JP5764669B2 - 熱可塑性加硫組成物、その製造方法、及びそれから製造される物品 - Google Patents
熱可塑性加硫組成物、その製造方法、及びそれから製造される物品 Download PDFInfo
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- JP5764669B2 JP5764669B2 JP2013546553A JP2013546553A JP5764669B2 JP 5764669 B2 JP5764669 B2 JP 5764669B2 JP 2013546553 A JP2013546553 A JP 2013546553A JP 2013546553 A JP2013546553 A JP 2013546553A JP 5764669 B2 JP5764669 B2 JP 5764669B2
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- 229920002678 cellulose Polymers 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- OGIBIEJZCZSNJK-UHFFFAOYSA-N dicyclopentadiene, 3-methyl Chemical compound C1C2C3C(C)=CCC3C1C=C2 OGIBIEJZCZSNJK-UHFFFAOYSA-N 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- VCJPGLFMFFFWFN-UHFFFAOYSA-N formic acid azide Chemical compound [N-]=[N+]=[N-].C(=O)O VCJPGLFMFFFWFN-UHFFFAOYSA-N 0.000 description 1
- XJRPXNWUCVZVJP-UHFFFAOYSA-N formyl azide Chemical class [N-]=[N+]=NC=O XJRPXNWUCVZVJP-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- GJTGYNPBJNRYKI-UHFFFAOYSA-N hex-1-ene;prop-1-ene Chemical compound CC=C.CCCCC=C GJTGYNPBJNRYKI-UHFFFAOYSA-N 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 125000003454 indenyl group Chemical class C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- QAXLLGNKYJQIQK-UHFFFAOYSA-N oct-1-ene;prop-1-ene Chemical compound CC=C.CCCCCCC=C QAXLLGNKYJQIQK-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical class [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- HSVFKFNNMLUVEY-UHFFFAOYSA-N sulfuryl diazide Chemical compound [N-]=[N+]=NS(=O)(=O)N=[N+]=[N-] HSVFKFNNMLUVEY-UHFFFAOYSA-N 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
第1の成分:第1のプロピレン系ポリマー
(1) g’=(IVbranched/IVlinear)
第2の成分:硬化性又は加硫性ゴム
任意の第3の成分:第2のプロピレン系ポリマー
任意の第4の成分
追加の任意成分
GPC法
メルトインデックス及びメルトフローレート
ショアA硬度
引張及び伸び特性
ムーニー粘度
引裂強さ
密度
融点
Claims (5)
- (i)1〜20wt%のα−オレフィンを含み、インターポリマーの数平均分子量(Mn)において測定されるg’比が1未満、MFR(ASTM D−1238−04に従って、2.16kg、230℃の条件にて測定する)が0.01以上、密度が0.850g/cc以上、及び分子量分布Mw/Mnが3.5以下で特徴付けられるプロピレン/α−オレフィンコポリマーと、(ii)それらの組合せとからなる群より選択される第1のプロピレン系ポリマーからなる第1の成分を、熱可塑性加硫組成物の総重量に対して5wt%〜95wt%、並びに
0.85〜0.88g/ccの密度、0.001〜5g/10minのメルトインデックス(I2 )(ASTM D−1238−04に従って、190℃/2.16kgの条件にて測定する)、及びASTM 1646−04に従って、1分間の予熱、4分間の回転子の運転時間で測定した5〜400のムーニー粘度(ML 1+4、125℃)を有する硬化性又は加硫性ゴムと、それらの組合せからなる群より選択され、少なくとも1種のゴムが加硫可能である第2の成分を、熱可塑性加硫組成物の総重量に対して5wt%〜95wt%
含み、8MPa以上の引張破断強さ及び少なくとも330N/cmの23℃における引裂強さを有し、引張破断強さは、101.6mm×152.4×3.2mmの大きさを有する射出成型したプラークの流動方向に5インチ/minの引張速度で引っ張るミクロ引張法ASTM D1708を用いて測定され、引裂強さはASTM D624 ダイCにより測定される、
熱可塑性加硫組成物。 - (i)プロピレンホモポリマーと、(ii)少なくとも80wt%のプロピレンを含むプロピレン−α−オレフィンインターポリマーと、(iii)それらの組合せからなる群より選択される120℃を超える融解温度を有する第2のプロピレン系ポリマーを含む第3の成分を、熱可塑性加硫組成物の総重量に対して0wt%超から50wt%まで更に含む、請求項1に記載の熱可塑性加硫組成物。
- フェノール樹脂、過酸化物、マレイミド、ケイ素含有アジド、及びそれらの組合せからなる群より選択される第4の成分を、熱可塑性加硫組成物の総重量に対して0wt%を超え2wt%まで更に含む、請求項2に記載の熱可塑性加硫組成物。
- 第1のプロピレン系ポリマーが、インターポリマーの数平均分子量(Mn)において測定される、0.85未満のg’比を有する、請求項1〜3のいずれか一項に記載の熱可塑性加硫組成物。
- 第1のプロピレン系ポリマーの相対的な組成ドリフトが50%未満で特徴付けられる、請求項1〜4のいずれか一項に記載の熱可塑性加硫組成物。
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PCT/CN2010/080500 WO2012088689A1 (en) | 2010-12-30 | 2010-12-30 | Thermoplastic vulcanizate composition, method of producing the same, and articles made therefrom |
Publications (2)
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JP2014501308A JP2014501308A (ja) | 2014-01-20 |
JP5764669B2 true JP5764669B2 (ja) | 2015-08-19 |
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US (1) | US9309396B2 (ja) |
EP (1) | EP2658919B1 (ja) |
JP (1) | JP5764669B2 (ja) |
KR (1) | KR101843217B1 (ja) |
CN (1) | CN103403086B (ja) |
BR (1) | BR112013016647B1 (ja) |
WO (1) | WO2012088689A1 (ja) |
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KR101837328B1 (ko) | 2013-12-24 | 2018-03-09 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 열가소성 가황물을 포함하는 조성물, 발포된 물질, 및 그로부터 제조된 물품 |
US20170181498A1 (en) | 2014-07-25 | 2017-06-29 | Exxonmobil Chemical Patents Inc. | Footwear Compositions Comprising Propylene-Based Elastomers |
US9359014B1 (en) * | 2014-12-02 | 2016-06-07 | Building Materials Investment Corporation | Thermoplastic olefin building materials |
JP6021964B2 (ja) * | 2015-02-04 | 2016-11-09 | 株式会社ブリヂストン | タイヤ |
JP2018154821A (ja) * | 2017-03-16 | 2018-10-04 | Mcppイノベーション合同会社 | 熱可塑性エラストマー組成物 |
JP6965644B2 (ja) * | 2017-09-05 | 2021-11-10 | Mcppイノベーション合同会社 | 動的架橋型熱可塑性エラストマー組成物及びその成形体 |
JP6965643B2 (ja) * | 2017-09-05 | 2021-11-10 | Mcppイノベーション合同会社 | 非発泡成形用動的架橋型熱可塑性エラストマー組成物 |
JP6965645B2 (ja) * | 2017-09-05 | 2021-11-10 | Mcppイノベーション合同会社 | 複合成形体用動的架橋型熱可塑性エラストマー組成物及び複合成形体 |
US12018166B2 (en) * | 2018-06-29 | 2024-06-25 | Dow Global Technologies Llc | Thermoplastic vulcanizates modified polypropylene for subsea insulation |
CN112997033B (zh) * | 2018-09-14 | 2023-07-25 | 国际人造丝公司 | 热塑性硫化橡胶组合物、其制备和在柔性管状管道中的用途 |
CN112969574A (zh) * | 2018-09-14 | 2021-06-15 | 埃克森美孚化学专利公司 | 用于油气应用的柔性管道的聚合物内/压力护套中的热塑性硫化橡胶组合物 |
US11458677B2 (en) * | 2019-12-26 | 2022-10-04 | Industrial Technology Research Institute | Selective laser sintering composition and selective laser sintering 3D printing method employing the same |
KR20210141807A (ko) * | 2020-05-13 | 2021-11-23 | 주식회사 나노텍세라믹스 | 발포 조성물 및 이를 이용한 발포체 성형방법 |
CN111844673A (zh) * | 2020-07-08 | 2020-10-30 | 上海叶心材料科技有限公司 | 应用于tpv汽车仪表板的高强度丙烯弹性体使用方法 |
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WO2012088689A1 (en) | 2012-07-05 |
EP2658919A1 (en) | 2013-11-06 |
US9309396B2 (en) | 2016-04-12 |
BR112013016647A2 (pt) | 2017-07-11 |
BR112013016647B1 (pt) | 2020-04-07 |
US20130324658A1 (en) | 2013-12-05 |
CN103403086B (zh) | 2016-12-07 |
EP2658919B1 (en) | 2018-07-25 |
KR101843217B1 (ko) | 2018-03-28 |
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