JP3157748B2 - 導電性高分子を用いた固体電解コンデンサ及びその製造方法 - Google Patents

導電性高分子を用いた固体電解コンデンサ及びその製造方法

Info

Publication number: JP3157748B2
Authority: JP; Japan
Prior art keywords: conductive polymer; compound layer; polymer compound; solid electrolytic; electrolytic capacitor
Prior art date: 1997-07-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP20487797A

Other languages

English (en)

Japanese (ja)

Other versions

JPH1154373A (ja

Inventor

隆深海

健二荒木

智次荒井

勇治青木

健一高橋

Original Assignee

富山日本電気株式会社

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-07-30

Filing date

1997-07-30

Publication date

2001-04-16

1997-07-30 Application filed by 富山日本電気株式会社 filed Critical 富山日本電気株式会社

1997-07-30 Priority to JP20487797A priority Critical patent/JP3157748B2/ja

1998-07-23 Priority to US09/121,269 priority patent/US6154358A/en

1998-07-27 Priority to DE69839716T priority patent/DE69839716D1/de

1998-07-27 Priority to EP98114011A priority patent/EP0895259B1/en

1998-07-29 Priority to KR1019980030562A priority patent/KR100334918B1/ko

1999-02-26 Publication of JPH1154373A publication Critical patent/JPH1154373A/ja

2000-07-26 Priority to US09/626,076 priority patent/US6210450B1/en

2001-04-16 Application granted granted Critical

2001-04-16 Publication of JP3157748B2 publication Critical patent/JP3157748B2/ja

2017-07-30 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920001940 conductive polymer Polymers 0.000 title claims description 62
239000003990 capacitor Substances 0.000 title claims description 47
238000000034 method Methods 0.000 title claims description 29
239000007787 solid Substances 0.000 title claims description 27
238000004519 manufacturing process Methods 0.000 title claims description 10
150000001875 compounds Chemical class 0.000 claims description 62
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 32
238000006116 polymerization reaction Methods 0.000 claims description 23
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 16
229920000642 polymer Polymers 0.000 claims description 14
239000007784 solid electrolyte Substances 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 8
229930192474 thiophene Natural products 0.000 claims description 8
229910052751 metal Inorganic materials 0.000 claims description 7
239000002184 metal Substances 0.000 claims description 7
239000007800 oxidant agent Substances 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
229910044991 metal oxide Inorganic materials 0.000 claims description 3
150000004706 metal oxides Chemical class 0.000 claims description 3
230000001590 oxidative effect Effects 0.000 claims description 2
YMMGRPLNZPTZBS-UHFFFAOYSA-N 2,3-dihydrothieno[2,3-b][1,4]dioxine Chemical compound O1CCOC2=C1C=CS2 YMMGRPLNZPTZBS-UHFFFAOYSA-N 0.000 claims 2
239000000243 solution Substances 0.000 description 25
229920000128 polypyrrole Polymers 0.000 description 24
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
239000008188 pellet Substances 0.000 description 20
229920000767 polyaniline Polymers 0.000 description 15
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 14
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 12
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 12
229920000123 polythiophene Polymers 0.000 description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 6
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
239000000178 monomer Substances 0.000 description 6
229910052715 tantalum Inorganic materials 0.000 description 6
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 6
239000011148 porous material Substances 0.000 description 5
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
229910002804 graphite Inorganic materials 0.000 description 4
239000010439 graphite Substances 0.000 description 4
FYMCOOOLDFPFPN-UHFFFAOYSA-K iron(3+);4-methylbenzenesulfonate Chemical compound [Fe+3].CC1=CC=C(S([O-])(=O)=O)C=C1.CC1=CC=C(S([O-])(=O)=O)C=C1.CC1=CC=C(S([O-])(=O)=O)C=C1 FYMCOOOLDFPFPN-UHFFFAOYSA-K 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
239000000843 powder Substances 0.000 description 4
WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 3
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 3
238000002048 anodisation reaction Methods 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 3
239000002019 doping agent Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000003822 epoxy resin Substances 0.000 description 3
238000007654 immersion Methods 0.000 description 3
229920001197 polyacetylene Polymers 0.000 description 3
229920000647 polyepoxide Polymers 0.000 description 3
230000000379 polymerizing effect Effects 0.000 description 3
-1 polyparaphenylene Polymers 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000005406 washing Methods 0.000 description 3
GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 2
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
150000001448 anilines Chemical class 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
239000012046 mixed solvent Substances 0.000 description 2
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
150000003233 pyrroles Chemical class 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
239000000758 substrate Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
OJFOWGWQOFZNNJ-UHFFFAOYSA-N 3,4-dimethyl-1h-pyrrole Chemical compound CC1=CNC=C1C OJFOWGWQOFZNNJ-UHFFFAOYSA-N 0.000 description 1
229920000265 Polyparaphenylene Polymers 0.000 description 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
239000012935 ammoniumperoxodisulfate Substances 0.000 description 1
MIAUJDCQDVWHEV-UHFFFAOYSA-N benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1S(O)(=O)=O MIAUJDCQDVWHEV-UHFFFAOYSA-N 0.000 description 1
239000004020 conductor Substances 0.000 description 1
229920000547 conjugated polymer Polymers 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000006355 external stress Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
150000002391 heterocyclic compounds Chemical class 0.000 description 1
239000012212 insulator Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000033116 oxidation-reduction process Effects 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000012827 research and development Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors

Landscapes

Engineering & Computer Science (AREA)
Power Engineering (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Microelectronics & Electronic Packaging (AREA)
Materials Engineering (AREA)
Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

JP20487797A 1997-07-30 1997-07-30 導電性高分子を用いた固体電解コンデンサ及びその製造方法 Expired - Fee Related JP3157748B2 (ja)

Priority Applications (6)

Application Number	Priority Date	Filing Date	Title
JP20487797A JP3157748B2 (ja)	1997-07-30	1997-07-30	導電性高分子を用いた固体電解コンデンサ及びその製造方法
US09/121,269 US6154358A (en)	1997-07-30	1998-07-23	Solid electrolytic capacitor using a conducting polymer
DE69839716T DE69839716D1 (de)	1997-07-30	1998-07-27	Leitende Polymere verwendender Festelektrolytkondensator und dessen Herstellungsverfahren
EP98114011A EP0895259B1 (en)	1997-07-30	1998-07-27	Solid electrolytic capacitor using conducting polymers and method of making same
KR1019980030562A KR100334918B1 (ko)	1997-07-30	1998-07-29	도전성폴리머를이용한고체전해커패시터및그제조방법
US09/626,076 US6210450B1 (en)	1997-07-30	2000-07-26	Method of making solid electrolyte capacitor using a conducting polymer solid electrolytic capacitor using a conducting polymer method of making

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP20487797A JP3157748B2 (ja)	1997-07-30	1997-07-30	導電性高分子を用いた固体電解コンデンサ及びその製造方法

Publications (2)

Publication Number	Publication Date
JPH1154373A JPH1154373A (ja)	1999-02-26
JP3157748B2 true JP3157748B2 (ja)	2001-04-16

Family

ID=16497885

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP20487797A Expired - Fee Related JP3157748B2 (ja)	1997-07-30	1997-07-30	導電性高分子を用いた固体電解コンデンサ及びその製造方法

Country Status (5)

Country	Link
US (2)	US6154358A (ko)
EP (1)	EP0895259B1 (ko)
JP (1)	JP3157748B2 (ko)
KR (1)	KR100334918B1 (ko)
DE (1)	DE69839716D1 (ko)

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JP4366055B2 (ja) *	2002-08-01	2009-11-18	ローム株式会社	固体電解コンデンサの製造方法
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JP2005093591A (ja) *	2003-09-16	2005-04-07	Sanyo Electric Co Ltd	固体電解コンデンサ
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JP4701680B2 (ja) *	2004-11-05	2011-06-15	Ｔｄｋ株式会社	固体電解コンデンサ及びその製造方法
JP4799853B2 (ja) *	2004-11-22	2011-10-26	株式会社フジクラ	光電変換素子用電極、光電変換素子および色素増感太陽電池
JP4799852B2 (ja) *	2004-11-22	2011-10-26	株式会社フジクラ	光電変換素子用電極、光電変換素子および色素増感太陽電池
US7324329B2 (en) *	2005-12-22	2008-01-29	Giner, Inc.	Electrochemical-electrolytic capacitor and method of making the same
EP1978533B1 (en) *	2005-12-28	2016-11-16	Showa Denko K.K.	Capacitor and method for manufacturing same
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US7515396B2 (en) *	2007-03-21	2009-04-07	Avx Corporation	Solid electrolytic capacitor containing a conductive polymer
US7483259B2 (en) *	2007-03-21	2009-01-27	Avx Corporation	Solid electrolytic capacitor containing a barrier layer
JP2009209259A (ja) *	2008-03-04	2009-09-17	Nec Tokin Corp	導電性高分子およびそれを用いた固体電解コンデンサ
US8486799B2 (en) *	2009-03-02	2013-07-16	Showa Denko K.K.	Method for manufacturing solid electrolytic capacitor
JP2011124544A (ja) *	2009-09-30	2011-06-23	Hc Starck Clevios Gmbh	選択された色数の単量体およびそれより調製されたコンデンサ
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JPH0645199A (ja) *	1992-07-24	1994-02-18	Nippon Chemicon Corp	固体電解コンデンサ
JP2765462B2 (ja) *	1993-07-27	1998-06-18	日本電気株式会社	固体電解コンデンサおよびその製造方法
JPH0745481A (ja) *	1993-07-29	1995-02-14	Nec Corp	固体電解コンデンサ及びその製造方法
JP3068430B2 (ja) *	1995-04-25	2000-07-24	富山日本電気株式会社	固体電解コンデンサ及びその製造方法
JP3223790B2 (ja) *	1995-06-26	2001-10-29	松下電器産業株式会社	コンデンサ及びその製造方法
JP3294973B2 (ja) *	1995-09-21	2002-06-24	旭光学工業株式会社	カメラのバリヤ移動制限機構
US5812367A (en) *	1996-04-04	1998-09-22	Matsushita Electric Industrial Co., Ltd.	Solid electrolytic capacitors comprising a conductive layer made of a polymer of pyrrole or its derivative
KR100442073B1 (ko) *	1996-04-26	2004-09-18	닛뽄 케미콘 가부시끼가이샤	고체전해콘덴서및그제조방법
JPH10284351A (ja)	1997-04-09	1998-10-23	Nichicon Corp	固体電解コンデンサ及びその製造方法

1997
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1998
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EP0895259A3 (en)	2001-04-25
KR100334918B1 (ko)	2002-06-20
EP0895259B1 (en)	2008-07-16
US6154358A (en)	2000-11-28
EP0895259A2 (en)	1999-02-03
DE69839716D1 (de)	2008-08-28
JPH1154373A (ja)	1999-02-26
US6210450B1 (en)	2001-04-03

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