EP0693145B1 - Verfahren zur umwandlung von natriumsulfat - Google Patents

Verfahren zur umwandlung von natriumsulfat Download PDF

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Publication number
EP0693145B1
EP0693145B1 EP94912988A EP94912988A EP0693145B1 EP 0693145 B1 EP0693145 B1 EP 0693145B1 EP 94912988 A EP94912988 A EP 94912988A EP 94912988 A EP94912988 A EP 94912988A EP 0693145 B1 EP0693145 B1 EP 0693145B1
Authority
EP
European Patent Office
Prior art keywords
liquor
sodium
stage
waste
wash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94912988A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0693145A1 (de
Inventor
Michael Bobik
Dieter Chybin
Alfred Glasner
Karin Taferner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Austrian Energy and Environment AG and Co KG
Austrian Energy and Environment SGP Waagner Biro GmbH
Original Assignee
Austrian Energy and Environment AG and Co KG
Austrian Energy and Environment SGP Waagner Biro GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Austrian Energy and Environment AG and Co KG, Austrian Energy and Environment SGP Waagner Biro GmbH filed Critical Austrian Energy and Environment AG and Co KG
Publication of EP0693145A1 publication Critical patent/EP0693145A1/de
Application granted granted Critical
Publication of EP0693145B1 publication Critical patent/EP0693145B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/12—Combustion of pulp liquors
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/0064—Aspects concerning the production and the treatment of green and white liquors, e.g. causticizing green liquor
    • D21C11/0071—Treatment of green or white liquors with gases, e.g. with carbon dioxide for carbonation; Expulsion of gaseous compounds, e.g. hydrogen sulfide, from these liquors by this treatment (stripping); Optional separation of solid compounds formed in the liquors by this treatment
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/04—Regeneration of pulp liquors or effluent waste waters of alkali lye
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
    • D21C11/063—Treatment of gas streams comprising solid matter, e.g. the ashes resulting from the combustion of black liquor
    • D21C11/066—Separation of solid compounds from these gases; further treatment of recovered products
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/12—Combustion of pulp liquors
    • D21C11/125—Decomposition of the pulp liquors in reducing atmosphere or in the absence of oxidants, i.e. gasification or pyrolysis
    • D21C11/127—Decomposition of the pulp liquors in reducing atmosphere or in the absence of oxidants, i.e. gasification or pyrolysis with post-combustion of the gases

Definitions

  • EP-B1 223 821 discloses a pyrolysis process for the waste liquor, in which a part of the combustible components formed during the pyrolysis are burned and the inorganic residues are obtained in the molten state and are quenched. Here, too, the solid residues from exhaust gas cleaning are not introduced into the melt.
  • a sensible procedure for the H 2 S stripping makes it necessary to divide the H 2 S stripping 11 into several apparatuses (FIG. 2). Since sodium carbonate is formed in the relevant stripping step due to the two simultaneous desorption reactions, it is therefore necessary to carry out an intermediate fortification with C0 2 after each stripping step in order to transfer the carbonate back to the bicarbonate and thus to increase the H 2 S partial pressure that determines the mass transport.
  • the two desorption reactions with H 2 S and CO 2 are as follows: 1.2NaHS + CO 2nd + H 2nd O ⁇ Well 2nd CO 3rd + H 2nd S 2. 2NaHCO 3rd ⁇ Well 2nd CO 3rd + CO 2nd + H 2nd O 3. NaHCO 3rd + NaHS ⁇ well 2nd CO 3rd + H 2nd S

Landscapes

  • Treating Waste Gases (AREA)
  • Paper (AREA)
EP94912988A 1993-04-05 1994-03-31 Verfahren zur umwandlung von natriumsulfat Expired - Lifetime EP0693145B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AT682/93 1993-04-05
AT0068293A AT398992B (de) 1993-04-05 1993-04-05 Verfahren zur umwandlung von natriumsulfat
PCT/AT1994/000038 WO1994023124A1 (de) 1993-04-05 1994-03-31 Verfahren zur umwandlung von natriumsulfat

Publications (2)

Publication Number Publication Date
EP0693145A1 EP0693145A1 (de) 1996-01-24
EP0693145B1 true EP0693145B1 (de) 1997-09-17

Family

ID=3497044

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94912988A Expired - Lifetime EP0693145B1 (de) 1993-04-05 1994-03-31 Verfahren zur umwandlung von natriumsulfat

Country Status (8)

Country Link
US (1) US5759345A (fi)
EP (1) EP0693145B1 (fi)
AT (1) AT398992B (fi)
AU (1) AU6532294A (fi)
CA (1) CA2160008C (fi)
DE (1) DE59404103D1 (fi)
FI (1) FI954695A0 (fi)
WO (1) WO1994023124A1 (fi)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007036380A1 (de) * 2007-07-31 2009-02-05 Voith Patent Gmbh Verfahren und Anlage zur Aufbereitung der Ablauge eines Sulfitverfahrens
FI125337B (fi) * 2010-10-18 2015-08-31 Andritz Oy Menetelmä ja järjestely epäpuhtauksien erottamiseksi nesteistä tai höyryistä
CN102874769B (zh) * 2012-10-09 2014-07-02 广西大学 碱熔物中硫化钠的氧化转化方法及装置
CN109233884A (zh) * 2018-10-17 2019-01-18 四川锐源能环科技有限公司 一种液态危险废物处理***
US10888818B2 (en) * 2019-01-15 2021-01-12 Honeywell International Inc. Integrated mercaptan extraction and/or sweetening processes combined with thermal oxidation and flue gas treatment
CN111717897A (zh) * 2019-03-19 2020-09-29 萍乡市华星环保工程技术有限公司 一种采用硫泡沫制酸的方法
CN115401054B (zh) * 2022-09-16 2023-04-07 贵州中蓝环保科技有限公司 一种无害化处理电解锰渣的方法
CN115716078A (zh) * 2022-10-17 2023-02-28 北京中科国润环保科技有限公司 二氧化碳资源化利用的方法和***

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3366535A (en) * 1966-07-11 1968-01-30 William T Neiman Process for regenerating waste liquor for reuse in kraft pulping operation
US3826710A (en) * 1972-04-21 1974-07-30 Owens Illinois Inc Carbonation system for recovery of sodium base pulping liquor
US4148684A (en) * 1976-11-08 1979-04-10 Mei Systems Inc. Methods for recovery and recycling of chemicals from sodium sulfite and sodium bisulfite pulping operations
AT351359B (de) * 1977-06-08 1979-07-25 Erco Envirotech Ltd Verfahren zur entfernung des natriumchlorids bei der herstellung von zellstoff
SE448173B (sv) * 1985-06-03 1987-01-26 Croon Inventor Ab Forfarande for utvinning av kemikalier fran cellulosaavlut genom pyrolys
SE456254B (sv) * 1987-02-12 1988-09-19 Korsnes Ab Sett att rena gronlut i sulfatmassafabrikers kemikalieatervinning
AT398440B (de) * 1991-10-25 1994-12-27 Waagner Biro Ag Verfahren zur rückgewinnung der chemikalien der kochlauge
JP3447112B2 (ja) * 1994-05-23 2003-09-16 アルインコ株式会社 作業台の伸縮脚

Also Published As

Publication number Publication date
AU6532294A (en) 1994-10-24
CA2160008C (en) 2001-06-12
DE59404103D1 (de) 1997-10-23
AT398992B (de) 1995-02-27
WO1994023124A1 (de) 1994-10-13
US5759345A (en) 1998-06-02
FI954695A (fi) 1995-10-03
EP0693145A1 (de) 1996-01-24
FI954695A0 (fi) 1995-10-03
CA2160008A1 (en) 1994-10-13
ATA68293A (de) 1994-07-15

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