GB1007020A - Photographic processes, emulsions and developer solutions - Google Patents

Photographic processes, emulsions and developer solutions

Info

Publication number
GB1007020A
GB1007020A GB8950/63A GB895063A GB1007020A GB 1007020 A GB1007020 A GB 1007020A GB 8950/63 A GB8950/63 A GB 8950/63A GB 895063 A GB895063 A GB 895063A GB 1007020 A GB1007020 A GB 1007020A
Authority
GB
United Kingdom
Prior art keywords
amino
sulphonic acid
acid
mercapto
hydroxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8950/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agfa Gevaert NV
Original Assignee
Agfa AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa AG filed Critical Agfa AG
Publication of GB1007020A publication Critical patent/GB1007020A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
    • C07D263/58—Benzoxazoles; Hydrogenated benzoxazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/60—Naphthoxazoles; Hydrogenated naphthoxazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/04—1,3-Oxazines; Hydrogenated 1,3-oxazines
    • C07D265/12—1,3-Oxazines; Hydrogenated 1,3-oxazines condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/70—Sulfur atoms
    • C07D277/72—2-Mercaptobenzothiazole
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/84—Naphthothiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D293/00—Heterocyclic compounds containing rings having nitrogen and selenium or nitrogen and tellurium, with or without oxygen or sulfur atoms, as the ring hetero atoms
    • C07D293/10—Heterocyclic compounds containing rings having nitrogen and selenium or nitrogen and tellurium, with or without oxygen or sulfur atoms, as the ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D293/12—Selenazoles; Hydrogenated selenazoles
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
    • G03C1/346—Organic derivatives of bivalent sulfur, selenium or tellurium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)

Abstract

Sodium 2 - mercapto - naphtho - 11,21,4,5oxazole - 5 - sulphonate is prepared by refluxing 1 - amino - 2 - hydroxynaphthalene - 4 - sulphonic acid dissolved in aqueous caustic soda with carbon disulphide in methanol. Similarly, the sulphonates of other 2-mercapto-naphthoxazoles are prepared by using the following sulpho-naphthols in the above preparation: 2 - amino - 3 - hydroxynaphthalene - 6 - sulphonic acid, 1 - hydroxy - 2 - aminonaphthalene - 4 - sulphonic acid, 1 - amino - 2 - hydroxynaphthalene - 6 - sulphonic acid or 2 - hydroxy - 3 - amino - naphthalene - 5 : 7-disulphonic acid. Similarly, substituted 2-mercaptobenzoxazoles are prepared by reacting the following aminophenols with carbon disulphide in the above manner; 2-amino-4-chlorophenol-6-sulphonic acid, 2-aminophenol-4-sulphonic acid, 2-amino-6-chlorophenol-4-sulphonic acid (the resulting sulpho-benzoxazole is converted into its barium salt), 3-amino-4-hydroxybenzoic acid, 2-hydroxy-3-amino-benzoic acid, 1 - hydroxy - 2 - amino - benzene - 4 - or 5-sulphonamide, and 1-hydroxy-2-amino-4-methyl-benzene-6-sulphonic acid. Sodium 2 - mercapto - naphtho - 11,81; 4,6-oxazine-8-sulphonate is prepared by the above method from 1-amino-8-hydroxynaphthalene-6-sulphonic acid and carbon disulphide. By using 1 - hydroxy - 8 - amino - 3,6 - disulphonic acid the corresponding naphthoxazine-5 : 8-disulphonate is obtained. Sodium 2 - mercaptobenzthiazole - 5 - sulphonate is obtained by first adding the sodium salt of 2 - nitrochlorobenzene - 4 - sulphonic acid to an aqueous solution of sodium sulphite, and then adding carbon disulphide and refluxing. Instead of the nitrochlorobenzene compound referred to above the following compounds may be used to give substituted 2-mercaptobenzthiazoles: 1 - chloro - 2 - nitrobenzene - 4 - methylsulphonamide, 1 - chloro-2 - nitro - benzene - 4 - (p - chlorophenylsulphonamide or 4 - chloro - 3 - nitrobenzoic acid. By a similar reaction using potassium selenide instead of sodium sulphide, 2-mercapto-5-sulpho-benzselenazole is obtained. This reaction also is performed using 4-chloro-3-nitrobenzoic acid. Sulphonic acid derivatives of 2 - mercapto - 6 : 7 - benzo - benzthiazole and 2-mercapto-benzthiazine are prepared by sulphonating them with oleum at 20 DEG C.
GB8950/63A 1962-03-08 1963-03-06 Photographic processes, emulsions and developer solutions Expired GB1007020A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEA39654A DE1151731B (en) 1962-03-08 1962-03-08 Process for preventing fogging in silver halide emulsion layers

Publications (1)

Publication Number Publication Date
GB1007020A true GB1007020A (en) 1965-10-13

Family

ID=6931496

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8950/63A Expired GB1007020A (en) 1962-03-08 1963-03-06 Photographic processes, emulsions and developer solutions

Country Status (5)

Country Link
US (1) US3305362A (en)
BE (1) BE629343A (en)
CH (1) CH446884A (en)
DE (1) DE1151731B (en)
GB (1) GB1007020A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4820616A (en) * 1986-02-22 1989-04-11 Agfa-Gevaert Aktiengesellschaft Color photographic recording material
EP0754971A1 (en) 1995-07-18 1997-01-22 Agfa-Gevaert N.V. Material for industrial radiography and development method thereof

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1447577B1 (en) * 1964-03-11 1970-05-14 Agfa Ag Stabilized supersensitization of halogen silver emulsions
GB1201621A (en) * 1967-05-18 1970-08-12 Agfa Gevaert Nv Process for stabilizing developed photographic images
US3808005A (en) * 1968-02-22 1974-04-30 Agfa Gevaert Nv Silver halide emulsion stabilized with a bidentate heterocyclic compound containing a sulpho or a carboxyl group
US3655380A (en) * 1970-01-14 1972-04-11 Eastman Kodak Co Diffusion transfer product and process containing 5-seleno-1,2,3,4-tetrazole
BR7100500D0 (en) * 1970-03-20 1973-06-07 Eastman Kodak Co PHOTOGRAPHIC ELEMENT
JPS589939B2 (en) * 1974-09-03 1983-02-23 富士写真フイルム株式会社 color
JPS5442617B2 (en) * 1974-12-28 1979-12-15
JPS6148832A (en) * 1984-08-16 1986-03-10 Fuji Photo Film Co Ltd Silver halide photosensitive material
JPS61170732A (en) * 1985-01-25 1986-08-01 Fuji Photo Film Co Ltd Silver halide photographic sensitive material
US4683189A (en) * 1985-04-19 1987-07-28 Fuji Photo Film Co., Ltd. Toners for silver halide diffusion transfer image with sulfo or carboxyl groups
DE3605712A1 (en) * 1986-02-22 1987-08-27 Agfa Gevaert Ag PHOTOGRAPHIC RECORDING MATERIAL AND METHOD FOR PRODUCING PHOTOGRAPHIC IMAGES
JP2514369B2 (en) * 1986-07-31 1996-07-10 コニカ株式会社 Method for forming dye image with excellent rapid processability
DE3739766A1 (en) * 1987-11-24 1989-06-08 Agfa Gevaert Ag GRADATION VARIABLE SW PAPER
DE4214196C2 (en) * 1992-04-30 2003-08-28 Agfa Gevaert Ag Color photographic silver halide material
US5919612A (en) * 1996-01-26 1999-07-06 Agfa-Gevaert Ag Color photographic silver halide material
EP1578527A1 (en) * 2002-09-13 2005-09-28 Ciphergen Biosystems, Inc. Preparation and use of mixed mode solid substrates for chromatography adsorbents and biochip arrays

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2453346A (en) * 1945-10-25 1948-11-09 Eastman Kodak Co Stabilization of processed photographic emulsions to high temperatures and humidities
BE510333A (en) * 1951-03-30
US3113026A (en) * 1959-01-19 1963-12-03 Gen Aniline & Film Corp Polyvinyl alcohol photographic silver halide emulsions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4820616A (en) * 1986-02-22 1989-04-11 Agfa-Gevaert Aktiengesellschaft Color photographic recording material
EP0754971A1 (en) 1995-07-18 1997-01-22 Agfa-Gevaert N.V. Material for industrial radiography and development method thereof

Also Published As

Publication number Publication date
BE629343A (en)
DE1151731B (en) 1963-07-18
CH446884A (en) 1967-11-15
US3305362A (en) 1967-02-21

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