JP7010567B2 - 導光物品用のアクリルポリビニルアセタールフィルム - Google Patents
導光物品用のアクリルポリビニルアセタールフィルム Download PDFInfo
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- JP7010567B2 JP7010567B2 JP2018564299A JP2018564299A JP7010567B2 JP 7010567 B2 JP7010567 B2 JP 7010567B2 JP 2018564299 A JP2018564299 A JP 2018564299A JP 2018564299 A JP2018564299 A JP 2018564299A JP 7010567 B2 JP7010567 B2 JP 7010567B2
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Images
Classifications
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- G—PHYSICS
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- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
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- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
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- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
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- Wood Science & Technology (AREA)
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- Laminated Bodies (AREA)
- Optical Elements Other Than Lenses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
H2C=CR1C(O)OR8
[式中、R1はH又はメチルであり、R8は1~22個の炭素を有するアルキル、又は2~20個の炭素及び酸素若しくは硫黄から選択される1~6個のヘテロ原子を有するヘテロアルキルである]。アルキル基又はヘテロアルキル基は、直鎖状、分枝状、環状、又はこれらの組み合わせとすることができる。
Lは任意の結合基であり、
R2はオレフィン基であり、これは任意に置換されている]。
再帰反射性輝度
再帰反射係数、RA、を、標準試験ASTME810-03にしたがって測定し、ここで、RAはカンデラ毎ルクス毎平方メートル(cd/(lux-平方メートル))で示される。ASTME810-03で使用した入射角は4度であり、かつ観測角は0.2度であった。
接着シロップ1は、1ガロン(3.8リットル)のジャーに、IOA、AA、及びIrg 651を表2に示す量で充填し、光開始剤が溶解し、均一な混合物が得られるまで撹拌することによって調製した。ジャーの蓋にある開口部を介して挿入した管を通して、窒素ガスを導入することによって、混合物を脱気し、少なくとも5分間激しくバブリングした。撹拌しながら、混合物を、被覆に適していると思われる粘度を有するプレ接着剤シロップが形成されるまで、UV-A光に曝露した。UV曝露後、空気をジャー内に導入した。光源は、365nmのピーク発光波長を有するLEDアレイであった。予備重合後、0.2pphのTMPTAを、終夜ローリングすることによってシロップ中に混合した。
ベースシロップ1を、ノッチバーコーターを使用して、0.002インチ(51マイクロメートル)の厚さで第2の試料PET1上にコーティングした。ベースシロップ1組成物を、350ナノメートルのピーク発光波長を有する複数の蛍光ランプを使用して、3600ミリジュール/平方センチメートルの総UV-Aエネルギーへ曝露し、PET1上に非感圧性接着剤(PSA)アクリルフィルムを得た。接着シロップ1を、ノッチバーコーターを使用して、0.002インチ(51マイクロメートル)の厚さでPET1上にコーティングした。照射された非PSAアクリルフィルム/PET1の組み合わせを、全ての間隙設定が0.008インチ(203マイクロメートル)の2-ロールコーティングステーションを使用して、接着シロップ1がコーティングされたPET1と密着させ、350ナノメートルのピーク放出波長を有する複数の蛍光ランプを使用して、4263ミリジュール/平方センチメートルの総UV-Aエネルギーへ曝露した。順番に、PET1、PSA、非PSAアクリルフィルム、及びPET1を有する構造体を得た。次に、DLX2ラン由来のロット9番からPET1ライナーを取り外し、接着層を露出させ、次いで、ハンドスクィーズロールラミネーターを用いて、3M(商標)Advanced Engineer Grade Prismatic Sheeting Series 7930の上部に積層した。
ベースシロップ2の構成成分へMAX 100 WHITE SPEEDMIXER(FleckTek,Inc.,Landrum,SCから入手可能)を添加し、3500RPMで5分間混合した。ベースシロップ2を、未処理のPETライナー間に2.0ミルの厚さでコーティングし、UVA光へ曝露した。低強度検出ヘッド(EIT Inc.,Sterling,VAから入手可能)を備えたPowermap(商標)放射計を使用して総エネルギーを測定すると、1824mJ/cm2であった。
なお、以上の各実施形態に加えて以下の態様について付記する。
(付記1)
少なくとも30℃のTgを有し、(メタ)アクリルポリマー及び以下の式を有する重合単位を含むポリビニルアセタールポリマーを含む本体層と、
前記本体層に近接し、かつ光学要素を含む、第2の層と
を含む、導光物品。
(付記2)
前記本体層が60℃以下のTgを有する、付記1に記載の導光物品。
(付記3)
前記本体層及び/又は第2の層が、顔料、着色剤、装飾用添加剤、UV吸収剤、又はこれらの組み合わせを含む、付記1又は2に記載の導光物品。
(付記4)
前記本体層が、25℃及び1ヘルツで少なくとも1MPaの引張弾性率を有する、付記1~3のいずれか一項に記載の導光物品。
(付記5)
前記本体層が、0℃未満のTgを有する単官能性アルキル(メタ)アクリレートモノマーの重合単位を、少なくとも、20、25、30、35、40、50重量%含む、付記1~4のいずれか一項に記載の導光物品。
(付記6)
前記本体層が、0℃未満のTgを有する単官能性アルキル(メタ)アクリレートモノマーの重合単位を、85重量%以下含む、付記1~5のいずれか一項に記載の導光物品。
(付記7)
前記単官能性アルキル(メタ)アクリレートモノマーの重合単位が、-10℃、-20℃、-30℃、-40℃、又は-50℃未満のTgを有する、付記5又は6に記載の導光物品。
(付記8)
前記本体層が、8個の炭素原子を含むアルキル基を有するアルキル(メタ)アクリレートモノマーの重合単位を含む、付記1~7のいずれか一項に記載の導光物品。
(付記9)
前記本体層が、ポリビニルアセタールポリマーを、5~30重量%含む、付記1~8のいずれか一項に記載の導光物品。
(付記10)
前記本体層が光開始剤を含む、付記1~9のいずれか一項に記載の導光物品。
(付記11)
前記本体層が、前記導光物品の最外面を形成する、付記1~10のいずれか一項に記載の導光物品。
(付記12)
前記光学要素が、ビーズ又は微細構造化要素を含む、付記1~11のいずれか一項に記載の導光物品。
(付記13)
前記微細構造化要素が、縦方向に延びるプリズム又はコーナーキューブ要素である、付記12に記載の導光物品。
(付記14)
前記コーナーキューブ要素が、切頭型キューブ又はフルキューブを含む、付記13に記載の導光物品。
(付記15)
前記微細構造化要素が、重合性樹脂の反応生成物を含む、付記12~14のいずれか一項に記載の導光物品。
(付記16)
前記微細構造化要素が、固化した熱可塑性樹脂を含む、付記12~15のいずれか一項に記載の導光物品。
(付記17)
前記本体層が、前記第2の層と一体に連結されている、付記1~16のいずれか一項に記載の導光物品。
(付記18)
前記本体層が、前記第2の層へ熱的に結合されている、付記17に記載の導光物品。
(付記19)
前記本体層が、前記第2の層へ接着結合されている、付記17に記載の導光物品。
(付記20)
前記本体層が、前記第2の層に近接しているが、1つ以上の追加の層によって前記第2の層から離れて間隔があいている、付記1~16のいずれか一項に記載の導光物品。
(付記21)
前記追加の層が、接着促進層、インク、構造支持層である、付記20に記載の導光物品。
(付記22)
前記第2の層又は本体層上に接着促進表面処理を含み、接着促進表面処理が、プライマー層、又はこれらの組み合わせから選択される、付記1~21のいずれか一項に記載の導光物品。
(付記23)
ロールの両端部によって制限された幅を有するシート材のロールである、付記1~22のいずれか一項に記載の導光物品。
(付記24)
前記光学要素に隣接する又はその上の鏡面反射性コーティングを更に含む、付記1~23のいずれか一項に記載の導光物品。
(付記25)
前記光学要素の一部に結合されたシールフィルムを更に含む、付記1~24のいずれか一項に記載の導光物品。
(付記26)
第1の領域及び第2の領域を含む接着層を更に含み、前記第2の領域が、前記第1の領域を囲み、かつ前記微細構造化要素に接触しており、前記第1の領域及び前記第2の領域が、前記接着層と前記微細構造化要素の間に低屈折率層を形成するのに十分異なる特性を有する、付記1~25のいずれか一項に記載の導光物品。
(付記27)
前記本体層とは反対側の、前記第2の層上に接着層を更に含む、付記1~26のいずれか一項に記載の導光物品。
(付記28)
前記接着層が剥離ライナーで覆われ、前記剥離ライナーが、前記導光物品の最外面を形成している、付記27に記載の導光物品。
(付記29)
再帰反射性シート材である、付記1~28のいずれか一項に記載の導光物品。
Claims (8)
- 前記本体層が、25℃及び1ヘルツで少なくとも1MPaの引張弾性率を有する、請求項1に記載の再帰反射物品。
- 前記本体層が、0℃未満のTgを有する単官能性アルキル(メタ)アクリレートモノマーの重合単位を、85重量%以下含む、請求項1又は2に記載の再帰反射物品。
- 前記単官能性アルキル(メタ)アクリレートモノマーの重合単位が、-10℃、-20℃、-30℃、-40℃、又は-50℃未満のTgを有する、請求項3に記載の再帰反射物品。
- 前記本体層が、前記第2の層と一体に連結されている、請求項1~4のいずれか一項に記載の再帰反射物品。
- 前記コーナーキューブ要素に隣接する又はその上の鏡面反射性コーティングを更に含む、請求項1~5のいずれか一項に記載の再帰反射物品。
- 前記コーナーキューブ要素の一部に結合されたシールフィルムを更に含む、請求項1~6のいずれか一項に記載の再帰反射物品。
- 再帰反射性シート材である、請求項1~7のいずれか一項に記載の再帰反射物品。
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EP3465293A1 (en) | 2019-04-10 |
JP2019520607A (ja) | 2019-07-18 |
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US20190302317A1 (en) | 2019-10-03 |
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