CN112521581A - 一种合成革用水性聚氨酯面层树脂及其制备方法及应用 - Google Patents

一种合成革用水性聚氨酯面层树脂及其制备方法及应用 Download PDF

Info

Publication number
CN112521581A
CN112521581A CN202011467474.9A CN202011467474A CN112521581A CN 112521581 A CN112521581 A CN 112521581A CN 202011467474 A CN202011467474 A CN 202011467474A CN 112521581 A CN112521581 A CN 112521581A
Authority
CN
China
Prior art keywords
surface layer
synthetic leather
acetone solution
stirring
waterborne polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202011467474.9A
Other languages
English (en)
Other versions
CN112521581B (zh
Inventor
钱建中
钱洪祥
陈杰
尹小婷
翁闯
刘亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Huide Technology Co ltd
Original Assignee
Shanghai Huide Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Huide Technology Co ltd filed Critical Shanghai Huide Technology Co ltd
Priority to CN202011467474.9A priority Critical patent/CN112521581B/zh
Publication of CN112521581A publication Critical patent/CN112521581A/zh
Application granted granted Critical
Publication of CN112521581B publication Critical patent/CN112521581B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/6692—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/722—Combination of two or more aliphatic and/or cycloaliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/146—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes characterised by the macromolecular diols used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/147—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes characterised by the isocyanates used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明公开了一种合成革用水性聚氨酯面层树脂，其特征在于，按重量百分比计算，包括：二异氰酸酯9～10.5％，聚合物二醇19～23％，小分子二醇扩链剂0.55～1.05％，亲水扩链剂二羟甲基丙酸0.9～1.1％，有机铋催化剂0.003～0.005％，中和剂三乙胺0.65～0.83％，二元胺扩链剂N,N'‑双(2‑羟乙基)乙二胺1.2～2.1％，去离子水65％。本发明还公开了其制备方法和应用。本发明通过使用一种带有羟基的二胺扩链剂N,N'‑双(2‑羟乙基)乙二胺来按比例制备合成革用水性聚氨酯面层树脂后进行水性聚氨酯面层浆料的生产，在不改变现有生产工艺的条件下，即可改善水性面层与无溶剂中间层之间的剥离。

Description

一种合成革用水性聚氨酯面层树脂及其制备方法及应用
技术领域
本发明涉及聚氨酯合成革制备技术领域，特别涉及一种合成革用水性聚氨酯面层树脂及其制备方法及在水性&无溶剂聚氨酯合成革中的应用。
背景技术
随着各项环保法规的出台以及人们环保意思的提高，环保型聚氨酯合成革越来越受到人们的重视与发展。其中水性面层搭配无溶剂中间层制备的合成革的发展最为迅速，但现在普遍存在一个问题，即水性面层与无溶剂中间层之间的结合力偏弱，存在剥离强度低的问题。
CN201810319239.3通过在无溶剂中间层中引入双键，搭配含有双键的水性面层，具体制备方法是：先在离型纸上涂覆双键封端型水性聚氨酯乳液，干燥固化后得到水性面层；然后在水性面层上涂覆无溶剂聚氨酯树脂，干燥至半干状态时与基布贴合，并进一步加热熟化；分离离型纸，经UV光固化后得到高剥离水性&无溶剂合成革。
虽然解决了水性面层与无溶剂中间层的剥离强度低的问题，但也增加了一道UV光固化的工序，提高了合成革的制造门槛与生产成本。
发明内容
本发明的目的在于提供一种合成革用水性聚氨酯面层树脂及其制备方法及在水性&无溶剂聚氨酯合成革中的应用，来解决现有技术中水性面层与无溶剂中间层之间剥离强度低的问题。
为了实现本发明的目的，所采用的技术方案是：
一种合成革用水性聚氨酯面层树脂，按重量百分比计算，包括：
Figure BDA0002834904380000011
Figure BDA0002834904380000021
在本发明的一个优选实施例中，所述聚合物二醇为聚四氢呋喃醚二元醇或聚己二酸丁二醇酯二元醇中的任意一种或多种，所述聚合物二元醇数均分子量为2000g/mol。
在本发明的一个优选实施例中，所述有机铋催化剂为聚合物二醇质量的0.02％。
在本发明的一个优选实施例中，所述二异氰酸酯为异佛尔酮二异氰酸酯或4,4’-二环己基甲烷二异氰酸酯中的任意一种或多种。
在本发明的一个优选实施例中，所述小分子二醇扩链剂为乙二醇或1,4-丁二醇中的任意一种或多种。
一种合成革用水性聚氨酯面层树脂的制备方法，包括如下步骤：
步骤一：将所述二异氰酸酯、聚合物二醇、小分子二醇扩链剂、亲水扩链剂二羟甲基丙酸、有机铋催化剂、第一丙酮溶液依次投入反应釜中，在异氰酸酯基团过量的情况下在60～70℃下至采用二正丁胺滴定法测定下的NCO％不高于3.47％；
步骤二：降温至30～40℃后加入第二丙酮溶液降粘后搅拌加入所述中和剂三乙胺后继续搅拌得混合物；
步骤三：将所述步骤二当中的混合物在1000～1500rpm的转速下在所述去离子水当中进行搅拌分散；
步骤四：在所述步骤三的分散产物中加入所述二元胺扩链剂N,N'-双(2-羟乙基)乙二胺后继续搅拌；
步骤五:在40～55℃温度下减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂；
在本发明的一个优选实施例中，所述第一丙酮溶液与分散前PU固体份的比例为20:80，分散前PU固体份为步骤一和二中除第一丙酮溶液与第二丙酮溶液以外所有原料的质量总和。
在本发明的一个优选实施例中，所述第一丙酮溶液与第二丙酮溶液之和，与分散前PU固体份的比例为40:60，分散前PU固体份为步骤一和二中除第一丙酮溶液与第二丙酮溶液以外所有原料的质量总和。
在本发明的一个优选实施例中，所述去离子水与PU固体份的比例为35:65，PU固体份为所述步骤一至步骤四当中的配方中除去离子水、第一丙酮溶液和第二丙酮溶液以外的所有原料的质量总和。
一种合成革用水性聚氨酯面层树脂在水性&无溶剂聚氨酯合成革中的应用，所述应用为通过所述合成革用水性聚氨酯面层树脂来配制水性聚氨酯面层浆料。
在本发明的一个优选实施例中，所述水性聚氨酯面层浆料，按重量份计算，包括如下组分：
Figure BDA0002834904380000031
在本发明的一个优选实施例中，所述水性聚氨酯面层浆料由如下方式制备而得：
步骤一：将所述水性聚氨酯面层浆料的各组分依次加入搅拌桶内，在500～1000rpm下增稠至3000～5000cps，得水性聚氨酯面层工作浆；
步骤二：将所述水性聚氨酯面层工作浆涂覆在离型纸(优选工作浆厚度0.2mm)上后在100～130℃的温度下进行烘干(优选烘干时间为3～5分钟)得水性面层；
步骤三：在步骤二的水性面层上涂覆无溶剂中间层(优选涂覆厚度为厚度0.3mm)后在100℃下预熟化(优选预熟化时间为1～2分钟)，再贴合基布，再在130～140℃温度下烘烤(优选烘烤时间为烘烤3～5分钟)之后将革样从离型纸上剥离。
本发明的有益效果为：
通过使用一种带有羟基的二胺扩链剂N,N'-双(2-羟乙基)乙二胺来按比例制备合成革用水性聚氨酯面层树脂后进行水性聚氨酯面层浆料的生产，在不改变现有生产工艺的条件下，即可改善水性面层与无溶剂中间层之间的剥离。
具体实施方式
本发明主要原理在于：在水性面层中通过N,N'-双(2-羟乙基)乙二胺在扩链后向水性面层聚氨酯链中引入羟基，而聚氮丙啶类固化剂不会与羟基发生反应，所以涂覆无溶剂中间层前，水性面层含有大量羟基。
因为加入N,N'-双(2-羟乙基)乙二胺，使得相比常规水性聚氨酯，在聚氨酯链中引入了羟基可以和无溶剂层中的异氰酸酯基团参与化学反应；
无溶剂中间层一般有A、B、C三个组分，A组分为羟基封端聚合物多元醇混合物，B组分为异氰酸酯封端的改性异氰酸酯混合物，C组分为催化剂，其中，B组分中异氰酸酯的摩尔数相对于A组分中羟基的摩尔数过量，所以，将无溶剂中间层涂覆在水性面层后，其B组分中的异氰酸酯基团与水性面层中的羟基基团也会反应，使水性面层与无溶剂中间层通过化学键连接起来，来提高剥离强度。
文中的第一丙酮溶液或第二丙酮溶液均为市售的丙酮溶液，并无其他特别含义。
实施例1
将9.19份异佛尔酮二异氰酸酯、21.9份聚四氢呋喃醚二元醇、0.67份乙二醇、1.05份二羟甲基丙酸、0.004份有机铋催化剂、8.4份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤2.41％，采用二正丁胺滴定法测定；降温至30～40℃，加入14份第二丙酮溶液降粘，搅拌10～30分钟，加入0.79份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.4份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
实施例2
将9.19份异佛尔酮二异氰酸酯、21.6份聚己二酸丁二醇酯二元醇、0.99份1,4-丁二醇、1.04份二羟甲基丙酸、0.004份有机铋催化剂、8.4份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤2.41％，采用二正丁胺滴定法测定；降温至30～40℃，加入14份第二丙酮溶液降粘，搅拌10～30分钟，加入0.78份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.4份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
实施例3
将9.93份异佛尔酮二异氰酸酯、20.71份聚己二酸丁二醇酯二元醇、0.63份乙二醇、0.99份二羟甲基丙酸、0.004份有机铋催化剂、8.25份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤3.47％，采用二正丁胺滴定法测定；降温至30～40℃，加入13.75份第二丙酮溶液降粘，搅拌10～30分钟，加入0.75份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.99份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
实施例4
将10.36份4,4’-二环己基甲烷二异氰酸酯、20.62份聚四氢呋喃醚二元醇、0.95份1,4-丁二醇、0.99份二羟甲基丙酸、0.004份有机铋催化剂、8.41份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤2.29％，采用二正丁胺滴定法测定；降温至30～40℃，加入14.02份第二丙酮溶液降粘，搅拌10～30分钟，加入0.75份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.34份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
实施例5
将11.15份4,4’-二环己基甲烷二异氰酸酯、19.7份聚己二酸丁二醇酯二元醇、0.6份乙二醇、0.94份二羟甲基丙酸、0.004份有机铋催化剂、8.28份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤3.29％，采用二正丁胺滴定法测定；降温至30～40℃，加入13.79份第二丙酮溶液降粘，搅拌10～30分钟，加入0.71份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.89份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
实施例6
将11.15份4,4’-二环己基甲烷二异氰酸酯、19.43份聚四氢呋喃醚二元醇、0.89份1,4-丁二醇、0.93份二羟甲基丙酸、0.004份有机铋催化剂、8.28份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤3.29％，采用二正丁胺滴定法测定；降温至30～40℃，加入13.79份第二丙酮溶液降粘，搅拌10～30分钟，加入0.7份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.89份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
实施例7
将4.67份异佛尔酮二异氰酸酯、5.51份4,4’-二环己基甲烷二异氰酸酯、10.32份聚四氢呋喃醚二元醇、10.32份聚己二酸丁二醇酯二元醇、0.32份乙二醇、0.47份1,4-丁二醇、0.99份二羟甲基丙酸、0.004份有机铋催化剂、8.33份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤2.88％，采用二正丁胺滴定法测定；降温至30～40℃，加入13.89份第二丙酮溶液降粘，搅拌10～30分钟，加入0.75份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.66份二元胺扩链剂N,N'-双(2-羟乙基)乙二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
对比例1
将9.13份异佛尔酮二异氰酸酯、21.77份聚四氢呋喃醚二元醇、0.66份乙二醇、1.04份二羟甲基丙酸、0.004份有机铋催化剂、8.35份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤2.41％，采用二正丁胺滴定法测定；降温至30～40℃，加入14份第二丙酮溶液降粘，搅拌10～30分钟，加入0.79份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.6份二元胺扩链剂异佛尔酮二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
对比例2
将4.64份异佛尔酮二异氰酸酯、5.47份4,4’-二环己基甲烷二异氰酸酯、10.25份聚四氢呋喃醚二元醇、10.25份聚己二酸丁二醇酯二元醇、0.32份乙二醇、0.46份1,4-丁二醇、0.98份二羟甲基丙酸、0.004份有机铋催化剂、8.28份第一丙酮溶液依次投入反应釜中，其中，异氰酸酯基团过量，60～70℃下反应至NCO％≤2.88％，采用二正丁胺滴定法测定；降温至30～40℃，加入13.79份第二丙酮溶液降粘，搅拌10～30分钟，加入0.74份中和剂三乙胺，搅拌10～30分钟，将上述混合物加入至1000～1500rpm高速搅拌下的65份去离子水中，维持搅拌10～30分钟，加入1.89份二元胺扩链剂异佛尔酮二胺，搅拌10～30分钟，在40～55℃减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
配制水性聚氨酯面层浆料，将所得水性聚氨酯面层工作浆涂覆在离型纸上，厚度0.2mm，100～130℃，3～5分钟烘干，再在水性面层上涂覆无溶剂中间层，厚度0.3mm，100℃，1～2分钟，贴合基布，再130～140℃，烘烤3～5分钟，将革样从离型纸上剥离，测试剥离强度。
表1：实施例1～7和对比例1～2的剥离强度。
Figure BDA0002834904380000091
由表1可知：采用含N,N'-双(2-羟乙基)乙二胺扩链剂的水性面层剥离强度均高于使用不含羟基二胺扩链剂的水性面层。

Claims (10)

1.一种合成革用水性聚氨酯面层树脂，其特征在于，按重量百分比计算，包括：
Figure FDA0002834904370000011
2.如权利要求1所述的一种合成革用水性聚氨酯面层树脂，其特征在于，所述聚合物二醇为聚四氢呋喃醚二元醇或聚己二酸丁二醇酯二元醇中的任意一种或多种，所述聚合物二元醇数均分子量为2000g/mol。
3.如权利要求1所述的一种合成革用水性聚氨酯面层树脂，其特征在于，所述有机铋催化剂为聚合物二醇质量的0.02％。
4.如权利要求1所述的一种合成革用水性聚氨酯面层树脂，其特征在于，所述二异氰酸酯为异佛尔酮二异氰酸酯或4,4’-二环己基甲烷二异氰酸酯中的任意一种或多种。
5.如权利要求1所述的一种合成革用水性聚氨酯面层树脂，其特征在于，所述小分子二醇扩链剂为乙二醇或1,4-丁二醇中的任意一种或多种。
6.如权利要求1-5当中任意一项所述的一种合成革用水性聚氨酯面层树脂的制备方法，其特征在于，包括如下步骤：
步骤一：将所述二异氰酸酯、聚合物二醇、小分子二醇扩链剂、亲水扩链剂二羟甲基丙酸、有机铋催化剂、第一丙酮溶液依次投入反应釜中，在异氰酸酯基团过量的情况下在60～70℃下反应至采用二正丁胺滴定法测定下的NCO％不高于3.47％；
步骤二：降温至30～40℃后加入第二丙酮溶液降粘后搅拌加入所述中和剂三乙胺后继续搅拌得混合物；
步骤三：将所述步骤二当中的混合物加入至1000～1500rpm高速搅拌下的去离子水中并维持搅拌；
步骤四：在所述步骤三的分散产物中加入所述二元胺扩链剂N,N'-双(2-羟乙基)乙二胺后继续搅拌；
步骤五:在40～55℃温度下减压蒸馏脱除丙酮，得到所述合成革用水性聚氨酯面层树脂。
7.如权利要求6所述的一种合成革用水性聚氨酯面层树脂的制备方法，其特征在于，所述第一丙酮溶液与分散前PU固体份的比例为20:80，分散前PU固体份为步骤一和二中除第一丙酮溶液与第二丙酮溶液以外所有原料的质量总和；
所述第一丙酮溶液与第二丙酮溶液之和与分散前PU固体份的比例为40:60，分散前PU固体份为步骤一和二中除第一丙酮溶液与第二丙酮溶液以外所有原料的质量总和；
所述去离子水与PU固体份的比例为35:65，PU固体份为所述步骤一至步骤四当中的配方中除去离子水、第一丙酮溶液和第二丙酮溶液以外的所有原料的质量总和。
8.如权利要求1-5当中任意一项所述的一种合成革用水性聚氨酯面层树脂在水性&无溶剂聚氨酯合成革中的应用，其特征在于，所述应用为通过所述合成革用水性聚氨酯面层树脂来配制水性聚氨酯面层浆料并制备水性&无溶剂聚氨酯合成革。
9.如权利要求8所述的一种应用，其特征在于，所述水性聚氨酯面层浆料，按重量份计算，包括如下组分：
Figure FDA0002834904370000021
10.如权利要求9所述的一种应用，其特征在于，所述水性聚氨酯面层浆料由如下方式制备而得：
步骤一：将所述水性聚氨酯面层浆料的各组分依次加入搅拌桶内，在500～1000rpm下增稠至3000～5000cps，得水性聚氨酯面层工作浆；
步骤二：将所述水性聚氨酯面层工作浆涂覆在离型纸上后在100～130℃的温度下进行烘干得水性面层；
步骤三：在步骤二的水性面层上涂覆无溶剂中间层后在100℃下预熟化，再贴合基布，再在130～140℃温度下烘烤之后将革样从离型纸上剥离。
CN202011467474.9A 2020-12-14 2020-12-14 一种合成革用水性聚氨酯面层树脂及其制备方法及应用 Active CN112521581B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011467474.9A CN112521581B (zh) 2020-12-14 2020-12-14 一种合成革用水性聚氨酯面层树脂及其制备方法及应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011467474.9A CN112521581B (zh) 2020-12-14 2020-12-14 一种合成革用水性聚氨酯面层树脂及其制备方法及应用

Publications (2)

Publication Number Publication Date
CN112521581A true CN112521581A (zh) 2021-03-19
CN112521581B CN112521581B (zh) 2022-11-25

Family

ID=74999559

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011467474.9A Active CN112521581B (zh) 2020-12-14 2020-12-14 一种合成革用水性聚氨酯面层树脂及其制备方法及应用

Country Status (1)

Country Link
CN (1) CN112521581B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116082598A (zh) * 2022-12-14 2023-05-09 合肥安利聚氨酯新材料有限公司 一种具有抗冲击性能的水性聚氨酯树脂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086426A (zh) * 2015-09-07 2015-11-25 山东天庆科技发展有限公司 一种水性镜面树脂及其制备方法
CN111662423A (zh) * 2020-06-16 2020-09-15 中国科学院山西煤炭化学研究所 一种羟基功能化水性聚氨酯的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086426A (zh) * 2015-09-07 2015-11-25 山东天庆科技发展有限公司 一种水性镜面树脂及其制备方法
CN111662423A (zh) * 2020-06-16 2020-09-15 中国科学院山西煤炭化学研究所 一种羟基功能化水性聚氨酯的制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116082598A (zh) * 2022-12-14 2023-05-09 合肥安利聚氨酯新材料有限公司 一种具有抗冲击性能的水性聚氨酯树脂及其制备方法和应用

Also Published As

Publication number Publication date
CN112521581B (zh) 2022-11-25

Similar Documents

Publication Publication Date Title
CN110835401B (zh) 一种水性聚氨酯面层树脂及其制备方法
CN111793188B (zh) 含羟基自消光水性聚氨酯及由其组成的自消光涂料
CN109160994B (zh) 一种用于干法涂层底胶水性聚氨酯分散体及其制备方法和用途
CN107759764B (zh) 二氧化硅负载的高强度水性聚氨酯乳液的生产工艺
CN111909351A (zh) 一种超纤含浸用水性聚氨酯的合成方法及应用
US20200299448A1 (en) Synthesis method for high weather-resistant red water-based polyurethane emulsion
CN111154059B (zh) 一种环氧树脂改性聚醚胺增强水性聚氨酯乳液及制备方法
CN111909346B (zh) 高温自交联聚氨酯水分散体的制备
CN112724347B (zh) 一种生物基水性聚氨酯树脂及其制备方法和应用
CN103130977A (zh) 一种双组分水性木器漆的聚氨酯多元醇分散体及其制备方法
CN109535372B (zh) 一种水性聚氨酯及其制备方法
CN113025184A (zh) 一种高附着力水性聚氨酯涂料树脂及其制备方法
EP0841357A2 (de) Verfahren zur Herstellung von Polyurethan-Hybrid-Dispersionen
CN106928428B (zh) 水性聚氨酯乳液及其制备方法
CN103467693A (zh) 一种具有良好冻融稳定性的水性聚氨酯的制备方法
EP0884336B1 (de) Wässerige Polyurethandispersionen aus Polypropylenglykol mit geringem Harnstoffgehalt
JP3557858B2 (ja) ポリウレタン樹脂水分散液の製造方法
CN112521581B (zh) 一种合成革用水性聚氨酯面层树脂及其制备方法及应用
CN112358598B (zh) 一种合成革用水性聚氨酯面层树脂及其制备方法
EP2049581B1 (de) Polyetheramin-makromonomere mit zwei benachbarten hydroxylgruppen und ihre verwendung zur herstellung von polyurethanen
CN104592469A (zh) 阴离子型聚氨酯水分散体、其预聚物单体及制备工艺
CN115595036A (zh) 一种替塑光油用的丙烯酸改性聚氨酯分散体及其制备方法
CN111925494B (zh) 一种高粘性水性聚氨酯及其制备方法
KR20010068475A (ko) 수분산 폴리우레탄의 제조방법
CN112538152B (zh) 一种水性聚氨酯-聚脲分散体及制备方法和应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant