KR920703483A - 메틸나프탈렌의 촉매적 불균등화 방법 - Google Patents

메틸나프탈렌의 촉매적 불균등화 방법

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Publication number
KR920703483A
KR920703483A KR1019920701396A KR920701396A KR920703483A KR 920703483 A KR920703483 A KR 920703483A KR 1019920701396 A KR1019920701396 A KR 1019920701396A KR 920701396 A KR920701396 A KR 920701396A KR 920703483 A KR920703483 A KR 920703483A
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South Korea
Prior art keywords
zeolite
methylnaphthalene
ray diffraction
diffraction pattern
lines described
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KR1019920701396A
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English (en)
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KR0146717B1 (ko
Inventor
제이 안게빈 필립
쥬니어 토마스 프란시스 데그난
오웬 말러 데비드
Original Assignee
에디워드 에이취. 발란스
모빌 오일 코퍼레이션
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Publication of KR920703483A publication Critical patent/KR920703483A/ko
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Publication of KR0146717B1 publication Critical patent/KR0146717B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • C07C15/24—Polycyclic condensed hydrocarbons containing two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

메틸나프탈렌의 촉매적 불균등화 방법
[도면의 간단한 설명]
제1도 내지 5도는 각각 실시예 1, 3, 4, 5 및 7의 하소된 결정성 생성물의 X-선 회절 패턴을 나타낸다.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 적어도 하나의 메틸나프탈렌을 함유하는 공급원료를 하소된 형태가 명세서중의 표1에서 기재된 라인을 포함하는 X-선 회절패턴을 갖는 제올라이트를 함유하는 촉매와 접촉시킴을 특징으로 하여, 적어도 하나의 메틸나프탈렌을 함유하는 공급원료를 불균등화 반응시켜 나프탈렌 및 적어도 하나의 디메틸나프탈렌을 함유하는 생성물을 제조하는 방법.
  2. 제1항에 있어서, 제올라이트가 명세서중의 표 II에 기재된 라인을 포함하는 X-선 회절 패턴을 갖는 방법.
  3. 제1항에 있어서, 제올라이트가 명세서중의 표 III에 기재된 라인을 포함하는 X-선 회절 패턴을 갖는 방법.
  4. 제1항에 있어서, 제올라이트가 명세서중의 표 IV에 기재된 라인을 포함하는 X-선 회절 패턴을 갖는 방법.
  5. 제1항 내지 4항중의 어느 하나에 있어서, 제올라이트가 사이클로헥산 증기에 대해서는 4.5중량% 이상이고, n-헥산 증기에 대해서는 10중량%이상인 평형 흡착 용량을 갖는 방법.
  6. 제1항 내지 4항중의 어느 하나에 있어서, 제올라이트가 몰 관계식 X2O3: (n)YO2의 조성을 가지며, 여기에서 n은 적어도 약 10이고 X는 3가 원소이며, Y가 4가 원소인 방법.
  7. 제6항에 있어서, X가 알루미늄을 포함하며 Y가 실리콘을 포함하는 방법.
  8. 제1항에 있어서, 공급원료가 2-메틸나프탈렌을 포함하는 방법.
  9. 제1항에 있어서, 전환 조건이 300 내지 675℃의 온도, 100 내지 14000KPa(대기압 내지 2000 psig)의 압력 및 0.1 내지 500의 WHSV을 포함하는 방법.
  10. 제9항에 있어서, 전환 조건이 375 내지 575℃의 온도, 240 내지 7000KPa의 압력, 및 0.5 내지 100의 WHSV을 포함하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920701396A 1989-12-21 1990-04-09 메틸나프탈렌의 촉매적 불균등화 방법 KR0146717B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/454,481 US4982040A (en) 1988-10-06 1989-12-21 Process for the catalytic disproportionation of methylnaphthalenes
US454,481 1989-12-21
US454.481 1989-12-21
PCT/US1990/001930 WO1991009824A1 (en) 1989-12-21 1990-04-09 A process for the catalytic disproportionation of methylnaphthalenes

Publications (2)

Publication Number Publication Date
KR920703483A true KR920703483A (ko) 1992-12-18
KR0146717B1 KR0146717B1 (ko) 1998-08-17

Family

ID=23804780

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920701396A KR0146717B1 (ko) 1989-12-21 1990-04-09 메틸나프탈렌의 촉매적 불균등화 방법

Country Status (10)

Country Link
US (1) US4982040A (ko)
EP (1) EP0511207B1 (ko)
JP (1) JP2790916B2 (ko)
KR (1) KR0146717B1 (ko)
AT (1) ATE117975T1 (ko)
AU (1) AU5548390A (ko)
DE (1) DE69016673T2 (ko)
DK (1) DK0511207T3 (ko)
ES (1) ES2071820T3 (ko)
WO (1) WO1991009824A1 (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5030787A (en) * 1990-01-24 1991-07-09 Mobil Oil Corp. Catalytic disproportionation/transalkylation utilizing a C9+ aromatics feed
US5329059A (en) * 1993-07-06 1994-07-12 Mobil Oil Corp. Alkylaromatic disproportionation
US5723711A (en) * 1996-11-06 1998-03-03 Kobe Steel, Ltd. Process for preparing 2-methylnaphthalene
KR100621823B1 (ko) * 2004-07-21 2006-09-14 재단법인서울대학교산학협력재단 2,6-디알킬테트랄린의 제조 방법
CN102527428B (zh) * 2006-02-14 2014-11-26 埃克森美孚化学专利公司 制备分子筛组合物的方法
US7799316B2 (en) * 2006-02-14 2010-09-21 Exxonmobil Chemical Patents Inc. Process for manufacturing MCM-22 family molecular sieves
US7846418B2 (en) * 2006-02-14 2010-12-07 Exxonmobil Chemical Patents Inc. MCM-22 family molecular sieve composition
US7959899B2 (en) * 2006-07-28 2011-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions
WO2008016456A2 (en) 2006-07-28 2008-02-07 Exxonmobil Chemical Patents Inc. Molecular sieve composition (emm-10), its method of making, and use for hydrocarbon conversions
WO2008013639A1 (en) 2006-07-28 2008-01-31 Exxonmobil Chemical Patents Inc. Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions
CN102216215B (zh) * 2008-07-28 2014-03-26 埃克森美孚化学专利公司 使用emm-12制备烷基芳族化合物的方法
US8212096B2 (en) 2008-07-28 2012-07-03 Exxonmobil Chemical Patents Inc. Hydroalkylation of aromatic compounds using EMM-13
WO2010014404A1 (en) * 2008-07-28 2010-02-04 Exxonmobil Chemical Patents Inc. Process of making alkylaromatics using emm-13
KR101273039B1 (ko) * 2008-07-28 2013-06-10 엑손모빌 케미칼 패턴츠 인코포레이티드 신규한 분자체 조성물 ｅｍｍ-12, 이의 제조 방법 및 이를 사용하는 공정
US8466333B2 (en) 2008-07-28 2013-06-18 Exxonmobil Chemical Patents Inc. Process of making alkylaromatics using EMM-12
US8704023B2 (en) * 2008-07-28 2014-04-22 Exxonmobil Chemical Patents Inc. Molecular sieve composition EMM-13, a method of making and a process of using the same
EP2322972A1 (fr) * 2009-11-12 2011-05-18 Johnson Controls Technology Company Dispositif d'affichage, notamment pour véhicule automobile

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855328A (en) * 1971-12-14 1974-12-17 Sun Research Development Isomerization and/or transalkylation and/or disproportionation of alkylnaphthalenes
US4418235A (en) * 1980-02-14 1983-11-29 Mobil Oil Corporation Hydrocarbon conversion with zeolite having enhanced catalytic activity
DE3117135A1 (de) * 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
JPS58145616A (ja) * 1982-02-22 1983-08-30 Teijin Yuka Kk 新規結晶性アルミノシリケ−トゼオライト及びその製造法
US4465253A (en) * 1983-04-19 1984-08-14 The United States Of America As Represented By The Secretary Of The Air Force Flexible line support assembly
JPS6045536A (ja) * 1983-08-22 1985-03-12 Teijin Yuka Kk メチル置換ナフタレン類のトランスメチル化方法
JPH0811739B2 (ja) * 1983-10-25 1996-02-07 三菱化学株式会社 メチルナフタレン類の不均化方法
US4670615A (en) * 1984-12-18 1987-06-02 Mobil Oil Corporation Hydrocarbon compound conversion
DE3681493D1 (de) * 1985-04-22 1991-10-24 Ici Plc Alkylierungsverfahren.
US4717780A (en) * 1985-06-27 1988-01-05 Mobil Oil Corp. Catalytic aromatics conversion
NZ218939A (en) * 1986-01-29 1989-11-28 Chevron Res Zeolite ssz-25; mole ratio of sio 2 or geo 2 to other framework oxides greater than 20 to 1
US4826667A (en) * 1986-01-29 1989-05-02 Chevron Research Company Zeolite SSZ-25
US4723049A (en) * 1987-05-18 1988-02-02 Cosden Technology, Inc. Toluene disproportionation process
US4761514A (en) * 1987-05-18 1988-08-02 Cosden Technology, Inc. Toluene disproportionation process
IT1205681B (it) * 1987-05-26 1989-03-31 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio e boro

Also Published As

Publication number Publication date
AU5548390A (en) 1991-07-24
KR0146717B1 (ko) 1998-08-17
DE69016673T2 (de) 1995-06-01
EP0511207A4 (en) 1992-09-03
ES2071820T3 (es) 1995-07-01
US4982040A (en) 1991-01-01
JP2790916B2 (ja) 1998-08-27
EP0511207A1 (en) 1992-11-04
DE69016673D1 (de) 1995-03-16
JPH05502012A (ja) 1993-04-15
DK0511207T3 (da) 1995-04-10
WO1991009824A1 (en) 1991-07-11
EP0511207B1 (en) 1995-02-01
ATE117975T1 (de) 1995-02-15

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