KR101021749B1 - 전기 전도 유기 중합체/나노입자 복합체 및 이들의 이용방법 - Google Patents
전기 전도 유기 중합체/나노입자 복합체 및 이들의 이용방법 Download PDFInfo
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- KR101021749B1 KR101021749B1 KR1020057004948A KR20057004948A KR101021749B1 KR 101021749 B1 KR101021749 B1 KR 101021749B1 KR 1020057004948 A KR1020057004948 A KR 1020057004948A KR 20057004948 A KR20057004948 A KR 20057004948A KR 101021749 B1 KR101021749 B1 KR 101021749B1
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- nanoparticles
- layer
- aqueous dispersion
- polymer
- paampsa
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/17—Carrier injection layers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
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Abstract
Description
PAni/PAAMPSA에 첨가된 무기 나노입자가 유리 기판상의 OLED의 발광 특성에 미치는 영향 | ||||||
실시예 | 코팅 두께 (nm) | 전도성 (S/cm) | 전압 (볼트)@ 8.3 mA/cm2 | 효율 (Cd/A)@8.3 mA/cm2 | 광도 (Cd/m2)@3.3mA/cm2, 80℃ | 반감기 (hr)@3.3 mA/cm2, 80 ℃ |
비교예 1 | 137@1,200rpm | 3.6X10-5 | 4.2 | 8.3 | 115 | 12 |
실시예 1 | 114@1,200rpm | 8.2X10-7 | 4.8 | 8.1 | 135 | 29 |
실시예 2 | 166@1,200rpm | 7.6X10-7 | 4.9 | 7.4 | 108 | 30 |
실시예 3 | 113@1,200rpm | 8.3X10-8 | 4.1 | 8.0 | 148 | 61 |
실시예 4 | 300@6,000rpm | 9.0X10-7 | 4.3 | 5.3 | 130 | 42 |
수성 PAni/PAAMPSA 분산액의 점성 | |||
점성 (cps) | |||
샘플 | 10 s-1 | 100 s-1 | 1000 s-1 |
비교예 1 | 5.50 | 4.52 | 4.10 |
실시예 4 | 8.30 | 6.80 | 6.15 |
Claims (8)
- 전기 전도성 유기 중합체 및 다수의 나노입자의 수성 분산액을 포함하고, 여기서 나노입자가 수성 분산액의 전도성을 전도성 중합체의 전도성 미만의 값으로 감소시키는 조성물.
- 제1항에 있어서, 상기 전기 전도성 유기 중합체가 폴리(2-아크릴아미도-2-메틸-1-프로판술폰산)을 반대이온으로 갖는 폴리아닐린 (PAni/PAAMPSA) 및 폴리(스티렌술폰산)을 반대 이온으로 갖는 폴리(에틸렌디옥시티오펜) (PEDT/PSS)에서 선택되는 조성물.
- 제1항에 있어서, 상기 나노입자가 무기 나노입자, 유기 나노입자 또는 이들의 혼합물인 조성물.
- 제3항에 있어서, 상기 무기 나노입자가 실리카, 알루미나 및 전기 전도성 금속 산화물, 및 이들의 혼합물에서 선택되고, 상기 유기 나노입자가 폴리아크릴레이트, 탄소 나노튜브 및 퍼플루오로에틸렌 술포네이트, 및 이들의 혼합물에서 선택되는 조성물.
- 전기 전도성 유기 중합체의 수성 분산액에 다수의 나노입자를 첨가하는 것을 포함하는, 수성 분산액으로부터 기판상에 주조된 완충층의 전도성을 약 10-3 S/cm 미만의 값으로 감소시키는 방법.
- 전도성 유기 중합체의 수성 분산액에 다수의 나노입자를 첨가하는 것과 상기 수성 분산액으로부터 층을 기판상에 주조하는 것을 포함하는 방법으로 제조된 완충층을 하나 이상 갖는 유기 전자 장치.
- 제6항에 있어서, 포토센서, 포토스위치, 포토레지스터, 포토트랜지스터, 포토튜브, IR 검출기, 광전지, 태양전지, 발광 다이오드, 바이오센서, 발광 다이오드 디스플레이 또는 다이오드 레이져인 장치.
- 폴리(2-아크릴아미도-2-메틸-1-프로판술폰산)을 반대이온으로 갖는 폴리아닐린 (PAni/PAAMPSA) 및 폴리(스티렌술폰산)을 반대 이온으로 갖는 폴리(에틸렌디옥시티오펜) (PEDT/PSS)에서 선택된 하나 이상의 전도성 중합체를 포함하는 전기 전도성 중합체, 및 이와 분산된 다수의 나노입자를 포함하고, 상기 나노입자는 폴리아크릴레이트, 탄소 나노튜브 및 퍼플루오로에틸렌 술포네이트, 및 이들의 혼합물에서 선택되는 것인 고 저항 완충층.
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KR (1) | KR101021749B1 (ko) |
CN (1) | CN100540628C (ko) |
AU (1) | AU2003279011A1 (ko) |
CA (1) | CA2500304A1 (ko) |
HK (1) | HK1080889A1 (ko) |
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JP2009534831A (ja) | 2006-04-18 | 2009-09-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 高エネルギーポテンシャル二重層組成物 |
US8153029B2 (en) | 2006-12-28 | 2012-04-10 | E.I. Du Pont De Nemours And Company | Laser (230NM) ablatable compositions of electrically conducting polymers made with a perfluoropolymeric acid applications thereof |
US20080251768A1 (en) | 2007-04-13 | 2008-10-16 | Che-Hsiung Hsu | Electrically conductive polymer compositions |
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US8241526B2 (en) | 2007-05-18 | 2012-08-14 | E I Du Pont De Nemours And Company | Aqueous dispersions of electrically conducting polymers containing high boiling solvent and additives |
KR20100065302A (ko) | 2007-07-27 | 2010-06-16 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 무기 나노입자를 포함하는 전기 전도성 중합체의 수성 분산물 |
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Patent Citations (1)
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JP2002500408A (ja) * | 1997-12-23 | 2002-01-08 | バイエル・アクチエンゲゼルシヤフト | 導電性コーテイングを製造するためのスクリーン印刷ペースト |
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TW200417592A (en) | 2004-09-16 |
US7189771B2 (en) | 2007-03-13 |
EP1546283A1 (en) | 2005-06-29 |
JP2010100854A (ja) | 2010-05-06 |
US20110155966A1 (en) | 2011-06-30 |
CA2500304A1 (en) | 2004-04-08 |
EP2341118A1 (en) | 2011-07-06 |
KR20050084574A (ko) | 2005-08-26 |
WO2004029176A9 (en) | 2007-10-11 |
US20040124504A1 (en) | 2004-07-01 |
TWI302563B (en) | 2008-11-01 |
JP5222828B2 (ja) | 2013-06-26 |
WO2004029176A1 (en) | 2004-04-08 |
US20050070654A1 (en) | 2005-03-31 |
AU2003279011A1 (en) | 2004-04-19 |
JP4464277B2 (ja) | 2010-05-19 |
EP1546283B1 (en) | 2012-06-20 |
CN100540628C (zh) | 2009-09-16 |
CN1685031A (zh) | 2005-10-19 |
JP2006502254A (ja) | 2006-01-19 |
US8455865B2 (en) | 2013-06-04 |
HK1080889A1 (en) | 2006-05-04 |
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