ES8504876A1 - Un procedimiento mejorado para preparar una espuma fenolica - Google Patents
Un procedimiento mejorado para preparar una espuma fenolicaInfo
- Publication number
- ES8504876A1 ES8504876A1 ES523969A ES523969A ES8504876A1 ES 8504876 A1 ES8504876 A1 ES 8504876A1 ES 523969 A ES523969 A ES 523969A ES 523969 A ES523969 A ES 523969A ES 8504876 A1 ES8504876 A1 ES 8504876A1
- Authority
- ES
- Spain
- Prior art keywords
- resole
- sulfonic acid
- foaming
- phenolic foam
- phenolic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR UNA ESPUMA FENOLICA QUE TIENE UNA ESTRUCTURA DE CELULAS CERRADAS UNIFORME, CON CELULAS SUSTANCIALMENTE EXENTAS TANTO DE ROTURAS COMO DE PERFORACIONES.CONSISTE EN HACER REACCIONAR UN RESOL ACUOSO DE FENOL-FORMALDEHIDO, UN TENSIOACTIVO Y UN AGENTE DE SOPLADO, EN PRESENCIA DE UN CATALIZADOR ACIDO, PARA OBTENER UNA COMPOSICION ESPUMABLE DE RESOL FENOLICA, Y A CONTINUACION SE ESPUMA Y SE CURA DICHA COMPOSICION EN UN MOLDE SUSTANCIALMENTE CERRADO. COMO CATALIZADOR ACIDO SE UTILIZA UN ACIDO ARIL-SULFONICO ANHIDRO QUE TIENE UN PKA INFERIOR A DOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/396,706 US4444912A (en) | 1981-07-10 | 1982-07-09 | Phenolic foam and composition and method for preparing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
ES523969A0 ES523969A0 (es) | 1985-05-01 |
ES8504876A1 true ES8504876A1 (es) | 1985-05-01 |
Family
ID=23568334
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES523969A Expired ES8504876A1 (es) | 1982-07-09 | 1983-07-08 | Un procedimiento mejorado para preparar una espuma fenolica |
Country Status (21)
Country | Link |
---|---|
US (1) | US4444912A (es) |
JP (1) | JPS5962645A (es) |
AT (1) | AT387578B (es) |
AU (1) | AU540541B2 (es) |
BE (1) | BE897256A (es) |
CA (1) | CA1209749A (es) |
CH (1) | CH662578A5 (es) |
DE (1) | DE3324433A1 (es) |
DK (1) | DK317683A (es) |
ES (1) | ES8504876A1 (es) |
FI (1) | FI76825C (es) |
FR (1) | FR2529902B1 (es) |
GB (1) | GB2124631B (es) |
IT (1) | IT1172291B (es) |
LU (1) | LU84908A1 (es) |
NL (1) | NL188754C (es) |
NO (1) | NO159937C (es) |
NZ (1) | NZ204806A (es) |
PT (1) | PT77005B (es) |
SE (1) | SE459810B (es) |
ZA (1) | ZA834751B (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4900759A (en) * | 1981-05-20 | 1990-02-13 | Monsanto Company | Phenolic foams |
US4478958A (en) * | 1981-07-10 | 1984-10-23 | Kopper Company, Inc. | Method for preparing phenolic foams using anhydrous aryl sulfonic acid catalysts |
CA1238149A (en) * | 1984-10-30 | 1988-06-14 | Jacynthe Cote | Closed cell phenolic foams |
JPS61283631A (ja) * | 1985-06-10 | 1986-12-13 | Sumitomo Deyurezu Kk | フエノ−ル樹脂発泡体の製造方法 |
US4882364A (en) * | 1987-08-28 | 1989-11-21 | Fiberglas Canada Inc. | Process for manufacturing closed cell phenolic foams |
JPH01289840A (ja) * | 1988-05-17 | 1989-11-21 | Showa Highpolymer Co Ltd | フェノール樹脂発泡性組成物 |
US4956394A (en) * | 1989-12-12 | 1990-09-11 | Thermal Products International | Closed cell phenolic foam containing alkyl glucosides |
US5232745A (en) * | 1991-03-01 | 1993-08-03 | Manville Corporation | Method of neutralizing acid containing compositions present in an insulation board |
US5407963A (en) * | 1994-06-09 | 1995-04-18 | Willson; Jennifer | Non-CFC foam produced using blended surfactants |
JP3162293B2 (ja) * | 1996-06-25 | 2001-04-25 | 花王株式会社 | 鋳型成型用粘結剤組成物 |
AU7270598A (en) * | 1997-05-02 | 1998-11-27 | Jiffy Foam, Incorporated | Method for making a closed-cell phenolic resin foam |
JPH11172033A (ja) * | 1997-12-10 | 1999-06-29 | Asahi Chem Ind Co Ltd | フェノールフォーム |
US6586484B1 (en) * | 1997-12-10 | 2003-07-01 | Owens Corning Fiberglas Technology, Inc. | Phenol foam |
JP3813062B2 (ja) | 1998-07-03 | 2006-08-23 | 旭化成建材株式会社 | フェノールフォーム |
US6492432B1 (en) | 1999-11-09 | 2002-12-10 | American Foam Technologies, Inc. | Novolac-epoxy resin foam, foamable composition for making novolac-epoxy resin foam and method of making novolac-epoxy resin foam |
US7318499B2 (en) * | 2004-02-20 | 2008-01-15 | Honeywell International, Inc. | Noise suppression structure and method of making the same |
JP4925390B2 (ja) * | 2004-07-14 | 2012-04-25 | 旭有機材工業株式会社 | フェノール樹脂発泡体の製造方法 |
KR102242076B1 (ko) | 2013-12-27 | 2021-04-20 | 아사히 가세이 겐자이 가부시키가이샤 | 페놀 수지 발포체 |
CN106414573B (zh) * | 2014-01-24 | 2020-03-17 | 旭化成建材株式会社 | 酚醛树脂发泡体及其制造方法 |
GB2571940B (en) | 2018-03-12 | 2020-03-25 | Kingspan Holdings Irl Ltd | An insulation product and method for manufacturing same |
GB2575988B (en) | 2018-07-30 | 2020-07-22 | Kingspan Holdings Irl Ltd | Phenolic foam and method of manufacture thereof |
Family Cites Families (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA674181A (en) * | 1963-11-12 | D. Nelson John | Cellular phenolic resin | |
CA866876A (en) * | 1971-03-23 | Weissenfels Franz | Process for the production of foamed phenolic resins | |
US2446429A (en) * | 1944-10-20 | 1948-08-03 | Gen Electric | Cellular phenolic resin |
US2653139A (en) * | 1950-05-20 | 1953-09-22 | Westinghouse Electric Corp | In-place expanded cellular resinous bodies and processes for producing them from phenol-aldehyde resins with the aid of a peroxide |
US2728741A (en) * | 1952-11-01 | 1955-12-27 | Lockheed Aircraft Corp | Phenol-formaldehyde resins for foaming compositions |
US2933461A (en) * | 1954-08-31 | 1960-04-19 | Westinghouse Electric Corp | Method for producing a cured expanded phenolic-aldehyde resin |
US2979469A (en) * | 1957-12-30 | 1961-04-11 | Owens Corning Fiberglass Corp | Production of phenolic foams |
US3389094A (en) * | 1963-10-10 | 1968-06-18 | Union Carbide Corp | Foaming phenol-formaldehyde resins with fluorocarbons |
US3298973A (en) * | 1963-10-10 | 1967-01-17 | Union Carbide Corp | Phenolic foam compositions |
US3271331A (en) * | 1963-10-10 | 1966-09-06 | Union Carbide Corp | Phenolic foams stabilized by siloxane-oxyalkylene copolymers |
US3336243A (en) * | 1963-11-04 | 1967-08-15 | Dow Chemical Co | Phenol-formaldehyde resin composition |
US3389095A (en) * | 1963-12-16 | 1968-06-18 | Dow Chemical Co | Process for stabilizing phenolic foam with alkylene oxide and product obtained therefrom |
FR1462228A (fr) * | 1965-07-08 | 1966-04-15 | Saint Gobain | Procédé pour l'obtention de mousses de résines phénoliques |
US3385010A (en) * | 1966-03-25 | 1968-05-28 | Norton Co | Abrasive disc |
US3484391A (en) * | 1966-04-14 | 1969-12-16 | Atomic Energy Commission | Phenolic foam composition |
US3639303A (en) * | 1967-06-15 | 1972-02-01 | Ici Ltd | Phenolic foams |
FR1578941A (es) * | 1968-05-09 | 1969-08-22 | ||
US4111911A (en) * | 1968-06-06 | 1978-09-05 | Dynamit Nobel Aktiengesellschaft | Method of hardening liquid resols |
US4102832A (en) * | 1968-06-06 | 1978-07-25 | Dynamit Nobel Aktiengesellschaft | Method of hardening and foaming liquid resols using a mixture of diluent and aromatic sulfonic acid |
FR2016760A1 (es) * | 1968-06-06 | 1970-05-15 | Dynamit Nobel Ag | |
US3830894A (en) * | 1968-08-19 | 1974-08-20 | F Weissenfels | Process for the preparation of filled phenol resin foam materials |
SU367117A1 (ru) * | 1968-11-21 | 1973-01-23 | СПОСОБ полу*1Ёни ПЁНОПЛАСТОВ | |
US3640911A (en) * | 1969-04-04 | 1972-02-08 | Union Carbide Corp | Phenolic foam process |
US3673130A (en) * | 1969-04-04 | 1972-06-27 | Union Carbide Corp | Non-punking phenolic foam |
DE1920867C3 (de) * | 1969-04-24 | 1975-10-02 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Phenolharzschaumstoffen |
PL82451B1 (es) * | 1969-06-23 | 1975-10-31 | Dynamit Nobel Ag | |
US3915772A (en) * | 1969-07-30 | 1975-10-28 | Dynamit Nobel Ag | Process for the improvement of adhesion of protective layers to phenolic resin foams |
GB1275871A (en) * | 1970-01-12 | 1972-05-24 | Tac Construction Materials Ltd | Improvements in the manufacture of panels with foam phenol-formaldehyde cores |
US3692706A (en) * | 1970-02-06 | 1972-09-19 | Ciba Geigy Ag | Foamed materials and their preparation |
US3872033A (en) * | 1970-03-13 | 1975-03-18 | Fibreglass Ltd | Foamed reaction product of a resale with a sulfonated novolac |
DE2058663B2 (de) * | 1970-11-28 | 1975-08-28 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Phenolharzschaumstoffen |
US3740358A (en) * | 1971-04-14 | 1973-06-19 | Butler Manufacturing Co | Heat-resistant phenolic foam compositions |
US3823103A (en) * | 1971-07-21 | 1974-07-09 | Union Carbide Corp | Aqueous dispersions based on heathardenable phenolic resins containing a gum mixture stabilizing agent |
BE786953A (fr) * | 1971-07-30 | 1973-01-29 | Pilkington Brothers Ltd | Novolaques sulfonees et produits expanses. |
BE790734A (fr) * | 1971-11-02 | 1973-02-15 | Dynamit Nobel Ag | Procede pour ameliorer la force d'adherence des couches de recouvrementcellulosiques aux mousses phenoliques |
BE791023A (fr) * | 1971-11-08 | 1973-05-07 | Dow Chemical Co | Mousses ameliorees a base de resols phenoliques et leur procedede preparation |
US3842020A (en) * | 1971-11-08 | 1974-10-15 | Dow Chemical Co | Method of expanding a resole resin containing expandable thermoplastic microspheres and product obtained therefrom |
US4042314A (en) * | 1971-12-02 | 1977-08-16 | Dynamit Nobel Aktiengesellschaft | Apparatus for the continuous manufacture of phenolic resin foam in endless sheets |
ZA721386B (en) * | 1971-12-02 | 1972-11-29 | Dynamit Nobel Ag | Process and device for the continous production of phenolic-resin foam in endless runs |
US3999230A (en) * | 1971-12-02 | 1976-12-28 | Dynamit Nobel Aktiengesellschaft | Apparatus for the continuous manufacture of phenolic resin foam in endless sheets |
CA1026068A (en) * | 1972-06-09 | 1978-02-14 | Exxon Research And Engineering Company | Phenolic foam and method of manufacture |
US3835208A (en) * | 1972-06-09 | 1974-09-10 | Exxon Research Engineering Co | Method for producing an integral skin phenolic foam |
US4067829A (en) * | 1973-03-19 | 1978-01-10 | The Dow Chemical Company | Preparation of a cured resole resin |
US3953645A (en) * | 1973-04-26 | 1976-04-27 | The Celotex Corporation | Phenolic polymer, related products and processes thereof |
US4048145A (en) * | 1973-04-26 | 1977-09-13 | The Celotex Corporation | Phenolic polymer prepared from o-cresol |
US3876620A (en) * | 1973-04-26 | 1975-04-08 | Celotex Corp | Process of preparing phenolic-aldehyde polymer using o-cresol |
US3821337A (en) * | 1973-05-07 | 1974-06-28 | Exxon Research Engineering Co | Process for controlled curing of foams |
DE2333469C2 (de) * | 1973-06-30 | 1975-07-10 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur Herstellung eines mittel- bis grobporigen Phenolharzhartschaumes mit verbesserter Abriebfestigkeit |
SU548037A1 (ru) * | 1973-10-08 | 1984-05-15 | Предприятие П/Я Г-4059 | Композици дл получени пенопласта |
US4001148A (en) * | 1974-03-21 | 1977-01-04 | Deutsche Texaco Aktiengesellschaft | Process for the production of flame-resistant phenolic resin foam plastics |
US4033909A (en) * | 1974-08-13 | 1977-07-05 | Union Carbide Corporation | Stable phenolic resoles |
GB1488527A (en) * | 1974-11-07 | 1977-10-12 | Ciba Geigy Ag | Method of making a synthetic resin foam |
US3968300A (en) * | 1975-02-24 | 1976-07-06 | The Celotex Corporation | Phenolic polymer, related products and processes thereof |
JPS5825093B2 (ja) * | 1975-06-23 | 1983-05-25 | 住友ベークライト株式会社 | フエノ−ルジユシハツポウタイノ セイゾウホウホウ |
US4033910A (en) * | 1975-09-26 | 1977-07-05 | Union Carbide Corporation | Methyl formate as an adjuvant in phenolic foam formation |
FR2331588A1 (fr) * | 1975-11-17 | 1977-06-10 | Charbonnages Ste Chimique | Procede de preparation de mousses formo-phenoliques |
US4070313A (en) * | 1976-01-16 | 1978-01-24 | Union Carbide Corporation | Non punking phenolic foam |
US4133931A (en) * | 1976-05-19 | 1979-01-09 | The Celotex Corporation | Closed cell phenolic foam |
CA1105250A (en) * | 1976-05-21 | 1981-07-21 | Wellington Chemical Industries, Inc. | Anti-odorant compositions |
US4122045A (en) * | 1976-05-24 | 1978-10-24 | Armstrong Cork Company | Non-punking non-corrosive phenolic foam containing sodium tetraborate |
US4303758A (en) * | 1976-06-07 | 1981-12-01 | Gusmer Frederick E | Method of preparing closed cell phenol-aldehyde foam and the closed cell foam thus prepared |
US4107107A (en) * | 1976-06-16 | 1978-08-15 | Westinghouse Electric Corp. | Process for the manufacture of a flame resistant, insulating, energy-absorbing, porous phenolic foam |
JPS535065A (en) * | 1976-07-05 | 1978-01-18 | Nitto Chem Ind Co Ltd | Treatment of exhaust gas containing hydrocyanic acid |
US4018725A (en) * | 1976-08-09 | 1977-04-19 | H. H. Robertson Company | Phenolic foam products and method of making the same |
US4075139A (en) * | 1977-02-22 | 1978-02-21 | The Upjohn Company | Process of making a cured resole foam and product produced therefrom |
US4119584A (en) * | 1977-03-25 | 1978-10-10 | Union Carbide Corporation | Phenolic foam modified with phosphorus-containing isocyanate-terminated prepolymers |
US4219623A (en) * | 1977-07-26 | 1980-08-26 | Reichhold Limited | Phenol formaldehyde resin foams |
US4176106A (en) * | 1977-07-28 | 1979-11-27 | Union Carbide Corporation | Phenol/formaldehyde resoles and cellular products derived therefrom |
US4140842A (en) * | 1977-09-29 | 1979-02-20 | The Celotex Corporation | Phenolic foam and surfactant useful therein |
US4207400A (en) * | 1977-11-16 | 1980-06-10 | Monsanto Company | Foamable resole resin composition |
GB2024227B (en) * | 1978-06-05 | 1983-03-23 | Monsanto Co | Foamable resole resin compositions containing calcium oxide |
AU4774379A (en) * | 1978-06-05 | 1979-12-13 | Monsanto Company | Foamable resole resin composition |
US4202945A (en) * | 1979-04-03 | 1980-05-13 | Leinhardt Franklyn J | Phenolic foam materials and method of making same |
US4423163A (en) * | 1980-10-09 | 1983-12-27 | Koppers Company, Inc. | Method of producing phenolic foam using pressure and foam produced by the method |
US4419460A (en) * | 1980-12-22 | 1983-12-06 | Monsanto Company | Phenolic foams |
-
1982
- 1982-07-09 US US06/396,706 patent/US4444912A/en not_active Expired - Fee Related
-
1983
- 1983-06-21 FI FI832258A patent/FI76825C/fi not_active IP Right Cessation
- 1983-06-29 ZA ZA834751A patent/ZA834751B/xx unknown
- 1983-06-30 AU AU16422/83A patent/AU540541B2/en not_active Ceased
- 1983-07-04 NZ NZ204806A patent/NZ204806A/en unknown
- 1983-07-05 NO NO832443A patent/NO159937C/no unknown
- 1983-07-06 SE SE8303861A patent/SE459810B/sv not_active IP Right Cessation
- 1983-07-07 DE DE19833324433 patent/DE3324433A1/de active Granted
- 1983-07-08 AT AT0252083A patent/AT387578B/de active
- 1983-07-08 IT IT48656/83A patent/IT1172291B/it active
- 1983-07-08 GB GB08318586A patent/GB2124631B/en not_active Expired
- 1983-07-08 NL NLAANVRAGE8302442,A patent/NL188754C/xx not_active IP Right Cessation
- 1983-07-08 ES ES523969A patent/ES8504876A1/es not_active Expired
- 1983-07-08 PT PT77005A patent/PT77005B/pt unknown
- 1983-07-08 DK DK317683A patent/DK317683A/da not_active Application Discontinuation
- 1983-07-08 CH CH3779/83A patent/CH662578A5/de not_active IP Right Cessation
- 1983-07-08 BE BE0/211148A patent/BE897256A/fr not_active IP Right Cessation
- 1983-07-08 CA CA000432127A patent/CA1209749A/en not_active Expired
- 1983-07-08 JP JP58125373A patent/JPS5962645A/ja active Granted
- 1983-07-11 LU LU84908A patent/LU84908A1/fr unknown
- 1983-07-11 FR FR8311548A patent/FR2529902B1/fr not_active Expired
Also Published As
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19970203 |