房装置用熱交換器 |
EP0716263A2 (en) * | 1994-12-06 | 1996-06-12 | Matsushita Electric Industrial Co., Ltd. | Combustion apparatus |
JPH09280517A (ja) * | 1996-04-17 | 1997-10-31 | Matsushita Electric Ind Co Ltd | 触媒燃焼装置 |
Also Published As
Publication number | Publication date |
---|---|
EP1367322A1 (en) | 2003-12-03 |
KR100541489B1 (ko) | 2006-01-11 |
US20030157448A1 (en) | 2003-08-21 |
JPWO2002066894A1 (ja) | 2004-06-24 |
CN1457417A (zh) | 2003-11-19 |
US6669469B2 (en) | 2003-12-30 |
KR20020089515A (ko) | 2002-11-29 |
CN1217127C (zh) | 2005-08-31 |
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