KR927003495A - 에테르의 제조방법 - Google Patents
에테르의 제조방법 Download PDFInfo
- Publication number
- KR927003495A KR927003495A KR1019920701231A KR920701231A KR927003495A KR 927003495 A KR927003495 A KR 927003495A KR 1019920701231 A KR1019920701231 A KR 1019920701231A KR 920701231 A KR920701231 A KR 920701231A KR 927003495 A KR927003495 A KR 927003495A
- Authority
- KR
- South Korea
- Prior art keywords
- zeolite
- olefin
- ray diffraction
- diffraction pattern
- alcohol
- Prior art date
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims description 8
- 238000002360 preparation method Methods 0.000 title description 2
- 238000000034 method Methods 0.000 claims 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 7
- 229910021536 Zeolite Inorganic materials 0.000 claims 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 6
- 239000010457 zeolite Substances 0.000 claims 6
- 238000002441 X-ray diffraction Methods 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 238000006266 etherification reaction Methods 0.000 claims 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 2
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- KFVUXNKQQOUCAH-UHFFFAOYSA-N butan-1-ol;propan-2-ol Chemical compound CC(C)O.CCCCO KFVUXNKQQOUCAH-UHFFFAOYSA-N 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
에테르의 제조방법
[도면의 간단한 설명]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 표 I표 II명세서중의 표 I 에 기재된 라인을 갖는 X-선 회절 패턴을 나타내는 다공성의 산성 합성 결정성 제올라이트를 촉매로 사용하여 에테르화 반응 조건하에서 적어도 하나의 올레핀을 적어도 하나의 알콜과 반응시킴을 특징으로 하여 에테르 또는 에테르 혼합물을 제조하는 방법.
- 제1항에 있어서, 제올라이트가 명세서중의 표 II에 기재된 라인을 갖는 X-선 회절 패턴을 나타내는 방법.
- 제1항에 있어서, 제올라이트가 명세서중의 표 III에 기재된 라인을 갖는 X-선 회절 패턴을 나타내는 방법.
- 제1항에 있어서, 제올라이트가 명세서중의 표 VI에 기재된 라인을 갖는 X-선 회절 패턴을 나타내는 방법.
- 제1 내지 4항중의 어느 하나에 있어서, 제올라이트가 사이클로헥산 증기의 경우에는 4.5 중량% 이상이고, n-헥산 증기의 졍우에는 10중량% 이상인 평형 흡착 용량을 갖는 방법.
- 제l 내지 4항중의 어느 하나에 있어서, 제올라이트가 몰관계식 X2O3: (n)YO2인 조성을 가지며, 여기에서 n은 적어도 10이고 X는 3가 윈소이며 Y가 4가 윈소인 방법.
- 제6항에 있어서, X가 알루미늄을 포함하며 Y가 실리콘을 포함하는 방법.
- 제1 내지 4항중의 어느 하나에 있어서, 올레핀이 3 내지 10개의 탄소원자를 갖는 방법.
- 제8항에 있어서, 올레핀이 이소부텐 또는 이소펜텐인 방법.
- 제8항에 있어서, 알콜이 8개 이하의 탄소원자를 갖는 방법.
- 제9항에 있어서, 알콜이 메탄올, 에탄올, n-프로판올, 이소프로판올 부탄올 또는 이들의 혼합물인 방법.
- 제1 내지 4항중의 어느 하나에 있어서, 에테르화 반응 조건이 20 내지 200℃의 온도, 100 내지 20260kpa (1 내지 200 가압)의 총시스템 압력 및 0.1 내지 5의 올레핀/알콜 몰비율인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/456,702 US4962239A (en) | 1988-10-06 | 1989-12-26 | Process for preparing ethers |
US456,702 | 1989-12-26 | ||
PCT/US1990/001922 WO1991009829A1 (en) | 1989-12-26 | 1990-04-09 | Process for preparing an ether |
Publications (2)
Publication Number | Publication Date |
---|---|
KR927003495A true KR927003495A (ko) | 1992-12-18 |
KR0161298B1 KR0161298B1 (ko) | 1999-01-15 |
Family
ID=23813816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920701231A KR0161298B1 (ko) | 1989-12-26 | 1990-04-09 | 에테르의 제조방법 |
Country Status (13)
Country | Link |
---|---|
US (1) | US4962239A (ko) |
EP (1) | EP0507770B1 (ko) |
JP (1) | JP2806630B2 (ko) |
KR (1) | KR0161298B1 (ko) |
AT (1) | ATE126192T1 (ko) |
AU (1) | AU632803B2 (ko) |
CA (1) | CA2072102A1 (ko) |
DD (1) | DD298379A5 (ko) |
DE (1) | DE69021588T2 (ko) |
DK (1) | DK0507770T3 (ko) |
ES (1) | ES2075204T3 (ko) |
WO (1) | WO1991009829A1 (ko) |
ZA (1) | ZA904078B (ko) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994019304A1 (en) * | 1987-09-25 | 1994-09-01 | Mobil Oil Corporation | Production of alkyl tertiary alkyl ethers |
US5225609A (en) * | 1991-12-17 | 1993-07-06 | Mobil Oil Corporation | Production of tertiary alkyl ether using improved zeolite catalyst |
US5136108A (en) * | 1991-09-13 | 1992-08-04 | Arco Chemical Technology, L.P. | Production of oxygenated fuel components |
US5198590A (en) * | 1992-01-28 | 1993-03-30 | Arco Chemical Technology, L.P. | Hydrocarbon conversion |
US5231235A (en) * | 1992-06-01 | 1993-07-27 | Mobil Oil Corp. | Process for preparing ethers |
US5316753A (en) * | 1992-10-09 | 1994-05-31 | Chevron Research And Technology Company | Zeolite SSZ-35 |
US5414146A (en) * | 1993-08-23 | 1995-05-09 | Mobil Oil Corporation | Multizone catalytic process |
US5600045A (en) * | 1993-12-02 | 1997-02-04 | The Dow Chemical Company | Process for conversion of crude hydrocarbon mixtures |
US5470810A (en) * | 1994-02-02 | 1995-11-28 | Mobil Oil Corporation | Catalyst and method of manufacture |
US6585863B2 (en) | 2000-08-08 | 2003-07-01 | Procter & Gamble Company | Photocatalytic degradation of organic compounds |
US7402187B2 (en) * | 2002-10-09 | 2008-07-22 | Chevron U.S.A. Inc. | Recovery of alcohols from Fischer-Tropsch naphtha and distillate fuels containing the same |
US6824574B2 (en) * | 2002-10-09 | 2004-11-30 | Chevron U.S.A. Inc. | Process for improving production of Fischer-Tropsch distillate fuels |
WO2005102975A1 (ja) * | 2004-04-23 | 2005-11-03 | Central Glass Company, Limited | フッ素化エーテルの製造方法 |
US7846418B2 (en) * | 2006-02-14 | 2010-12-07 | Exxonmobil Chemical Patents Inc. | MCM-22 family molecular sieve composition |
CN102527428B (zh) * | 2006-02-14 | 2014-11-26 | 埃克森美孚化学专利公司 | 制备分子筛组合物的方法 |
US7799316B2 (en) * | 2006-02-14 | 2010-09-21 | Exxonmobil Chemical Patents Inc. | Process for manufacturing MCM-22 family molecular sieves |
WO2008016456A2 (en) | 2006-07-28 | 2008-02-07 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (emm-10), its method of making, and use for hydrocarbon conversions |
US7959899B2 (en) * | 2006-07-28 | 2011-06-14 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions |
WO2008013639A1 (en) | 2006-07-28 | 2008-01-31 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions |
WO2010014404A1 (en) * | 2008-07-28 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Process of making alkylaromatics using emm-13 |
US8466333B2 (en) | 2008-07-28 | 2013-06-18 | Exxonmobil Chemical Patents Inc. | Process of making alkylaromatics using EMM-12 |
US8704023B2 (en) * | 2008-07-28 | 2014-04-22 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition EMM-13, a method of making and a process of using the same |
KR101273039B1 (ko) * | 2008-07-28 | 2013-06-10 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 신규한 분자체 조성물 emm-12, 이의 제조 방법 및 이를 사용하는 공정 |
US8212096B2 (en) | 2008-07-28 | 2012-07-03 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using EMM-13 |
CN102216215B (zh) * | 2008-07-28 | 2014-03-26 | 埃克森美孚化学专利公司 | 使用emm-12制备烷基芳族化合物的方法 |
EP2322972A1 (fr) * | 2009-11-12 | 2011-05-18 | Johnson Controls Technology Company | Dispositif d'affichage, notamment pour véhicule automobile |
US8927769B2 (en) | 2012-08-21 | 2015-01-06 | Uop Llc | Production of acrylic acid from a methane conversion process |
US9023255B2 (en) | 2012-08-21 | 2015-05-05 | Uop Llc | Production of nitrogen compounds from a methane conversion process |
US9370757B2 (en) | 2012-08-21 | 2016-06-21 | Uop Llc | Pyrolytic reactor |
US9434663B2 (en) | 2012-08-21 | 2016-09-06 | Uop Llc | Glycols removal and methane conversion process using a supersonic flow reactor |
US8933275B2 (en) * | 2012-08-21 | 2015-01-13 | Uop Llc | Production of oxygenates from a methane conversion process |
US9656229B2 (en) | 2012-08-21 | 2017-05-23 | Uop Llc | Methane conversion apparatus and process using a supersonic flow reactor |
US9308513B2 (en) | 2012-08-21 | 2016-04-12 | Uop Llc | Production of vinyl chloride from a methane conversion process |
US9205398B2 (en) | 2012-08-21 | 2015-12-08 | Uop Llc | Production of butanediol from a methane conversion process |
US9689615B2 (en) | 2012-08-21 | 2017-06-27 | Uop Llc | Steady state high temperature reactor |
US9707530B2 (en) | 2012-08-21 | 2017-07-18 | Uop Llc | Methane conversion apparatus and process using a supersonic flow reactor |
US8937186B2 (en) | 2012-08-21 | 2015-01-20 | Uop Llc | Acids removal and methane conversion process using a supersonic flow reactor |
US9327265B2 (en) | 2012-08-21 | 2016-05-03 | Uop Llc | Production of aromatics from a methane conversion process |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE133661C (ko) * | ||||
US4182914A (en) * | 1974-01-22 | 1980-01-08 | Nippon Oil Company Limited | Process for continuously producing diisopropyl ether |
US4042633A (en) * | 1976-06-07 | 1977-08-16 | Gulf Oil Canada Limited | Process for preparing diisopropyl ether |
US4175210A (en) * | 1978-06-19 | 1979-11-20 | Gulf Research And Development Company | Etherification process |
DE3166088D1 (en) * | 1980-12-19 | 1984-10-18 | Ici Plc | Production of ethers |
US4334890A (en) * | 1981-02-03 | 1982-06-15 | The Halcon Sd Group, Inc. | Process for gasoline blending stocks |
US4418219A (en) * | 1981-03-02 | 1983-11-29 | National Distillers And Chemical Corporation | Preparation of methyl tertiary-butyl ether |
DE3117135A1 (de) * | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe |
JPS5925345A (ja) * | 1982-08-02 | 1984-02-09 | Mitsubishi Gas Chem Co Inc | 第三級エ−テルの製造法 |
US4605787A (en) * | 1984-08-16 | 1986-08-12 | Mobil Oil Corporation | Process for the preparation of alkyl tert-alkyl ethers |
NZ218939A (en) * | 1986-01-29 | 1989-11-28 | Chevron Res | Zeolite ssz-25; mole ratio of sio 2 or geo 2 to other framework oxides greater than 20 to 1 |
US4826667A (en) * | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
US4684757A (en) * | 1986-07-18 | 1987-08-04 | Mobil Oil Corporation | Process for converting methanol to alkyl ethers, gasoline, distillate and alkylate liquid hydrocarbons |
US4831195A (en) * | 1987-04-29 | 1989-05-16 | Mobil Oil Corporation | Production of ethers from methanol |
IT1205681B (it) * | 1987-05-26 | 1989-03-31 | Eniricerche Spa | Materiale sintetico cristallino poroso contenente ossidi di silicio e boro |
US4835329A (en) * | 1987-12-08 | 1989-05-30 | Mobil Oil Corporation | Process for producing high octane gasoline |
US4830635A (en) * | 1987-12-08 | 1989-05-16 | Mobil Oil Corporation | Production of liquid hydrocarbon and ether mixtures |
US4820877A (en) * | 1987-12-28 | 1989-04-11 | Mobil Oil Corporation | Etherification process improvement |
US4814519A (en) * | 1987-12-30 | 1989-03-21 | Mobil Oil Corporation | Production of ethers from olefins |
US4827046A (en) * | 1988-04-11 | 1989-05-02 | Mobil Oil Corporation | Extraction of crude methanol and conversion of raffinate |
-
1989
- 1989-12-26 US US07/456,702 patent/US4962239A/en not_active Expired - Fee Related
-
1990
- 1990-04-09 JP JP2506207A patent/JP2806630B2/ja not_active Expired - Lifetime
- 1990-04-09 EP EP90906460A patent/EP0507770B1/en not_active Expired - Lifetime
- 1990-04-09 AU AU54287/90A patent/AU632803B2/en not_active Ceased
- 1990-04-09 KR KR1019920701231A patent/KR0161298B1/ko not_active IP Right Cessation
- 1990-04-09 DK DK90906460.2T patent/DK0507770T3/da active
- 1990-04-09 ES ES90906460T patent/ES2075204T3/es not_active Expired - Lifetime
- 1990-04-09 CA CA002072102A patent/CA2072102A1/en not_active Abandoned
- 1990-04-09 WO PCT/US1990/001922 patent/WO1991009829A1/en active IP Right Grant
- 1990-04-09 DE DE69021588T patent/DE69021588T2/de not_active Expired - Fee Related
- 1990-04-09 AT AT90906460T patent/ATE126192T1/de not_active IP Right Cessation
- 1990-05-28 ZA ZA904078A patent/ZA904078B/xx unknown
- 1990-06-06 DD DD90341364A patent/DD298379A5/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2072102A1 (en) | 1991-06-27 |
EP0507770B1 (en) | 1995-08-09 |
JP2806630B2 (ja) | 1998-09-30 |
EP0507770A1 (en) | 1992-10-14 |
DE69021588D1 (de) | 1995-09-14 |
DE69021588T2 (de) | 1996-01-18 |
ES2075204T3 (es) | 1995-10-01 |
WO1991009829A1 (en) | 1991-07-11 |
ATE126192T1 (de) | 1995-08-15 |
ZA904078B (en) | 1992-01-29 |
JPH05502855A (ja) | 1993-05-20 |
AU632803B2 (en) | 1993-01-14 |
DK0507770T3 (da) | 1995-12-11 |
EP0507770A4 (en) | 1993-03-31 |
KR0161298B1 (ko) | 1999-01-15 |
AU5428790A (en) | 1991-07-24 |
DD298379A5 (de) | 1992-02-20 |
US4962239A (en) | 1990-10-09 |
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