KR20080028997A - 금속 재료용 수계 표면 처리제 및 표면 피복 금속 재료 - Google Patents
금속 재료용 수계 표면 처리제 및 표면 피복 금속 재료 Download PDFInfo
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- KR20080028997A KR20080028997A KR1020087003559A KR20087003559A KR20080028997A KR 20080028997 A KR20080028997 A KR 20080028997A KR 1020087003559 A KR1020087003559 A KR 1020087003559A KR 20087003559 A KR20087003559 A KR 20087003559A KR 20080028997 A KR20080028997 A KR 20080028997A
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- Prior art keywords
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- acid
- resin
- metal material
- organic compound
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- 239000003960 organic solvent Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- LYTNHSCLZRMKON-UHFFFAOYSA-L oxygen(2-);zirconium(4+);diacetate Chemical compound [O-2].[Zr+4].CC([O-])=O.CC([O-])=O LYTNHSCLZRMKON-UHFFFAOYSA-L 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
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- 239000012466 permeate Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
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- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 238000007493 shaping process Methods 0.000 description 1
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- 238000003756 stirring Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
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- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
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Abstract
Description
Claims (12)
- 50℃ 를 초과하는 유리 전이 온도 및 40℃ 이하의 최저 막 형성 온도를 갖는 수분산성 우레탄 수지 (A), 메틸올화 페놀 및 그 축합물, 카르보디이미드 수지, 에폭시계 수지, 실란커플링제, 유기 포스폰산류 및 그 부분적 알칼리 금속염 또는 암모늄염 또는 탄소수 1 ∼ 4 인 알칸올과의 부분적인 에스테르, 유기 포스핀산류, 폴리올의 인산에스테르, 아민 화합물, 이소시아네이트 화합물, 알데히드 화합물, 카르복실산, 아미노 수지, 그리고 이소시아나토기에 중아황산 알칼리 금속염을 부가시킴으로써 이소시아나토기를 보호한 우레탄프리폴리머에서 선택되는 적어도 1 종의 유기 화합물 (B), 및 지르코늄 화합물 (C) 을 물에 배합하여 이루어지는 금속 재료용 수계 표면 처리제.
- 제 1 항에 있어서,우레탄 수지 (A) 의 산가(酸價)가 15 ∼ 40 의 범위이고, 또한 그 수지의 피막 물성으로서, 항장력이 40 ∼ 90N/㎟ 이고, 또한 신도가 50 ∼ 500% 인 수계 표면 처리제.
- 제 1 항 또는 제 2 항에 있어서,유기 화합물 (B) 이 메틸올화 페놀 및 그 축합물 그리고 카르보디이미드 수지에서 선택되는 적어도 1 종인 수계 표면 처리제.
- 제 3 항에 있어서,유기 화합물 (B) 로서의 유기 포스폰산류 또는 그 부분적 알칼리 금속염 또는 암모늄염 또는 탄소수 1 ∼ 4 인 알칸올과의 부분적인 에스테르, 유기 포스핀산류, 또는 폴리올의 인산에스테르를 추가로 배합한 수계 표면 처리제.
- 제 1 항 또는 제 2 항에 있어서,유기 화합물 (B) 이 에폭시계 수지로서, 에폭시계 수지가 비스페놀 A 또는 F 를 골격 중의 단위로서 갖는 에폭시 수지, 또는 이러한 에폭시 수지의 글리시딜기의 일부 또는 전부가 실란 변성 또는 인산류의 변성된 에폭시 수지인 수계 표면 처리제.
- 제 5 항에 있어서,유기 화합물 (B) 로서의 유기 포스폰산류 또는 그 부분적 알칼리 금속염 또는 암모늄염 또는 탄소수 1 ∼ 4 인 알칸올과의 부분적인 에스테르, 유기 포스핀산류, 또는 폴리올의 인산에스테르를 추가로 배합한 수계 표면 처리제.
- 제 1 항 또는 제 2 항에 있어서,유기 화합물 (B) 이 실란커플링제인 수계 표면 처리제.
- 제 7 항에 있어서,유기 화합물 (B) 로서의 유기 포스폰산류 또는 그 부분적 알칼리 금속염 또는 암모늄염 또는 탄소수 1 ∼ 4 인 알칸올과의 부분적인 에스테르, 유기 포스핀산류, 또는 폴리올의 인산에스테르를 추가로 배합한 수계 표면 처리제.
- 제 1 항 또는 제 2 항에 있어서,유기 화합물 (B) 이 유기 포스폰산류 또는 그 부분적 알칼리 금속염 또는 암모늄염 또는 탄소수 1 ∼ 4 인 알칸올과의 부분적인 에스테르, 유기 포스핀산류, 또는 폴리올의 인산에스테르인 수계 표면 처리제.
- 제 1 항 내지 제 9 항 중 어느 한 항에 있어서,우레탄 수지 (A) 와 유기 화합물 (B) 의 배합비 (A)/(B) 가 고형분 질량비로서 1000/1 ∼ 10/1 의 범위이고, 우레탄 수지 (A) 와 지르코늄 화합물 (C) 의 배합비가 (A) 의 고형분/Zr 원자의 질량비로서 1000/1 ∼ 10/1 의 범위인 수계 표면 처리제.
- 제 1 항 내지 제 10 항 중 어느 한 항에 기재된 수계 표면 처리제를 금속 재료 표면의 적어도 편면에 도포하여 건조시키고, 건조 피막 질량으로서 0.5 ∼ 3g/㎡ 의 피막을 형성시킨 표면 피복 금속 재료.
- 제 11 항에 있어서,금속 재료가 알루미늄재, 알루미늄 합금재 또는 알루미늄-아연계 합금 도금 강판인 표면 피복 금속 재료.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JPJP-P-2005-00236949 | 2005-08-17 | ||
JP2005236949A JP3872493B1 (ja) | 2005-08-17 | 2005-08-17 | 金属材料用水系表面処理剤及び表面被覆金属材料 |
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EP (1) | EP1959030B1 (ko) |
JP (1) | JP3872493B1 (ko) |
KR (1) | KR100971645B1 (ko) |
CN (1) | CN101384677B (ko) |
WO (1) | WO2007020762A2 (ko) |
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KR100928798B1 (ko) * | 2007-11-13 | 2009-11-25 | 주식회사 포스코 | 향상된 내알칼리성과 가공성을 갖는 크롬 프리 수지 용액조성물, 이를 이용한 강판의 표면처리 방법 및 표면처리된 강판 |
KR100952613B1 (ko) | 2007-12-31 | 2010-04-15 | 현대하이스코 주식회사 | 크롬프리 실링 용액 및 이를 이용한 인산염전기아연도금강판의 제조 방법 |
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CN105733430A (zh) * | 2014-12-11 | 2016-07-06 | 宝山钢铁股份有限公司 | 一种热镀铝锌钢板用表面处理剂、热镀铝锌钢板及其制造方法 |
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JP7163151B2 (ja) * | 2018-11-28 | 2022-10-31 | 株式会社放電精密加工研究所 | 水性防錆表面処理組成物 |
JP7143786B2 (ja) * | 2019-03-04 | 2022-09-29 | 日本製鉄株式会社 | 塗装金属板およびその製造方法 |
KR102314431B1 (ko) * | 2019-09-24 | 2021-10-20 | 주식회사 포스코 | 우수한 내흑변성 및 내알칼리성을 부여하는 삼원계 용융아연합금 도금강판용 표면처리 용액 조성물, 이를 이용하여 표면처리된 삼원계 용융아연합금 도금강판 및 그 제조 방법 |
JP6779357B1 (ja) * | 2019-12-26 | 2020-11-04 | 日本パーカライジング株式会社 | 金属表面処理剤、並びに皮膜を有する金属材料及びその製造方法 |
WO2021207950A1 (en) * | 2020-04-15 | 2021-10-21 | Henkel Ag & Co. Kgaa | Anti-blackening coating composition |
JP2023131621A (ja) * | 2022-03-09 | 2023-09-22 | 日本パーカライジング株式会社 | アルミニウム材用水系表面処理組成物 |
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JPH0247278A (ja) | 1988-08-08 | 1990-02-16 | Toyota Motor Corp | 耐摩耗性Ti系部材 |
EP0787831A4 (en) * | 1995-08-11 | 1998-11-11 | Nippon Steel Corp | RESIN CHROMATE COMPOSITION AND SURFACE TREATED SHEET |
JP2001081392A (ja) | 1999-09-13 | 2001-03-27 | Nippon Parkerizing Co Ltd | 密着性に優れた水系塗装下地用処理剤、金属材料の製造方法および金属材料 |
JP3865693B2 (ja) | 2002-12-26 | 2007-01-10 | 日本ペイント株式会社 | アルミニウム−亜鉛合金メッキ鋼板処理用水性樹脂組成物、被覆方法及びアルミニウム−亜鉛合金メッキ鋼板 |
JP2005298837A (ja) | 2004-04-06 | 2005-10-27 | Kansai Paint Co Ltd | 金属表面処理組成物及びそれを使用した金属板 |
JP4969831B2 (ja) * | 2004-10-26 | 2012-07-04 | 日本パーカライジング株式会社 | 金属表面処理剤、金属材料の表面処理方法及び表面処理金属材料 |
JP4975999B2 (ja) * | 2004-10-26 | 2012-07-11 | 日本パーカライジング株式会社 | 金属表面処理剤、金属材料の表面処理方法及び表面処理金属材料 |
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JP3872493B1 (ja) | 2007-01-24 |
WO2007020762A2 (ja) | 2007-02-22 |
EP1959030A2 (en) | 2008-08-20 |
EP1959030A4 (en) | 2012-08-01 |
CN101384677A (zh) | 2009-03-11 |
EP1959030B1 (en) | 2013-10-30 |
WO2007020762A3 (ja) | 2008-10-16 |
JP2007051323A (ja) | 2007-03-01 |
CN101384677B (zh) | 2011-06-08 |
KR100971645B1 (ko) | 2010-07-22 |
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