ES2074426T3 - Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad. - Google Patents

Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad.

Info

Publication number
ES2074426T3
ES2074426T3 ES88111492T ES88111492T ES2074426T3 ES 2074426 T3 ES2074426 T3 ES 2074426T3 ES 88111492 T ES88111492 T ES 88111492T ES 88111492 T ES88111492 T ES 88111492T ES 2074426 T3 ES2074426 T3 ES 2074426T3
Authority
ES
Spain
Prior art keywords
cps
organic solvent
atoms
carbon
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES88111492T
Other languages
English (en)
Inventor
Chin Chien Hsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodrich Corp
Original Assignee
BF Goodrich Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp
Application granted granted Critical
Publication of ES2074426T3 publication Critical patent/ES2074426T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/923—Ethylenic monomers containing at least one salt group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

POLIMERO Y PROCESO DE POLIMERIZACION DE UN MONOMERO CARGADO CONTENIENDO AL MENOS UN 85% DE UN MONOMERO CARBOXILO NO SATURADO ALQUENO NUMERADO DE 3 A 5 ATOMOS DE CARBONO DE HASTA UN 15% DE COMONOMERO COPOLIMERIZABLE, EN PRESENCIA DE UN MEDIO DE MEZCLA DE REACCION CONTENIENDO UN DISOLVENTE ORGANICO Y UN HIDROCARBURO DISOLVENTE EN RAZON DE PESO RESPECTIVO DE 95/5 A 1/99, DICHO DISOLVENTE ORGANICO SE SELECCIONA DE ENTRE ACETONAS, ESTERES, ETERES Y ALCOHOLES TENIENDO PARAMETROS DE SOLUBILIDAD EN EL RANGO DE 8 A 15 Y DICHO HIDROCARBURO DISOLVENTE SE SELECCIONA DE ENTRE ALIFATICOS Y ALQUENOS CICLICOS ALIFATICOS CONTENIENDO DE 4 A 12 ATOMOS DE CARBONO Y AROMATICOS DISTINTOS DEL BENCENO DE 7 A 9 ATOMOS DE CARBONO. DICHO DISOLVENTE ORGANICO Y DICHO HIDROCARBURO DISOLVENTE SON PREFERIBLEMENTE LIQUIDOS A TEMPERATURA AMBIENTE. VISCOSIDAD DE 0,2% DE DE PESO DE POLIMERO ES SUPERIOR A 15.000 CPS, PREFERIBLEMENTE SUPERIOR A 20.000 CPS, Y SU CARACTERISTICA DE CLARIDAD ES AL MENOS DEL 80%, PREFERIBLEMENTEDEL 85% LA TRANSMITANCIA. VISCOSIDAD ESPESANTE DEL 1% CONTENIENDO UN 1% DE SAL DE CLORURO SODICO ES MAYOR DE 5.000 CPS, PREFERIBLEMENTE MAYOR DE 8.000 CPS.
ES88111492T 1988-02-19 1988-07-16 Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad. Expired - Lifetime ES2074426T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/157,685 US4996274A (en) 1988-02-19 1988-02-19 Polycarboxylic acids with higher thickening capacity and better clarity

Publications (1)

Publication Number Publication Date
ES2074426T3 true ES2074426T3 (es) 1995-09-16

Family

ID=22564825

Family Applications (1)

Application Number Title Priority Date Filing Date
ES88111492T Expired - Lifetime ES2074426T3 (es) 1988-02-19 1988-07-16 Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad.

Country Status (13)

Country Link
US (1) US4996274A (es)
EP (1) EP0328725B1 (es)
JP (1) JP3023110B2 (es)
KR (1) KR970007242B1 (es)
CN (1) CN1019499B (es)
AU (1) AU612670B2 (es)
BR (1) BR8803727A (es)
CA (1) CA1336852C (es)
DE (1) DE3853716T2 (es)
ES (1) ES2074426T3 (es)
MX (1) MX171770B (es)
PT (1) PT88478B (es)
ZA (1) ZA885408B (es)

Families Citing this family (37)

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JPH0222312A (ja) * 1988-05-26 1990-01-25 Sumitomo Seika Chem Co Ltd 架橋型カルボキシル基含有重合体の製造方法
AU6788890A (en) * 1989-12-29 1991-07-04 B.F. Goodrich Company, The Oxidation resistant polymeric thickeners and method relating thereto
US5034488A (en) * 1990-01-11 1991-07-23 Gaf Chemicals Corporation Slurry polymerization of crosslinked maleic anhydride-alkyl vinyl ether copolymers in a solvent system comprising a carboxylic acid ester and a saturated hydrocarbon
EP0521934A4 (en) * 1990-03-29 1993-02-17 Isp Investments Inc. Copolymers of maleic anhydride and acrylic acid useful in denture adhesives
GB9114095D0 (en) * 1991-06-29 1991-08-14 Allstate Limited Improvements in water-soluble polymers
JPH059235A (ja) * 1991-07-04 1993-01-19 Daicel Chem Ind Ltd 無水マレイン酸−アルキルビニルエ−テル共重合体の製造方法
DE4213283A1 (de) 1992-04-23 1993-10-28 Basf Ag Verwendung von Copolymerisaten aus Carbonsäuren und langkettigen Verbindungen mit isolierten C-C-Mehrfachverbindungen als Verdickungs- oder Dispergiermittel
DE4213971A1 (de) 1992-04-29 1993-11-04 Basf Ag Copolymerisate aus carbonsaeuren und quartaeren ammoniumverbindungen und ihre verwendung als verdickungs- oder dispergiermittel
US5338345A (en) * 1993-05-05 1994-08-16 Eastman Kodak Company Water-based water repellent coating compositions
IT1270968B (it) * 1993-08-25 1997-05-26 Sigma Prod Chim Acidi poliacrilici reticolati a basso tenore di solventi, procedimento per la loro produzione e loro uso come agenti addensanti
US5342911A (en) * 1993-08-25 1994-08-30 3V Inc. Crosslinked polyacrylic acids having low solvent residue, a process for the preparation thereof and the use thereof as thickening agents
DE4330767A1 (de) * 1993-09-10 1995-03-16 Hoechst Ag Polymermischungen mit Wasser
US5422233A (en) * 1994-05-17 1995-06-06 Polaroid Corporation Photographic processing compositions including hydrophobically modified thickening agent
DE19546698A1 (de) * 1995-12-14 1997-06-19 Basf Ag Copolymerisate aus Carbonsäuren und mehrfach olefinisch ungesättigten Carbonsäurederivaten und ihre Verwendung als Verdickungs- oder Dispergiermittel
US5804624A (en) * 1997-04-30 1998-09-08 Wang; Jianming Water-based silicone resin compositions
US5997764A (en) * 1997-12-04 1999-12-07 The B.F. Goodrich Company Thickened bleach compositions
US6297337B1 (en) 1999-05-19 2001-10-02 Pmd Holdings Corp. Bioadhesive polymer compositions
US6689200B2 (en) 2001-07-25 2004-02-10 The Sherwin-Williams Company Film-forming water-based water repellent coating compositions
JP3940009B2 (ja) 2002-03-18 2007-07-04 住友精化株式会社 カルボキシル基含有水溶性重合体の製造方法
GB2393908A (en) * 2002-10-12 2004-04-14 Reckitt Benckiser Inc Thickened, abrasive containing, liquid disinfectant
JP4759236B2 (ja) 2004-07-28 2011-08-31 住友精化株式会社 カルボキシル基含有水溶性重合体の製造方法
JP2005097630A (ja) * 2004-12-07 2005-04-14 Nippon Junyaku Kk 水溶性架橋共重合体粉末の製造方法
DE102005019398A1 (de) * 2005-04-25 2006-10-26 Basf Ag Verfahren zur Herstellung von Fällungspolymeren durch Sprühpolymerisation
JP5221958B2 (ja) 2005-11-14 2013-06-26 住友精化株式会社 アルキル変性カルボキシル基含有水溶性共重合体
JP5149626B2 (ja) 2005-11-21 2013-02-20 住友精化株式会社 アルキル変性カルボキシル基含有水溶性共重合体
CN101410418B (zh) 2006-03-31 2011-11-09 巴斯夫欧洲公司 制备丙烯酸酯共聚物的方法
JP5271079B2 (ja) * 2006-05-12 2013-08-21 住友精化株式会社 顆粒状カルボキシル基含有重合体粒子の製造方法及び顆粒状カルボキシル基含有重合体粒子
KR101522046B1 (ko) * 2007-06-19 2015-05-20 스미또모 세이까 가부시키가이샤 과립 형상 카르복실기 함유 중합체 입자의 제조 방법 및 과립 형상 카르복실기 함유 중합체 입자
JP4998727B2 (ja) * 2007-09-27 2012-08-15 日本純薬株式会社 増粘用不飽和カルボン酸系重合体粉末の製造方法
WO2010059765A1 (en) * 2008-11-21 2010-05-27 Hercules Incorporated Non-hydrocarbyl hydrophobically modified polycarboxylic polymers
JP5544706B2 (ja) * 2008-12-02 2014-07-09 東亞合成株式会社 不飽和カルボン酸系架橋重合体およびこの重合体の製造方法
JP5674223B2 (ja) 2009-08-04 2015-02-25 住友精化株式会社 カルボキシル基含有水溶性重合体の製造方法
US20110218295A1 (en) * 2010-03-02 2011-09-08 Basf Se Anionic associative rheology modifiers
JP5799957B2 (ja) 2010-10-29 2015-10-28 株式会社ワコール スカートタイプの補整用下着
US20130196890A1 (en) 2012-01-30 2013-08-01 Reckitt Benckiser Llc Stable, viscous, peroxide containing lavatory treatment compositions
US9707162B2 (en) 2012-11-30 2017-07-18 Reckitt & Colman (Overseas) Limited Microbicidal personal care compositions comprising metal ions
EP2907828A1 (de) 2014-02-14 2015-08-19 Basf Se Verfahren zur Herstellung von kationogen-ampholytischen VP/VI-Copolymeren

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2798053A (en) * 1952-09-03 1957-07-02 Goodrich Co B F Carboxylic polymers
NL230828A (es) * 1957-08-27
US3915921A (en) * 1974-07-02 1975-10-28 Goodrich Co B F Unsaturated carboxylic acid-long chain alkyl ester copolymers and tri-polymers water thickening agents and emulsifiers
US3940351A (en) * 1974-07-02 1976-02-24 The B. F. Goodrich Company Polymerization of carboxylic acid monomers and alkyl acrylate esters in chlorofluoroethane
US4062817A (en) * 1977-04-04 1977-12-13 The B.F. Goodrich Company Water absorbent polymers comprising unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, and another acrylic ester containing alkyl group 2-8 carbon atoms
US4066583A (en) * 1977-05-16 1978-01-03 The B. F. Goodrich Company Flexible water absorbent polymer compositions comprising (a) unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, additional monomer plus (b) aliphatic diol
US4267103A (en) * 1978-12-07 1981-05-12 The B. F. Goodrich Company Solvent polymerization of carboxyl containing monomers
DE2927132A1 (de) * 1979-07-05 1981-01-08 Bayer Ag Verfahren zur herstellung vernetzter acrylsaeurepolymerisate
CA1321435C (en) * 1986-12-15 1993-08-17 Chao-Jen Chung Non-aqueous polymeric dispersion compositions having improved metal adhesion

Also Published As

Publication number Publication date
EP0328725A3 (en) 1990-06-27
PT88478B (pt) 1994-04-29
CN1019499B (zh) 1992-12-16
DE3853716D1 (de) 1995-06-08
JPH01217017A (ja) 1989-08-30
US4996274A (en) 1991-02-26
EP0328725B1 (en) 1995-05-03
PT88478A (pt) 1989-10-04
ZA885408B (en) 1989-07-26
MX171770B (es) 1993-11-15
KR890013092A (ko) 1989-09-21
CN1035299A (zh) 1989-09-06
CA1336852C (en) 1995-08-29
KR970007242B1 (ko) 1997-05-07
AU612670B2 (en) 1991-07-18
AU1927988A (en) 1989-08-24
JP3023110B2 (ja) 2000-03-21
BR8803727A (pt) 1989-07-25
DE3853716T2 (de) 1995-09-07
EP0328725A2 (en) 1989-08-23

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