EP0607149A1 - Verfahren zum herstellen einer metallhalogenid-entladungslampe mit keramischen entladungsgefäss. - Google Patents
Verfahren zum herstellen einer metallhalogenid-entladungslampe mit keramischen entladungsgefäss.Info
- Publication number
- EP0607149A1 EP0607149A1 EP92909171A EP92909171A EP0607149A1 EP 0607149 A1 EP0607149 A1 EP 0607149A1 EP 92909171 A EP92909171 A EP 92909171A EP 92909171 A EP92909171 A EP 92909171A EP 0607149 A1 EP0607149 A1 EP 0607149A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tube
- filling
- bore
- electrode
- shaft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/36—Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
- H01J61/361—Seals between parts of vessel
- H01J61/363—End-disc seals or plug seals
Definitions
- the invention relates to a method for producing • metal halide discharge lamps with a ceramic discharge vessel.
- Such lamps usually have a quartz glass discharge vessel.
- efforts have recently been made to improve the color rendering of these lamps.
- the higher operating temperature required for this can be achieved with a ceramic discharge vessel.
- Typical power levels are 100-250 W.
- the ends of the tubular discharge vessel are usually closed with cylindrical ceramic end plugs into which a metal current lead-through is inserted in the middle.
- a particularly simple way of filling and evacuating the discharge vessel is that one of the two niobium tubes has a small opening in the vicinity of the electrode shaft attached to the tube in the interior of the discharge vessel, so that the amalgam and the inert gas can be evacuated and filled through this opening (GP-PS 2 072 939).
- the end of the niobium tube projecting from the outside is sealed gas-tight by a pinch with subsequent welding.
- the opening in the vicinity of the electrode shaft always remains continuous in order to ensure a connection between the interior of the discharge vessel and the interior of the lead-through tube, which acts as a cold spot, during operation.
- a method for evacuating and filling the discharge vessel is to be provided.
- the concrete form of gas-tight sealing of the für ⁇ guide in the end of the discharge vessel for example by means of an essentially ceramic plug 'or by means of a metal cap (DE-OS 30 12 322) for the present invention of unalloyed - minor importance. It can be done, for example, by means of glass solder or melting ceramics or also by direct sintering.
- the method according to the invention is suitable both for niobium and molybdenum-like bushings, in several embodiments it unfolds its particular value for molybdenum-like materials since it avoids stressing the material with regard to ductility.
- the present application therefore deals in particular with the problem of how brittle bushings can be processed and how the evacuation and filling of a discharge vessel can be designed in such a way that brittle materials similar to molybdenum can also be used.
- a known for high pressure sodium lamps Abdichtungs ⁇ technique (DE-OS 40 37 721. Article 54 (3)) is to close the first end of the Entladungsge 'fäßes, then to evacuate in a glove box, the discharge volume through the second, still open end and to fill with it. The second end is then fitted with an electrode system and closed by heating, the first end having to be cooled in order to prevent the filling from escaping.
- This method is however rather time-consuming and Lich umpli ⁇ M and costly, because the two ends sealed at different times, and are also a glove box is needed.
- the method according to the invention is distinguished in that both ends of the ceramic discharge vessel are equipped with electrode systems which are subsequently sealed by heating, be it by melting a melting ceramic or by direct sintering.
- a pre-assembled structural unit is understood as the electrode system, which consists of the electrode (shaft and tip) which is attached to the leadthrough, for example by butt welding, the leadthrough itself being used for the sealing (usually a ceramic end plug) is used.
- the bushing may be recessed on one or both sides of the stopper, and an external electrical lead may also be attached to the bushing.
- the implementation can also take on the task of the sealing agent itself.
- one end which is designed as a blind end, is now completely sealed.
- the type of implementation used there is insignificant for the present invention.
- the other end is also largely sealed, but only to the extent that it can still serve as a pump end by initially leaving an additional filling hole free, which the Connects discharge volume to the outside space arranged in a glovebox; the bore can possibly also be connected directly to a supply line for evacuation and / or filling via a coupling.
- the advantage of this method is that the cooling of the blind end when sealing the filling bore is largely eliminated and the length of the lamp can thus be considerably shortened.
- the energy required to close the filling hole is namely only a fraction of the heat required to seal the electrode system.
- the bore can be made in the side wall of the discharge vessel itself or in a second and third embodiment in the electrode system (sealing means or bushing).
- the advantage of the first embodiment is that when the lamp is in operation, the thermal load in the area of the side wall is significantly lower than in the area of the electrode system, so that a simple melting ceramic (or glass solder) can be used for sealing.
- the implementation at this end can be pin-shaped or tubular.
- the bore in the sealing means is made outside the lamp axis.
- This constellation is particularly favorable in the case of a pin-shaped feedthrough and in the case of a stopper made of cermet, wherein a melting ceramic which is as high-melting as possible must be used for sealing.
- a melting ceramic which is as high-melting as possible must be used for sealing.
- it can also be used for a tubular bushing.
- the feedthrough is tubular and the filling bore is located in the vicinity of the electrode shaft in a part of the feedthrough which faces the discharge volume.
- the bore connects the discharge volume to the interior of the tubular bushing. It is located either in the side wall of the tube or at the end of the tube.
- the filling bore is used to da ⁇ to evacuate the discharge volume and filling, wherein both the inert gas and the metal halides or metal and possibly in excess, in each case in the solid form (as a compact metal halides , Metal as a piece of wire or foil), are introduced through the bore into the discharge volume.
- the bore is then closed indirectly or directly by heating.
- the filling bore if it is installed in ceramic material, in particular in the side wall or in the mostly ceramic sealant, must be heated slowly and over a large area , for example by means of a gas burner or an expanded laser beam, since cracks would otherwise form in the ceramic.
- the third embodiment is particularly advantageous, namely a tubular bushing with a bore near the electrode shaft.
- the hole is in metallic instead of ceramic material, it can be heated up considerably more quickly and also point-wise, so that cooling of the blind end is completely dispensed with and the overall length of the lamp can be chosen to be particularly short.
- the focused beam from a laser, which is threaded into the tube is particularly suitable for heating and sealing; an Nd-YAG laser with a wavelength of 1.06 ⁇ m is particularly suitable.
- the heating by means of a laser can also take place through the wall of the discharge vessel, since its translucent ceramic material does not absorb the 1.06 ⁇ m radiation.
- Sealing is carried out either by a previously filled in high-melting (preferably only at more than 1700 ° C.) or by melting the pipe material itself.
- a particularly preferred embodiment is the closing by indirect heating, in which the inside diameter of the pipe is applied ⁇ fitted filler rod, the length of which corresponds approximately to the length of the tube, is inserted into the tube and is welded to the end of the tube which is remote from the discharge.
- the advantage of this arrangement is the particularly reliable sealing and the easy accessibility to the welding point, whereby the need to thread a laser beam is eliminated and the quality of the sealing achieved can be better monitored. This is offset by the high cost of materials due to the solid filling rod.
- a first possibility is to insert the electrode shaft, whose diameter is considerably smaller than that of the molybdenum tube, centered into one end of the tube by means of a gauge, then to heat the tube or at least its end surrounding the shaft to about 400 ° C. and then squeezing the heated and thereby becoming ductile molybdenum tube around the electrode shaft and possibly fixing it mechanically by spot welding.
- the sealing is done by a welding technique, in particular by using a heat source, in particular a laser beam, on the pinch is judged.
- the laser beam is focused on a point of the pinch while the tube rotates about its own axis.
- the filling hole is created laterally in the tube wall near the electrode shaft, for example by a single laser pulse with an oblique incidence. It is typically a 0.6 to 0.8 mm hole. This technique is very simple and reliable. However, closing the filling hole is then relatively complex, since it is located clearly above the end of the switch and therefore a larger amount of metal solder must be used to fill up the inner volume of the tube up to the filling hole.
- a modification of this technique provides that, at the same time as the electrode shaft, a spacer for the bore, which is arranged in parallel, is inserted into the end of the molybdenum tube by means of a gauge. After the pipe has been made ductile by heating to 400 ° C., the pipe end is squeezed around the electrode shaft and at the same time around the placeholder for the bore (for example a pin or a short piece of pipe) and the shaft is fixed. Then the placeholder is removed so that the hole is created. In this modification, when the pinch is sealed, the assembly is not rotated and only a part of the pinch that is located away from the bore is melted. With this technique, one manufacturing step (separate production of the bore) can be saved.
- the hole is also located at the end of the tube near the axis, so that subsequent closing after the filling process is made considerably easier.
- the hole can be better targeted with the laser beam, on the other hand, the seal is more reliable because the metallic solder, which melts due to the laser heating, automatically enters the filling hole under the influence of gravity. runs and is held there reliably by the capillary action of the hole, which is only 0.6 to 0.8 mm in size. In addition, only a small amount of Metallot, compared to a side hole, is necessary.
- the pipe end itself can serve as a filling hole; there is no crushing.
- the diameter of the electrode shaft is adapted to that of the molybdenum tube by melting the end of the electrode shaft and thereby sphering it.
- the diameter of the spherical shaft end which is determined by the length of the melted-back section of the shaft, is selected such that it is approximately matched to the inside diameter of the tube. Only then is the spherical shaft end inserted into the tube, mechanically fixed (by spot welding) and the tube end welded to the shaft and thereby sealed.
- a lateral filling hole can then again be created, for example by mechanically creating a hole or by directing a laser from the outside onto the pipe wall near the pipe end.
- This solution originally seemed to fail because the obvious vertical impact of the laser on the tube wall at right angles to the tube axis and intersecting it was very high due to simultaneous perforation of the rear wall. Closing such a double hole would not be economical. Instead, the laser is directed obliquely at the pipe wall, which avoids a second hole. You can also drop the laser at right angles to the tube axis, but offset to the side, and cut a cross slot.
- the electrode shaft is first attached to the inner tube wall, a slight displacement of the electrode shaft from the lamp axis being consciously accepted.
- the opening remaining at the end of the pipe is used as a filling hole.
- the molybdenum tube, including the filling hole, is then closed by a filling rod, which expediently has a recess for the electrode shaft.
- the filler rod is connected to the tube at the end remote from the discharge, as already described.
- This embodiment combines the advantages of the techniques described hitherto in a particularly advantageous manner because both the production of a separate filling bore and the squeezing of the tube end for holding the electrode shaft are avoided in an elegant manner. It is also not necessary to screw the electrode shaft.
- Figure 1 is a metal halide discharge lamp, partially cut Figure 2 shows a second embodiment of the
- Figure 3 shows a third embodiment of the
- FIG. 9 shows an exemplary embodiment of the region of the pump end of a lamp with a cer- et plug.
- a metal halide discharge lamp with an output of 150 W is shown schematically in FIG. It consists of a cylindrical outer bulb 1 made of quartz glass which defines a lamp axis and which is squeezed 2 and base 3 on two sides.
- the axially disposed discharge vessel 4 made of Al 7 0, ceramic is bulged in the center 5 and has zylindri ⁇ specific ends 6. It is mounted by means of two power supply lines 7 that are connected to the base parts 3 via foils 8 in the outer bulb. 1
- the power supply lines 7 made of molybdenum are welded to pin-shaped bushings 9, which are sintered directly into a ceramic end plug 10 of the discharge vessel, that is to say without soldering glass.
- the two bushings 9 made of niobium (or also molybdenum) each hold an electrode 11 on the discharge side, consisting of an electrode shaft 12 made of tungsten and a spherical tip 13 formed on the discharge side end.
- the discharge vessel is filled with an inert ignition gas , for example argon, from mercury and additives to metal halides.
- the electrode shaft 12 is sufficient . up into the axial bore in the end plug 10, because the pin-shaped bushing 9 is recessed in the bore on the discharge side. On the other hand, the pin 9 protrudes at the outer end of the end plug and is directly connected to the power supply 7.
- a filling bore 15 is provided near the pump end 6a, which is closed after filling by a glass solder or a melting ceramic 20.
- One possibility for heating the additional filling bore 15, which is provided with a ceramic melt mass, is heating by means of a laser beam expanded in a special optic or also by means of a gas burner. The mass melts and is held in the filling bore, which acts as a capillary, and cools there, which completes the seal.
- FIG. 2 shows the area of the pump end 6a of the discharge vessel in detail for a second exemplary embodiment.
- the discharge vessel has a wall thickness of 1.2 mm at its two ends.
- the cylindrical plug 10 made of Al-O, ceramic, which is inserted into the end 6 of the discharge vessel, has an outer diameter of 3.3 mm and a height of 6 mm.
- a niobium pin 9 with a length of 12 mm and a diameter of 0.6 mm is sintered directly into the axial bore 14 of the plug.
- the electrode shaft 12 (diameter 0.55 mm) is butt welded to the niobium pin 9.
- the outer section 16 of the niobium stick is closely surrounded by a ceramic sleeve 18.
- the bore 14 is widened at the end 17 of the end plug remote from the discharge.
- the sleeve 18 is inserted into this enlarged bore section 19 and is fixed in that a glass solder 20 is added at this point.
- the sleeve prevents graying and stabilizes the niobium stick, which becomes brittle when sintered.
- the filling bore 24 is in this case parallel to the lamp axis, but laterally offset, through the plug 10. As already explained, it is sealed with a high-melting ceramic 20 when the evacuation and filling process is complete.
- the melting when fastening the sleeve 18 and the sealing of the filling bore 24 can advantageously take place in one step.
- an A 0, filling rod can be introduced into the filling bore 24.
- FIG. 3 A particularly preferred embodiment is shown in FIG. 3.
- the difference from FIG. 2 is that the niobium pin 21, which has a length of 5 mm and a diameter of 0.8 mm, is recessed on both sides in the opening 14. so that on a sleeve can be dispensed with.
- the electrode shaft 12 made of tungsten wire has a diameter of 0.75 mm and a length of 7 mm. It extends 0.5 mm deep into the opening 14.
- a tungsten wire is also butt welded to the pin 21 as a connecting part 22 for external power supply.
- the connecting part 22 also has a wire diameter of 0.75 mm; it has the length of 11 mm.
- the interface 23 between the connecting part and the bushing is also arranged approximately 0.5 mm deep in the axial opening 14 of the end plug. Since contact between the tungsten pin 22 and the glass solder 20 in the filling bore 24 should be avoided due to the different expansion coefficients, which could otherwise lead to cracks in the ceramic, a sleeve 18 made of niobium is also here (or also made of ceramic), which advantageously surrounds the tungsten pin 22, since, in contrast to tungsten or molybdenum, these two materials have an expansion coefficient adapted to the melting ceramic 20. Instead of, or in addition to, the sleeve, a collar 25 (shown in dashed lines) formed on the stopper 10 and surrounding the tungsten pin 22 can also be used.
- FIG. 4a and 4b Another embodiment is shown in Figures 4a and 4b.
- a thin-walled molybdenum tube 26 is sintered directly into the stopper 10.
- a tungsten pin as electrode shaft 27 with helical part 28 is crimped and welded in a gas-tight manner.
- the filling bore 29 is made in the side wall of the tube. It is closed after the filling process in that a metallic Solder compact 42 (eg titanium solder or a mixture of Ti and Mo or Zr / Mo) or a wire section made of solder material (eg titanium, Zr), which has a melting point of more than 1700 ° C., is filled into the tube 26.
- a metallic Solder compact 42 eg titanium solder or a mixture of Ti and Mo or Zr / Mo
- solder material eg titanium, Zr
- a finely focused laser beam (Nd-YAG) 30 is directed into the tube in the tube axis and heats the metallot 42 (FIG. 4a). This melts and seals the filling bore 29 'acting as a capillary (FIG. 4b).
- Nd-YAG laser beam
- FIG. 5 An additional exemplary embodiment is shown in FIG. 5. It essentially corresponds to the arrangement according to FIG. 4, in that a thin-walled molybdenum tube 33 is also sintered directly into the plug 10 at the pump end 6a and a tungsten pin is attached to the tube end as an electrode shaft 32.
- the filling bore 29 in the side wall of the tube is mechanically closed by inserting a filling rod 37, which is adapted to the inside diameter of the tube 26, into the tube 32 after the discharge vessel has been evacuated and filled, and thus fills up the dead volume inside the tube and also covers the filling hole.
- the end facing the shaft can have a concave curvature 38 for better adaptation.
- the filler rod 37 made of molybdenum or tungsten protrudes from the outer end of the tube 33 and is welded there gas-tight to the tube end, for example by means of laser welding 46 or by means of a gas burner.
- a filler rod which is flush with the pipe end or somewhat recessed therein can also be used.
- the molybdenum tube 26 has, for example, an inner diameter of 1.3 mm and a wall thickness of 0.1 mm, while the electrode has a tungsten shaft 27 with a diameter of 0.5 mm.
- the electrode shaft 27 is inserted centered into one end of the molybdenum tube 26 approximately 1 mm deep (FIG. 6a).
- the tube 26 is then heated to 400 ° C. by supplying heat (FIG. 6b), so that the material, which is brittle per se, becomes ductile.
- a pin with a diameter of 0.6 mm arranged parallel thereto is inserted into the tube end as a placeholder 30 for the filling bore (shown in dashed lines in FIG. 6b) .
- the placeholder 30 is removed again, so that in addition to the electrode shaft 27, which is expediently arranged here outside the tube axis, an opening remains at the end 45 of the tube 26, which as Filling hole 31 is used ( Figure 6e).
- the electrode shaft 27 is attached in the pinch without the filling bore 31 being closed. The attachment can also be done before removing the placeholder.
- the method step according to FIG. 6g is omitted in this variant. Immediate welding is dispensed with. Instead, the final sealing after filling is carried out either by a metallot or by a filler rod ( Figure 4 or 5).
- FIGS. 7a to 7c A further possibility of fastening an electrode in a molybdenum tube is explained with reference to FIGS. 7a to 7c.
- the electrode shaft 32 the diameter of which is again considerably smaller than the inside diameter of the molybdenum tube 33, is melted back at one end by the addition of heat until a spherical end 34 is formed, the outside diameter of which corresponds to the inside diameter of the member lybdenum tube 33 is adapted.
- the length of the back melted shaft section 35 determines the diameter of the spherical end 34.
- the spherical end 34 is inserted into the pipe end (arrow) and attached there (for example by laser or spot welding).
- the pipe end 45 can now, if desired, be sealed again, for example.
- the tube 33 advantageously rotating about its axis in the direction of the arrow (FIG. 7b).
- the filling bore 36 ' is produced by directing a laser 46' at right angles to the tube axis, but offset laterally, towards the tube end 45 just behind the welding point and with a single laser pulse approximately 0.7 mm wider Transversal slot 36 'is created in the tube wall ( Figure 7c).
- FIGS. 8a and 8b A particularly simple possibility of fastening an electrode in a molybdenum tube is shown in FIGS. 8a and 8b.
- an electrode 11 with a shaft diameter of 0.5 mm, is inserted into the tube 26 about 0.8 mm deep and laterally at the end 45 of the tube 26, e.g. by means of laser beam 46, attached (indicated by dashed lines in FIG. 8a).
- the tube 26 has an inner diameter of approximately 1.2 mm and a wall thickness of typically 0.2 mm.
- a filling rod 37 'made of molybdenum is inserted into the tube 26 (FIG. 8b), which has a recess 47 for the electrode shaft 27.
- the filling tube 37 ' is somewhat shorter than the tube 26, so that it can be welded very easily at the tube end remote from the discharge, for example by axial laser incidence 46 ".
- the electrode is attached to the leadthrough in a manner that is mirror-symmetrical to the pump end.
- the invention is not limited to the embodiments shown.
- features of individual exemplary embodiments can be combined with one another.
- a filler rod can be used in all of the exemplary embodiments, that is to say also in the tubes which are closed with a pinch.
- the welding step at the crimped pipe end and also the step of final sealing at the crimped pipe end by means of a metallot is eliminated.
- the filler rod technology has the main advantage that the welding takes place at the end of the pipe. On the one hand, this position is easily accessible, on the other hand, it is considerably less exposed to temperature than the front end of the tube which faces the discharge.
- a welded connection is more reliable than a soldered connection.
- the pump end can be equipped with a tubular feedthrough, while the blind end has a pin-shaped feedthrough. It is also possible to use a cermet stopper, which is a ceramic stopper that has a low contains a metal, at the blind end.
- the manufacturing method according to the invention is also suitable for a cermet plug 39 at the pump end 6a.
- a cermet plug 39 at the pump end 6a.
- EP-PA 272 930 e.g. EP-PA 272 930
- a separate implementation can be dispensed with, since the cermet is itself conductive (FIG. 9).
- the electrode shaft 40 aligned in the lamp axis is seated directly in the cermet stopper 39 which performs the task, while a power supply 41 is attached to the outer end.
- the manufacturing process corresponds to the steps discussed in connection with FIG. 2.
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
- Ceramic Products (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE9112690U DE9112690U1 (de) | 1991-10-11 | 1991-10-11 | Hochdruckentladungslampe |
DE9112690U | 1991-10-11 | ||
PCT/DE1992/000372 WO1993007638A1 (de) | 1991-10-11 | 1992-05-06 | Verfahren zum herstellen einer metallhalogenid-entladungslampe mit keramischen entladungsgefäss |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0607149A1 true EP0607149A1 (de) | 1994-07-27 |
EP0607149B1 EP0607149B1 (de) | 1995-10-11 |
Family
ID=6872172
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92909171A Expired - Lifetime EP0607149B1 (de) | 1991-10-11 | 1992-05-06 | Verfahren zum herstellen einer metallhalogenid-entladungslampe mit keramischem entladungsgefäss |
EP92116463A Withdrawn EP0536609A1 (de) | 1991-10-11 | 1992-09-25 | Hochdruckentladungslampe |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92116463A Withdrawn EP0536609A1 (de) | 1991-10-11 | 1992-09-25 | Hochdruckentladungslampe |
Country Status (9)
Country | Link |
---|---|
US (2) | US5484315A (de) |
EP (2) | EP0607149B1 (de) |
JP (2) | JP3150341B2 (de) |
KR (1) | KR100255426B1 (de) |
CN (1) | CN1073801A (de) |
CA (1) | CA2117260A1 (de) |
DE (2) | DE9112690U1 (de) |
HU (2) | HU214232B (de) |
WO (1) | WO1993007638A1 (de) |
Families Citing this family (40)
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DE9112690U1 (de) * | 1991-10-11 | 1991-12-05 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH, 8000 München | Hochdruckentladungslampe |
DE9206727U1 (de) * | 1992-05-18 | 1992-07-16 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH, 8000 München | Hochdruckentladungslampe |
DE4242122A1 (de) * | 1992-12-14 | 1994-06-16 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Verfahren zur Herstellung einer vakuumdichten Abdichtung zwischen einem keramischen und einem metallischen Partner, insbesondere zur Anwendung bei der Herstellung eines Entladungsgefäßes für eine Lampe, sowie damit hergestellte Entladungsgefäße und Lampen |
EP0609477B1 (de) * | 1993-02-05 | 1999-05-06 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH | Keramisches Entladungsgefäss für Hochdruckentladungslampe und Herstellungsverfahren derselben und damit verbundene Dichtungsmaterialien |
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- 1992-05-06 KR KR1019940701170A patent/KR100255426B1/ko not_active IP Right Cessation
- 1992-05-06 WO PCT/DE1992/000372 patent/WO1993007638A1/de active IP Right Grant
- 1992-05-06 HU HU9401009A patent/HU214232B/hu not_active IP Right Cessation
- 1992-05-06 EP EP92909171A patent/EP0607149B1/de not_active Expired - Lifetime
- 1992-05-06 DE DE59204013T patent/DE59204013D1/de not_active Expired - Fee Related
- 1992-09-25 EP EP92116463A patent/EP0536609A1/de not_active Withdrawn
- 1992-09-30 JP JP074353U patent/JPH0744253U/ja active Pending
- 1992-09-30 CN CN92111589A patent/CN1073801A/zh active Pending
- 1992-10-01 US US07/954,815 patent/US5352952A/en not_active Expired - Fee Related
- 1992-10-09 HU HU929200239U patent/HU64U/hu unknown
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Also Published As
Publication number | Publication date |
---|---|
HU9200239V0 (en) | 1992-11-28 |
EP0607149B1 (de) | 1995-10-11 |
CN1073801A (zh) | 1993-06-30 |
DE59204013D1 (de) | 1995-11-16 |
JPH0744253U (ja) | 1995-11-07 |
HU64U (en) | 1993-01-28 |
JP3150341B2 (ja) | 2001-03-26 |
CA2117260A1 (en) | 1993-04-15 |
HUT66139A (en) | 1994-09-28 |
HU9401009D0 (en) | 1994-07-28 |
EP0536609A1 (de) | 1993-04-14 |
HU214232B (hu) | 1998-03-02 |
KR100255426B1 (ko) | 2000-05-01 |
DE9112690U1 (de) | 1991-12-05 |
JPH06511592A (ja) | 1994-12-22 |
WO1993007638A1 (de) | 1993-04-15 |
US5484315A (en) | 1996-01-16 |
US5352952A (en) | 1994-10-04 |
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