DE1016260B - Verfahren zur Herstellung von O, O-Dialkyl-thiol-phosphorsaeure-S-mercaptomethyl-triestern - Google Patents

Verfahren zur Herstellung von O, O-Dialkyl-thiol-phosphorsaeure-S-mercaptomethyl-triestern

Info

Publication number: DE1016260B
Authority: DE; Germany
Prior art keywords: thiol; dialkyl; phosphoric acid; mercaptomethyl; triesters
Prior art date: 1956-03-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

DEF19748A

Other languages

German (de)

English (en)

Inventor

Dr Gerhard Schrader

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee

Bayer AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1956-03-09

Filing date

1956-03-09

Publication date

1957-09-26

Priority to BE555653D priority Critical patent/BE555653A/fr

1956-03-09 Application filed by Bayer AG filed Critical Bayer AG

1956-03-09 Priority to DEF19748A priority patent/DE1016260B/de

1957-02-20 Priority to CH352999D priority patent/CH352999A/de

1957-03-08 Priority to FR1169205D priority patent/FR1169205A/fr

1957-09-26 Publication of DE1016260B publication Critical patent/DE1016260B/de

Status Pending legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 5
238000004519 manufacturing process Methods 0.000 title description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 16
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 7
-1 aromatic Mercaptans Chemical class 0.000 claims description 4
238000006243 chemical reaction Methods 0.000 claims description 4
125000001931 aliphatic group Chemical group 0.000 claims description 2
150000002148 esters Chemical class 0.000 description 12
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
238000003756 stirring Methods 0.000 description 10
239000003921 oil Substances 0.000 description 6
239000002253 acid Substances 0.000 description 4
239000008098 formaldehyde solution Substances 0.000 description 4
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
230000000749 insecticidal effect Effects 0.000 description 2
239000000575 pesticide Substances 0.000 description 2
KJRCEJOSASVSRA-UHFFFAOYSA-N propane-2-thiol Chemical compound CC(C)S KJRCEJOSASVSRA-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
241001454295 Tetranychidae Species 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000012230 colorless oil Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
SUVIGLJNEAMWEG-UHFFFAOYSA-N propane-1-thiol Chemical compound CCCS SUVIGLJNEAMWEG-UHFFFAOYSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
230000009885 systemic effect Effects 0.000 description 1
150000003580 thiophosphoric acid esters Chemical class 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

DEF19748A 1956-03-09 1956-03-09 Verfahren zur Herstellung von O, O-Dialkyl-thiol-phosphorsaeure-S-mercaptomethyl-triestern Pending DE1016260B (de)

Priority Applications (4)

Application Number	Priority Date	Filing Date	Title
BE555653D BE555653A (fr)	1956-03-09
DEF19748A DE1016260B (de)	1956-03-09	1956-03-09	Verfahren zur Herstellung von O, O-Dialkyl-thiol-phosphorsaeure-S-mercaptomethyl-triestern
CH352999D CH352999A (de)	1956-03-09	1957-02-20	Verfahren zur Herstellung von a-Methyl-merkapto-thiol-phosphorsäureestern
FR1169205D FR1169205A (fr)	1956-03-09	1957-03-08	Procédé pour la préparation d'esters alpha-méthylmercapto-thiol-phosphoriques

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DEF19748A DE1016260B (de)	1956-03-09	1956-03-09	Verfahren zur Herstellung von O, O-Dialkyl-thiol-phosphorsaeure-S-mercaptomethyl-triestern

Publications (1)

Publication Number	Publication Date
DE1016260B true DE1016260B (de)	1957-09-26

Family

ID=7089428

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DEF19748A Pending DE1016260B (de)	1956-03-09	1956-03-09	Verfahren zur Herstellung von O, O-Dialkyl-thiol-phosphorsaeure-S-mercaptomethyl-triestern

Country Status (4)

Country	Link
BE (1)	BE555653A (fr)
CH (1)	CH352999A (fr)
DE (1)	DE1016260B (fr)
FR (1)	FR1169205A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3025316A (en) *	1958-10-18	1962-03-13	Bayer Ag	Thiophosphoric acid esters and a process for their production
DE1138977B (de) *	1960-02-24	1962-10-31	Ciba Geigy	Schaedlingsbekaempfungsmittel
DE1212777B (de) *	1963-11-07	1966-03-17	Bayer Ag	Fungitoxische Mittel

Citations (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2565921A (en) *	1948-03-26	1951-08-28	American Cyanamid Co	Condensation of o, o-diesters of dithiophosphoric acid and aliphatic alcohols or mercaptans with higher aliphatic aldehydes
US2565920A (en) *	1948-03-26	1951-08-28	American Cyanamid Co	Triesters of dithiophosphoric acid
DE830509C (de) *	1950-05-24	1952-02-04	Bayer Ag	Verfahren zur Herstellung von neutralen Estern der Thiophosphorsaeure
US2586655A (en) *	1948-03-26	1952-02-19	American Cyanamid Co	S-alkoxymethyl-o, o'-dialkyldithiophosphates

0
- BE BE555653D patent/BE555653A/fr unknown
1956
- 1956-03-09 DE DEF19748A patent/DE1016260B/de active Pending
1957
- 1957-02-20 CH CH352999D patent/CH352999A/de unknown
- 1957-03-08 FR FR1169205D patent/FR1169205A/fr not_active Expired

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2565921A (en) *	1948-03-26	1951-08-28	American Cyanamid Co	Condensation of o, o-diesters of dithiophosphoric acid and aliphatic alcohols or mercaptans with higher aliphatic aldehydes
US2565920A (en) *	1948-03-26	1951-08-28	American Cyanamid Co	Triesters of dithiophosphoric acid
US2586655A (en) *	1948-03-26	1952-02-19	American Cyanamid Co	S-alkoxymethyl-o, o'-dialkyldithiophosphates
DE833807C (de) *	1948-03-26	1952-03-13	American Cyanamid Co	Verfahren zur Herstellung von Dithiophosphorsaeuretriestern
DE830509C (de) *	1950-05-24	1952-02-04	Bayer Ag	Verfahren zur Herstellung von neutralen Estern der Thiophosphorsaeure

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3025316A (en) *	1958-10-18	1962-03-13	Bayer Ag	Thiophosphoric acid esters and a process for their production
DE1138977B (de) *	1960-02-24	1962-10-31	Ciba Geigy	Schaedlingsbekaempfungsmittel
DE1212777B (de) *	1963-11-07	1966-03-17	Bayer Ag	Fungitoxische Mittel

Also Published As

Publication number	Publication date
BE555653A (fr)
FR1169205A (fr)	1958-12-24
CH352999A (de)	1961-03-31

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