CN105596232B - Peelable nail polish glue and preparation method thereof - Google Patents
Peelable nail polish glue and preparation method thereof Download PDFInfo
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- CN105596232B CN105596232B CN201610038642.XA CN201610038642A CN105596232B CN 105596232 B CN105596232 B CN 105596232B CN 201610038642 A CN201610038642 A CN 201610038642A CN 105596232 B CN105596232 B CN 105596232B
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- nail polish
- byk
- irgacure
- polish glue
- peelable
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
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- Life Sciences & Earth Sciences (AREA)
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of peelable nail polish glue and preparation method thereof.Peelable nail polish glue of the invention, in parts by weight, it is made of UV curing compound, 0.05-0.1 parts of levelling agents, 1-10 parts of wetting agent, 0.2-1 parts of defoaming agent, 1-10 parts of UV nail polish special-used colour starch, 3-5 parts A and 3-5 parts of photoinitiator bs of photoinitiator of 50-80 parts of UV solidified resin A, 50-80 part.There are after 365nmUV-LED light irradiation quick setting capabilities after peelable nail polish glue film of the invention, the technical fields such as the manicure of various people can be widely used.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable nail polish glue and preparation method thereof, it should
Peelable nail polish glue is irradiated especially suitable for 365nm UV-LED light source to be solidified.
Background technique
Ms likes having deep love for derived from one kind to manicure.Nail polish glue using when with tool be applied to nail, by common UV light
Crosslink polymerization reaction after the light source treatment with irradiation of source, the nail polish adhesive curing object of generation is beautiful in colour, glittering and translucent full, change
It is infinite, it is the favorite of ladies.Compared with common UV light source curing mode, UV-LED light source is high with luminous efficiency, the service life is long,
Many advantages, such as reaction speed is fast, heat release is few, energy-saving and environmental protection has gradually substituted common UV light source.With enriching for city life
With the quickening of rhythm of life transformation, ladies have liked the nail of allegro transformation oneself.Peelable nail polish glue is easy to use,
Do not have to whole of cleaner energy when needing to remove to peel off, easily, is particularly suitable for child and uses.But current peelable nail polish glue
Generally aqueous, the transparent water that need to arrange in pairs or groups or sealing water use；It is not so good as oiliness nail polish glue in persistence, drying is slower, and can
Stripping nail polish glue is generally added to peelable component in the formula of nail polish glue, makes troubles to the production and use of nail polish glue.
Based on background above, need to develop one kind can rapid curing and meanwhile have decorative effect, have from removing component,
The good peelable nail polish glue and preparation method thereof of peeling effect.
Summary of the invention
One of the object of the invention be to provide one kind can rapid curing and meanwhile have decorative effect, have from removing component, stripping
The peelable nail polish glue good from effect.
The second object of the present invention is to providing a kind of above-mentioned preparation method of peelable nail polish glue.
Technical solution of the present invention is specifically described as follows.
The present invention provides a kind of peelable nail polish glue, and in parts by weight, raw material composition and content are as follows:
Wherein the chemical structural formula of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；N is the integer within the scope of 1-30.
In the present invention, UV curing compound is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydro
Furanacrylate, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropanes 4 third
Olefin(e) acid ester, three (2- ethoxy) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris
Acrylate, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobomyl acrylate
Ester, Tricyclodecane Dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, ring carbon acid
One or more of ester mono acrylic ester, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer.
In the present invention, the UV nail polish special-used colour starch is comprising green-yellow light, blue green light, red, white, green, orange
Various colors including color, purple, yellow, orange, pink, pink, light green, fluorescein, fluorescence green, fluorescein, fluorescent blue
UV nail polish special-used colour starch.
In the present invention, the levelling agent be selected from Digao Tego Glide 410, Germany BYK Bi Ke BYK-UV3510,
One or more of BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348；The UV wetting agent
One or both of NP-100 or Germany's 333 levelling agent of BYK selected from Dow company；The defoaming agent is selected from
One of German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038 or
It is several；The photoinitiator A be selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular light draw
Send out one or more of agent Esacure KIP 150；The photoinitiator b is selected from BASF BASF photoinitiator
It is one or more of in Irgacure 2959, IRGACURE500 or IRGACURE819DW.
In the present invention, in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows:
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are proportionally added into reaction vessel,
Add polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, catalyst is added, stir lower constant temperature 3~
5h stops heating, drops to room temperature to temperature to get UV solidified resin A.
The present invention also provides a kind of preparation methods of peelable nail polish glue, the specific steps are as follows:
According to formula, UV wetting agent, levelling agent, defoaming are added in the high speed disperser of control revolving speed 300-400r/min
Revolving speed is down to 300r/min after dispersing 15-20min under 600-800r/min revolving speed, added by agent and UV nail polish special-used colour starch
Enter UV solidified resin A, UV curing compound and photoinitiator A, photoinitiator b, continue disperse 5-10min, be uniformly mixed to get
To peelable nail polish glue.
Beneficial achievement of the invention is as follows:
A kind of peelable nail polish glue of the invention, due to containing crowd after a kind of peelable nail polish glue curing of coating of the invention
Rapid curing can be achieved under the UV-LED light source irradiation of 365nm in mostly crosslinkable acrylate structural.
Further, peelable first is precoated through 365nm UV-LED light irradiation after the resulting peelable nail polish glue film of the present invention
The surface of the glass slide of factice, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with not
Viscous hand is as the standard being fully cured, and the shortest time used characterizes when being fully cured with peelable nail polish glue), through detecting,
The curing time of the peelable nail polish glue of quick-drying of the invention is 10-50s.
Further, peelable nail polish glue of the invention, the UV solidified resin A molecular structure as main film forming substance are to have
Machine silicon structure reduces the interaction between film and substrate with very low surface energy, is allowed to embody preferably from removing
Property, it is not required to add removing auxiliary agent again.Peel strength newly thinks carefully the CMT5104 electronic tension tester of company in room temperature using Shenzhen
180 ° of peel test, tensile speed are carried out by GB/T2790-1995 standard " 180 ° of peeling strength test methods of adhesive " down
50mm/min；Measuring peel strength is 0.21~0.24kN/m；
Further, peelable nail polish glue prepared by the present invention joined UV nail polish special-used colour starch, make it have light resistance,
Weatherability, resistant to chemical media and heat resistance.
In conclusion a kind of peelable nail polish glue of the invention, with faster curing rate and with good after film
Good decorative effect.And preparation method is due to simple process, it is easy to control, thus have technology maturation, quickly, the spies such as efficiently
Point, and it is suitable for industrialized production.
Specific embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment and the information of manufacturer used in the present invention are as follows:
GFJ-0.4 type high speed disperser, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein: in parts by weight, raw material composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows: by 10 parts of Methyl Hydrogen Polysiloxane Fluids and 10 parts of ethoxylations
Trimethylolpropane trimethacrylate is added in the three-necked flask of 500ml, adds 0.01 part of hydroquinone of polymerization retarder, is led to
Enter protective gas, stir and heat, be warming up to 60 DEG C, the complex compound of 0.03 part of chloroplatinic acid is added, stir lower constant temperature 3h, stops adding
Heat drops to room temperature to flask temperature to get UV solidified resin A.
UV curing compound is diethylene glycol diacrylate, tetrahydrofuran acrylate, hyperbranched polyester acrylic ester
The mixture of the composition of 1:2:1 in mass ratio；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The UV nail polish special-used colour starch is the yellowish green MG-1 that Dongguan City Chun Liang process materials Co., Ltd provides；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than the mixture of 1:1:2 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:1 composition；
In the present embodiment, a kind of preparation method of peelable nail polish glue specifically comprises the following steps:
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are added to 500ml according to a certain percentage
Three-necked flask in, add a certain amount of polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, be added
Catalyst stirs lower 3~5h of constant temperature, stops heating, drop to room temperature to flask temperature to get UV solidified resin A.
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 300r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent, 0.05 part of levelling agent, 0.2 part of defoaming agent and 1 part of UV nail polish special-used colour starch are added in high speed disperser,
Revolving speed is down to 300r/min after dispersing 15min under 600r/min revolving speed, 50 parts of UV solidified resin A, 50 parts of UV solidifications are added
Compound and 3 parts of photoinitiator A, 3 parts of photoinitiator bs continue to disperse 5min, are uniformly mixed to get peelable nail polish glue is arrived.
Peelable nail polish glue is precoated through 365nm UV-LED light irradiation after the resulting peelable nail polish glue film of the present embodiment
Glass slide surface, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free
As the standard being fully cured, the shortest time used is characterized when being fully cured with peelable nail polish glue), through detecting, this hair
The curing time of the peelable nail polish glue of bright quick-drying is 10s.
Further, a kind of peelable nail polish glue of the present embodiment, the UV solidified resin A molecule knot as main film forming substance
Structure is organosilicon structures, with very low surface energy, reduces the interaction between film and substrate, is allowed to embody and preferably may be used
Fissility, peel strength newly think carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.24kN/m；
Fast curing properties after the resulting peelable nail polish glue film of the present embodiment in summary have preferable removing
Property.
Embodiment 2
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows: by 20 parts of Methyl Hydrogen Polysiloxane Fluids and 20 parts of ethoxylations
Trimethylolpropane trimethacrylate is added in the three-necked flask of 500ml, adds 0.02 part of hydroquinone of polymerization retarder, is led to
Enter protective gas, stir and heat, be warming up to 80 DEG C, the complex compound of 0.05 part of chloroplatinic acid is added, stir lower constant temperature 5h, stops adding
Heat drops to room temperature to flask temperature to get UV solidified resin A.
UV curing compound is diethylene glycol diacrylate, tetrahydrofuran acrylate, alkoxy acrylic ester by matter
Measure the mixture formed than 1:2:1；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The UV nail polish special-used colour starch is the sky blue UV nail polish that Foshan City's hard iron light Materials Co., Ltd provides
Special-used colour starch；
The defoaming agent is German BYK Bi Ke BYK-024, BYK-025, BYK-035 are what 1:1:1 was formed in mass ratio
Mixture；
The photoinitiator A be BASF Irgacure 184D, Irgacure TPO, Irgacure 369,
The mixture of the 1:1:1:1 in mass ratio of Irgacure 819 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:2 composition；
In the present embodiment, a kind of preparation method of peelable nail polish glue specifically comprises the following steps:
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 400r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoaming agent and 10 parts of UV nail polish special-used colour starch, through 800r/min
Disperse that revolving speed is down to 300r/min after 20min under revolving speed, 80 parts of UV solidified resin A, 80 parts of UV curing compounds, 5 parts are added
Photoinitiator A and 5 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get peelable nail polish glue is arrived.
Peelable nail polish glue is precoated through 365nm UV-LED light irradiation after the resulting peelable nail polish glue film of the present embodiment
Glass slide surface, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free
As the standard being fully cured, the shortest time used is characterized when being fully cured with peelable nail polish glue), through detecting, this hair
The curing time of the peelable nail polish glue of bright quick-drying is 50s.
Further, a kind of peelable nail polish glue of the present embodiment, the UV solidified resin A molecule knot as main film forming substance
Structure is organosilicon structures, with very low surface energy, reduces the interaction between film and substrate, is allowed to embody and preferably may be used
Fissility, peel strength newly think carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.21kN/m；
Fast curing properties after the resulting peelable nail polish glue film of the present embodiment in summary have preferable removing
Property.
In conclusion the peelable nail polish glue of the present embodiment is using UV curing formula, the high speed curable of UV is improved
Its curing rate, only 10-50s.Easily peelable, peel strength is 0.21~0.24kN/m；Peelable nail polish glue joined UV and refer to
Nail polish special-used colour starch makes it have light resistance, weatherability, resistant to chemical media and heat resistance.
The content is only the basic explanation under present inventive concept, and any etc. made by technical solution according to the present invention
Effect transformation, is within the scope of protection of the invention.
Claims (7)
1. a kind of peelable nail polish glue, which is characterized in that in parts by weight, raw material composition and content are as follows:
Wherein the chemical structural formula of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；N is the integer within the scope of 1-30.
2. peelable nail polish glue according to claim 1, which is characterized in that UV curing compound is selected from dipentaerythritol six
Acrylate, diethylene glycol diacrylate, tetrahydrofuran acrylate, pentaerythritol tetraacrylate, ethoxylated bisphenol A bis-
Methacrylate, two-trimethylolpropane tetra-acrylates, three (2- ethoxy) isocyanuric acid triacrylates, Ji Wusi
Alcohol triacrylate, ethoxyquin trimethylolpropane trimethacrylate, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin
Pentaerythritol tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation neopentyl glycol dipropyl
Olefin(e) acid ester, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, ring carbon
One or more of acid esters mono acrylic ester, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer.
3. peelable nail polish glue according to claim 1, which is characterized in that the UV nail polish special-used colour starch be comprising
Green-yellow light, blue green light, red, white, green, orange, purple, yellow, orange, pink, pink, light green, fluorescein, fluorescence
The UV nail polish special-used colour starch of various colors including green, fluorescein, fluorescent blue.
4. peelable nail polish glue according to claim 1, which is characterized in that the levelling agent is selected from Digao Tego
Glide 410, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-
One or more of 348；One in NP-100 or Germany BYK 333 of the UV wetting agent selected from Dow company
Kind or two kinds；The defoaming agent be selected from Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038 or
One or more of BYK-044；The photoinitiator A be selected from BASF Irgacure1173, Irgacure 184D,
Irgacure TPO、Irgacure 369、Irgacure 651、Irgacure 379、Irgacure 819、Irgacure 907
Or one or more of macromolecular photoinitiator Esacure KIP 150；The photoinitiator b is selected from BASF BASF light
It is one or more of in initiator Irgacure 2959, IRGACURE500 or IRGACURE819 DW.
5. peelable nail polish glue according to claim 1, which is characterized in that the UV solidified resin A is in parts by weight
It calculates, composition and content are as follows:
The UV solidified resin A is prepared as follows:
Methyl Hydrogen Polysiloxane Fluid and ethoxylated trimethylolpropane triacrylate are proportionally added into reaction vessel, then plus
Enter polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, catalyst is added, stirs lower 3~5h of constant temperature, stop
It only heats, drops to room temperature to temperature to get UV solidified resin A.
6. peelable nail polish glue as described in claim 1, which is characterized in that curing time 10-50s, in tensile speed
The peel strength measured when 50mm/min is 0.21~0.24kN/m.
7. a kind of preparation method of peelable nail polish glue as described in claim 1, which is characterized in that specific step is as follows:
UV wetting agent, levelling agent, defoaming agent and UV nail polish are added in the high speed disperser of control revolving speed 300-400r/min
Revolving speed is down to 300r/min after dispersing 15-20min under 600-800r/min revolving speed by special-used colour starch, and UV solidified resin is added
A, UV curing compound and photoinitiator A, photoinitiator b continue to disperse 5-10min, are uniformly mixed to get peelable nail polish is arrived
Glue.
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| CN201610038642.XA CN105596232B (en) | 2016-01-20 | 2016-01-20 | Peelable nail polish glue and preparation method thereof |
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| CN201610038642.XA CN105596232B (en) | 2016-01-20 | 2016-01-20 | Peelable nail polish glue and preparation method thereof |
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| CN112807246B (en) * | 2019-11-15 | 2023-01-13 | 万华化学集团股份有限公司 | Ultraviolet-curing optically variable nail polish and preparation method thereof |
| CN112480314B (en) * | 2020-12-04 | 2022-11-11 | 西安石油大学 | Film-forming substance for water-based strippable nail polish and preparation method thereof |
| CN113576144B (en) * | 2021-08-03 | 2022-09-13 | 上海慧姿化妆品有限公司 | Composition for nail sticker and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
-
2016
- 2016-01-20 CN CN201610038642.XA patent/CN105596232B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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Granted publication date: 20190104 Termination date: 20220120 |