EP2938191B1 - Mélanges fongicides synergiques destinés au contrôle d'infection fongique dans les céréales - Google Patents

Mélanges fongicides synergiques destinés au contrôle d'infection fongique dans les céréales Download PDF

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EP2938191B1
EP2938191B1 EP13867094.8A EP13867094A EP2938191B1 EP 2938191 B1 EP2938191 B1 EP 2938191B1 EP 13867094 A EP13867094 A EP 13867094A EP 2938191 B1 EP2938191 B1 EP 2938191B1
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Prior art keywords
mixture
fluxapyroxad
compound
formula
synergistic
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EP2938191A4 (fr
EP2938191A1 (fr
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David G. Ouimette
J. Todd MATHIESON
Gregory M. Kemmitt
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Corteva Agriscience LLC
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Dow AgroSciences LLC
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines

Definitions

  • This disclosure concerns a synergistic fungicidal composition containing (a) the compound of Formula I and (b) fluxapyroxad.
  • Fungicides are compounds, of natural or synthetic origin, which act to protect plants against damage caused by fungi.
  • Current methods of agriculture rely heavily on the use of fungicides. In fact, some crops cannot be grown usefully without the use of fungicides.
  • Using fungicides allows a grower to increase the yield and the quality of the crop and consequently, increase the value of the crop. In most situations, the increase in value of the crop is worth at least three times the cost of the use of the fungicide.
  • Synergism occurs when the activity of two, or more, compounds exceeds the activities of the compounds when used alone.
  • One object of this disclosure is to provide synergistic compositions comprising fungicidal compounds. Another object of this disclosure is to provide processes that use these synergistic compositions.
  • the synergistic compositions are capable of preventing or curing, or both, diseases caused by fungi of the class Ascomycetes.
  • the synergistic compositions have improved efficacy against the Ascomycete pathogens, including leaf blotch of wheat.
  • synergistic compositions are provided along with methods for their use.
  • Some embodiments include a synergistic fungicidal mixture comprising a fungicidally effective amount of the compound of Formula I and fluxapyroxad.
  • Some embodiments include a mixture of the compound of Formula I and fluxapyroxad in which the weight ratios of the compound of Formula I to fluxapyroxad is from about 1:1 to about 16:1. In some more particular embodiments, the weight ratio is from about 1:2 to about 16:1, from about 1:4 to about 16:1, or from about 1:8 to 16:1. In other more particular embodiments, the weight ratio is from about 1:1 to about 8:1, from about 1:1 to about 4:1, or about 1:1 to about 1:2.
  • Some embodiments include a mixture of the compound of Formula I and fluxapyroxad in which the weight ratios of the compound of Formula I to fluxapyroxad includes ratios selected from the group of ratios consisting of: about 1:1, about 1:2, about 1:3, about 1:4, about 1:5, about 1:6, about 1:7, about 1:8, about 1:9, about 1:10, about 1:11, about 1:12, about 1:13, about 1:14, about 1:16, about 2:1, about 3:1, about 4:1, about 5:1, about 6:1, about 7:1, about 8:1, about 9:1, about 10:1, about 11:1, about 12:1, about 13:1, about 14:1, and about 16:1, or within any range defined between any two of the foregoing values.
  • Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 1. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 2. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 3. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 4. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 5. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 6.
  • Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 7. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 8. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 9. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 10. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 11. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 12.
  • Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 13. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 14. Some embodiments include a mixture wherein the ratio of the compound of Formula I to fluxapyroxad is about 1 to about 16. Still other embodiments include a fungicidal composition comprising a fungicidally effective amount of the fungicidal mixture and an agriculturally acceptable adjuvant or carrier.
  • Yet other embodiments include methods of treating a plant, comprising the step of: applying a fungicidally effective amount of a mixture that includes the compound of Formula 1 and fluxapyroxad to a surface selected from at least one surface selected from the group of surfaces consisting of: at least one portion of a plant, soil adjacent to a plant, soil in contact with a plant, seeds, and equipment used in contact with a plant or a surface adjacent to a plant.
  • the fungicidally effective amount of the mixture is applied in the range of about 30 grams/hectare (g/ha) to about 200 g/ha of fluxapyroxad and about 35 g/ha to about 300 g/ha of the compound of Formula 1.
  • the present disclosure concerns a synergistic fungicidal mixture
  • a fungicidally effective amount of (a) the compound of Formula I, (3 S ,6 S ,7 R ,8 R )-8-benzyl-3-(3-((isobutyryloxy)methoxy)-4-methoxypicolinamido)-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl isobutyrate, and (b) fluxapyroxad, 3-(difluoromethyl)-1-methyl- N -(3',4',5'-trifluorobiphenyl-2-yl)pyrazole-4-carboxamide.
  • Fluxapyroxad is described in The e-Pesticide Manual, Version 5.2, 2011 .
  • the structure of fluxapyroxad is as follows:
  • the weight ratios of the compound of Formula I to fluxapyroxad at which the fungicidal effect is synergistic includes ratios in the ranges of about 1:1, about 1:2, about 1:3, about 1:4, about 1:5, about 1:6, about 1:7, about 1:8, about 1:9, about 1:10, about 1:11, about 1:12, about 1:13, about 1:14, about 1:16, about 2:1, about 3:1, about 4:1, about 5:1, about 6:1, about 7:1, about 8:1, about 9:1, about 10:1, about 11:1, about 12:1, about 13:1, about 14:1, and about 16:1.
  • the term "about”, as used herein, refers to a range of plus or minus 10%, e.g., about 1 includes the range of values from 0.9 to 1.1.
  • the rate at which the synergistic composition is applied will depend upon the particular type of fungus to be controlled, the degree of control required and the timing and method of application.
  • the composition of the disclosure can be applied at an application rate of between about 50 grams per hectare (g/ha) and about 1500 g/ha based on the total amount of active ingredients in the composition.
  • the composition of the disclosure can be applied at an application rate of between about 65 grams per hectare (g/ha) and about 500 g/ha based on the total amount of active ingredients in the composition.
  • Fluxapyroxad is applied at a rate between about 30 g/ha and about 200 g/ha and the compound of Formula I is applied at a rate between about 35 g/ha and about 300 g/ha.
  • the components of the synergistic mixture of the present disclosure can be applied either separately or as part of a multipart fungicidal system.
  • the synergistic mixture of the present disclosure can be applied in conjunction with one or more other fungicides to control a wider variety of undesirable diseases.
  • the presently claimed compounds may be formulated with the other fungicide(s), tank mixed with the other fungicide(s) or applied sequentially with the other fungicide(s).
  • Such other fungicides may include (RS)- N -(3,5-dichlorophenyl)-2-(methoxymethyl)-succinimide, 1,2-dichloropropane, 1,3-dichloro-1,1,3,3 -tetrafluoroacetone hydrate, 1-chloro-2,4-dinitronap h thalene, 1-chloro-2-nitropropane, 2-(2-heptadecyl-2-imidazolin-1-yl)ethanol, 2,3-dihydro-5-phenyl-1,4-dithi-ine 1,1,4,4-tetraoxide, 2-methoxyethylmercury acetate, 2-methoxyethylmercury chloride, 2-methoxyethylmercury silicate, 3-(4-chlorophenyl)-5-methylrhodanine, 4-(2-nitroprop-1-enyl)phenyl thiocyanateme, N-3, 5-dich
  • compositions described herein are preferably applied in the form of a formulation comprising a composition of (a) the compound of Formula I and (b) fluxapyroxad, together with a phytologically acceptable carrier.
  • Concentrated formulations can be dispersed in water, or another liquid, for application, or formulations can be dust-like or granular, which can then be applied without further treatment.
  • the formulations are prepared according to procedures which are conventional in the agricultural chemical art, but which are novel and important because of the presence therein of a synergistic composition.
  • the formulations that are applied most often are aqueous suspensions or emulsions.
  • Either such water-soluble, water suspendable, or emulsifiable formulations are solids, usually known as wettable powders, or liquids, usually known as emulsifiable concentrates, aqueous suspensions, or suspension concentrates.
  • the present disclosure contemplates all vehicles by which the synergistic compositions can be formulated for delivery and use as a fungicide.
  • any material to which these synergistic compositions can be added may be used, provided they yield the desired utility without significant interference with the activity of these synergistic compositions as antifungal agents.
  • Wettable powders which may be compacted to form water dispersible granules, comprise an intimate mixture of the synergistic composition, a carrier and agriculturally acceptable surfactants.
  • concentration of the synergistic composition in the wettable powder is usually from about 10% to about 90% by weight, more preferably about 25% to about 75% by weight, based on the total weight of the formulation.
  • the synergistic composition can be compounded with any of the finely divided solids, such as prophyllite, talc, chalk, gypsum, Fuller's earth, bentonite, attapulgite, starch, casein, gluten, montmorillonite clays, diatomaceous earths, purified silicates or the like.
  • the finely divided carrier is ground or mixed with the synergistic composition in a volatile organic solvent.
  • Effective surfactants comprising from about 0.5% to about 10% by weight of the wettable powder, include sulfonated lignins, naphthalenesulfonates, alkylbenzenesulfonates, alkyl sulfates, and non-ionic surfactants, such as ethylene oxide adducts of alkyl phenols.
  • Emulsifiable concentrates of the synergistic composition comprise a convenient concentration, such as from about 10% to about 50% by weight, in a suitable liquid, based on the total weight of the emulsifiable concentrate formulation.
  • the components of the synergistic compositions jointly or separately, are dissolved in a carrier, which is either a water miscible solvent or a mixture of water-immiscible organic solvents, and emulsifiers.
  • the concentrates may be diluted with water and oil to form spray mixtures in the form of oil-in-water emulsions.
  • Useful organic solvents include aromatics, especially the high-boiling naphthalenic and olefinic portions of petroleum such as heavy aromatic naphtha. Other organic solvents may also be used, such as, for example, terpenic solvents, including rosin derivatives, aliphatic ketones, such as cyclohexanone, and complex alcohols, such as 2-ethoxyethanol.
  • Emulsifiers which can be advantageously employed herein can be readily determined by those skilled in the art and include various nonionic, anionic, cationic and amphoteric emulsifiers, or a blend of two or more emulsifiers.
  • nonionic emulsifiers useful in preparing the emulsifiable concentrates include the polyalkylene glycol ethers and condensation products of alkyl and aryl phenols, aliphatic alcohols, aliphatic amines or fatty acids with ethylene oxide, propylene oxides such as the ethoxylated alkyl phenols and carboxylic esters solubilized with the polyol or polyoxyalkylene.
  • Cationic emulsifiers include quaternary ammonium compounds and fatty amine salts.
  • Anionic emulsifiers include the oil-soluble salts (e.g., calcium) of alkylaryl sulfonic acids, oil soluble salts or sulfated polyglycol ethers and appropriate salts of phosphated polyglycol ether.
  • Mixtures of two or more organic liquids are also often suitably employed in the preparation of the emulsifiable concentrate.
  • the preferred organic liquids are xylene, and propyl benzene fractions, with xylene being most preferred.
  • the surface-active dispersing agents are usually employed in liquid formulations and in the amount of from 0.1 to 20 percent by weight of the combined weight of the dispersing agent with the synergistic compositions.
  • the formulations can also contain other compatible additives, for example, plant growth regulators and other biologically active compounds used in agriculture.
  • Aqueous suspensions comprise suspensions of one or more water-insoluble compounds, dispersed in an aqueous vehicle at a concentration in the range from about 5% to about 70% by weight, based on the total weight of the aqueous suspension formulation.
  • Suspensions are prepared by finely grinding the components of the synergistic combination either together or separately, and vigorously mixing the ground material into a vehicle comprised of water and surfactants chosen from the same types discussed above. Other ingredients, such as inorganic salts and synthetic or natural gums, may also be added to increase the density and viscosity of the aqueous vehicle. It is often most effective to grind and mix at the same time by preparing the aqueous mixture and homogenizing it in an implement such as a sand mill, ball mill, or piston-type homogenizer.
  • the synergistic composition may also be applied as a granular formulation, which is particularly useful for applications to the soil.
  • Granular formulations usually contain from about 0.5% to about 10% by weight of the compounds, based on the total weight of the granular formulation, dispersed in a carrier which consists entirely or in large part of coarsely divided attapulgite, bentonite, diatomite, clay or a similar inexpensive substance.
  • Such formulations are usually prepared by dissolving the synergistic composition in a suitable solvent and applying it to a granular carrier which has been preformed to the appropriate particle size, in the range of from about 0.5 to about 3 mm.
  • Such formulations may also be prepared by making a dough or paste of the carrier and the synergistic composition, and crushing and drying to obtain the desired granular particle.
  • Dusts containing the synergistic composition are prepared simply by intimately mixing the synergistic composition in powdered form with a suitable dusty agricultural carrier, such as, for example, kaolin clay, ground volcanic rock, and the like. Dusts can suitably contain from about 1% to about 10% by weight of the synergistic composition/carrier combination.
  • a suitable dusty agricultural carrier such as, for example, kaolin clay, ground volcanic rock, and the like. Dusts can suitably contain from about 1% to about 10% by weight of the synergistic composition/carrier combination.
  • the formulations may contain agriculturally acceptable adjuvant surfactants to enhance deposition, wetting and penetration of the synergistic composition onto the target crop and organism. These adjuvant surfactants may optionally be employed as a component of the formulation or as a tank mix. The amount of adjuvant surfactant will vary from 0.01 percent to 1.0 percent volume/volume (v/v) based on a spray-volume of water, preferably 0.05 to 0.5 percent.
  • Suitable adjuvant surfactants include ethoxylated nonyl phenols, ethoxylated synthetic or natural alcohols, salts of the esters or sulfosuccinic acids, ethoxylated organosilicones, ethoxylated fatty amines and blends of surfactants with mineral or vegetable oils.
  • the formulations may optionally include combinations that can comprise at least 1% by weight of one or more of the synergistic compositions with another pesticidal compound.
  • additional pesticidal compounds may be fungicides, insecticides, nematocides, miticides, arthropodicides, bactericides or combinations thereof that are compatible with the synergistic compositions of the present disclosure in the medium selected for application, and not antagonistic to the activity of the present compounds.
  • the other pesticidal compound is employed as a supplemental toxicant for the same or for a different pesticidal use.
  • the pesticidal compound and the synergistic composition can generally be mixed together in a weight ratio of from 1:100 to 100:1.
  • the present disclosure includes within its scope methods for the control or prevention of fungal attack. These methods comprise applying to the fungus or the area adjacent to the the fungus, or to a plant or area adjacent to a plant in which the infestation is to be prevented (for example applying to wheat or barley plants), a fungicidally effective amount of the synergistic composition.
  • the synergistic composition is suitable for treatment of various plants at fungicidal levels, while exhibiting low phytotoxicity.
  • the synergistic composition is useful in a protectant or eradicant fashion.
  • the synergistic composition is applied by any of a variety of known techniques, either as the synergistic composition or as a formulation comprising the synergistic composition.
  • the synergistic compositions may be applied to the roots, seeds or foliage of plants for the control of various fungi, without damaging the commercial value of the plants.
  • the synergistic composition is applied in the form of any of the generally used formulation types, for example, as solutions, dusts, wettable powders, flowable concentrates, or emulsifiable concentrates. These materials are conveniently applied in various known fashions.
  • the synergistic composition has been found to have significant fungicidal effect particularly for agricultural use.
  • the synergistic composition is particularly effective for use with agricultural crops and horticultural plants, or with wood, paint, leather or carpet backing.
  • the synergistic composition is effective in controlling a variety of undesirable fungi that infect useful plant crops.
  • the synergistic composition can be used against a variety of Ascomycete and Basidiomycete fungi, including for example the following representative fungi species: wheat brown rust ( Puccinia recondita ; Bayer code PUCCRT); stripe rust of wheat ( Puccinia striiformis ; Bayer code PUCCST); leaf blotch of wheat ( Mycosphaerella graminicola; anamorph: Septoria tritici ; Bayer code SEPTTR); glume blotch of wheat ( Leptosphaeria nodorum ; Bayer code LEPTNO; anamorph: Stagonospora nodorum ) and black sigatoka disease of banana ( Mycosphaerella fijiensis ; BAYER code MYCOFI).
  • wheat brown rust Puccinia recondita ; Bayer code PUCCRT
  • the synergistic compositions have a broad range of efficacy as a fungicide.
  • the exact amount of the synergistic composition to be applied is dependent not only on the relative amounts of the components, but also on the particular action desired, the fungal species to be controlled, and the stage of growth thereof, as well as the part of the plant or other product to be contacted with the synergistic composition.
  • formulations containing the synergistic composition may not be equally effective at similar concentrations or against the same fungal species.
  • the synergistic compositions are effective in use with plants in a disease inhibiting and phytologically acceptable amount.
  • disease inhibiting and phytologically acceptable amount refers to an amount of the synergistic composition that kills or inhibits the plant disease for which control is desired, but is not significantly toxic to the plant.
  • concentration of synergistic composition required varies with the fungal disease to be controlled, the type of formulation employed, the method of application, the particular plant species, climate conditions, and the like.
  • compositions can be applied to fungi or the area adjacent to the fungus, or a plant or area adjacent to the plant, by the use of conventional ground sprayers, granule applicators, and by other conventional means known to those skilled in the art.
  • Treatments consisted of fungicides, including the compound of Formula I and fluxapyroxad.
  • Technical grades of materials were dissolved in acetone to make stock solutions, which were then used to perform 4-fold dilutions in acetone for each individual fungicide component or for the two-way mixture. Desired fungicide rates were obtained after mixing dilutions with 9 volumes of water containing 110 parts per million (ppm) Triton X-100.
  • the fungicide solutions (20 milliliters (mL)) were applied to 12 pots of plants using an automated booth sprayer, which utilized two 6218-1/4 JAUPM spray nozzles operating at 20 pounds per square inch (psi) set at opposing angles to cover both leaf surfaces. All sprayed plants were allowed to air dry prior to further handling. Control plants were sprayed in the same manner with a solvent blank.
  • Leaf Blotch of Wheat Mycosphaerella graminicola ; anamorph: Septoria tritici ; Bayer code: SEPTTR).
  • Wheat plants (variety Yuma) were grown from seed in a greenhouse in plastic pots with a surface area of 27.5 square centimeters (cm 2 ) containing 50% mineral soil/50% soil-less Metro mix, with 8 - 12 seedlings per pot. The plants were utilized for testing when the first leaf was fully emerged, which typically occurred 7 - 8 days after planting. Test plants were inoculated with an aqueous spore suspension of Septoria tritici either (a) 3 days prior to fungicide treatments (3-day curative test, 3DC) or (b) 1 day after fungicide treatments (1-day protectant test, 1DP). After inoculation the plants were placed in a dew room from 1 - 3 days to allow for infection to occur. The plants were then placed in the greenhouse for symptom development to occur, which in the case of SEPTTR typically required 25 - 30 days.

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Claims (8)

  1. Mélange fongicide synergique comprenant une quantité efficace sur le plan fongique du composé de formule I, isobutyrate de (3S,6S,7R,8R)-8-benzyl-3-(3-((isobutyryloxy)méthoxy)-4-méthoxypicolinamido)-6-méthyl-4,9-dioxo-1,5-dioxonan-7-yl, et de fluxapyroxade.
    Figure imgb0007
  2. Mélange selon la revendication 1, le rapport pondéral entre le composé de formule I et le fluxapyroxade étant compris entre 1:1 et 16:1.
  3. Mélange selon la revendication 1, le rapport entre le composé de formule I et le fluxapyroxade étant compris entre 1 et 1.
  4. Mélange selon la revendication 1, le rapport entre le composé de formule I et le fluxapyroxade étant compris entre 1 et 4.
  5. Mélange selon la revendication 1, le rapport entre le composé de formule I et le fluxapyroxade étant compris entre 1 et 16.
  6. Composition fongicide comprenant une quantité efficace sur le plan fongique du mélange fongicide selon la revendication 1 et un adjuvant ou vecteur acceptable en agriculture.
  7. Procédé de traitement d'une plante, comprenant l'étape consistant à : appliquer une quantité efficace sur le plan fongique d'un mélange qui comprend le composé de formule 1 et du fluxapyroxade sur une surface choisie dans le groupe constitué par : au moins une partie d'une plante, le sol adjacent à une plante, le sol en contact avec une plante, les semences, et l'équipement utilisé en contact avec une plante ou une surface adjacente à une plante.
  8. Procédé selon la revendication 7, la quantité efficace sur le plan fongique du mélange étant appliquée dans une plage comprise entre 30 g/ha et 200 g/ha de fluxapyroxade et entre 35 g/ha et 300 g/ha de composé de formule 1.
EP13867094.8A 2012-12-28 2013-12-23 Mélanges fongicides synergiques destinés au contrôle d'infection fongique dans les céréales Active EP2938191B1 (fr)

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