KR960017689A - 포스포노메틸화 키토산 - Google Patents

포스포노메틸화 키토산 Download PDF

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Publication number
KR960017689A
KR960017689A KR1019950044497A KR19950044497A KR960017689A KR 960017689 A KR960017689 A KR 960017689A KR 1019950044497 A KR1019950044497 A KR 1019950044497A KR 19950044497 A KR19950044497 A KR 19950044497A KR 960017689 A KR960017689 A KR 960017689A
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South Korea
Prior art keywords
general formula
alkali metal
chitosan according
chitosan
phosphonomethylated
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KR1019950044497A
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English (en)
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KR100394158B1 (ko
Inventor
쿤 마르틴
마이어 토마스
스테렝 알베르
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베르너 발덱
시바-가이기 에이지
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Publication of KR960017689A publication Critical patent/KR960017689A/ko
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Publication of KR100394158B1 publication Critical patent/KR100394158B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
    • C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
    • C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Polymers & Plastics (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

본 발명은 다음 일반식(1)의 반복단위를 함유하는 포스포노메틸화 키토산에 관한 것이다.
상기식에서, R1은 수소 또는 일반식(1p) (여기서, X1과, X2는 각각 독립적으로 수소, C1∼C5알킬 또는 알칼리 금속 이온 또는 암모늄 이온이다)의 라디칼이고, R2는 일반식(1p)의 라디칼이며, n은 50내지 4000이다.
본 발명의 화합물은 금속 이온 봉쇄제, 표백제용 안정화제로서 뿐만 아니라 향장 조성물에서의 보습제로서 다양하게 활용된다.

Description

포스포노메틸화 키토산
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 본 발명은 다음 일반식(1)의 반복단위를 함유하는 포스포노메틸화 키토산.
    상기식에서, R1은 수소 또는 일반식(1p) (여기서, X1과, X2는 각각 독립적으로 수소, C1∼C5알킬 또는 알칼리 금속 이온 또는 암모늄 이온이다)의 라이칼이고, R2는 일반식(1p)의 라디칼이며, n은 50내지 4000이다.
  2. 본 발명은 다음 일반식(2)의 반복단위를 함유하는 포스포노메틸화 키토산.
    상기식에서, X1과, X2는 각각 독립적으로 수소, C1∼C5알킬 또는 알칼리 금속 이온 또는 암모늄 이온이고, n은 50내지 4000이다.
  3. 제1항 또는 제2항에 있어서, 일반식(1)에서, X1과, X2는 각각 독립적으로 알칼리 금속이고 n이 200내지 2000인 키토산.
  4. 다음 일반식(1a)의 반복단위를 함유하는 화합물을 산성매질 속에서 0내지 4의 pH 및 80내지 120℃의 온도 범위하에서 5내지 24시간의 반응시간 동안 포름알데히드 및 인산과 반응시켜 일반식(1)의 반복단위를 함유하는 화합물을 수득함을 포함하는, 제1항 내지 제3항 중의 어느 한 항에 따르는 키토산의 제조방법.
    상기식에서, R1은 수소 또는 일반식(1p) (여기서, X1과, X2는 각각 독립적으로 수소, C1∼C5알킬 또는 알칼리 금속 이온 또는 암모늄 이온이다)의 라디칼이고, R2는 일반식(1p)의 라디칼이며, n은 50내지 4000이다
  5. 알칼리 토금속 이온용 금속 이온 봉쇄제로서, 금속 이온용 착화제로서 또는 표백제용 안정화제로서의 제1항에 따르는 키토산의 용도.
  6. 섬유재료를 하나 이상의 과화합물(per compound), 알칼리 금속 하이드록사이드, 수용성 마그네슘염 및 제1항에 따르는 키토산을 포함하는 수성 액으로 처리함을 포함하는, 셀룰로즈계 섬유재료의 표백방법.
  7. 하나 이상의 과화합물, 알칼리 금속 하이드록사이드, 수용성 마그네슘 염 및 제1항에 따르는 키토산을 포함하는 표백액.
  8. 제6항에 따라 표백한 셀룰로즈계 섬유재료.
  9. 무기 또는 유기 기재에 고체 침착물이 접착되거나 형성되는 것을 방지하기 위한, 제1항에 따르는 포스포 노메틸화 키토산의 용도.
  10. 제1항에 따르는 하나 이상의 포스포노메틸화 키토산을 항장적으로 허용되는 담체 또는 보조제와 함께 포함하는 항장 조성물.
  11. 피막과 점막용 보습제로서의 제1항에 따르는 포스포노메틸화 키토산의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950044497A 1994-11-24 1995-11-23 포스포노메틸화키토산및이의제조방법 KR100394158B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH354494 1994-11-24
CH03544/94 1994-11-24

Publications (2)

Publication Number Publication Date
KR960017689A true KR960017689A (ko) 1996-06-17
KR100394158B1 KR100394158B1 (ko) 2003-12-24

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ID=4258276

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Country Status (9)

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US (2) US5777091A (ko)
EP (1) EP0713882B1 (ko)
JP (1) JP3998734B2 (ko)
KR (1) KR100394158B1 (ko)
BR (1) BR9505506A (ko)
DE (1) DE59504682D1 (ko)
ES (1) ES2127499T3 (ko)
NO (1) NO304984B1 (ko)
RU (1) RU2158741C2 (ko)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19741721A1 (de) * 1997-09-22 1999-03-25 Huels Chemische Werke Ag Wasch- und Reinigungsmittelformulierungen mit Chitin/Chitosan-Derivaten als Schmutzlösepolymer
DE69806638T2 (de) 1997-12-22 2003-03-13 Ciba Sc Holding Ag Verwendung von polyanionisch und polyanionisch-derivatisiert natürlichen polysacchariden für die inhibierung von alkalischer phosphatase
US6258755B1 (en) * 1998-12-28 2001-07-10 Venture Innovations, Inc. Chitosan-containing well drilling and servicing fluids
US6277792B1 (en) * 1998-12-28 2001-08-21 Venture Innovations, Inc. Viscosified aqueous fluids and viscosifier therefor
FR2799647B1 (fr) 1999-10-15 2001-12-07 Oreal Composition sous forme d'emulsion eau-dans-huile, contenant des fibres, et son utilisation dans le domaine cosmetique
FR2799646B1 (fr) * 1999-10-15 2001-12-07 Oreal Composition sous forme d'emulsion eau-dans-huile, contenant des fibres, et son utilisation dans le domaine cosmetique
GB0024489D0 (en) * 2000-10-06 2000-11-22 Reckitt Benckiser Uk Ltd Improvements in or relating to organic compositions
EP1206931A1 (en) * 2000-11-15 2002-05-22 ERPHAR Société d'Etudes et de Recherches Pharmaceutiques et Cosmétiques Chitosan formulations
DE10105143A1 (de) * 2001-02-06 2002-08-08 Basf Ag Verfahren zur UV-Schutzausrüstung von textilem Material
US6508958B1 (en) * 2001-07-16 2003-01-21 Gerald Wojcik Composition and process for inhibiting corrosion of metallic substrates
JP2006249077A (ja) * 2005-02-10 2006-09-21 Ezaki Glico Co Ltd リン酸化糖を含有する皮膚外用剤
WO2008090583A1 (en) * 2007-01-22 2008-07-31 Universita' Degli Studi Di Siena Phosphated derivatives of polysaccharides and uses thereof
EP2090645A1 (en) * 2008-01-22 2009-08-19 Thermphos Trading GmbH Surface treatment composition containing sugar phosphonates
JP5900968B2 (ja) * 2011-01-14 2016-04-06 株式会社ダステック 高分子鉄キレート剤
CN105625021A (zh) * 2016-03-31 2016-06-01 太仓市锦达印染有限公司 混纺织物印染前处理的连续生产工艺
CN113737030B (zh) * 2021-08-30 2022-07-05 中南大学 一种用水溶性高分子络合剂分离稀土的方法
CN113667038A (zh) * 2021-08-30 2021-11-19 中南大学 一种水溶性磷酰化壳聚糖及其制备方法
WO2023149402A1 (ja) * 2022-02-03 2023-08-10 東ソー株式会社 水溶性キレートポリマー及びその製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA775575A (en) * 1961-11-13 1968-01-09 R. Irani Riyad Organic phosphorus compounds
US3879376A (en) * 1971-05-10 1975-04-22 Oreal Chitosan derivative, method of making the same and cosmetic composition containing the same
IT1229167B (it) * 1989-04-10 1991-07-22 Texcontor Ets Complessi del ferro o di altri metalli con derivati solfonati del chitosano
DE4227019A1 (de) * 1992-08-14 1994-02-17 Geckeler Kurt E Priv Doz Dr Herstellung und Modifikation von Materialien auf der Basis von Amino- oder Amidpolymeren
DE59409748D1 (de) * 1993-06-11 2001-06-21 Ciba Sc Holding Ag Bleichhilfsmittel
US5670082A (en) * 1993-06-11 1997-09-23 Ciba-Geigy Corporation Bleaching auxiliary

Also Published As

Publication number Publication date
BR9505506A (pt) 1997-10-28
NO954741L (no) 1996-05-28
KR100394158B1 (ko) 2003-12-24
NO954741D0 (no) 1995-11-23
EP0713882B1 (de) 1998-12-30
DE59504682D1 (de) 1999-02-11
EP0713882A1 (de) 1996-05-29
JP3998734B2 (ja) 2007-10-31
ES2127499T3 (es) 1999-04-16
RU2158741C2 (ru) 2000-11-10
NO304984B1 (no) 1999-03-15
US5922851A (en) 1999-07-13
JPH08225601A (ja) 1996-09-03
US5777091A (en) 1998-07-07

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