CN105434189B - A kind of peelable nail polish glue and preparation method thereof - Google Patents
A kind of peelable nail polish glue and preparation method thereof Download PDFInfo
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- CN105434189B CN105434189B CN201610038374.1A CN201610038374A CN105434189B CN 105434189 B CN105434189 B CN 105434189B CN 201610038374 A CN201610038374 A CN 201610038374A CN 105434189 B CN105434189 B CN 105434189B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/544—Dendrimers, Hyperbranched polymers
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Abstract
The invention discloses a kind of peelable nail polish glue and preparation method thereof.The peelable nail polish glue of the present invention, in parts by weight, it is made of the photoinitiator b of the reactive diluent of UV solidified resins B, 50-80 part of 50-80 parts of UV solidified resins A, 50-80 part, 0.05-0.1 parts of levelling agents, 1-10 parts of wetting agent, 0.2-1 parts of antifoaming agent, 1-10 parts of UV mill bases, 3-5 parts of A and 3-5 parts of photoinitiator.There are after the peelable nail polish glue film of the present invention after 365nmUV-LED light irradiations quick setting capabilities, the technical fields such as the manicure of various people can be widely used.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable nail polish glue and preparation method thereof, it should
Peelable nail polish glue irradiates solidification especially suitable for the UV-LED light sources of 365nm.
Background technology
Ms likes having deep love for derived from one kind to manicure.Nail polish glue using when with tool be applied to nail, by common UV light
Crosslink polymerisation after the light source treatment with irradiation of source, the nail polish adhesive curing object of generation is beautiful in colour, glittering and translucent full, change
It is infinite, it is the favorite of ladies.Compared with common UV light sources curing mode, UV-LED light sources have luminous efficiency height, long lifespan,
Many advantages, such as reaction speed is fast, heat release is few, energy-saving and environmental protection has gradually substituted common UV light sources.With enriching for city life
With the quickening of rhythm of life transformation, ladies have liked the allegro transformation nail of oneself.Peelable nail polish glue is easy to use,
Do not have to whole of cleaner energy when needing to remove to peel off, easily, is particularly suitable for child and uses.But current peelable nail polish glue
Generally aqueous, the transparent water that need to arrange in pairs or groups or sealing water use；It is not so good as oiliness nail polish glue in persistence, drying is slower, and can
Stripping nail polish glue is generally added to peelable component in the formula of nail polish glue, makes troubles to the production and use of nail polish glue.
Based on background above, need to develop one kind can rapid curing and meanwhile have decorative effect, have from stripping component,
The good peelable nail polish glue and preparation method thereof of peeling effect.
Invention content
One of the object of the invention provide it is a kind of can with UV-LED light source energy rapid curings and meanwhile have high glaze, do not add
The good peelable nail polish glue of peelable effect that remover can be achieved with.
The two of the object of the invention provide a kind of above-mentioned preparation method of peelable nail polish glue.
Technical scheme of the present invention is specifically described as follows.
The present invention provides a kind of peelable nail polish glue, and in parts by weight, raw material composition and content are as follows：
Wherein：The chemical constitution of the UV solidified resins A is as follows：
Wherein：M is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resins B is hyperbranched UV solidified resins；
The reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetras acid
Ester, three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list
One or more of acrylate, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer；
The UV mill bases are in mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010 or Huang F512
One or more.
In the present invention, the levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510,
One or more of BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348；The wetting agent is
One or both of NP-100 or Germany's 333 levelling agents of BYK of Dow company；The antifoaming agent is Germany BYK
One or more of Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044, BYK-038.
In the present invention, the photoinitiator A is BASF Irgacure1173, Irgacure 184D, Irgacure
TPO, Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular
One or more of photoinitiator Esacure KIP 150；The photoinitiator b is selected from BASF BASF photoinitiators
It is one or more of in Irgacure 2959, IRGACURE500 or IRGACURE819DW.
In the present invention, in parts by weight, raw material composition and content are as follows by the UV solidified resins A：
The UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and pentaerythritol triacrylate are proportionally added into reaction vessel, resistance is added
Poly- agent, is passed through protective gas, stirs and heats, and is warming up to 60~80 DEG C, and catalyst is added, and stirs 3~5h of lower constant temperature, stops adding
Heat waits for that temperature drops to room temperature to get UV solidified resins A.
The present invention also provides a kind of preparation methods of peelable nail polish glue, are as follows：
According to formula, wetting agent, levelling agent, antifoaming agent are added in the high speed dispersor of control rotating speed 300-400r/min
With UV mill bases, rotating speed is down to 300r/min after disperseing 15-20min under 600-800r/min rotating speeds, UV solidified resins are added
A, UV solidified resins B, reactive diluent and photoinitiator A, photoinitiator b, continue disperse 5-30min, be uniformly mixed to get to
Peelable nail polish glue.
The useful achievement of the present invention is as follows：
A kind of peelable nail polish glue of the present invention, UV solidified resins A as a result of multi-functional acrylate and
The rapid curing that hyperbranched UV solidified resins B with dissaving structure makes it have under the irradiation of 365nmUV-LED lamp sources is anti-
It should be able to power.Have the characteristics that covering with paint is convenient and efficient, color is bright changeable, peelable good.
Further, the load glass of peelable nail polish glue is precoated after peelable nail polish glue film of the invention through UV nail polish light irradiations
The surface of piece, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, when being fully cured with peelable nail polish glue the shortest time used characterize), after testing, of the invention is fast
The hardening time for doing peelable nail polish glue is 1-7s.
Further, peelable nail polish glue of the invention, the UV solidified resin A molecular structures as main film forming substance are to have
Machine silicon structure has very low surface energy, reduces the interaction between film and base material, is allowed to embody preferably from stripping
Property, it is not required to add stripping auxiliary agent again.Peel strength newly thinks carefully the CMT5104 electronic tension testers of company in room temperature using Shenzhen
The peel test that GB/T2790-1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 °, tensile speed are pressed down
50mm/min；It is 0.21~0.25kN/m to measure peel strength；
Further, the UV solidified resin B of the dissaving structure with toughening effect of addition, make peelable nail polish glue have
Certain toughness.
In conclusion a kind of peelable nail polish glue of the present invention, has quick solid under the irradiation of 365nmUV-LED lamp sources
Change ability has higher toughness, gloss and color capability after film.And preparation method is due to simple for process, it is easily-controllable
System, therefore have the characteristics that technology maturation, quick, efficient, and suitable for industrialized production.
Specific implementation mode
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows：
In parts by weight, composition and content are as follows by the wherein UV solidified resins A：
The UV solidified resins A is prepared as follows：By 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of pentaerythrites
Triacrylate is added in the three-necked flask of 500ml, is added 0.005 part of polymerization inhibitor p-hydroxyanisole, is passed through protection
Gas is stirred and is heated, and is warming up to 60 DEG C, and 0.03 part of catalyst chloroplatinic acid/vinyl double seal head complex compound is added, and stirs lower perseverance
Warm 3h stops heating, waits for that flask temperature drops to room temperature to get UV solidified resins A.
The UV solidified resins B is hyperbranched polyester acrylic ester prepolymer；
The reactive diluent is diethylene glycol diacrylate, isobornyl acrylate, acrylated hyperbranched polyester
Ester in mass ratio 1：1:The mixture of 1 composition.
The levelling agent is the high Tego Glide of enlightening 410；
The wetting agent is the NP-100 of Dow company；
The antifoaming agent is Germany BYK-035, BYK-037 in mass ratio 1：1 mixture；
The UV mill bases are purple F612；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than 1:1:The mixture of 1 composition；
The photoinitiator b be BASF BASF photoinitiators Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable nail polish glue specifically comprises the following steps：
According to formula, in the GFJ-0.4 types high speed dispersor for controlling rotating speed 300r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of antifoaming agent and 1 part of UV mill base, through disperseing under 600r/min rotating speeds
Rotating speed is down to 300r/min after 15min, be added 50 parts of UV solidified resins A, 50 parts of UV solidified resins B, 50 portions of reactive diluents,
3 parts of photoinitiator A and 3 parts of photoinitiator bs continue to disperse 50min, be uniformly mixed to get to peelable nail polish glue.
The UV-LED light irradiations through 365nm precoat the load of peelable nail polish glue after the peelable nail polish glue film of the present embodiment
The surface of slide, according to fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, using it is tack-free as
The standard being fully cured, when being fully cured with peelable nail polish glue shortest time used characterize), it is after testing, of the invention
The hardening time of the peelable nail polish glue of quick-drying is 1s.Purple effect is presented in film after solidification.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.25kN/m；
Higher curing rate after the peelable nail polish glue film of the present embodiment in summary, it is easily peelable, while have compared with
Good color effect.
Embodiment 2
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows：
In parts by weight, composition and content are as follows by the wherein UV solidified resins A：
The UV solidified resins A is prepared as follows：By 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of pentaerythrites
Triacrylate is added in the three-necked flask of 500ml, is added 0.01 part of hydroquinone of polymerization retarder, is passed through protective gas,
It stirs and heats, be warming up to 80 DEG C, 0.05 part of catalyst chloroplatinic acid/aqueous isopropanol is added, stir lower constant temperature 5h, stop adding
Heat waits for that flask temperature drops to room temperature to get UV solidified resins A.
The UV solidified resins B is hyperbranched polyester acrylic ester prepolymer；
The reactive diluent is diethylene glycol diacrylate, isobornyl acrylate, acrylated hyperbranched polyester
Ester in mass ratio 1：2:The mixture of 1 composition.
The levelling agent is Germany BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
The wetting agent is Germany BYK 333；
The antifoaming agent is Germany BYK Bi Ke BYK-024, BYK-025 in mass ratio 1:The mixture of 1 composition；
The UV mill bases are mill base indigo plant F4049；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Than 1:1：More than 1 kinds of mixture；
The photoinitiator b be BASF BASF photoinitiators Irgacure 2959, IRGACURE500 in mass ratio
2:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of peelable nail polish glue specifically comprises the following steps：
According to formula, in the GFJ-0.4 types high speed dispersor for controlling rotating speed 400r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of antifoaming agent and 10 parts of UV mill bases, through disperseing under 800r/min rotating speeds
Rotating speed is down to 300r/min after 20min, be added 80 parts of UV solidified resins A, 80 parts of UV solidified resins B, 80 portions of reactive diluents,
5 parts of photoinitiator A and 5 parts of photoinitiator bs continue to disperse 30min, be uniformly mixed to get to peelable nail polish glue.
The UV-LED light irradiations through 365nm precoat the load of peelable nail polish glue after the peelable nail polish glue film of the present embodiment
The surface of slide, according to fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, using it is tack-free as
The standard being fully cured, when being fully cured with peelable nail polish glue shortest time used characterize), it is after testing, of the invention
The hardening time of the peelable nail polish glue of quick-drying is 7s.Blue color effect is presented after solidification.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.21kN/m；
Higher curing rate after the peelable nail polish glue film of the present embodiment in summary, it is easily peelable, while have compared with
Good color effect.
In conclusion the peelable nail polish glue of the present embodiment is using UV curing formulas, the high speed curable of UV improves
Its curing rate, only 1~7s；Easily peelable, peel strength is 0.21~0.25kN/m；The peelable nail polish glue addition of the present invention
UV mill bases bring ever-changing color to peelable nail polish glue, addition has toughening effect UV solidified resin B, and making can
Removing nail polish glue has certain toughness.
Above said content is only the basic explanation under present inventive concept, and is appointed made by technical solution according to the present invention
What equivalent transformation, is within the scope of protection of the invention.
Claims (6)
1. a kind of peelable nail polish glue, which is characterized in that in parts by weight, raw material composition and content are as follows：
Wherein：The chemical constitution of the UV solidified resins A is as follows：
Wherein：M is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resins B is hyperbranched UV solidified resins；
The reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra-acrylates, three
(2- ethoxys) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, tristane
Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester,
Carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylic acid
One or more of ester and vinyl ethers monomer；
The UV mill bases in mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010 or Huang F512 one
Kind is several.
2. peelable nail polish glue according to claim 1, which is characterized in that the levelling agent is selected from the high Tego of enlightening
Glide 410, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-
One or more of 348；The wetting agent is the NP-100 of Dow company；The antifoaming agent is finished for Germany BYK
One or more of gram BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044.
3. peelable nail polish glue according to claim 1, which is characterized in that the photoinitiator A is BASF
Irgacure1173、Irgacure 184D、Irgacure TPO、Irgacure 369、Irgacure 651、Irgacure
379, one or more of Irgacure 819, Irgacure 907 or macromolecular photoinitiator Esacure KIP 150；Institute
The photoinitiator b stated is in BASF BASF photoinitiators Irgacure 2959, IRGACURE500 or IRGACURE819DW
It is one or more of.
4. peelable nail polish glue according to claim 1, which is characterized in that the UV solidified resins A is in parts by weight
It calculates, raw material composition and content are as follows：
The UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and pentaerythritol triacrylate are proportionally added into reaction vessel, inhibition is added
Agent is passed through protective gas, stirs and heats, and is warming up to 60~80 DEG C, and catalyst is added, and stirs 3~5h of lower constant temperature, stops adding
Heat waits for that temperature drops to room temperature to get UV solidified resins A.
5. the peelable nail polish glue according to one of claim 1-4, which is characterized in that hardening time 1-7s is being stretched
The peel strength measured when speed 50mm/min is 0.21~0.25kN/m.
6. a kind of preparation method of peelable nail polish glue as described in claim 1, which is characterized in that be as follows：
According to formula, wetting agent, levelling agent, antifoaming agent and UV are added in the high speed dispersor of control rotating speed 300-400r/min
Rotating speed is down to 300r/min by mill base after disperseing 15-20min under 600-800r/min rotating speeds, and UV solidified resins A, UV are added
Solidified resin B, reactive diluent and photoinitiator A, photoinitiator b continue to disperse 5-30min, be uniformly mixed to get to peelable
From nail polish glue.
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| CN201610038374.1A CN105434189B (en) | 2016-01-20 | 2016-01-20 | A kind of peelable nail polish glue and preparation method thereof |
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| CN201610038374.1A CN105434189B (en) | 2016-01-20 | 2016-01-20 | A kind of peelable nail polish glue and preparation method thereof |
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| CN105434189B true CN105434189B (en) | 2018-10-30 |
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| CN107556964B (en) * | 2017-09-22 | 2021-01-26 | 东莞市联灏新材料技术开发有限公司 | Radiation-curable quantum dot material sealant composition |
| CN107898697A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田环保节能科技有限公司 | A kind of Environmental-friendnail nail enamel |
| CN111110588A (en) * | 2020-01-16 | 2020-05-08 | 佛山市蓝狐生物科技有限公司 | Peelable base glue and preparation method thereof |
| CN113667358A (en) * | 2021-08-30 | 2021-11-19 | 广东蓝天优创美化妆品有限公司 | Color paste for low-odor UV (ultraviolet) nail polish gel and preparation method thereof |
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|---|---|---|---|---|
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
| CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
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| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
| CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
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