JPWO2014119453A1 - 防汚膜付き透明基体 - Google Patents
防汚膜付き透明基体 Download PDFInfo
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- JPWO2014119453A1 JPWO2014119453A1 JP2014559646A JP2014559646A JPWO2014119453A1 JP WO2014119453 A1 JPWO2014119453 A1 JP WO2014119453A1 JP 2014559646 A JP2014559646 A JP 2014559646A JP 2014559646 A JP2014559646 A JP 2014559646A JP WO2014119453 A1 JPWO2014119453 A1 JP WO2014119453A1
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- transparent substrate
- antifouling film
- film
- main surface
- antifouling
- Prior art date
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- 239000000758 substrate Substances 0.000 title claims abstract description 155
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 117
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 41
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000011737 fluorine Substances 0.000 claims abstract description 40
- 150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 36
- 230000003746 surface roughness Effects 0.000 claims abstract description 16
- 239000011521 glass Substances 0.000 claims description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims description 9
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 9
- 229910000484 niobium oxide Inorganic materials 0.000 claims description 6
- 239000010408 film Substances 0.000 description 152
- 238000000034 method Methods 0.000 description 27
- 238000010438 heat treatment Methods 0.000 description 18
- 239000002904 solvent Substances 0.000 description 17
- 238000003426 chemical strengthening reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- 239000005871 repellent Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 235000002639 sodium chloride Nutrition 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000005354 aluminosilicate glass Substances 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000006059 cover glass Substances 0.000 description 2
- 229910021488 crystalline silicon dioxide Inorganic materials 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 1
- HJIMAFKWSKZMBK-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F HJIMAFKWSKZMBK-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003302 alkenyloxy group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- -1 for example Chemical group 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229960004624 perflexane Drugs 0.000 description 1
- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 230000026683 transduction Effects 0.000 description 1
- 238000010361 transduction Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/538—Roughness
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/77—Coatings having a rough surface
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Liquid Crystal (AREA)
- Optical Elements Other Than Lenses (AREA)
Abstract
Description
前記透明基体の前記第1の主面側に設けられた防汚膜であるフッ素含有有機ケイ素化合物被膜と、を有し、
前記防汚膜の表面粗さRMSが0.05μm以上0.25μm以下であって、粗さ曲線の要素の平均長さRSmが10μm以上40μm以下である、防汚膜付き透明基体を提供する。
[第1の実施形態]
本実施形態では、本発明の防汚膜付き透明基体について説明する。
ここで、qは1以上、好ましくは2〜20の整数である。
ここで、q'は1以上、好ましくは1〜20の整数である。
[第2の実施形態]
本実施形態では、第1の実施形態において、低反射膜をさらに設けた構成について説明する。その他の構成については第1の実施形態で説明したとおりであるためここでは省略する。
(1)評価方法
以下の例1〜例7において得られた防汚膜付き透明基体の特性評価方法について以下に説明する。
(表面形状の測定)
例1〜例7で用いた防汚膜成膜後の試料の防汚膜の表面形状について、レーザー顕微鏡(キーエンス社製、商品名:VK−9700)を用いて、50倍の倍率で平面プロファイルを測定した。そして、得られた平面プロファイルから、JIS B 0601(2001)に基づいて表面粗さRMSおよび粗さ曲線要素の平均長さRSmの値を得た。
(ヘイズの測定)
実施例、比較例において、防汚膜を形成した後の試料について透過へイズの測定を行った。ヘイズの測定は、ヘイズメーター(スガ試験機株式会社製、型式:HZ−V3)を用いて行った。
(擦り耐久性(耐摩耗性)試験)
例1〜例7において防汚膜成膜後の試料について、該試料の防汚膜について擦り耐久性試験を以下の手順により行った。
(2)実験手順
[例1]
以下の手順により、防汚膜付き透明基体を製造した。
[例2]
透明基体として化学強化処理が施されたガラス基板(旭硝子株式会社製、商品名:ドラゴントレイル(登録商標))を用い、該ガラス基板の第1の主面にフロスト処理された透明基体Bを用いた以外は例1と同様にして、透明基体Bの第1の主面に防汚膜を成膜した。得られた防汚膜付き透明基体について例1と同様にして評価を行った。結果を表1に示す。
[例3]
透明基体として化学強化処理が施されたガラス基板(旭硝子株式会社製、商品名:ドラゴントレイル(登録商標))を用い、該ガラス基板の第1の主面にフロスト処理された透明基体Cを用いた以外は例1と同様にして、透明基体Cの第1の主面に防汚膜を成膜した。得られた防汚膜付き透明基体について例1と同様にして評価を行った。結果を表1に示す。
[例4]
透明基体A上に、以下のようにして低反射膜を成膜した。
[例5]
透明基体として化学強化処理が施されたガラス基板(旭硝子株式会社製、商品名:ドラゴントレイル(登録商標))を用い、該ガラス基板の第1の主面にフロスト処理された透明基体Dを用いた以外は例1と同様にして、透明基体Dの第1の主面に防汚膜を成膜した。得られた防汚膜付き透明基体について例1と同様にして評価を行った。結果を表1に示す。
[例6]
透明基体として化学強化処理が施されたガラス基板(旭硝子株式会社製、商品名:ドラゴントレイル(登録商標))を用い、該ガラス基板の第1の主面にフロスト処理された透明基体Eを用いた以外は例1と同様にして、透明基体Eの第1の主面に防汚膜を成膜した。得られた防汚膜付き透明基体について例1と同様にして評価を行った。結果を表1に示す。
[例7]
透明基体として例5と同じ透明基体Dを用いた以外は例4と同様にして、低反射膜と防汚膜を形成し、得られた防汚膜付き透明基体について、例1と同様にして評価を行った。結果を表1に示す。
12 防汚膜
13 低反射膜
前記透明基体の前記第1の主面側に設けられたフッ素含有有機ケイ素化合物からなる防汚膜と、低反射膜と、を有し、
前記防汚膜の表面粗さRMSが0.05μm以上0.25μm以下であって、前記防汚膜の粗さ曲線の要素の平均長さRSmが10μm以上40μm以下であり、
前記透明基体の前記第1の主面の表面に前記低反射膜、前記防汚膜の順に積層されている防汚膜付き透明基体を提供する。
Claims (6)
- 第1の主面と、前記第1の主面に対向する第2の主面とを有し、前記第1の主面の表面に防眩加工が施された透明基体と、
前記透明基体の前記第1の主面側に設けられた防汚膜であるフッ素含有有機ケイ素化合物被膜と、を有し、
前記防汚膜の表面粗さRMSが0.05μm以上0.25μm以下であって、粗さ曲線の要素の平均長さRSmが10μm以上40μm以下である、防汚膜付き透明基体。 - 前記防汚膜付き透明基体のヘイズが2%以上30%以下である請求項1に記載の防汚膜付き透明基体。
- 前記透明基体がガラス基板である請求項1または2に記載の防汚膜付き透明基体。
- 前記透明基体の前記第1の主面の表面に低反射膜、フッ素含有有機ケイ素化合物被膜の順に積層されている請求項1乃至3何れか一項に記載の防汚膜付き透明基体。
- 前記低反射膜が、酸化ニオブ層と酸化ケイ素層との積層体である請求項4に記載の防汚膜付き透明基体。
- 前記低反射膜が複数の膜が積層された積層体であって、該積層体は全体で2層以上6層以下の膜が積層されている請求項4または5に記載の防汚膜付き透明基体。
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Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6693420B2 (ja) * | 2014-11-20 | 2020-05-13 | Agc株式会社 | 透明板、タッチパッド、およびタッチパネル |
AU2015353548B2 (en) * | 2014-11-25 | 2018-04-05 | Ppg Industries Ohio, Inc. | Antiglare touch screen displays and other coated articles and methods of forming them |
JP6624195B2 (ja) * | 2015-03-03 | 2019-12-25 | 株式会社スリーボンド | 防曇剤組成物 |
CN105022202A (zh) * | 2015-08-04 | 2015-11-04 | 汕头超声显示器(二厂)有限公司 | 一种抗反射电驱动3d液晶透镜 |
DE112016003678B4 (de) | 2015-08-10 | 2021-07-15 | AGC Inc. | Glasplatte mit Antiverschmutzungsschicht |
WO2017030046A1 (ja) * | 2015-08-19 | 2017-02-23 | 旭硝子株式会社 | 積層体 |
WO2017043538A1 (ja) * | 2015-09-11 | 2017-03-16 | 日本電気硝子株式会社 | ディスプレイ用カバー部材及びその製造方法 |
CN105174735B (zh) * | 2015-10-19 | 2017-08-11 | 上海光和光学制造股份有限公司 | 一种防眩玻璃及其制备方法 |
JP2017116573A (ja) | 2015-12-21 | 2017-06-29 | 旭硝子株式会社 | ガラス基板の製造方法およびガラス基板 |
JP6969626B2 (ja) * | 2016-01-12 | 2021-11-24 | Agc株式会社 | 防汚層付きガラス基体の製造方法 |
JP6686449B2 (ja) * | 2016-01-12 | 2020-04-22 | Agc株式会社 | 防汚層付きガラス基体およびディスプレイ用前面板 |
JP7306438B2 (ja) * | 2016-01-12 | 2023-07-11 | Agc株式会社 | 防汚層付きガラス基体及び表示装置用前面板 |
JP2017206392A (ja) * | 2016-05-16 | 2017-11-24 | 旭硝子株式会社 | ガラス物品 |
JP6696486B2 (ja) * | 2016-10-07 | 2020-05-20 | Agc株式会社 | 防眩膜付基体、防眩膜形成用液状組成物及び防眩膜付基体の製造方法 |
JP6939398B2 (ja) * | 2016-11-07 | 2021-09-22 | Agc株式会社 | 積層体 |
US11555950B2 (en) | 2016-12-12 | 2023-01-17 | Nippon Electric Glass Co., Ltd. | Transparent article |
JP7087514B2 (ja) | 2017-03-23 | 2022-06-21 | Agc株式会社 | アンチグレアガラス基板 |
CN114296159B (zh) | 2017-04-11 | 2023-11-14 | 日本电气硝子株式会社 | 透明物品 |
WO2018198983A1 (ja) * | 2017-04-27 | 2018-11-01 | 京セラ株式会社 | 装飾部品 |
JP6819446B2 (ja) * | 2017-04-27 | 2021-01-27 | 大日本印刷株式会社 | タッチパネル用表面部材、タッチパネル、表示装置、及びタッチパネル用表面部材の選別方法 |
KR102579362B1 (ko) * | 2017-05-08 | 2023-09-18 | 코닝 인코포레이티드 | 광학 및 내-스크래치성 코팅 위에 내구성의 윤활성 지문-방지 코팅을 갖는 유리, 유리-세라믹 및 세라믹 제품 및 그 제조방법 |
JP2018197183A (ja) * | 2017-05-23 | 2018-12-13 | Agc株式会社 | ガラス物品、および表示装置 |
JP6805966B2 (ja) * | 2017-05-24 | 2020-12-23 | Agc株式会社 | カバー部材、カバー部材の製造方法および表示装置 |
DE112018003147T5 (de) | 2017-06-20 | 2020-03-05 | AGC Inc. | Glasplatte |
WO2019044994A1 (ja) * | 2017-08-30 | 2019-03-07 | 日本電気硝子株式会社 | 透明物品 |
JP6881172B2 (ja) * | 2017-09-13 | 2021-06-02 | Agc株式会社 | 反射防止膜付透明基体、およびそれを用いた表示装置 |
JP7275471B2 (ja) * | 2017-10-02 | 2023-05-18 | Agc株式会社 | 透明基体および表示装置 |
JP7040234B2 (ja) | 2018-04-04 | 2022-03-23 | 日本電気硝子株式会社 | 物品 |
JP2019203931A (ja) * | 2018-05-21 | 2019-11-28 | 株式会社ダイセル | 防眩フィルムならびにその製造方法および用途 |
KR20210132679A (ko) | 2019-03-01 | 2021-11-04 | 닛산 가가쿠 가부시키가이샤 | 방현성 피막 형성용 도포액, 방현성 피막 및 그것을 갖는 적층체 |
CN113891919A (zh) * | 2019-05-31 | 2022-01-04 | Agc株式会社 | 带拒水拒油层的基材 |
EP3978232B1 (en) * | 2019-05-31 | 2024-06-05 | Agc Inc. | Transparent substrate with antifouling layer |
WO2023204145A1 (ja) * | 2022-04-19 | 2023-10-26 | Agc株式会社 | ガラス積層体、カバーガラス、および表示装置 |
CN114713031A (zh) * | 2022-04-19 | 2022-07-08 | 杭州卧特松环保科技有限公司 | 反渗透膜层组件及抗高cod与杂质污染的反渗透膜元件 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07126041A (ja) | 1993-10-27 | 1995-05-16 | Asahi Glass Co Ltd | 撥水性光散乱ガラス成形体及びその製品 |
US5674625A (en) * | 1993-11-10 | 1997-10-07 | Central Glass Company, Limited | Multilayered water-repellent film and method of forming same on glass substrate |
EP0748775A3 (en) * | 1995-05-30 | 1998-11-25 | Central Glass Company, Limited | Water-repellent glass plate having minutely roughed metal-oxide base film |
JPH11171594A (ja) | 1997-12-15 | 1999-06-29 | Nippon Sheet Glass Co Ltd | 撥水性ガラス物品およびその製造方法 |
JP3802842B2 (ja) * | 1998-07-07 | 2006-07-26 | 住友化学株式会社 | タッチパネル用上部透明電極板およびそれを含む装置 |
DE102004026344B4 (de) * | 2004-05-26 | 2008-10-16 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Verfahren zum Herstellen einer hydrophoben Beschichtung, Vorrichtung zum Durchführen des Verfahrens und Substrat mit einer hydrophoben Beschichtung |
US7291386B2 (en) * | 2004-08-26 | 2007-11-06 | 3M Innovative Properties Company | Antiglare coating and articles |
FR2893266B1 (fr) * | 2005-11-14 | 2007-12-21 | Commissariat Energie Atomique | Produit superhydrophile ou superhydrophobe, procede pour sa realisation et utilisation de ce produit |
JP2007144916A (ja) * | 2005-11-30 | 2007-06-14 | Asahi Glass Co Ltd | 超撥水性基体 |
JPWO2008072707A1 (ja) * | 2006-12-15 | 2010-04-02 | 旭硝子株式会社 | 撥水性表面を有する物品 |
JP5262066B2 (ja) * | 2007-10-31 | 2013-08-14 | 凸版印刷株式会社 | 反射防止フィルムの製造方法及びこれを含む偏光板の製造方法 |
EP2252557A4 (en) * | 2008-02-05 | 2013-07-03 | Corning Inc | DAMAGE-RESISTANT GLASS ARTICLE FOR USE AS A GLASS COVER IN ELECTRONIC DEVICES |
JP5326407B2 (ja) * | 2008-07-31 | 2013-10-30 | セイコーエプソン株式会社 | 時計用カバーガラス、および時計 |
JP5036827B2 (ja) * | 2008-09-05 | 2012-09-26 | 株式会社シンクロン | 成膜方法及び撥油性基材 |
JP5114355B2 (ja) * | 2008-10-08 | 2013-01-09 | 株式会社Snt | 撥水・撥油性コーティング物品およびその製造 |
JP5641498B2 (ja) * | 2009-04-10 | 2014-12-17 | 国立大学法人 香川大学 | 撥水撥油性透明部材とその製造方法及びそれらを用いた物品 |
US20100285272A1 (en) * | 2009-05-06 | 2010-11-11 | Shari Elizabeth Koval | Multi-length scale textured glass substrates for anti-fingerprinting |
US20100304086A1 (en) * | 2009-05-29 | 2010-12-02 | Alain Robert Emile Carre | Super non-wetting, anti-fingerprinting coatings for glass |
WO2011004873A1 (ja) * | 2009-07-10 | 2011-01-13 | 旭硝子株式会社 | 防曇性物品およびその製造方法、防曇膜形成用コーティングキット |
CN102741048B (zh) * | 2010-01-19 | 2014-09-03 | 旭硝子株式会社 | 拒水性基体及其制造方法 |
JP2011180211A (ja) * | 2010-02-26 | 2011-09-15 | Sumitomo Chemical Co Ltd | 偏光板、液晶パネル及び液晶表示装置 |
US9017566B2 (en) * | 2010-04-30 | 2015-04-28 | Corning Incorporated | Anti-glare surface treatment method and articles thereof |
US20120107558A1 (en) * | 2010-11-01 | 2012-05-03 | Shari Elizabeth Koval | Transparent substrate having durable hydrophobic/oleophobic surface |
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