NL8703157A - Werkwijze voor het selectief hydrogeneren van acetylenen. - Google Patents

Werkwijze voor het selectief hydrogeneren van acetylenen. Download PDF

Info

Publication number: NL8703157A
Authority: NL; Netherlands
Prior art keywords: catalyst; process according; hydrogen; butadiene; alkynes
Prior art date: 1986-12-30

Application number

NL8703157A

Other languages

English (en)

Dutch (nl)

Original Assignee

Labofina Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-30

Filing date

1987-12-29

Publication date

1988-07-18

1987-12-29 Application filed by Labofina Sa filed Critical Labofina Sa

1988-07-18 Publication of NL8703157A publication Critical patent/NL8703157A/nl

Links

238000000034 method Methods 0.000 title claims description 41
238000005984 hydrogenation reaction Methods 0.000 title description 34
HSFWRNGVRCDJHI-UHFFFAOYSA-N Acetylene Chemical compound C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title description 8
239000003054 catalyst Substances 0.000 claims description 75
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 47
239000001257 hydrogen Substances 0.000 claims description 40
229910052739 hydrogen Inorganic materials 0.000 claims description 40
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 39
150000001345 alkine derivatives Chemical class 0.000 claims description 30
229910052763 palladium Inorganic materials 0.000 claims description 23
239000007788 liquid Substances 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 8
239000002184 metal Substances 0.000 claims description 8
235000013305 food Nutrition 0.000 claims description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
229910001020 Au alloy Inorganic materials 0.000 claims 1
239000003353 gold alloy Substances 0.000 claims 1
JUWSSMXCCAMYGX-UHFFFAOYSA-N gold platinum Chemical compound [Pt].[Au] JUWSSMXCCAMYGX-UHFFFAOYSA-N 0.000 claims 1
KDKYADYSIPSCCQ-UHFFFAOYSA-N but-1-yne Chemical group CCC#C KDKYADYSIPSCCQ-UHFFFAOYSA-N 0.000 description 19
150000002430 hydrocarbons Chemical class 0.000 description 18
229930195733 hydrocarbon Natural products 0.000 description 16
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
239000000203 mixture Substances 0.000 description 13
150000000475 acetylene derivatives Chemical class 0.000 description 10
WFYPICNXBKQZGB-UHFFFAOYSA-N butenyne Chemical group C=CC#C WFYPICNXBKQZGB-UHFFFAOYSA-N 0.000 description 10
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 10
239000004215 Carbon black (E152) Substances 0.000 description 9
230000004913 activation Effects 0.000 description 9
235000013844 butane Nutrition 0.000 description 8
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 8
239000000243 solution Substances 0.000 description 8
239000010931 gold Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 6
238000002474 experimental method Methods 0.000 description 6
238000002347 injection Methods 0.000 description 6
239000007924 injection Substances 0.000 description 6
235000016709 nutrition Nutrition 0.000 description 5
230000035764 nutrition Effects 0.000 description 5
239000011148 porous material Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000011069 regeneration method Methods 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
229920002554 vinyl polymer Polymers 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 4
238000004230 steam cracking Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
238000001816 cooling Methods 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
238000000746 purification Methods 0.000 description 3
229920003051 synthetic elastomer Polymers 0.000 description 3
239000005061 synthetic rubber Substances 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
238000001514 detection method Methods 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
230000007774 longterm Effects 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000011144 upstream manufacturing Methods 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910000570 Cupronickel Inorganic materials 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000011324 bead Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
239000003245 coal Substances 0.000 description 1
YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
239000007970 homogeneous dispersion Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
235000021056 liquid food Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000010338 mechanical breakdown Methods 0.000 description 1
235000015097 nutrients Nutrition 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000010926 purge Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

NL8703157A 1986-12-30 1987-12-29 Werkwijze voor het selectief hydrogeneren van acetylenen. NL8703157A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB8631017		1986-12-30
GB8631017A GB2199588B (en)	1986-12-30	1986-12-30	Process for the selective hydrogenation of acetylenes

Publications (1)

Publication Number	Publication Date
NL8703157A true NL8703157A (nl)	1988-07-18

Family

ID=10609665

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8703157A NL8703157A (nl)	1986-12-30	1987-12-29	Werkwijze voor het selectief hydrogeneren van acetylenen.

Country Status (9)

Country	Link
JP (1)	JP2560056B2 (it)
BE (1)	BE1000871A4 (it)
CA (1)	CA1290354C (it)
DE (1)	DE3744086C2 (it)
FI (1)	FI87453C (it)
FR (1)	FR2609023B1 (it)
GB (1)	GB2199588B (it)
IT (1)	IT1223624B (it)
NL (1)	NL8703157A (it)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19500366C1 (de) *	1995-01-09	1996-05-02	Basf Ag	Palladium-Trägerkatalysator und seine Verwendung
US6509292B1 (en) *	2001-03-30	2003-01-21	Sud-Chemie Inc.	Process for selective hydrogenation of acetylene in an ethylene purification process
DE102008043344A1 (de)	2008-10-31	2010-05-06	Evonik Oxeno Gmbh	Verfahren zur Herstellung von 1-Alkoxyocta-2,7-dien

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB510343A (en) *	1936-10-22	1939-07-26	Ig Farbenindustrie Ag	A process of hydrogenating monovinylacetylene
FR1217305A (fr) *	1957-12-17	1960-05-03	Bayer Ag	Procédé pour éliminer l'acétylène, le méthylacétylène et l'allène à partirde mélanges d'hydrocarbures
DE1184336B (de) *	1963-07-10	1964-12-31	Huels Chemische Werke Ag	Verfahren zur Entfernung von Methylacetylen und Propadien aus einem ueberwiegend Propen enthaltenden C-Kohlenwasserstoffgemisch
DE1210795B (de) *	1964-11-14	1966-02-17	Huels Chemische Werke Ag	Verfahren zur Entfernung von Butadien und bzw. oder Acetylenen aus einem ueberwiegend Butene bzw. Butadien enthaltenden C-Kohlenwasserstoffgemisch
DE1568542C3 (de) *	1966-06-15	1974-07-18	Bayer Ag, 5090 Leverkusen	Verfahren zur katalytischen Umwandlung von Butadien- und n-Buten-1-haltigen C tief 4 - Kohlenwasserstoffen
US3842137A (en) *	1973-01-02	1974-10-15	Monsanto Co	Selective hydrogenation of c4 acetylenic hydrocarbons
US3898298A (en) *	1973-04-13	1975-08-05	Atlantic Richfield Co	Selective hydrogenation of vinyl acetylene
US3859377A (en) *	1973-12-13	1975-01-07	Monsanto Co	Selective hydrogenation of c' 4 'acetylenic hydrocarbons
FR2421858A1 (fr) *	1978-04-05	1979-11-02	Inst Francais Du Petrole	Procede d'hydrogenation selective d'une fraction d'hydrocarbures renfermant au moins un hydrocarbure diolefinique et au moins un hydrocarbure acetylenique
JPS54141706A (en) *	1978-04-21	1979-11-05	Nippon Oil Co Ltd	Removal of acetylenes in 4c hydrocarbon mixture containing butadiene
US4247745A (en) *	1978-09-13	1981-01-27	Westinghouse Electric Corp.	Vacuum-type contactor assembly
FR2460989A1 (fr) *	1979-07-06	1981-01-30	Inst Francais Du Petrole	Procede de purification d'une coupe d'hydrocarbures aromatiques contenant des hydrocarbures insatures olefiniques et acetyleniques
DE3143647A1 (de) *	1981-11-04	1983-05-11	Chemische Werke Hüls AG, 4370 Marl	Verfahren zur selektiven hydrierung von mehrfach ungesaettigten kohlenwasserstoffen in kohlenwasserstoff-gemischen
JPS58149987A (ja) *	1982-03-02	1983-09-06	Sumitomo Chem Co Ltd	炭化水素類の選択的水素添加の方法

1986
- 1986-12-30 GB GB8631017A patent/GB2199588B/en not_active Expired - Fee Related
1987
- 1987-12-24 DE DE3744086A patent/DE3744086C2/de not_active Revoked
- 1987-12-26 JP JP62328448A patent/JP2560056B2/ja not_active Expired - Lifetime
- 1987-12-28 FR FR878718223A patent/FR2609023B1/fr not_active Expired
- 1987-12-29 NL NL8703157A patent/NL8703157A/nl active Search and Examination
- 1987-12-30 BE BE8701501A patent/BE1000871A4/fr not_active IP Right Cessation
- 1987-12-30 FI FI875774A patent/FI87453C/fi not_active IP Right Cessation
- 1987-12-30 CA CA000555579A patent/CA1290354C/en not_active Expired - Lifetime
- 1987-12-30 IT IT23273/87A patent/IT1223624B/it active

Also Published As

Publication number	Publication date
FI87453B (fi)	1992-09-30
FI875774A0 (fi)	1987-12-30
FR2609023B1 (fr)	1989-10-20
JPS63185935A (ja)	1988-08-01
FI87453C (fi)	1993-01-11
CA1290354C (en)	1991-10-08
BE1000871A4 (fr)	1989-04-25
FR2609023A1 (fr)	1988-07-01
IT8723273A0 (it)	1987-12-30
GB2199588A (en)	1988-07-13
FI875774A (fi)	1988-07-01
IT1223624B (it)	1990-09-29
GB8631017D0 (en)	1987-02-04
DE3744086C2 (de)	2000-05-04
DE3744086A1 (de)	1988-07-14
GB2199588B (en)	1990-12-05
JP2560056B2 (ja)	1996-12-04

Legal Events

Date	Code	Title
1994-08-01	BA	A request for search or an international-type search has been filed
1994-09-01	BB	A search report has been drawn up
1994-12-01	BC	A request for examination has been filed
2003-12-01	BN	A decision not to publish the application has become irrevocable

Publication	Publication Date	Title
JP2560057B2 (ja)	1996-12-04	アセチレン類の選択的水素化用の改良方法
JP4606521B2 (ja)	2011-01-05	炭化水素流れ中のアセチレンと１，２―ブタジエンを同時的に選択的水素化する方法
AU682385B2 (en)	1997-10-02	Selective hydrogenation of highly unsaturated compounds in hydrocarbon streams
JP3691071B2 (ja)	2005-08-31	高度不飽和化合物の選択的水素化のための改良された方法、および炭化水素流れ中のオレフィンの異性化
EP1299329B1 (en)	2005-07-20	Process for the preparation of hydrocarbons
EP1663918A1 (en)	2006-06-07	Process for liquid phase hydrogenation
WO2006019717A1 (en)	2006-02-23	Process for the selective hydrogenation of alkynes and/or dienes in an olefin-containing hydrocarbon stream
EP0875288B1 (en)	2002-10-09	Process for ring opening of cyclic compounds
CA2089113C (en)	2004-12-21	Selective hydrogenation of c5 streams
WO2002008156A1 (en)	2002-01-31	Method and catalyst for opening naphthenic rings of naphthenic ring-containing compounds
EA023914B1 (ru)	2016-07-29	Способ очистки сырьевых потоков этиленсодержащих отходящих газов
NL8703157A (nl)	1988-07-18	Werkwijze voor het selectief hydrogeneren van acetylenen.
US20060155154A1 (en)	2006-07-13	Process for the selective hydrogenation of alkynes
EP0011906B1 (en)	1983-02-23	Process for selective hydrogenation of dienes in pyrolysis gasoline
JP4324865B2 (ja)	2009-09-02	炭化水素燃料油の製造方法
RU2309179C2 (ru)	2007-10-27	Способ гидрирования ароматических соединений в углеводородном сырье, содержащем тиофеновые соединения
WO2002007877A1 (en)	2002-01-31	Ring opening with group viii metal catalysts supported on modified substrate
US4266086A (en)	1981-05-05	Process for removing α-acetylenes from diolefins
JPH0148317B2 (it)	1989-10-18
JPH0745419B2 (ja)	1995-05-17	スチレン類の精製方法
WO2002007881A1 (en)	2002-01-31	Naphthene ring opening over an iridium ring opening catalyst
JPH085814B2 (ja)	1996-01-24	スチレン類の精製方法
WO2004043888A1 (en)	2004-05-27	Process for the selective hydrogenation of alkynes
AU2001278958A1 (en)	2002-02-05	Method and catalyst for opening naphthenic rings of naphthenic ring-containing compounds