KR900007805A - 살충 활성이 있는 니트로 화합물 - Google Patents

살충 활성이 있는 니트로 화합물 Download PDF

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KR900007805A
KR900007805A KR1019890017215A KR890017215A KR900007805A KR 900007805 A KR900007805 A KR 900007805A KR 1019890017215 A KR1019890017215 A KR 1019890017215A KR 890017215 A KR890017215 A KR 890017215A KR 900007805 A KR900007805 A KR 900007805A
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chloro
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고조 시오카와
신이치 쯔보이
고이치 모리야
유미 하토리
이쿠로 혼다
가츠히코 시부야
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다테노 고자부로
니혼 도큐수 노야쿠 세이조 가부시키가이샤
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    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/36—Radicals substituted by singly-bound nitrogen atoms
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61—Halogen atoms or nitro radicals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01—Chemical elements
    • H01L2924/01006—Carbon [C]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
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Abstract

내용 없음

Description

살충 활성이 있는 니트로 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 일반식(Ⅰ)의 신규 니트로 화합물
    상기식에서, R1및 R2는 수소 또는 C1-4알킬이고, R3는 -S-R4또는(여기에서, R4는 C1-4알킬이고, R5및 R6는 수소 또는 C1-4알킬이다)이며, Y는 CH 또는 N이고, Z는 할로겐 또는 C1-C4알킬로 치환될 수 있는 질소원자 하나 이상을 갖는 5- 또는 6-원헤테로사이클릭 그룹이며, 단 Y가 CH일 때, R1은 C1-C4알킬이다.
  2. 제1항에 있어서, R1및 R2가 수소 또는 메틸이고, R3가 -S-R4또는(여기에서, R4는 메틸이고, R5및 R6는 수소 또는 메틸이다)이며, Y가 CH 또는 N이고, Z가 염소 또는 메틸로 치환될 수 있는 3-피리딜, 4-피리딜 또는 5-티아졸릴이며, 단 Y가 CH일 때, R1이 메틸인 일반식(Ⅰ)의 니트로 화합물.
  3. 제1항에 있어서, R1및 R2가 수소 또는 메틸이고,(여기에서, R5및 R6는 수소 또는 메틸이다)이며, Y가 CH 또는 N이고, Z가 2-클로로-5-피리딜 또는 2-클로로-5-티아졸릴이며, 단 Y가 CH일 때, R1이 메틸인 일반식(Ⅰ)의 화합물.
  4. 제1항에 있어서, R1및 R2가 수소 또는 메틸이고, R3가(여기에서, R5및 R6는 수소 또는 메틸이다)이며, Y가 CH 또는 N이고, Z가 2-클로로-5-피리딜 또는 2-클롤-5-티아졸릴이며, 단 Y가 CH일때, R1이 메틸이거나 R2가 수소이고 R3가(여기에서, R5와 R6중 어느 하나는 수소이고, 나머지 하나는 메틸이다) 이때, Y가 N인 일반식(Ⅰ)의 화합물.
  5. 제1항에 있어서, R1및 R2가 수소 또는 메틸이고, R3가(여기에서, R5및 R6는 수소 또는 메틸이다)이며, Y가 N이고, Z가 2-클로로-5-피리딜인 일반식(Ⅰ)의 화합물.
  6. 제1항에 있어서, 개개 구조가
    구조식의 3-(2-클로로-5-피리딜메틸)-1-메틸-2-니트로구아니딘,
    구조식의 3-(-2-클로로-5-피리딜메틸)-1,1-1-디메틸-2-니트로구아니딘,
    구조식의 3-(-2-클로로-5-피리딜메틸)-1.3-디메틸-2-니트로구아니딘,
    구조식의 3-(-2-클로로-5-피리딜메틸)-1,1,3-트리메틸-2-니트로구아니딘,
    구조식의 3-(-2-클로로-5-피리딜메틸)-3-메틸-2-니트로구아니딘,
    구조식의 [1-(-2-클로로-5-피리딜)에틸아미노]-1-디메틸아미노-2-니트로에틸렌,
    구조식의 -아미노-1-[1-(2-클로로-5-피리딜)-에틸아미노]-2-니트로에틸렌,
    구조식의 1-[1(2-클로로-5-피리딜)에틸아미노]-1-메틸아미노-2-니트로에틸렌,
    구조식의 1-{N-[1-(2-클로로-5-피리딜)에틸]-N-메틸아미노}-1-디메틸아미노 -2-니트로에틸렌, 및
    구조식3-2-클로로-5-티아졸릴메틸)-1-메틸-2-니트로구아니딘인 일반식(Ⅰ)의 화합물.
  7. a)[R3가 -S-R4이고 Y가 CH일 때, R1이 R7(여기에서, R7은 C1-4알킬이다)으로 치환될 경우] 일반식(Ⅱ)의 화합물(여기에서, R4는 제1항에서 정의한 바와 같다)을 불활성 용매의 존재하에 일반식(Ⅲ)의 화합물(여기에서, R7, R2및 Z는 제1항에서 정의한 바와 같다)과 반응시키거나, b)(R3가 |이고 Y가 CH일 때, R1이 R7으로 치환될 경우)일반식(Ⅰa)의 화합물(여기에서, R7, R2, R4및 Z는 제1항에서 정의한 바와 같다)을 불활성 용매의 존재하에 일반식(Ⅳ)의 화합물(여기에서, R5및 R6는 제1항에서 정의한 바와 같다)과 반응시키거나, c)(R3가 -S-R4이고 Y가 N일 경우)일반식(Ⅴ)의 화합물(여기에서, R2및 R2는 제1항에서 정의한 바와 같다)을 불활성 용매의 존재하에, 및 경우에 따라 산 결합재의 존재하에 일반식(Ⅵ)의 화합물(여기에서, R1및 Z는 제1항에서 정의한 바와 같고, Hal은 할로겐 원자를 나타낸다)과 반응시키거나, d)(R3가이고 Y가 N일 경우, 일반식 (Ⅰc)의 화합물(여기에서, R1, R2, R4및 Z는 제1항에서 정의한 바와 같다)를 불활성 용매의 존재하에 상기 일반식(Ⅳ)의 화합물과 반응시킴을 특징으로 하여 일반식(Ⅰ)의 니트로 화합물을 제조하는 방법.
    상기식에서, R1및 R2는 수소 또는 C-4알킬이고, R3는 -S-R4또는(여기에서, R4는 C-4알킬이고, Z는 할로겐 또는 C-4알킬로 치환될 수 있는 질소원자 하나 이상을 갖는 5- 또는 6-원 헤테로사이클릭 그룹이며, 단, Y가 CH일 경우, R1이 C-4알킬이다.
  8. 일반식(Ⅰ)의 니트로 화합물 하나 이상을 함유함을 특징으로 하는 살충용 조성물.
  9. 일반식(Ⅰ)의 니트로 화합물을 해충 및/또는 이의 서식지에 작용시킴을 특징으로 하여 해충을 방제하는 방법.
  10. 해충을 방제하기 위한 일반식(Ⅰ)의 니트로 화합물의 용도.
  11. 일반식(Ⅰ)의 니트로 화합물을 중량제 및/또는 계면 활성제와 혼합함을 특징으로 하여 살충용 조성물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890017215A 1988-11-29 1989-11-27 살충 활성이 있는 니트로 화합물 KR0149000B1 (ko)

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JP88-299419 1988-11-29
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EP0375907B1 (en) 1996-01-03
PH26414A (en) 1992-07-15
DE68925352T2 (de) 1996-05-15
ES2080739T3 (es) 1996-02-16
HU206432B (en) 1992-11-30
DE68925352D1 (de) 1996-02-15
DE122007000075I2 (de) 2008-04-17
JP2779403B2 (ja) 1998-07-23
BR8905999A (pt) 1990-06-19
KR0149000B1 (ko) 1998-10-15
US5051434A (en) 1991-09-24
NL350039I1 (nl) 2009-01-05
HUT51862A (en) 1990-06-28

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