ES2172035T3 - Procedimiento para alquilar compuestos organicos susceptibles de alquilacion. - Google Patents
Procedimiento para alquilar compuestos organicos susceptibles de alquilacion.Info
- Publication number
- ES2172035T3 ES2172035T3 ES97953684T ES97953684T ES2172035T3 ES 2172035 T3 ES2172035 T3 ES 2172035T3 ES 97953684 T ES97953684 T ES 97953684T ES 97953684 T ES97953684 T ES 97953684T ES 2172035 T3 ES2172035 T3 ES 2172035T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- procedure
- rental
- renting
- rent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
- B01J38/56—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- C07C2529/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- C07C2529/12—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCEDIMIENTO DE ALQUILACION DE HIDROCARBUROS EN EL CUAL UN COMPUESTO ORGANICO ALQUILABLE SE HACE REACCIONAR CON UN AGENTE DE ALQUILACION, PARA FORMAR UN ALQUILADO, EN PRESENCIA DE UN CATALIZADOR QUE COMPRENDE UNA FUNCION HIDROGENANTE Y UN CONSTITUYENTE ACIDO SOLIDO. EL CATALIZADOR SE SOMETE INTERMITENTEMENTE A UNA ETAPA DE REGENERACION, MEDIANTE SU PUESTA EN CONTACTO CON UNA CORRIENTE DE ALIMENTACION QUE CONTIENE UN HIDROCARBURO SATURADO E HIDROGENO. DICHA REGENERACION SE LLEVA A CABO AL 90 % O MENOS DEL CICLO ACTIVO DEL CATALIZADOR, DEFINIENDOSE DICHO CICLO ACTIVO COMO EL TIEMPO DESDE EL INICIO DEL SUMINISTRO DEL AGENTE DE ALQUILACION HASTA EL MOMENTO EN EL QUE EL 20 % DEL AGENTE DE ALQUILACION ABANDONA LA SECCION DEL REACTOR QUE CONTIENE EL CATALIZADOR SIN HABER SIDO TRANSFORMADO, SIN TENER EN CUENTA LA ISOMERIZACION EN EL INTERIOR DE LA MOLECULA. EL PROCEDIMIENTO DE LA INVENCION ES ESPECIALMENTE ADECUADO PARA LA ALQUILACION DE ISOBUTANO CON UNO O MAS BUTENOS, PARA FORMAR UN ALQUILADO CON UN RON ELEVADO.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL1004623A NL1004623C2 (nl) | 1996-11-27 | 1996-11-27 | Werkwijze voor het alkyleren van koolwaterstoffen. |
US3154296P | 1996-12-02 | 1996-12-02 | |
EP97202951 | 1997-09-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2172035T3 true ES2172035T3 (es) | 2002-09-16 |
Family
ID=27238509
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97953684T Expired - Lifetime ES2172035T3 (es) | 1996-11-27 | 1997-11-14 | Procedimiento para alquilar compuestos organicos susceptibles de alquilacion. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5986158A (es) |
EP (1) | EP0941211B1 (es) |
JP (1) | JP4278067B2 (es) |
KR (1) | KR100533754B1 (es) |
CN (1) | CN1088449C (es) |
AU (1) | AU5750598A (es) |
BR (1) | BR9713441B1 (es) |
CA (1) | CA2273333C (es) |
DE (1) | DE69710359T2 (es) |
ES (1) | ES2172035T3 (es) |
WO (1) | WO1998023560A1 (es) |
Families Citing this family (70)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU7823300A (en) | 1999-06-08 | 2001-01-31 | Bechtel Bwxt Idaho, Llc | Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas |
AU2001266005A1 (en) * | 2000-05-30 | 2001-12-11 | Akzo Nobel N.V. | Novel alkylation catalyst and its use in alkylation |
US20020013216A1 (en) | 2000-05-30 | 2002-01-31 | Broekhoven Emanuel Hermanus Van | Novel alkylation catalyst and its use in alkylation |
US7407905B2 (en) | 2000-06-14 | 2008-08-05 | Battelle Energy Alliance, Llc | Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts |
US6579821B1 (en) | 2000-06-14 | 2003-06-17 | Bechtel Bwxt Idaho, Llc | Method for reactivating solid catalysts used in alkylation reactions |
US6844479B2 (en) * | 2000-10-20 | 2005-01-18 | Abb Lummus Global Inc. | Alkylation process |
CN100528817C (zh) * | 2001-06-08 | 2009-08-19 | 阿尔伯麦尔荷兰有限公司 | 烃类的催化烷基化方法 |
DK1527035T3 (da) * | 2001-06-08 | 2015-06-08 | Albemarle Netherlands Bv | Kontinuerlig fremgangsmåde til alkyleringen af carbonhydrider |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US6924407B2 (en) * | 2001-08-27 | 2005-08-02 | The University Of Kansas | Pressure-tuned solid catalyzed heterogeneous chemical reactions |
ES2371238T3 (es) | 2001-11-06 | 2011-12-28 | Albemarle Netherlands B.V. | Catalizador de alquilación que contiene azufre y su uso. |
US7361797B2 (en) * | 2002-02-05 | 2008-04-22 | Abb Lummus Global Inc. | Hydrocarbon conversion using nanocrystalline zeolite Y |
CA2479625C (en) * | 2002-03-18 | 2011-05-10 | Akzo Nobel Nv | Alkylation of saturated hydrocarbons using interstage distillation |
US20040158113A1 (en) * | 2003-02-06 | 2004-08-12 | Girish Srinivas | Catalysts and process for converting fuel gases to gasoline |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US7145049B2 (en) * | 2003-07-25 | 2006-12-05 | Catalytic Distillation Technologies | Oligomerization process |
JP4508617B2 (ja) * | 2003-11-28 | 2010-07-21 | 薫 藤元 | イソパラフィン−オレフィンアルキル化用ゼオライト触媒および該触媒を用いたアルキル化法 |
AU2005211495B2 (en) | 2004-02-09 | 2010-02-18 | Albemarle Netherlands B.V. | Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7592282B2 (en) | 2004-11-11 | 2009-09-22 | Battelle Energy Alliance, Llc | Enhancement of alkylation catalysts for improved supercritical fluid regeneration |
US20060101712A1 (en) * | 2004-11-15 | 2006-05-18 | Burnett Don E | Small off-road engine green fuel |
AU2007215476B2 (en) | 2006-02-03 | 2011-11-10 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
SG187456A1 (en) | 2006-02-03 | 2013-02-28 | Grt Inc | Separation of light gases from halogens |
US7875754B2 (en) * | 2006-07-27 | 2011-01-25 | Lummus Technology Inc. | Method of improving alkylate yield in an alkylation reaction |
WO2008048427A1 (en) * | 2006-10-17 | 2008-04-24 | Abb Lummus Global, Inc. | Bimetallic alkylation catalysts |
TWI433829B (zh) * | 2007-01-26 | 2014-04-11 | Albemarle Netherlands Bv | 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法 |
KR20100027141A (ko) | 2007-05-24 | 2010-03-10 | 지알티, 인코포레이티드 | 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기 |
WO2009050067A1 (en) * | 2007-10-17 | 2009-04-23 | Albemarle Netherlands, B.V. | Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal |
EP2217374B1 (en) * | 2007-11-02 | 2022-03-09 | Badger Licensing, LLC | A process for rejuvenating a catalyst composition |
WO2009061303A1 (en) * | 2007-11-08 | 2009-05-14 | Lummus Technology Inc. | Method of improving alkylate yield in an alkylation reaction |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
CA2730934C (en) | 2008-07-18 | 2017-07-04 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
JP2012518522A (ja) | 2009-02-11 | 2012-08-16 | アルベマール・ユーロプ・エスピーアールエル | アルキル化触媒および関連する工程 |
KR101259708B1 (ko) * | 2010-02-04 | 2013-05-06 | 경희대학교 산학협력단 | 마이크로 플로우 리액터를 이용한 2차 아민 화합물을 제조하는 신규한 방법 |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
WO2012092436A1 (en) * | 2010-12-30 | 2012-07-05 | Virent, Inc. | Organo-catalytic biomass deconstruction |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9415385B2 (en) | 2011-11-21 | 2016-08-16 | Exxonmobil Research And Engineering Company | Activation of dual catalyst systems |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
US20170203285A1 (en) | 2014-07-07 | 2017-07-20 | Albemarle Europe Sprl | Alkylation Process Using a Catalyst Comprising Cerium Rich Rare Earth Containing Zeolites and a Hydrogenation Metal |
US10011538B2 (en) * | 2014-10-27 | 2018-07-03 | Exxonmobil Chemical Patents Inc. | Method of making aromatic hydrocarbons |
LT3310480T (lt) | 2015-06-22 | 2020-12-10 | Exelus, Inc. | Pagerintas katalizuotas alkilinimas, alkilinimo katalizatoriai ir alkilinimo katalizatorių gamybos būdai |
CN105195177B (zh) * | 2015-09-18 | 2017-12-26 | 宁波海越新材料有限公司 | 一种烷基化汽油催化剂及其制备方法 |
CN106631656B (zh) * | 2015-10-28 | 2019-09-24 | 中国石油化工股份有限公司 | 一种烷基化反应方法 |
CN106631655B (zh) * | 2015-10-28 | 2019-05-21 | 中国石油化工股份有限公司 | 一种烷基化反应方法 |
RU2637922C2 (ru) * | 2016-06-02 | 2017-12-08 | Публичное акционерное общество "Электрогорский институт нефтепереработки" (ПАО "ЭлИНП") | Способ алкилирования изобутана в трехфазном реакторе с неподвижным слоем катализатора |
US11225614B2 (en) | 2017-03-01 | 2022-01-18 | Emanuel Hermanus Van Broekhoven | Alkylation process with improved octane number |
CN109420403B (zh) * | 2017-08-31 | 2022-05-03 | 中国石油化工股份有限公司 | 一种重整氢气的利用方法、固体酸催化剂的再生方法和烷基化反应方法 |
CN110538675A (zh) * | 2018-05-28 | 2019-12-06 | 中国石油化工股份有限公司 | 固体酸烷基化催化剂及其制备方法和应用 |
CN110872529B (zh) * | 2018-09-04 | 2022-06-28 | 中国石油化工股份有限公司 | 固体酸烷基化反应方法和反应*** |
CN110876854B (zh) | 2018-09-06 | 2021-05-14 | 中国石油化工股份有限公司 | 一种低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置 |
CN110876855B (zh) | 2018-09-06 | 2021-05-14 | 中国石油化工股份有限公司 | 低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置 |
CN111482195B (zh) * | 2019-01-25 | 2021-05-14 | 中国石油化工股份有限公司 | 一种固体酸催化剂 |
WO2020151646A1 (zh) * | 2019-01-25 | 2020-07-30 | 中国石油化工股份有限公司 | 固体酸催化剂、其制备和应用 |
CN111482193B (zh) * | 2019-01-25 | 2021-08-06 | 中国石油化工股份有限公司 | 一种固体酸催化剂的制备方法 |
WO2021025835A1 (en) * | 2019-08-06 | 2021-02-11 | Exxonmobil Research And Engineering Company | Catalyst rejuvenation in multistage alkylation of isoparaffin |
CN111763130B (zh) | 2020-06-22 | 2023-01-03 | 南京克米斯璀新能源科技有限公司 | 一种用于生产长链烷基苯的方法 |
BR102021007444A2 (pt) * | 2021-04-19 | 2022-10-25 | Petróleo Brasileiro S.A. - Petrobras | Processo para a obtenção de alquil-naftênicos |
CN115678599A (zh) * | 2021-07-29 | 2023-02-03 | 中国石油化工股份有限公司 | 一种烷基化方法 |
US11851386B2 (en) | 2021-10-15 | 2023-12-26 | Exelus, Inc. | Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents |
CN115999617A (zh) * | 2021-10-22 | 2023-04-25 | 中国石油化工股份有限公司 | 一种利用重整氢气再生固体酸烷基化反应催化剂的方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3549557A (en) * | 1968-06-26 | 1970-12-22 | Union Carbide Corp | Isoparaffin alkylation process and catalyst for use therein |
US3851004A (en) * | 1973-09-27 | 1974-11-26 | Union Carbide Corp | Hydrocarbon alkylation process using catalyst regeneration |
FR2721603B1 (fr) * | 1994-06-22 | 1996-09-20 | Inst Francais Du Petrole | Procédé de réjuvénation d'un catalyseur solide d'alkylation. |
US5489732A (en) * | 1994-10-14 | 1996-02-06 | Uop | Fluidized solid bed motor fuel alkylation process |
-
1997
- 1997-11-14 JP JP52422798A patent/JP4278067B2/ja not_active Expired - Lifetime
- 1997-11-14 BR BRPI9713441-4A patent/BR9713441B1/pt not_active IP Right Cessation
- 1997-11-14 AU AU57505/98A patent/AU5750598A/en not_active Abandoned
- 1997-11-14 CN CN97180073A patent/CN1088449C/zh not_active Expired - Lifetime
- 1997-11-14 ES ES97953684T patent/ES2172035T3/es not_active Expired - Lifetime
- 1997-11-14 EP EP97953684A patent/EP0941211B1/en not_active Expired - Lifetime
- 1997-11-14 WO PCT/EP1997/006401 patent/WO1998023560A1/en active IP Right Grant
- 1997-11-14 DE DE69710359T patent/DE69710359T2/de not_active Expired - Lifetime
- 1997-11-14 KR KR10-1999-7003521A patent/KR100533754B1/ko not_active IP Right Cessation
- 1997-11-14 CA CA002273333A patent/CA2273333C/en not_active Expired - Lifetime
- 1997-11-20 US US08/974,762 patent/US5986158A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2273333A1 (en) | 1998-06-04 |
CN1088449C (zh) | 2002-07-31 |
DE69710359D1 (de) | 2002-03-21 |
KR20000052722A (ko) | 2000-08-25 |
BR9713441A (pt) | 2000-02-01 |
AU5750598A (en) | 1998-06-22 |
CA2273333C (en) | 2007-05-01 |
EP0941211B1 (en) | 2002-02-06 |
WO1998023560A1 (en) | 1998-06-04 |
CN1238747A (zh) | 1999-12-15 |
US5986158A (en) | 1999-11-16 |
JP2001504504A (ja) | 2001-04-03 |
EP0941211A1 (en) | 1999-09-15 |
JP4278067B2 (ja) | 2009-06-10 |
KR100533754B1 (ko) | 2005-12-06 |
BR9713441B1 (pt) | 2009-01-13 |
DE69710359T2 (de) | 2002-08-14 |
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