US20200056306A1 - Apparatus for manufacturing carbon fiber by using microwaves - Google Patents
Apparatus for manufacturing carbon fiber by using microwaves Download PDFInfo
- Publication number
- US20200056306A1 US20200056306A1 US16/346,011 US201716346011A US2020056306A1 US 20200056306 A1 US20200056306 A1 US 20200056306A1 US 201716346011 A US201716346011 A US 201716346011A US 2020056306 A1 US2020056306 A1 US 2020056306A1
- Authority
- US
- United States
- Prior art keywords
- precursor
- microwaves
- carbonization
- carbon fiber
- heating body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 45
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 45
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 238000003763 carbonization Methods 0.000 claims abstract description 83
- 239000002243 precursor Substances 0.000 claims abstract description 59
- 238000010438 heat treatment Methods 0.000 claims description 84
- 238000000034 method Methods 0.000 abstract description 24
- 239000000835 fiber Substances 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 9
- 230000006641 stabilisation Effects 0.000 description 8
- 238000011105 stabilization Methods 0.000 description 8
- 229920002239 polyacrylonitrile Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 5
- 230000009257 reactivity Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010000 carbonizing Methods 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/32—Apparatus therefor
- D01F9/322—Apparatus therefor for manufacturing filaments from pitch
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
- D01F9/225—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles from stabilised polyacrylonitriles
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/32—Apparatus therefor
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/003—Treatment with radio-waves or microwaves
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
Definitions
- the present invention relates to an apparatus for manufacturing carbon fiber by using microwaves. More particularly, the present invention relates to an apparatus and techniques for manufacturing carbon fiber by using microwaves which directly or indirectly heats and carbonizes a carbon fiber precursor, so that energy efficiency is improved because an entirety of a carbonization furnace is not heated, and a property of the precursor is adjusted by a simpler method by the microwaves.
- Carbon fiber can be obtained by pyrolyzing an organic precursor material in the form of fiber manufactured from polyacrylonitrile (PAN), pitch that is a petroleum-based/coal-based hydrocarbon residue, or rayon that is a carbon material of a fiber sheet in which a mass content of carbon elements is 90% or more, in an inert atmosphere.
- PAN polyacrylonitrile
- pitch that is a petroleum-based/coal-based hydrocarbon residue
- rayon that is a carbon material of a fiber sheet in which a mass content of carbon elements is 90% or more
- the carbon fiber is lighter than steel and has excellent strength, so that the carbon fiber is widely applied to various fields, such as the automotive field, the aerospace field, the wind power generation field, and the sports field.
- various fields such as the automotive field, the aerospace field, the wind power generation field, and the sports field.
- environmental regulations related to exhaust gas of a vehicle have been tightened due to environmental concerns, so that a light vehicle having high efficiency has been in increasing demand.
- a method of decreasing weight of a vehicle without sacrificing structural and mechanical strength, by using a carbon fiber reinforced composites has attracted attention.
- a process of carbonizing carbon fiber in the related art is performed by heat treatment at a high temperature of 1,000° C. to 1,500° C. by using an electric carbonization furnace.
- the electric carbonization furnace is generally divided into two or more heat zones including a heat zone for a low temperature and a heat zone for a high temperature.
- the carbonization process using the electric carbonization furnace has a scheme in which heat is transmitted to carbon fiber by an internal temperature of the carbonization furnace or heat moves in a direction from an outer side to an inner side of the fiber, so that there is a problem in that energy efficiency is not high.
- the carbonization process in the related art is a scheme in which the entirety of the carbonization furnace is heated in order to increase an internal temperature of the carbonization furnace, and a temperature of a heating furnace needs to be maintained higher than a carbonization temperature of a precursor, so there is a problem in that heat resistance is required.
- the present invention is conceived to solve the foregoing problems, and an object of the present invention is to provide an apparatus for manufacturing carbonized fiber using microwaves, which includes a carbonization furnace that directly heats a precursor by using microwaves in order to improve energy efficiency.
- Another object of the present invention is to provide an apparatus for manufacturing carbonized fiber using microwaves, which includes a heating body heated by microwaves inside a main body of a carbonization furnace in order to carbonize stabilized fiber having low reactivity to microwaves and increase energy efficiency for heating compared to a carbonization process of heating an entirety of a carbonization furnace in the related art.
- An apparatus for manufacturing carbonized fiber by using microwaves includes: a heat treatment furnace which stabilizes a precursor; and a carbonization furnace which is positioned at one side of the heat treatment furnace and carbonizes the stabilized precursor, in which the carbonization furnace carbonizes the precursor by using microwaves as a heat source.
- the carbonization furnace may include: a main body; a micro emitting unit which is positioned inside or outside the main body, and emits microwaves to the stabilized precursor; and a heating body which is positioned inside the main body and is heated by the microwaves.
- the heating body may occupy 0.1% to 5% of a volume of the main body.
- One or more carbonization furnaces may be positioned at one side of the heat treatment furnace.
- a continuous process may be performed by using rollers positioned at one side and the other side of each of the heat treatment furnace and the carbonization furnace.
- the carbonization furnace may have a carbonization temperature of 400° C. to 1,500° C.
- the carbonization furnace includes the emitting unit that emits microwaves inside or outside thereof and directly/indirectly heats the fiber passing the stabilization fiber to increase a carbonization speed of carbon fiber, so that the carbon fiber is obtained within a short time, thereby achieving increased energy efficiency.
- the carbonization furnace includes the heating body therein, so that there is no limit in the kind of precursor used for manufacturing the carbonized fiber, and the precursor is indirectly heated while the entirety of the carbonization furnace is not heated, thereby achieving increased energy efficiency compared to the carbonization process in the related art.
- FIG. 1 is a cross-sectional view of a carbon fiber manufacturing apparatus using microwaves according to an exemplary embodiment of the present invention.
- FIG. 2 is a cross-sectional view of a carbonization furnace according to the exemplary embodiment of the present invention.
- FIG. 3 is a perspective view of a heating body according to the exemplary embodiment of the present invention.
- FIG. 1 is a cross-sectional view of a carbon fiber manufacturing apparatus 100 using microwaves according to an exemplary embodiment of the present invention.
- the carbon fiber manufacturing apparatus 100 using the microwaves may include a heat treatment furnace 10 and a carbonization furnace 20 , and a process may be continuously performed by rollers positioned at one side and the other side of each of the heat treatment furnace 10 and the carbonization furnace 20 .
- the heat treatment furnace 10 is configured to stablilize a precursor, and may serve to make the precursor be in contact with air and oxidize the precursor.
- the process of stabilizing the precursor is a process of insolubilizing the precursor so as to have flame resistance when the precursor is carbonized.
- the stabilization of the precursor may provide an inner side of the heat treatment furnace 10 with an air atmosphere, and heat treat the precursor at a temperature of 200° C. to 300° C. for one to two hours to stabilize a fiber structure of the precursor. In this case, when a stabilization reaction of the precursor progresses, the stabilization may sharply progress, so that it is noted that the temperature is increased to 200° C. to 300° C. by stages. When the stabilization condition of the precursor is 200° C.
- the precursor may be formed of a composition of any one of a rayon-series material, a pitch-series material, a polyacrylonitrile-series material, and a cellulose-series material.
- the carbonization furnace 20 is configured to carbonize the stabilized precursor, and may carbonize the precursor by using microwaves as a heat source. During the carbonization process, the carbonization furnace may carbonize the precursor at a temperature of 400° C. to 1,500° C., and in this case, the carbonization process may be divided into low-temperature carbonization and high-temperature carbonization. The low-temperature carbonization may carbonize the precursor at a temperature of 400° C. to 900° C., and the high-temperature carbonization process may carbonize the precursor at a temperature of 900° C. to 1,500° C.
- the carbonization furnace 20 may be positioned at one side of the heat treatment furnace 10 , and may include a main body 21 and a micro emitting unit 22 for carbonizing the stabilized precursor.
- the main body 21 may mean a space in which a temperature is increased by the micro emitting unit 22 which is to be described below.
- the micro emitting unit 22 may be installed outside or inside an outer circumference surface of the main body and serve to emit microwaves onto the stabilized precursor.
- an energy intensity (output), an energy emission time, and the like, of the microwaves according to the present invention the carbon fiber having a required property may be irradiated with a high yield within a shorter reaction time.
- the carbonization furnace 20 according to the present invention may carbonize the precursor by directly heating the stabilized precursor by the microwaves to manufacture the carbon fiber.
- the microwaves directly heat the precursor without heating the main body unlike the carbonization technology in the related art, thereby achieving an advantage in that energy efficiency is improved compared to the carbonization process in the related art.
- FIG. 2 is a cross-sectional view of the carbonization furnace 20 according to the exemplary embodiment of the present invention
- FIG. 3 is a perspective view of a heating body 23 according to the exemplary embodiment of the present invention.
- the carbonization furnace 20 according to the present invention may further include the heating body 23 .
- the heating body 23 may be positioned inside the main body 21 , and is directly heated by the microwaves emitted from the micro emitting unit 22 to serve to indirectly carbonize the precursor. Further, the heating body may be formed of a composition of any one of silicon carbide, silicon, a metal silicide, carbon, and a carbon fiber composite material.
- the main body 21 is the configuration including any one or more of the micro emitting unit 22 and the heating body 23 , and it is noted that the configurations, such as a manipulating unit and an operating unit, additionally configurable in the carbonization process are not included inside the main body 21 .
- the main body 21 may be formed at a position with a size in which only the heating body 23 may be included.
- the heating body 23 is formed with an inlet through which the precursor enters and an outlet through which the carbon fiber formed by carbonizing the precursor is discharged.
- the inner side of the heating body 23 may be provided with an atmosphere of gas, such as nitrogen, argon, and helium or mixed gas thereof, and preferably, the carbonization process may be formed in a nitrogen atmosphere.
- the precursor stabilized in the heat treatment furnace 10 may be inserted into the heating body 23 in the nitrogen atmosphere, the heating body 23 is heated to a temperature of 400° C. to 1,500° C. by the microwaves emitted by the micro emitting unit 22 , and then, the precursor may be indirectly heated by radiant heat of the heating body 23 .
- the carbonization furnace 20 carbonizes the precursor by using the indirect heating, thereby achieving an advantage in that even the stabilized fiber having low reactivity to the microwaves may be carbonized, and achieving an effect in that it is possible to improve a property and energy efficiency of the manufactured carbon fiber according to a structure and a volume of the heating body 23 .
- the form of the heating body 23 is not limited.
- the volume of the heating body 23 exceeds 5%, a large amount of microwaves needs to be emitted for heating the heating body 23 , and a temperature inside the carbonization furnace 20 is not increased and tensile strength and modulus of the carbon fiber are decreased, so that there may be a problem in that energy efficiency of the carbonization process is decreased.
- FIG. 3 illustrates an example of the form of the heating body 23 according to the present invention.
- a structure of the heating body 23 may have a shape of any one of a plate and a hollow column structure.
- the heating body 23 may be formed of only one surface or two upper and lower surfaces. Further, the heating body 23 may be formed of three surfaces including any one of upper/lower/right surfaces and upper/lower/left surfaces.
- one or more holes may be formed in a part of the plate, and the hole may have a form of any one of a circle, a polygon, and an ellipse, but it is noted that the form of the hole is not limited. Further, according to some exemplary embodiments, the heating body 23 may be provided in a plate shaped like a net.
- the heating body 23 may have the form of a hollow column and a cross section of the column may have the form of any one of a circle, a quadrangle, a polygon, and an ellipse, but it is noted that the form of the cross section of the column of the heating body is not limited.
- the surface forming the shape may be formed with one or more holes, and the hole may have the form of any one of a circle, a polygon, and an ellipse, but it is noted that the form of the hole is not limited thereto.
- a space in which the precursor is accommodated may be divided into two or more spaces, and an inlet through which the precursor enters and an outlet through which the precursor is taken out may be formed in the divided spaces, respectively.
- the division of the accommodation space of the precursor in the heating body 23 complexly enables the direct heating and the indirect heating of the precursor and increases a movement distance of the precursor, so that the precursor is irradiated by the microwaves or the radiant heat of the heating body for a long time and is carbonized and graphitized, thereby minimizing external and internal temperature gradients and achieving an effect in that a generation of a crack in the carbon fiber is decreased.
- the carbonization furnace 20 may further include a chamber (not illustrated) including all of the main body 21 , the micro emitting unit 22 , and the heating body 23 inside thereof.
- the chamber may be positioned outside the main body 21 , and when the chamber may further include the configuration, for example, a manipulating unit and an operating unit, required for the carbonization of the precursor, in addition to the main body 21 , the micro emitting unit 22 , and the heating body 23 , a shape and a size of the chamber are not limited.
- one or more carbonization furnaces 20 may be positioned at one side of the heat treatment furnace 10 .
- One or more carbonization furnaces 20 are serially connected, so that a movement distance of the precursor within the carbonization furnace 20 is increased and the precursor is irradiated by the microwaves for a long time and is carbonized or graphitized to manufacture carbon fiber.
- One or more carbonization furnaces 20 are serially connected, so that only the outer surface of the precursor is heated by the high-temperature microwave radiant heat in a moment and the inner side of the precursor is not heated, thereby solving the problem in that a large temperature gradient between the inner side and the outer side is generated.
- Tensile strength and modulus were compared by using carbon fiber manufactured by using a carbonization furnace including a heating body having a volume of about 8% of a volume of a main body and the carbon fiber manufactured by using the carbonization furnace including the heating body having a volume of about 0.1% to 5% of a volume of the main body according to the exemplary embodiment of the present invention.
- Example 1 polyacrylonitrile fiber was prepared as a precursor and was heat treated in an air atmosphere at a temperature of 280° C. for two hours.
- Comparative Example 1 stabilized polyacrylonitrile fiber was inserted into a carbonization furnace including a heating body having a volume corresponding to about 8% of a volume of a main body and then a carbonization process was performed in a nitrogen atmosphere at a temperature of 800° C. to 1,500° C. for 20 minutes or longer. In this case, applied power of microwaves was set to 1.2 kW.
- Example 1 stabilized polyacrylonitrile fiber was inserted into a carbonization furnace including a heating body having a volume corresponding to about 0.13% of a volume of a main body and then a carbonization process was performed in a nitrogen atmosphere at a temperature of 800° C. to 1,500° C. within one minute. In this case, applied power of microwaves was set to 1 kW. Further, in Example 2, stabilized polyacrylonitrile fiber was inserted to a carbonization furnace including a heating body having a volume corresponding to about 1.8% of a volume of a main body and then a carbonization process was performed in a nitrogen atmosphere at a temperature of 800° C. to 1,500° C. within five minutes, and applied power of microwaves was set to 1.8 kW.
- tensile strength and elasticity of one string of the fiber were repeatedly measured by about 50 times using a Favimat tester and an average of the measured tensile strength and elasticity were calculated.
- Example 2 Example 1 Carbon Volume (%) of 0.13 1.8 8.6 condition heating body Applied power 1 1.8 1.2 (kW) Time (min) 1 ⁇ 5 >20 Carbon Tensile >2.5 >2.5 ⁇ 1.5 fiber strength property Modulus >190 >180 ⁇ 90
- Comparative Example 1 20 minutes or longer are required for increasing a temperature of the heating body to 800° C. to 1,500° C., and due to the large volume of the heating body and the long heating time, the tensile strength of the carbon fiber was measured to be 1.5 or less and modulus of the carbon fiber was measured at 90 or less. Accordingly, it can be seen that when the volume of the heating body is large, elasticity of the manufactured carbon fiber is inadequate, and energy efficiency of the production of the carbon fiber is degraded.
- Example 1 In order to increase a temperature of the heating body to 800° C. to 1,500° C., one minute is required in Example 1 and five minutes or less is required in Example 2. In this case, tensile strength and modulus of the carbon fiber of Example 1 and Example 2 are 2.5 or more and 190 or more, so that it can be seen that elasticity of the carbon fiber is excellent, and energy efficiency improved.
- the volume of the heating body is closely related to the properties of the carbon fiber and the energy efficiency of its production.
- the heating body is heated evenly by a small output of the microwaves within a short time, so that the tensile strength and the modulus of the carbon fiber are increased.
- Example 3 that is the carbonization furnace including the heating body having the volume of 0.1% to 5% of the volume of the main body according to the exemplary embodiment of the present invention.
- the heating body of Example 3 includes silicon carbide (SiC) having a volume corresponding to about 0.13% of a volume of a main body.
- the carbonization furnaces of Comparative Example 2 and Example 3 have the same size, and a time at which an internal temperature of the carbonization furnace reaches 1,000° C. by applying microwaves of 1.2 kW was measured.
- Example 2 the carbonization furnace has a temperature lower than 300° C. even after ten minutes, but in Example 3, the carbonization furnace reaches a temperature of 1,000° C. after two minutes.
- the carbonization furnace fails to reach the temperature at which the stabilized fiber becomes fiber having high reactivity to microwaves, and in Example 3, the temperature inside the carbonization furnace reaches a temperature region in which fiber having high reactivity to microwaves is manufactured by only the heating body within a short time, so that it is possible to effectively manufacture carbonized fiber.
- the stabilized fiber when the stabilized fiber passing the stabilization operation in the heat treatment furnace moves to the carbonization furnace, the stabilized fiber enters the region in which the stabilized fiber has high reactivity to the microwaves at a high speed by an increase in a temperature of the heating body, so that energy efficiency is improved and a carbonization property of the carbon fiber is adjusted by a simpler method by the use of microwaves.
Abstract
Description
- The present application is a National Stage entry of International Application No. PCT/KR2017/015018, filed Dec. 19, 2017, and claims priority to and the benefit of Korean Patent Application No. 10-2016-0173883 filed in the Korean Intellectual Property Office on Dec. 19, 2016, the entire contents of which are incorporated herein by reference.
- The present invention relates to an apparatus for manufacturing carbon fiber by using microwaves. More particularly, the present invention relates to an apparatus and techniques for manufacturing carbon fiber by using microwaves which directly or indirectly heats and carbonizes a carbon fiber precursor, so that energy efficiency is improved because an entirety of a carbonization furnace is not heated, and a property of the precursor is adjusted by a simpler method by the microwaves.
- Carbon fiber can be obtained by pyrolyzing an organic precursor material in the form of fiber manufactured from polyacrylonitrile (PAN), pitch that is a petroleum-based/coal-based hydrocarbon residue, or rayon that is a carbon material of a fiber sheet in which a mass content of carbon elements is 90% or more, in an inert atmosphere.
- The carbon fiber is lighter than steel and has excellent strength, so that the carbon fiber is widely applied to various fields, such as the automotive field, the aerospace field, the wind power generation field, and the sports field. For example, recently, environmental regulations related to exhaust gas of a vehicle have been tightened due to environmental concerns, so that a light vehicle having high efficiency has been in increasing demand. Thus, a method of decreasing weight of a vehicle without sacrificing structural and mechanical strength, by using a carbon fiber reinforced composites has attracted attention.
- However, since carbon fiber is expensive, the commercialization of carbon fiber is limited, and thus, there is an urgent demand for a development of a technology for mass producing carbon fiber having high performance at low cost.
- A process of carbonizing carbon fiber in the related art is performed by heat treatment at a high temperature of 1,000° C. to 1,500° C. by using an electric carbonization furnace. The electric carbonization furnace is generally divided into two or more heat zones including a heat zone for a low temperature and a heat zone for a high temperature. The carbonization process using the electric carbonization furnace has a scheme in which heat is transmitted to carbon fiber by an internal temperature of the carbonization furnace or heat moves in a direction from an outer side to an inner side of the fiber, so that there is a problem in that energy efficiency is not high.
- Further, the carbonization process in the related art is a scheme in which the entirety of the carbonization furnace is heated in order to increase an internal temperature of the carbonization furnace, and a temperature of a heating furnace needs to be maintained higher than a carbonization temperature of a precursor, so there is a problem in that heat resistance is required.
- In relation to this, there is a need for a process of carbonizing carbon fiber having high energy efficiency.
- The present invention is conceived to solve the foregoing problems, and an object of the present invention is to provide an apparatus for manufacturing carbonized fiber using microwaves, which includes a carbonization furnace that directly heats a precursor by using microwaves in order to improve energy efficiency.
- Another object of the present invention is to provide an apparatus for manufacturing carbonized fiber using microwaves, which includes a heating body heated by microwaves inside a main body of a carbonization furnace in order to carbonize stabilized fiber having low reactivity to microwaves and increase energy efficiency for heating compared to a carbonization process of heating an entirety of a carbonization furnace in the related art.
- An apparatus for manufacturing carbonized fiber by using microwaves according to the present invention includes: a heat treatment furnace which stabilizes a precursor; and a carbonization furnace which is positioned at one side of the heat treatment furnace and carbonizes the stabilized precursor, in which the carbonization furnace carbonizes the precursor by using microwaves as a heat source.
- The carbonization furnace may include: a main body; a micro emitting unit which is positioned inside or outside the main body, and emits microwaves to the stabilized precursor; and a heating body which is positioned inside the main body and is heated by the microwaves.
- The heating body may occupy 0.1% to 5% of a volume of the main body.
- One or more carbonization furnaces may be positioned at one side of the heat treatment furnace.
- A continuous process may be performed by using rollers positioned at one side and the other side of each of the heat treatment furnace and the carbonization furnace.
- The carbonization furnace may have a carbonization temperature of 400° C. to 1,500° C.
- According to the present invention, the carbonization furnace includes the emitting unit that emits microwaves inside or outside thereof and directly/indirectly heats the fiber passing the stabilization fiber to increase a carbonization speed of carbon fiber, so that the carbon fiber is obtained within a short time, thereby achieving increased energy efficiency.
- Further, the carbonization furnace includes the heating body therein, so that there is no limit in the kind of precursor used for manufacturing the carbonized fiber, and the precursor is indirectly heated while the entirety of the carbonization furnace is not heated, thereby achieving increased energy efficiency compared to the carbonization process in the related art.
-
FIG. 1 is a cross-sectional view of a carbon fiber manufacturing apparatus using microwaves according to an exemplary embodiment of the present invention. -
FIG. 2 is a cross-sectional view of a carbonization furnace according to the exemplary embodiment of the present invention. -
FIG. 3 is a perspective view of a heating body according to the exemplary embodiment of the present invention. - The present invention will be described in detail with reference to the accompanying drawings. Herein, repeated and detailed description of publicly known functions and configurations which may unnecessarily make the main point of the present invention unclear will be omitted. The exemplary embodiments of the present invention are provided for more completely explaining the present invention to those skilled in the art. Accordingly, shapes, sizes, and the like of the elements in the drawings may be exaggerated for clarity of the description.
- In the entire specification, unless explicitly described to the contrary, when it is said that a part “comprises/includes” a constituent element, this means that another constituent element may be further “included/comprised”, not that another constituent element is excluded.
- Hereinafter, an exemplary embodiment is presented for helping understanding of the present invention. However, the exemplary embodiment below is simply provided for more easy understanding of the present invention, and the contents of the present invention are not limited by the exemplary embodiment.
- <Carbon Fiber Manufacturing Apparatus Using Microwave>
-
FIG. 1 is a cross-sectional view of a carbonfiber manufacturing apparatus 100 using microwaves according to an exemplary embodiment of the present invention. The carbonfiber manufacturing apparatus 100 using the microwaves may include aheat treatment furnace 10 and acarbonization furnace 20, and a process may be continuously performed by rollers positioned at one side and the other side of each of theheat treatment furnace 10 and thecarbonization furnace 20. - The
heat treatment furnace 10 is configured to stablilize a precursor, and may serve to make the precursor be in contact with air and oxidize the precursor. The process of stabilizing the precursor is a process of insolubilizing the precursor so as to have flame resistance when the precursor is carbonized. The stabilization of the precursor may provide an inner side of theheat treatment furnace 10 with an air atmosphere, and heat treat the precursor at a temperature of 200° C. to 300° C. for one to two hours to stabilize a fiber structure of the precursor. In this case, when a stabilization reaction of the precursor progresses, the stabilization may sharply progress, so that it is noted that the temperature is increased to 200° C. to 300° C. by stages. When the stabilization condition of the precursor is 200° C. or lower and less than one hour, there may be a problem in that oxidization and stabilization are inadequate, and when the stabilization condition of the precursor is higher than 300° C. and longer than two hours, a property of the carbonized fiber may be negatively influenced, so that there may be a problem in energy loss. - Herein, the precursor may be formed of a composition of any one of a rayon-series material, a pitch-series material, a polyacrylonitrile-series material, and a cellulose-series material.
- The
carbonization furnace 20 is configured to carbonize the stabilized precursor, and may carbonize the precursor by using microwaves as a heat source. During the carbonization process, the carbonization furnace may carbonize the precursor at a temperature of 400° C. to 1,500° C., and in this case, the carbonization process may be divided into low-temperature carbonization and high-temperature carbonization. The low-temperature carbonization may carbonize the precursor at a temperature of 400° C. to 900° C., and the high-temperature carbonization process may carbonize the precursor at a temperature of 900° C. to 1,500° C. - Further, the
carbonization furnace 20 may be positioned at one side of theheat treatment furnace 10, and may include amain body 21 and amicro emitting unit 22 for carbonizing the stabilized precursor. - The
main body 21 may mean a space in which a temperature is increased by themicro emitting unit 22 which is to be described below. - The
micro emitting unit 22 may be installed outside or inside an outer circumference surface of the main body and serve to emit microwaves onto the stabilized precursor. By adjusting an energy intensity (output), an energy emission time, and the like, of the microwaves according to the present invention, the carbon fiber having a required property may be irradiated with a high yield within a shorter reaction time. - Further, the
carbonization furnace 20 according to the present invention may carbonize the precursor by directly heating the stabilized precursor by the microwaves to manufacture the carbon fiber. In thecarbonization furnace 20 according to the present invention, the microwaves directly heat the precursor without heating the main body unlike the carbonization technology in the related art, thereby achieving an advantage in that energy efficiency is improved compared to the carbonization process in the related art. -
FIG. 2 is a cross-sectional view of thecarbonization furnace 20 according to the exemplary embodiment of the present invention, andFIG. 3 is a perspective view of aheating body 23 according to the exemplary embodiment of the present invention. Thecarbonization furnace 20 according to the present invention may further include theheating body 23. Theheating body 23 may be positioned inside themain body 21, and is directly heated by the microwaves emitted from themicro emitting unit 22 to serve to indirectly carbonize the precursor. Further, the heating body may be formed of a composition of any one of silicon carbide, silicon, a metal silicide, carbon, and a carbon fiber composite material. - In this case, the
main body 21 is the configuration including any one or more of themicro emitting unit 22 and theheating body 23, and it is noted that the configurations, such as a manipulating unit and an operating unit, additionally configurable in the carbonization process are not included inside themain body 21. According to some exemplary embodiments, themain body 21 may be formed at a position with a size in which only theheating body 23 may be included. - The
heating body 23 is formed with an inlet through which the precursor enters and an outlet through which the carbon fiber formed by carbonizing the precursor is discharged. The inner side of theheating body 23 may be provided with an atmosphere of gas, such as nitrogen, argon, and helium or mixed gas thereof, and preferably, the carbonization process may be formed in a nitrogen atmosphere. For example, the precursor stabilized in theheat treatment furnace 10 may be inserted into theheating body 23 in the nitrogen atmosphere, theheating body 23 is heated to a temperature of 400° C. to 1,500° C. by the microwaves emitted by themicro emitting unit 22, and then, the precursor may be indirectly heated by radiant heat of theheating body 23. - Herein, the
carbonization furnace 20 according to the present invention carbonizes the precursor by using the indirect heating, thereby achieving an advantage in that even the stabilized fiber having low reactivity to the microwaves may be carbonized, and achieving an effect in that it is possible to improve a property and energy efficiency of the manufactured carbon fiber according to a structure and a volume of theheating body 23. - It is noted that as long as the
heating body 23 has a volume of 0.1% to 5% of a volume of themain body 21, the form of theheating body 23 is not limited. When the volume of theheating body 23 exceeds 5%, a large amount of microwaves needs to be emitted for heating theheating body 23, and a temperature inside thecarbonization furnace 20 is not increased and tensile strength and modulus of the carbon fiber are decreased, so that there may be a problem in that energy efficiency of the carbonization process is decreased. -
FIG. 3 illustrates an example of the form of theheating body 23 according to the present invention. A structure of theheating body 23 may have a shape of any one of a plate and a hollow column structure. For example, when the structure of theheating body 23 is provided in a plate shape, one or more plates may be provided, theheating body 23 may be formed of only one surface or two upper and lower surfaces. Further, theheating body 23 may be formed of three surfaces including any one of upper/lower/right surfaces and upper/lower/left surfaces. When theheating body 23 is provided in the plate shape, one or more holes may be formed in a part of the plate, and the hole may have a form of any one of a circle, a polygon, and an ellipse, but it is noted that the form of the hole is not limited. Further, according to some exemplary embodiments, theheating body 23 may be provided in a plate shaped like a net. - Further, the
heating body 23 may have the form of a hollow column and a cross section of the column may have the form of any one of a circle, a quadrangle, a polygon, and an ellipse, but it is noted that the form of the cross section of the column of the heating body is not limited. Herein, when theheating body 23 is provided in a three-dimensional shape, the surface forming the shape may be formed with one or more holes, and the hole may have the form of any one of a circle, a polygon, and an ellipse, but it is noted that the form of the hole is not limited thereto. In this case, a space in which the precursor is accommodated may be divided into two or more spaces, and an inlet through which the precursor enters and an outlet through which the precursor is taken out may be formed in the divided spaces, respectively. The division of the accommodation space of the precursor in theheating body 23 complexly enables the direct heating and the indirect heating of the precursor and increases a movement distance of the precursor, so that the precursor is irradiated by the microwaves or the radiant heat of the heating body for a long time and is carbonized and graphitized, thereby minimizing external and internal temperature gradients and achieving an effect in that a generation of a crack in the carbon fiber is decreased. - Further, the
carbonization furnace 20 may further include a chamber (not illustrated) including all of themain body 21, themicro emitting unit 22, and theheating body 23 inside thereof. The chamber may be positioned outside themain body 21, and when the chamber may further include the configuration, for example, a manipulating unit and an operating unit, required for the carbonization of the precursor, in addition to themain body 21, themicro emitting unit 22, and theheating body 23, a shape and a size of the chamber are not limited. - Further, one or
more carbonization furnaces 20 may be positioned at one side of theheat treatment furnace 10. One ormore carbonization furnaces 20 are serially connected, so that a movement distance of the precursor within thecarbonization furnace 20 is increased and the precursor is irradiated by the microwaves for a long time and is carbonized or graphitized to manufacture carbon fiber. One ormore carbonization furnaces 20 are serially connected, so that only the outer surface of the precursor is heated by the high-temperature microwave radiant heat in a moment and the inner side of the precursor is not heated, thereby solving the problem in that a large temperature gradient between the inner side and the outer side is generated. - Tensile strength and modulus were compared by using carbon fiber manufactured by using a carbonization furnace including a heating body having a volume of about 8% of a volume of a main body and the carbon fiber manufactured by using the carbonization furnace including the heating body having a volume of about 0.1% to 5% of a volume of the main body according to the exemplary embodiment of the present invention.
- To this end, an experiment was performed on one carbon fiber product manufactured by using the carbonization furnace including the heating body having the volume of about 8% and two carbon fiber products according to the exemplary embodiment of the present invention.
- In Comparative Example 1, Example 1, and Example 2, polyacrylonitrile fiber was prepared as a precursor and was heat treated in an air atmosphere at a temperature of 280° C. for two hours.
- In Comparative Example 1, stabilized polyacrylonitrile fiber was inserted into a carbonization furnace including a heating body having a volume corresponding to about 8% of a volume of a main body and then a carbonization process was performed in a nitrogen atmosphere at a temperature of 800° C. to 1,500° C. for 20 minutes or longer. In this case, applied power of microwaves was set to 1.2 kW.
- In Example 1, stabilized polyacrylonitrile fiber was inserted into a carbonization furnace including a heating body having a volume corresponding to about 0.13% of a volume of a main body and then a carbonization process was performed in a nitrogen atmosphere at a temperature of 800° C. to 1,500° C. within one minute. In this case, applied power of microwaves was set to 1 kW. Further, in Example 2, stabilized polyacrylonitrile fiber was inserted to a carbonization furnace including a heating body having a volume corresponding to about 1.8% of a volume of a main body and then a carbonization process was performed in a nitrogen atmosphere at a temperature of 800° C. to 1,500° C. within five minutes, and applied power of microwaves was set to 1.8 kW.
- In order to compare a mechanical property after the carbonization, tensile strength and elasticity of one string of the fiber were repeatedly measured by about 50 times using a Favimat tester and an average of the measured tensile strength and elasticity were calculated.
-
TABLE 1 Comparative Example 1 Example 2 Example 1 Carbon Volume (%) of 0.13 1.8 8.6 condition heating body Applied power 1 1.8 1.2 (kW) Time (min) 1 <5 >20 Carbon Tensile >2.5 >2.5 ~1.5 fiber strength property Modulus >190 >180 ~90 - Referring to the Table above, in Comparative Example 1, 20 minutes or longer are required for increasing a temperature of the heating body to 800° C. to 1,500° C., and due to the large volume of the heating body and the long heating time, the tensile strength of the carbon fiber was measured to be 1.5 or less and modulus of the carbon fiber was measured at 90 or less. Accordingly, it can be seen that when the volume of the heating body is large, elasticity of the manufactured carbon fiber is inadequate, and energy efficiency of the production of the carbon fiber is degraded.
- In order to increase a temperature of the heating body to 800° C. to 1,500° C., one minute is required in Example 1 and five minutes or less is required in Example 2. In this case, tensile strength and modulus of the carbon fiber of Example 1 and Example 2 are 2.5 or more and 190 or more, so that it can be seen that elasticity of the carbon fiber is excellent, and energy efficiency improved.
- As a result, according to the determination based on the result, it can be seen that the volume of the heating body is closely related to the properties of the carbon fiber and the energy efficiency of its production. As the volume of the heating body is small, the heating body is heated evenly by a small output of the microwaves within a short time, so that the tensile strength and the modulus of the carbon fiber are increased.
- Temperatures were compared between Comparative Example 2, that is a carbonization furnace including no heating body, and Example 3, that is the carbonization furnace including the heating body having the volume of 0.1% to 5% of the volume of the main body according to the exemplary embodiment of the present invention. Herein, the heating body of Example 3 includes silicon carbide (SiC) having a volume corresponding to about 0.13% of a volume of a main body.
- The carbonization furnaces of Comparative Example 2 and Example 3 have the same size, and a time at which an internal temperature of the carbonization furnace reaches 1,000° C. by applying microwaves of 1.2 kW was measured.
-
TABLE 2 Comparative Example 2 Example 3 Presence of x ∘ heating body Reach time at Not reached 2 1,000° C. (minute) - Referring to the Table, it can be seen that in Comparative Example 2, the carbonization furnace has a temperature lower than 300° C. even after ten minutes, but in Example 3, the carbonization furnace reaches a temperature of 1,000° C. after two minutes.
- That is, in Comparative Example 2, the carbonization furnace fails to reach the temperature at which the stabilized fiber becomes fiber having high reactivity to microwaves, and in Example 3, the temperature inside the carbonization furnace reaches a temperature region in which fiber having high reactivity to microwaves is manufactured by only the heating body within a short time, so that it is possible to effectively manufacture carbonized fiber.
- Accordingly, when the stabilized fiber passing the stabilization operation in the heat treatment furnace moves to the carbonization furnace, the stabilized fiber enters the region in which the stabilized fiber has high reactivity to the microwaves at a high speed by an increase in a temperature of the heating body, so that energy efficiency is improved and a carbonization property of the carbon fiber is adjusted by a simpler method by the use of microwaves.
- The present invention has been described with reference to the exemplary embodiment of the present invention, but those skilled in the art may appreciate that the present invention may be variously corrected and changed within the range without departing from the spirit and the area of the present invention described in the appending claims.
Claims (6)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2016-0173883 | 2016-12-19 | ||
KR20160173883 | 2016-12-19 | ||
PCT/KR2017/015018 WO2018117594A1 (en) | 2016-12-19 | 2017-12-19 | Apparatus for manufacturing carbon fiber by using microwaves |
Publications (1)
Publication Number | Publication Date |
---|---|
US20200056306A1 true US20200056306A1 (en) | 2020-02-20 |
Family
ID=62626763
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/346,011 Pending US20200056306A1 (en) | 2016-12-19 | 2017-12-19 | Apparatus for manufacturing carbon fiber by using microwaves |
Country Status (6)
Country | Link |
---|---|
US (1) | US20200056306A1 (en) |
EP (1) | EP3556916B1 (en) |
JP (1) | JP2020513486A (en) |
KR (1) | KR102037843B1 (en) |
CN (1) | CN110073041B (en) |
WO (1) | WO2018117594A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20190233979A1 (en) * | 2018-01-29 | 2019-08-01 | Uht Unitech Company Ltd. | Fiber pre-oxidization device |
US11459673B2 (en) | 2018-07-23 | 2022-10-04 | Lg Chem, Ltd. | Carbon fiber carbonization apparatus using microwave |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020022724A1 (en) | 2018-07-23 | 2020-01-30 | 주식회사 엘지화학 | Carbon fiber carbonizing apparatus using microwave |
TWI667339B (en) * | 2018-09-06 | 2019-08-01 | 永虹先進材料股份有限公司 | High-temperature carbonization furnace |
KR102134628B1 (en) * | 2020-01-08 | 2020-07-16 | 재단법인 철원플라즈마 산업기술연구원 | Apparatus and method manufacturing carbon fiber |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4822966A (en) * | 1987-02-20 | 1989-04-18 | Yuzuru Matsubara | Method of producing heat with microwaves |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101219721B1 (en) * | 2010-12-21 | 2013-01-08 | 한국에너지기술연구원 | Continuous Hybrid Carbon Fiber Production Method |
JP5787289B2 (en) * | 2011-06-20 | 2015-09-30 | ミクロ電子株式会社 | Heating device using microwaves |
JP2013231244A (en) * | 2012-04-27 | 2013-11-14 | Applied Materials Inc | Apparatus for producing carbon fiber |
KR101395811B1 (en) * | 2012-05-22 | 2014-05-16 | 한국과학기술연구원 | Preparation method for carbon fiber with high performance using textile grade polyacrylonitrile fiber |
KR101309730B1 (en) * | 2012-05-25 | 2013-09-17 | 포항공과대학교 산학협력단 | Method of manufacturing super strength carbon nanotube yarn |
JP5877448B2 (en) * | 2012-09-26 | 2016-03-08 | ミクロ電子株式会社 | Heating device using microwaves |
EP3026150B1 (en) * | 2013-07-26 | 2018-08-29 | Toho Tenax Co., Ltd. | Carbonization method and carbon fiber production method |
JP6469341B2 (en) | 2013-09-25 | 2019-02-13 | 第一工業製薬株式会社 | A curable resin composition and a coating composition containing the same. |
JP6486169B2 (en) * | 2015-03-31 | 2019-03-20 | 帝人株式会社 | Heating method, carbon fiber manufacturing method, carbon fiber, and heating device |
-
2017
- 2017-12-19 KR KR1020170174703A patent/KR102037843B1/en active IP Right Grant
- 2017-12-19 WO PCT/KR2017/015018 patent/WO2018117594A1/en active Application Filing
- 2017-12-19 EP EP17885137.4A patent/EP3556916B1/en active Active
- 2017-12-19 CN CN201780075534.2A patent/CN110073041B/en active Active
- 2017-12-19 JP JP2019530093A patent/JP2020513486A/en active Pending
- 2017-12-19 US US16/346,011 patent/US20200056306A1/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4822966A (en) * | 1987-02-20 | 1989-04-18 | Yuzuru Matsubara | Method of producing heat with microwaves |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20190233979A1 (en) * | 2018-01-29 | 2019-08-01 | Uht Unitech Company Ltd. | Fiber pre-oxidization device |
US11459673B2 (en) | 2018-07-23 | 2022-10-04 | Lg Chem, Ltd. | Carbon fiber carbonization apparatus using microwave |
Also Published As
Publication number | Publication date |
---|---|
EP3556916A4 (en) | 2019-11-27 |
WO2018117594A1 (en) | 2018-06-28 |
KR20180071184A (en) | 2018-06-27 |
JP2020513486A (en) | 2020-05-14 |
CN110073041B (en) | 2022-08-09 |
EP3556916A1 (en) | 2019-10-23 |
KR102037843B1 (en) | 2019-10-30 |
EP3556916B1 (en) | 2021-01-27 |
CN110073041A (en) | 2019-07-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20200056306A1 (en) | Apparatus for manufacturing carbon fiber by using microwaves | |
RU2009128759A (en) | METHOD FOR STABILIZING CARBON-CONTAINING FIBER AND METHOD FOR PRODUCING CARBON FIBER | |
TWI384098B (en) | High module carbon fiber and fabricating method thereof | |
CN103541042B (en) | High mode graphite fibre and manufacture method thereof | |
WO2015152019A1 (en) | Carbon fiber manufacturing device and carbon fiber manufacturing method | |
KR101219721B1 (en) | Continuous Hybrid Carbon Fiber Production Method | |
CN211522400U (en) | Microwave heating carbon fiber precursor annealing-pre-oxidation treatment equipment | |
KR20160116366A (en) | Method of manufacturing graphite sheet with excellent heat conductive property and graphit sheet manufactured | |
KR20200068527A (en) | Oxidation fiber manufacturing method | |
KR102012753B1 (en) | Precusor fiber for preparing carbon fiber, preparation method for producing the same and preparation method of carbon fiber | |
KR20120037044A (en) | Apparatus for maunfacturing carbon fiber using electrode | |
CN115626827B (en) | Method for rapidly preparing carbon product by microwave roasting | |
KR100956543B1 (en) | Preparation method of carbon fiber using irradiation and carbon fiber using thereof | |
CN105544021A (en) | Method for inhibiting unevenness of structures of carbon fibers | |
US20190233979A1 (en) | Fiber pre-oxidization device | |
KR102134628B1 (en) | Apparatus and method manufacturing carbon fiber | |
KR101219724B1 (en) | hybrid carbon fiber production method | |
KR101236210B1 (en) | Apparatus for maunfacturing carbon fiber | |
KR20120077683A (en) | Exhausting structure of carbonization furnace for manufacturing carbon fiber | |
KR102147418B1 (en) | Stabilization method of precusor fiber for preparing carbon fiber and preparation method of carbon fiber using the same | |
US11459673B2 (en) | Carbon fiber carbonization apparatus using microwave | |
JP3216683U (en) | Oxidized fiber structure | |
KR20220086847A (en) | Stabilization device and method for carbon fiber precursor, and carbon fiber manufacturing method including the same | |
RU70258U1 (en) | LONG-TERM VACUUM CAMERA FOR THERMAL PROCESSING OF THE PREDATOR IN ORDER TO PRODUCE CARBON FIBER FROM IT | |
TWM324188U (en) | Vertical-wind-passage-type oxidation oven containing carbon fiber |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: LG CHEM, LTD., KOREA, REPUBLIC OF Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KIM, SUJIN;LEE, ILHA;CHO, JOON HEE;AND OTHERS;REEL/FRAME:049024/0898 Effective date: 20180111 |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: FINAL REJECTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STCV | Information on status: appeal procedure |
Free format text: NOTICE OF APPEAL FILED |
|
STCV | Information on status: appeal procedure |
Free format text: APPEAL BRIEF (OR SUPPLEMENTAL BRIEF) ENTERED AND FORWARDED TO EXAMINER |
|
STCV | Information on status: appeal procedure |
Free format text: APPEAL BRIEF (OR SUPPLEMENTAL BRIEF) ENTERED AND FORWARDED TO EXAMINER |
|
STCV | Information on status: appeal procedure |
Free format text: EXAMINER'S ANSWER TO APPEAL BRIEF MAILED |
|
STCV | Information on status: appeal procedure |
Free format text: ON APPEAL -- AWAITING DECISION BY THE BOARD OF APPEALS |