KR880001597A - 알킬렌디아민 - Google Patents

알킬렌디아민 Download PDF

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KR880001597A
KR880001597A KR1019870006853A KR870006853A KR880001597A KR 880001597 A KR880001597 A KR 880001597A KR 1019870006853 A KR1019870006853 A KR 1019870006853A KR 870006853 A KR870006853 A KR 870006853A KR 880001597 A KR880001597 A KR 880001597A
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hydrogen
alkyl
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nitrogen
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KR950006711B1 (ko
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고조 시오까와
시니찌 쓰보이
신조 가가부
쇼꼬 사사끼
고이찌 모리야
유미 하또리
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고자부로 다떼노
니혼 도꾸슈 노야꾸 세이조 가부시끼가이샤
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    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
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    • C07D285/10—1,2,5-Thiadiazoles; Hydrogenated 1,2,5-thiadiazoles

Abstract

내용 없음

Description

알킬렌디아민
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 일반식(I)의 알킬렌디아민.
    상기식에서, W1은 산소, 황 및 질소중에서 선택된 적어도 하나의 헤테로 원자를 함유하는, 치환될 수 있는 5-또는 6-원 헤테로사이클릭 그룹이고, R1, R2및, R3은 수소 또는 알킬이며, R4는 수소, 알킬, 아릴, 아르알킬, 알콕시, 다알킬아미노, 알콕시알킬, 알킬티오알킬 또는 -CH2-W2(여기에서, W2는 상술한 W1과 동일한 의미를 가는다)이고, X는 황, -- (여기에서, R5는 수소 또는 알킬이다) 또는 단일 결합이며, X가 --R4는 일반식(I)에서의 그룹와 동일한 의미를 가질 수 있고, Y는 질소 또는(여기에서, R6는 수소, 알킬, 아릴, 아실 또는 시아노이다)이며, Z는 시아노 또는 니트로이고, A는 알킬에 의해 치환될 수 있는 에틸렌 또는 트리메틸렌이다.
  2. 제1항에 있어서, R1, R2및 R3는 수소 또는 C1-4알킬이고, R4는 수소, C1-4알킬, C6-10아릴, 벤질, 페네틸, C1-4알콕시, 총 탄소수 2 내지 6의 디알킬아미노, 총 탄소수 2 내지 6의 알콕시알킬, 총 탄소수 2 내지 4의 알킬티오알킬 또는 일반식 -CH2-W2(여기에서, W2는 상술한 W1과 동일한 의미를 갖는다)의 그룹이며, X는 황 또는 --(여기에서, R6는 수소 또는 C1-4알킬이다) 이고, X가인경우에 일반식(I)에서의 그룹는 일반식(I)에서의 그룹와 동일한 의미를 가지며, Y는 질소 또는(여기에서, R6는 수소, C1-4알킬, C6-10아릴, C1-4알킬카보닐, C1-4알콕시를 갖는 알콕시카보닐, 또는 시아노이다)이고, Z는 시아노 또는 니트로 이며, Z는 시아노 또는 니트로 이며, W1은 산소, 황 및 질소중에서 선택된 헤테로 원자 1 내지 3개를 함유하며 이들중 적어도 하나가 질소인 5 또는 6-원 헤테로사이클릭 그룹이고, 여기에서 그룹 W1은 할로겐, C1-4-알킬,C1-4-알콕시, C1-4-알킬티오, C1-4-할로알킬 및 C1-4-할로알콕시 중에서 선택된 적어도 하나의 치환체에 의해 임의로 치환되며, A는 메틸에 의해 임의로 치환될 수 있는 에틸렌 또는 메틸에 의해 임의 치환될 수 있는 트리메틸렌인 화합물.
    제1항에 있어서, R1, R2및 R3는 수소, 메틸 또는 에틸이고, R4는 수소, 메틸, 에틸, 페닐, 벤질, 메톡시, 디메틸아미노, 1-에톡시에틸, 1-에틸-티오에틸 또는 2-클로로-5-피리딜메틸이며, X는 황 또는(여기에서, R5는 수소 또는 메틸이다)이고, Y는 질소 또는(여기에서, R6는 수소, 메틸, 페닐, 아세틸, 에톡시카보닐 또는 시아노 이다)이고, Z는 시아노 또는 니토로 이며, W1은 산소, 황 및 질소중에서 선택된 헤테로 원자 1 내지 2개를 함유하며 이드중 적어도 하나가 질소인 5 또는 6-원 헤테로사이클릭 그룹이고, 여기에서 그룹 W1은 플루오로, 클로로, 브로모, 메틸, 메톡시, 메틸티오, 트리플루오로메틸 및 트리플루오로메톡시 중에서 선텍된 적어도 하나의 치환체에 의해 임의로 치환되며, A는 에틸렌 또는 트리메틸렌인 화합물.
  3. 내용 없음
  4. 제1 내지 3항중 어느 한 항에 있어서, 하기 화합물중의 하나중에서 선택된 알킬렌디아민 화합물.
    a) 하기구조식의 N-(2-클로로-5-피리딜메틸)-N-N'-(1-메틸티오-2-니트로비닐)에틸렌디아민
    b) 하기 구조식의 N-(2-클로로-5-피리딜메틸)-N-에틸-N'-(1-메틸티오-2-니트로비닐)에틸렌디아민
    c) 하기 구조식의 N-(2-클로로-5-피리딜메틸)-N'-(1-머캅토-2-니트로비닐)에틸렌디아민
    d) 하기 구조식의 N-(2-클로로-5-피리딜메틸)-N'-(1-머캅토-2-니트로비닐)트리메틸렌디아민
    e) 하기 구조식의 N-(2-클로로-5-피리딜메틸)-N-메틸-N'-(1-에틸티오-2-니트로비닐)에틸렌디아민
    f) 하기 구조식의 N-(2-클로로-5-피리딜메틸)-N-메틸-N'-(1-프로필티오-2-니트로비닐)에틸렌디아민
  5. a) X가 황이고, R4가 정의에서 "알콕시" 및 "디알킬아미노"이외의 정의를 가지며, 하기 일반식(III)에서 R4가 기호 R7으로 대치되나, 단 2개의 R"이 동시에 수소가 아닌 경우에는, 일반식(II)의 화합물을 불활성 용매의 존재하에 일반식(III)의 화합물과 반응시키거나 :
    b) X가인 경우에는, 일반식(VI)의 화합물을 불활성 용매의 존재하에 일반식(V)의 화합물과 반응시키거나 :
    c) X가이고, Y가 질소인 경우에는, 일반식(II)의 화합물을 불활성 용매의 존재하에 일반식(VI)의 화합물과 반응시키거나 :
    d) Y가이고, X가 단일결합이며, R4가 기호 R7으로 대치되는 경우에는, 일반식(II)의 화합물을 불활성 용매의 존재하에 일반식(VII)의 화합물과 반응시키거나 :
    e) X가 황이고, R4가 정의에서 "수소", "알콕시" 및 "디알킬아미노" 이외의 정의를 가지며 하기 일반식(IX)에서 R4가 기호 R8로 대치되는 경우에는, 일반식(VIII)의 화합물의 불활성 용매의 존재하 및 경우에 따라 염기의 존재하에 일반식(IX)의 화합물과 반응시킴을 특징으로 하여 일반식(I)의 알킬렌디아민을 제조하는 방법.
    상기식에서, W1은 산소, 황 및 질소중에서 선택된 적어도 하나의 헤테로 원자를 함유하는, 치환될 수 있는 5- 또는 6-원 헤테로사이클릭 그룹이고, R1, R2및 R3는 수로 또는 알킬이며, R4는 수소, 알킬, 아릴, 아르알킬, 알콕시, 디알킬아미노, 알콕시알킬, 알킬티오알킬 또는 -CH2-W2(여기에서, W2는 상술한 W1과 동일한 의미를 갖는다)이고, X는 황,(여기에서, R6는 수소 또는 알킬이다) 또는 단일 결합이며, X가인 경우에 일반식(I)에서의 그룹는 일반식(I)에서의 그룹와 동일한 의미를 갖고, Y는 질소 또는(여기에서, R6는 수소, 알킬, 아릴, 아실 또는 시아노이다)이며, Z는 시아노 또는 니트로이고, A는 알킬에 의해 치환될 수 있는 에틸렌 또는 트리메틸렌이며, R7은 알콕시 그룹 및 디알킬아미노 그룹을 제외한 R4의 정의와 동일하고, R8은 수소, 알콕시 그룹 및 디알킬아미노 그룹을 제외한 R4의 정의와 동일하며, Hal은 할로겐이다.
  6. 일반식(I)의 알킬렌디아민을 하나 이상 함유함을 특징으로 하는 살충 조성물.
  7. 일반식(I)의 알킬렌디아민을 해충 및/또는 그의 서식지에 작용시킴을 특징으로 하여 해충을 박멸하는 방법.
  8. 해충을 박멸하기 위한 일반식(I)에 따른 알킬렌디아민의 용도.
  9. 일반식(I)의 알킬렌디아민을 중량제 및/또는 계면활성제와 혼합함을 특징으로 하여 살충 조성물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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