KR950702215A - 폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(surfactants derived from polylxyalkylenes and substituted succinic anhydrides) - Google Patents

폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(surfactants derived from polylxyalkylenes and substituted succinic anhydrides)

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KR950702215A
KR950702215A KR1019940704735A KR19940704735A KR950702215A KR 950702215 A KR950702215 A KR 950702215A KR 1019940704735 A KR1019940704735 A KR 1019940704735A KR 19940704735 A KR19940704735 A KR 19940704735A KR 950702215 A KR950702215 A KR 950702215A
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닐 마이클 카펜터
고돈 맥그레고어
클리브 에드워드 윌네
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발레이 앤 모어랜드
임페리얼 케미칼 인더스트리스 피엘씨(Imperial Chemical Industries PLC)
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Publication of KR950702215A publication Critical patent/KR950702215A/ko

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Abstract

본 발명은 식중, R, R1, A, A1, Y, R2,m,n, 및p는 정의된 바와같고, 특히 알킬(알케닐) 그룹이 C14-C22그룹인 하기식 (Ⅰ) Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.R2및 (Ⅱ) Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.CpH2p.A.CO.(HR1)C.C(HR)CO.A1.Y의 폴리옥시알킬렌 에스테르와 알킬(알케닐) 숙신산 무수물의 아미드는 효과적인 계면활성제이다. 이들은 특히 놀랍게도 알킬(알케닐) 그룹 쇄 길이가 증가할 수록 운점이 상승하기 때문에 특히 주목할만하다. 당해 계면활성제는 울 정련과 폴리아크릴아미드를 유중수 에멀션을 물로 전화시키는데 효과적이다.

Description

폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(SURFACTANTSDERIVED FROM POLTOXYALKYLENES AND SUBSTITUTED SUCCININC ANHYDRIDS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기식 (Ⅰ) 또는 (Ⅱ)의 화합물.
    Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.R2(I)식중, R과 R1중 하나는 C6-C22알케닐 또는 알킬이고 다른 하나는 수소; A는 -0- 또는 -NR4- (R4는 수소 또는 C1-C6알킬);n은 2내지 100;m은 2 또는 3(폴리옥시알킬렌 쇄에 따라 다양할 수 있음); R2는 수소 또는 C1-C6알킬; A1은 -0-, -O- 또는 -NR4- (R4는 수소 또는 C1-C5알킬); A1이 -0- 인 경우 : Y는 양이온; 및 A1이 -0- 또는 -NR4- 인 경우 : Y는 C1내지 C6알킬 그(R3) 또는 식(CmH2mO)n.R2의 그룹(m,n및 독립적으로 상술한 바와같음); 단, A가 -0-이거나 A1이 -0-인 경우 그룹 R, R1및 임의의 그룹 R2및 R3내의 총 탄소원자수는 최소한 13임.
    또는 Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.CpH2p.A.CO.(HR1)C.C(HR)CO.A1.Y (Ⅱ)식중,m,n및 각각의 R, R1, A, A1및 Y는 독립적으로 상술한 바와같고;p는 2도는 3임.
  2. 제1항에 있어서, R과 R1중 하나는 C14-C22알케닐 또는 알킬이고 나머지 하나는 수소인 화합물.
  3. 제1항에 있어서, 하기식(Ia)의 화합물.
    (Ia) Y.-OOC.(HR)C.C(HR1).COO.(CmH2mO)n,R2식중,m, n는 제1항에서 정의한 바와같고; Y는 양이온이며; R과 R1중 하나는 C14내지 C22알케닐 또는 알킬 그룹이고 나머지는 수소임.
  4. 제1항에 있어서, 하기식 (Ib)의 화합물.
    (Ib) Y.-OOC.(HR)C.C(HR1).COO.(CmH2mO)n,R2식중, R, R1,m, n는 제1항에서 정의한 바와같고; Y는 C1-C6알킬 그룹 또는 식((CHmH2mO)n.R2의 그룹(식m, n및 R2는 독립적으로 제1항에서 정의한 바와같음.
  5. 제1항에 있어서, 하기식(Ic)의 화합물.
    (Ic) Y.-OOC.(HR)C.C(HR1).CO.NH.(CmH2mO)n,R2식중, R, R1,m, n및 R2는 제1항에서 정의한 바와같고; Y는 양이온임.
  6. 제1항에 있어서, 하기식(Id)의 화합물.
    (Id) Y.-OOC.(HR)C.C(HR1).CO.NH.(CmH2mO)n,R2식중, R 및 R1과 각각의m, n및 R2는 독립적으로제1항에서 정의한 바와 같음.
  7. 제4항 내지 제6항중 어느 한 항에 있어서, R과 R1중 하나는 C14-C22알케닐 그룹이고 나머지 하나는 수소인 화합물.
  8. 제1항 내지 제7항중 어느 한 항에 있어서,m은 2;p는 만일 존재한다면 2;n은 3내지 50 이고; Y는 H+, 알칼리금속 양이온, 또는 암모늄 양이온인 양이온이거나 메틸, 에틸 또는 부틸 그룹인 화합물.
  9. 제1항 내지 제8항중 어는 한 항에 정의된 바와같은 식(I) 또는 (Ⅱ)의 화합물을 유효량 포함하고있는 수성 믹스로 울왁스를 함유한 울을 세척하는 단계로 구성되는, 울 왁스를 제거하기위한 울 처리방법.
  10. 제9항에 있어서, 화합물은m은 2,n은 3내지 10, R2는 C1-C6알킬 그룹인 식(Ia)의 화합물인 방법.
  11. 제1항 내지 제8항중 어느 하나에 정의된 식(I) 또는 (Ⅱ)의 화합물을 유중수 에멀션에 포함시키는 단계 및 후속적으로 유증수 에멀션을 물로 희석시켜 전환시키는 단계로 구성되는, 폴리아크릴아미드를 수성상에 함유한 유중수 에멀션을 전화시키는 방법.
  12. 제11항에 있어서, 화합물인m은 2,n은 8내지 25, R2는 H 또는 C1-C6알킬 그룹인 화합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940704735A 1992-06-26 1993-06-25 폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(surfactants derived from polylxyalkylenes and substituted succinic anhydrides) KR950702215A (ko)

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GB9213571.4 1992-06-26
GB929213571A GB9213571D0 (en) 1992-06-26 1992-06-26 Surfactants
PCT/GB1993/001335 WO1994000508A1 (en) 1992-06-26 1993-06-25 Surfactants derived from polyoxyalkylenes and substituted succinic anhydrides

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HUT68780A (en) 1995-07-28
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GB9213571D0 (en) 1992-08-12
GB9313096D0 (en) 1993-08-11
WO1994000508A1 (en) 1994-01-06
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JPH07508546A (ja) 1995-09-21
AU679918B2 (en) 1997-07-17
NZ253297A (en) 1997-02-24
TW256854B (ko) 1995-09-11
EP0647248A1 (en) 1995-04-12
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ZA934479B (en) 1995-03-22
FI946075A0 (fi) 1994-12-23

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