SI1809691T1 - Sestave polimerov in kopolimerov poliestra, ki vsebujejo delce titanovega karbida - Google Patents

Sestave polimerov in kopolimerov poliestra, ki vsebujejo delce titanovega karbida Download PDF

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Publication number
SI1809691T1
SI1809691T1 SI200532199T SI200532199T SI1809691T1 SI 1809691 T1 SI1809691 T1 SI 1809691T1 SI 200532199 T SI200532199 T SI 200532199T SI 200532199 T SI200532199 T SI 200532199T SI 1809691 T1 SI1809691 T1 SI 1809691T1
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Slovenia
Prior art keywords
polyester
titanium carbide
particles
composition
polymer
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SI200532199T
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English (en)
Inventor
Zhiyong Xia
Original Assignee
Grupo Petrotemex, S.A. De C.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Grupo Petrotemex, S.A. De C.V. filed Critical Grupo Petrotemex, S.A. De C.V.
Publication of SI1809691T1 publication Critical patent/SI1809691T1/sl

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C08K3/14—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Claims (36)

  1. SESTAVE POLIMEROV IN KOPOLIMEROV POLIESTRA, KI VSEBUJEJO DELCE TITANOVEGA KARBIDA Patentni zahtevki
    1. Sestava poliestra z izboljšanim ponovnim segrevanjem, ki zajema: polimer poliestra; in delce titanovega karbida s povprečno velikostjo od 0,005 pm do 100 pm, ki so dispergirani v polimeru poliestra v količini od 0,5 ppm do 1000 ppm glede na skupno maso sestave poliestra.
  2. 2. Sestava poliestra iz patentnega zahtevka 1, pri čemer je povprečna velikost delcev titanovega karbida od 0,01 pm do 10 pm.
  3. 3. Sestava poliestra iz patentnega zahtevka 1, pri čemer je povprečna velikost delcev titanovega karbida od 0,01 pm do 5 pm.
  4. 4. Sestava poliestra iz patentnega zahtevka 1, pri čemer so delci titanovega karbida prisotni v količini od 1 ppm do 500 ppm glede na skupno maso sestave poliestra.
  5. 5. Sestava poliestra iz patentnega zahtevka 1, pri čemer so delci titanovega karbida prisotni v količini od 5 ppm do 50 ppm glede na skupno maso sestave poliestra.
  6. 6. Sestava poliestra iz patentnega zahtevka 1, pri čemer polimer poliestra zajema polietilen tereftalat.
  7. 7. Sestava poliestra iz patentnega zahtevka 1, pri čemer je oblika sestave poliestra predoblika steklenice za pijačo.
  8. 8. Sestava poliestra iz patentnega zahtevka 1, pri čemer ima sestava poliestra obliko steklenice za pijačo.
  9. 9. Sestava poliestra iz patentnega zahtevka 1, pri čemer ima sestava poliestra obliko ulitka.
  10. 10. Sestava poliestra iz patentnega zahtevka 1, pri čemer polimer poliestra zajema neprekinjeno fazo in pri čemer so delci titanovega karbida dispergirani v neprekinjeni fazi.
  11. 11. Sestava poliestra iz patentnega zahtevka 1, pri čemer delci titanovega karbida s povprečno velikostjo od 0,01 pm do 10 pm sestavi poliestra zagotavljajo temperaturo izboljšanja ponovnega segrevanja (RIT) najmanj 5 °C, pri čemer za predobliko L* ohranjajo vrednost 70 ali večjo.
  12. 12. Sestava poliestra iz patentnega zahtevka 1, pri čemer delci titanovega karbida zajemajo delce, prevlečene s titanovim karbidom.
  13. 13. Sestava poliestra iz patentnega zahtevka 1, pri čemer delci titanovega karbida zajemajo votle kroglice, ki vključujejo titanov karbid.
  14. 14. Sestava poliestra iz patentnega zahtevka 1, pri čemer delci titanovega karbida zajemajo titanov karbid s formulo od TiCo,47 do TiCi,o.
  15. 15. Sestava poliestra iz patentnega zahtevka 1, pri čemer delci titanovega karbida zajemajo najmanj 90-odstotni masni delež titanovega karbida glede na skupno maso delcev titanovega karbida.
  16. 16. Sestava poliestra iz patentnega zahtevka 15, pri čemer delci titanovega karbida dodatno zajemajo titanov nitrid.
  17. 17. Sestava poliestra iz patentnega zahtevka 15, pri čemer delci titanovega karbida dodatno zajemajo elementarni titan.
  18. 18. Sestava poliestra iz patentnega zahtevka 1, pri čemer je obseg (S) razporeditve velikosti delcev titanovega karbida od 0 do 10.
  19. 19. Sestava poliestra iz patentnega zahtevka 1, pri čemer je obseg (S) razporeditve velikosti delcev titanovega karbida od 0,01 do 2.
  20. 20. Sestava poliestra iz patentnega zahtevka 1, ki zajema: polimer poliestra, v katerem delci poli(etilen tereftalata) zajemajo najmanj 90-odstotni masni delež polimera poliestra; in delce titanovega karbida s povprečno velikostjo od 0,01 pm do 10 pm, ki so naključno dispergirani v polimeru poliestra v količini od 1 do 50 ppm, pri čemer ima sestava poliestra temperaturo izboljšanja ponovnega segrevanja 5 °C ali višjo, vrednost predoblike L* pa je 70 ali večja.
  21. 21. Postopek za pridobivanje sestave poliestra v skladu s patentnim zahtevkom 1, pri čemer omenjeni postopek zajema: korak esterifikacije, ki zajema transesterifikacijo diestra dikarboksilne kisline in diola ali neposredno esterifikacijo dikarboksilne kisline in diola, za pridobitev enega ali več monomerov poliestra ali oligomerov poliestra; korak polikondenzacije, ki zajema reakcijo enega ali več monomerov poliestra ali oligomerov poliestra v reakciji polikondenzacije v prisotnosti katalizatorja polikondenzacije, za pridobitev polimera poliestra z intrinzično viskoznostjo od 0,50 dl/g do 1,1 dl/g; korak pandikulacije, v katerem se staljeni polimer poliestra strdi v delce; poljubni korak prehajanja v trdno stanje, v katerem polimerizira trdni polimer z intrinzično viskoznostjo od 0,70 dl/g do 1,2 dl/g; in korak dodajanja delcev, ki zajema dodajanje in dispergiranje delcev titanovega karbida, da se zagotovi količina od 1 ppm do 500 ppm glede na maso polimera, pri čemer se korak dodajanja delcev izvede pred katerim koli prejšnjim korakom oziroma med njim ali po njem.
  22. 22. Postopek v skladu s patentnim zahtevkom 21, pri čemer postopek dodatno zajema korak oblikovanja, ki sledi koraku prehajanja v trdno stanje, pri čemer korak oblikovanja zajema taljenje in ekstrudiranje nastalega trdnega polimera za pridobitev oblikovanega elementa, v katerem so dispergirani delci titanovega karbida.
  23. 23. Postopek v skladu s patentnim zahtevkom 22, pri čemer se korak dodajanja delcev izvede med korakom prehajanja v trdno stanje ali po njem in pred korakom oblikovanja.
  24. 24. Postopek v skladu s patentnim zahtevkom 21, pri čemer korak dodajanja delcev zajema dodajanje delcev titanovega karbida kot termoplastičnega koncentrata pred korakom oblikovanja ali med njim, pri čemer termoplastični koncentrat zajema delce titanovega karbida v količini od 100 ppm do 5000 ppm glede na maso termoplastičnega koncentrata.
  25. 25. Postopek v skladu s patentnim zahtevkom 21, pri čemer je povprečna velikost delcev titanovega karbida od 0,005 pm do 100 pm.
  26. 26. Postopek v skladu s patentnim zahtevkom 21, pri čemer se korak dodajanja delcev izvede pred korakom polikondenzacije ali med njim.
  27. 27. Postopek v skladu s patentnim zahtevkom 21, pri čemer se korak dodajanja delcev izvede pred korakom partikulacije ali med njim.
  28. 28. Postopek v skladu s patentnim zahtevkom 21, pri čemer se korak dodajanja delcev izvede pred korakom prehajanja v trdno stanje ali med njim.
  29. 29. Postopek v skladu s patentnim zahtevkom 22, pri čemer se korak dodajanja delcev izvede pred korakom oblikovanja ali med njim.
  30. 30. Postopek v skladu s patentnim zahtevkom 21, pri čemer dikarboksilna kislina zajema tereftalno kislino.
  31. 31. Postopek v skladu s patentnim zahtevkom 21, pri čemer diester dikarboksilne kisline zajema dimetil tereftalat.
  32. 32. Postopek v skladu s patentnim zahtevkom 21, pri čemer diol zajema etilenglikol.
  33. 33. Postopek v skladu s patentnim zahtevkom 21, pri čemer dikarboksilna kislina zajema naftalensko dikarboksilno kislino.
  34. 34. Postopek v skladu s patentnim zahtevkom 21, pri čemer dikarboksilna kislina zajema aromatsko dikarboksilno kislino.
  35. 35. Postopek v skladu s patentnim zahtevkom 24, pri čemer termoplastični koncentrat zajema: delce titanovega karbida v količini od 0,15-odstotnega masnega deleža do vključno 3 5-odstotnega masnega deleža glede na maso termoplastičnega koncentrata; in termoplastični polimer v količini od najmanj 65-odstotnega masnega deleža glede na maso termoplastičnega koncentrata.
  36. 36. Postopek v skladu s patentnim zahtevkom 35, pri čemer termoplastični polimer zajema eno ali več naslednjih vrst polimerov: poliester, poliolefin ali polikarbonat.
SI200532199T 2004-11-12 2005-10-27 Sestave polimerov in kopolimerov poliestra, ki vsebujejo delce titanovega karbida SI1809691T1 (sl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/988,263 US20060105129A1 (en) 2004-11-12 2004-11-12 Polyester polymer and copolymer compositions containing titanium carbide particles
EP05820957.8A EP1809691B1 (en) 2004-11-12 2005-10-27 Polyester polymer and copolymer compositions containing titanium carbide particles
PCT/US2005/038606 WO2006055198A1 (en) 2004-11-12 2005-10-27 Polyester polymer and copolymer compositions containing titanium carbide particles

Publications (1)

Publication Number Publication Date
SI1809691T1 true SI1809691T1 (sl) 2018-05-31

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Country Link
US (1) US20060105129A1 (sl)
EP (1) EP1809691B1 (sl)
JP (1) JP2008519883A (sl)
KR (1) KR20070084189A (sl)
CN (1) CN101056925A (sl)
AR (1) AR051610A1 (sl)
BR (1) BRPI0517468A (sl)
CA (1) CA2585365A1 (sl)
ES (1) ES2666892T3 (sl)
HU (1) HUE037282T2 (sl)
LT (1) LT1809691T (sl)
MX (1) MX2007005742A (sl)
PL (1) PL1809691T3 (sl)
PT (1) PT1809691T (sl)
SI (1) SI1809691T1 (sl)
TW (1) TW200632012A (sl)
WO (1) WO2006055198A1 (sl)

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LT1809691T (lt) 2018-04-10
CA2585365A1 (en) 2006-05-26
EP1809691A1 (en) 2007-07-25
CN101056925A (zh) 2007-10-17
WO2006055198A1 (en) 2006-05-26
KR20070084189A (ko) 2007-08-24
ES2666892T3 (es) 2018-05-08
TW200632012A (en) 2006-09-16
MX2007005742A (es) 2007-07-09
PL1809691T3 (pl) 2018-06-29
EP1809691B1 (en) 2018-03-14
AR051610A1 (es) 2007-01-24
BRPI0517468A (pt) 2008-10-07
HUE037282T2 (hu) 2018-08-28
JP2008519883A (ja) 2008-06-12
US20060105129A1 (en) 2006-05-18
PT1809691T (pt) 2018-04-30

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