KR920701087A - C_9^+ 방향족의 접촉전환법 - Google Patents

C_9^+ 방향족의 접촉전환법

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Publication number
KR920701087A
KR920701087A KR1019910700789A KR910700789A KR920701087A KR 920701087 A KR920701087 A KR 920701087A KR 1019910700789 A KR1019910700789 A KR 1019910700789A KR 910700789 A KR910700789 A KR 910700789A KR 920701087 A KR920701087 A KR 920701087A
Authority
KR
South Korea
Prior art keywords
zeolite
ray diffraction
lines
diffraction pattern
aromatic compound
Prior art date
Application number
KR1019910700789A
Other languages
English (en)
Other versions
KR100210191B1 (ko
Inventor
피터 레오나드 압실 로비트
데이튼 창 크라렌스
한 스코트
오웬 말러 데이비드
새드 시하비 데이비드
Original Assignee
에드워드 에이취. 바란스
모빌오일 코퍼레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/449,169 external-priority patent/US4973784A/en
Application filed by 에드워드 에이취. 바란스, 모빌오일 코퍼레이션 filed Critical 에드워드 에이취. 바란스
Publication of KR920701087A publication Critical patent/KR920701087A/ko
Application granted granted Critical
Publication of KR100210191B1 publication Critical patent/KR100210191B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C07C4/18—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Financial Or Insurance-Related Operations Such As Payment And Settlement (AREA)
  • Multi-Process Working Machines And Systems (AREA)

Abstract

내용 없음

Description

C9+방향족의 접촉전환법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시에 1의 하소된 결정성 생성물의 X-선 회절 패턴을 나타낸 것이다. 제2도는 실시예 3의 하소된 결정성 생성물의 X-선 회절 패턴을 나타낸 것이다. 제3도는 실시예 4의 하소된 결정성 생성물의 X-선 회절패턴을 나타낸 것이다.

Claims (12)

  1. 최소한 한 종류의 C9 +방향족 화합물이 함유된 공급액을 컨스트레인트 인덱스가 1-3인 제올라이트로 이루어진 전환촉매와 접촉하여 C6-C8방향족 화합물이 함유된 생성물로 전환하는 방법.
  2. 1항에서, 제올라이트가 제올라이트 β이거나 ZSM-12인 방법.
  3. 1항에서, 제올라이트의 X-선 회절패턴이 명세서중 표 Ⅰ의 라인을 지님이 특징인 방법.
  4. 1항에서, 제올라이트의 X-선 회절패턴이 명세서중 표 Ⅱ의 라인을 지님이 특징인 방법.
  5. 1항에서, 제올라이트의 X-선 회절패턴이 명세서중 표 Ⅲ의 라인을 지님이 특징인 방법.
  6. 1항에서, 제올라이트의 X-선 회절패턴이 명세서중 표 Ⅳ의 라인을 지님이 특징인 방법.
  7. 3-6항중 어느 하나에서, 제올라이트의 평형 흡착용량이 사이클로헥산 증기에 대해서 4.5wt%이상, n-헥산 증기에 대해서 10wt%이상인 방법.
  8. 3-6항중 어느 하나에서, 몰비에 관한 제올라이트 조성이 다음과 같은 방법.
    X2O3: (n)YO2
    여기서 n은 최소한 10, X는 3가 원소, Y는 4가 원소.
  9. 8항에서, X가 알루미늄, Y가 실리콘인 방법.
  10. 1항에서, 공급액중 C9 +방향족 화합물이 트리메틸벤젠, 디메틸에틸벤젠, 디에틸벤젠 그리고 이들의 혼합물중에서 선택된 방법.
  11. 1항에서, C9 +방향족 화합물(들)이 전체 공급액의 최소한 3무게%를 차지하고 나머지는 톨루엔 및/또는 벤젠인 방법.
  12. 1항에서, 전환조건에서 온도가 90-675℃, 압력이 100-7000(대기압-1000psig), 수소/탄화수소 몰비가 0.1-500인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700789A 1989-12-13 1990-04-09 C9+ 방향족의 접촉 전환법 KR100210191B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US449,169 1989-12-13
US07/449,169 US4973784A (en) 1988-10-06 1989-12-13 Process for reducing the durene content of effluent resulting from the catalytic conversion of C1 -C4 oxygenates to gasoline
US46964590A 1990-01-24 1990-01-24
US469645 1990-01-24
US469,645 1990-01-24
PCT/US1990/001895 WO1991008998A1 (en) 1989-12-13 1990-04-09 A process for the catalytic conversion of a c9+ aromatics feed
US449169 2003-05-30

Publications (2)

Publication Number Publication Date
KR920701087A true KR920701087A (ko) 1992-08-11
KR100210191B1 KR100210191B1 (ko) 1999-07-15

Family

ID=27035626

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910700789A KR100210191B1 (ko) 1989-12-13 1990-04-09 C9+ 방향족의 접촉 전환법

Country Status (17)

Country Link
EP (1) EP0457853B1 (ko)
JP (1) JP2801775B2 (ko)
KR (1) KR100210191B1 (ko)
AT (1) ATE156471T1 (ko)
AU (1) AU635261B2 (ko)
BG (1) BG61142B1 (ko)
BR (1) BR9007077A (ko)
CA (1) CA2042361C (ko)
DE (1) DE69031214T2 (ko)
DK (1) DK0457853T3 (ko)
ES (1) ES2104604T3 (ko)
HU (1) HU212752B (ko)
NO (1) NO300371B1 (ko)
RO (1) RO108555B1 (ko)
RU (1) RU2011650C1 (ko)
SG (1) SG43877A1 (ko)
WO (1) WO1991008998A1 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5488194A (en) * 1994-05-16 1996-01-30 Mobil Oil Corp. Selective production of para-dialkyl substituted benzenes and catalyst therefor
US6504076B1 (en) * 2001-05-18 2003-01-07 Fina Technology, Inc. Method of conversion of heavy aromatics
WO2007114127A1 (ja) * 2006-03-29 2007-10-11 Toray Industries, Inc. エチルベンゼンの転化方法およびパラキシレンの製造方法
JP5292699B2 (ja) * 2006-03-29 2013-09-18 東レ株式会社 エチルベンゼンの転化方法およびパラキシレンの製造方法
ITMI20061548A1 (it) * 2006-08-03 2008-02-04 Polimeri Europa Spa Composizioni catalitiche per idrodealchilazioni altamente selettive di idrocarburi alchilaromatici
TWI473652B (zh) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
WO2011090124A1 (ja) 2010-01-20 2011-07-28 Ｊｘ日鉱日石エネルギー株式会社 炭化水素製造用触媒および炭化水素の製造方法
US20130030232A1 (en) 2010-01-20 2013-01-31 Jx Nippon Oil & Energy Corporation Catalyst for production of monocyclic aromatic hydrocarbons and method of producing monocyclic aromatic hydrocarbons
EP2957622A1 (en) * 2010-03-26 2015-12-23 JX Nippon Oil & Energy Corporation Method for producing monocyclic aromatic hydrocarbons
US9862897B2 (en) 2013-02-21 2018-01-09 Jx Nippon Oil & Energy Corporation Method for producing monocyclic aromatic hydrocarbon

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4046827A (en) * 1975-09-26 1977-09-06 Mobil Oil Corporation High selectivity transalkylation
JPS5278838A (en) * 1975-12-22 1977-07-02 Mobil Oil Method of carrying out alternatively catalytic conversion reaction and thermal dealkylation of alkylaromatic hydocarbons in single reactor
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4251676A (en) * 1979-12-28 1981-02-17 Mobil Oil Corporation Selective cracking reactions by cofeeding organic amine or ammonia
US4418235A (en) * 1980-02-14 1983-11-29 Mobil Oil Corporation Hydrocarbon conversion with zeolite having enhanced catalytic activity
US4575573A (en) * 1981-11-09 1986-03-11 Mobil Oil Corporation Catalysis over activated zeolites
US4577048A (en) * 1981-12-22 1986-03-18 Mobil Oil Corporation Catalysis over activated high silica zeolites
US4599470A (en) * 1982-11-18 1986-07-08 The British Petroleum Company P.L.C. Process for the transalkylation or dealkylation of alkyl aromatic hydrocarbons
JPS60246330A (ja) * 1984-05-21 1985-12-06 Idemitsu Petrochem Co Ltd ベンゼンおよびメチル置換ベンゼンの製造方法
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta

Also Published As

Publication number Publication date
DK0457853T3 (da) 1998-02-16
RU2011650C1 (ru) 1994-04-30
AU635261B2 (en) 1993-03-18
HUT58672A (en) 1992-03-30
NO300371B1 (no) 1997-05-20
DE69031214T2 (de) 1998-02-26
WO1991008998A1 (en) 1991-06-27
BG94991A (bg) 1993-12-24
DE69031214D1 (de) 1997-09-11
BG61142B1 (bg) 1996-12-31
ATE156471T1 (de) 1997-08-15
EP0457853A1 (en) 1991-11-27
JPH04504577A (ja) 1992-08-13
NO912711L (no) 1991-08-29
JP2801775B2 (ja) 1998-09-21
HU903627D0 (en) 1991-10-28
BR9007077A (pt) 1992-03-03
NO912711D0 (no) 1991-07-10
ES2104604T3 (es) 1997-10-16
EP0457853A4 (en) 1992-06-03
EP0457853B1 (en) 1997-08-06
CA2042361A1 (en) 1991-06-14
CA2042361C (en) 2000-12-19
KR100210191B1 (ko) 1999-07-15
HU212752B (en) 1996-10-28
AU5443190A (en) 1991-07-18
RO108555B1 (ro) 1994-06-30
SG43877A1 (en) 1997-11-14

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