KR910011915A - 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법 - Google Patents

올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법 Download PDF

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KR910011915A
KR910011915A KR1019900021918A KR900021918A KR910011915A KR 910011915 A KR910011915 A KR 910011915A KR 1019900021918 A KR1019900021918 A KR 1019900021918A KR 900021918 A KR900021918 A KR 900021918A KR 910011915 A KR910011915 A KR 910011915A
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compound
organic aluminum
titanium
olefin
catalyst
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KR1019900021918A
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KR940006217B1 (ko
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도시유끼 쓰쓰이
겐지 스끼무라
다까시 우에다
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다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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Priority claimed from JP34091889A external-priority patent/JP2837720B2/ja
Priority claimed from JP34091289A external-priority patent/JP2953522B2/ja
Priority claimed from JP34091589A external-priority patent/JP2953524B2/ja
Application filed by 다께바야시 쇼오고, 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 filed Critical 다께바야시 쇼오고
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Abstract

내용 없음

Description

올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에서, 사용되는 벤젠 불용성의 유기알미늄 옥시화합물의 IR 스펙트럼을 나타낸는 그래프.

Claims (10)

  1. 〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 티타늄 촉매성분과, 〔B-1〕시클로알카디에닐 골격을 갖는 리간드를 함유하는 천이금속 화합물과, 〔C〕유기알미늄 옥시화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  2. 〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 티타늄 촉매성분과, 〔B-1〕시클로알카디에닐 골격을 갖는 리간드를 함유하는 천이금속 화합물과, 〔C〕유기알미늄 옥시화합물과, 〔D〕유기 알미늄 화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  3. 〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-1〕시클로알카디에닐 골격을 갖는 리간드를 함유하는 천이금속 화합물과, 〔C〕유기알미늄 옥시화합물과을 함유하는 현탁액중에서 올레핀을 예비중합시켜 제조된 것이 특징인 올레핀 중합용촉매.
  4. 〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-1〕시클로알카디에닐 골격을 갖는 리간드를 함유하는 천이금속 화합물과, 〔C〕유기알미늄 옥시화합물과, 〔D〕유기알미늄 화합물을 현탁액중에서 오레핀을 예비중합시켜 제조된 것이 특징인 올레핀 중합용촉매.
  5. (Ⅰ)〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-1〕시클로알카디에닐 골격을 갖는 리간드를 함유하는 천이금속 화합물과, 〔C〕유기알미늄 옥시화합물과 현탁액중에서 올레핀을 예비중합시켜 제조한 고체촉매와 (Ⅱ)〔C〕유기 알미늄 옥시화합물 및/또는〔D〕유기알미늄 화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  6. (Ⅰ)〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-1〕시클로알카디에닐 골격을 갖는 리간드를 함유하는 천이금속 화합물과, 〔C〕유기알미늄 옥시화합물및〔D〕유기알미늄 화합물을 함유하는 현탁액중에서 올레핀을 예비중합시켜 제조한 고체 촉매와, (Ⅱ)〔C〕유기알미늄 옥시화합물 및/또는〔D〕유기알미늄 화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  7. 〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-2〕시클로알카디에닐 골격을 갖는 리간드와, 붕소를 함유하는 음이온을 함유하는 천이금속 및〔C〕유기알미늄 옥시화합물 및/또는〔D〕유기 알미늄 화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  8. (Ⅰ)〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-2〕시클로알카디에닐 골격을 갖는 리간드와, 붕소를 함유하는 음이온을 함유하는 천이금속 화합물을 함유하는 현탁액중에서 올레핀을 예비 중합시켜 제조한 고체 촉매성분과, (Ⅱ)〔C〕유기 알미늄 옥시화합물 및/또는〔D〕유기알미늄 화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  9. (Ⅰ)〔A〕티타늄, 마그네슘, 및 할로겐을 필수성분으로 하는 고체 티타늄 촉매성분과, 〔B-2〕시클로알카디에닐 골격을 갖는 리간드와, 붕소를 함유하는 음이온을 함유하는 천이금속 화합물및 〔C〕유기알미늄 옥시화합물과, 및/또는〔D〕유기 알미늄 화합물을 함유하는 것이 특징인 올레핀 중합용촉매.
  10. 제1∼9항에 있어서, 임의의 1항의 올레핀 중합용 촉매의 존재하에서 올레핀을 중합, 또는 공중합시키는 것이 특징인 올레핀 중합방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900021918A 1989-12-29 1990-12-27 올레핀 중합용 촉매 및 이 올레핀 중합용 촉매를 사용한 올레핀의 중합방법 KR940006217B1 (ko)

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JP34091889A JP2837720B2 (ja) 1989-12-29 1989-12-29 オレフィン重合用触媒およびオレフィンの重合方法
JP1-340918 1989-12-29
JP34091289A JP2953522B2 (ja) 1989-12-29 1989-12-29 オレフィン重合用固体触媒およびオレフィンの重合方法
JP34091589A JP2953524B2 (ja) 1989-12-29 1989-12-29 オレフィン重合用触媒およびオレフィンの重合方法
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