CN105534742B - A kind of peelable nail polish glue and preparation process - Google Patents
A kind of peelable nail polish glue and preparation process Download PDFInfo
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- CN105534742B CN105534742B CN201610038373.7A CN201610038373A CN105534742B CN 105534742 B CN105534742 B CN 105534742B CN 201610038373 A CN201610038373 A CN 201610038373A CN 105534742 B CN105534742 B CN 105534742B
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- byk
- nail polish
- polish glue
- irgacure
- photoinitiator
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- 0 CCC(C*C(*C(*)(CC1CC*2*c(cc3)cc4c3O4)O[Si]12C(*)(*)O[Si](C)([C@](C)C=CC=CCC)C(*)(*)O[Si](C)(C)C(OCC(CC)(COC(*C=C)=O)COC(C=C)=*)=O)=O)(COC(C=C)=O)COC(C=C)=O Chemical compound CCC(C*C(*C(*)(CC1CC*2*c(cc3)cc4c3O4)O[Si]12C(*)(*)O[Si](C)([C@](C)C=CC=CCC)C(*)(*)O[Si](C)(C)C(OCC(CC)(COC(*C=C)=O)COC(C=C)=*)=O)=O)(COC(C=C)=O)COC(C=C)=O 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/544—Dendrimers, Hyperbranched polymers
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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- Cosmetics (AREA)
Abstract
The invention discloses a kind of peelable nail polish glue and preparation processes.The peelable nail polish glue of the present invention, in parts by weight, it is made of the photoinitiator b of UV solidified resins B, the 0.05-0.1 part levelling agent of 50-80 parts of UV solidified resins A, 50-80 part, 1-10 parts of wetting agent, 0.2-1 parts of antifoaming agent, 1-10 parts of UV mill bases, 3-5 parts of A and 3-5 parts of photoinitiator.Rapid curing can be irradiated after the peelable nail polish glue film of the present invention through the UV light of 365nm, hardening time is 1~5s.The technical fields such as the manicure of various people can be widely used.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable nail polish glue and preparation process, it should
Peelable nail polish glue is irradiated especially suitable for 365nm UV-LED light sources to be cured.
Background technology
Ms likes having deep love for derived from one kind to manicure.Nail polish glue using when with tool be applied to nail, by common UV light
Crosslink polymerisation after the light source treatment with irradiation of source, the nail polish adhesive curing object of generation is beautiful in colour, glittering and translucent full, change
It is infinite, it is the favorite of ladies.Compared with common UV light sources curing mode, UV-LED light sources have luminous efficiency height, long lifespan,
Many advantages, such as reaction speed is fast, heat release is few, energy-saving and environmental protection has gradually substituted common UV light sources.With enriching for city life
With the quickening of rhythm of life transformation, ladies have liked the allegro transformation nail of oneself.Peelable nail polish glue is easy to use,
Do not have to whole of cleaner energy when needing to remove to peel off, easily, is particularly suitable for child and uses.But current peelable nail polish glue
Generally aqueous, the transparent water that need to arrange in pairs or groups or sealing water use；It is not so good as oiliness nail polish glue in persistence, drying is slower, and can
Stripping nail polish glue is generally added to peelable component in the formula of nail polish glue, makes troubles to the production and use of nail polish glue.
Invention content
For overcome the deficiencies in the prior art, present invention aims at provide a kind of peelable first that can be fast curing-formed
Factice and preparation process.
Technical scheme of the present invention is specific as follows.
The present invention provides a kind of peelable nail polish glue, and in parts by weight, raw material composition and content are as follows：
Wherein：
The chemical constitution of the UV solidified resins A is as follows：
Wherein：M is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resins B is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetras acid
Ester, three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list
One or more of acrylate, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer；
The UV mill bases are in mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010, Huang F512
It is one or more of；
The wetting agent is the NP-100 of Dow company.
The antifoaming agent be selected from Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038,
One or more of BYK-044, BYK-038；The levelling agent is selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke
One or more of BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348.
In the present invention, the photoinitiator A is selected from BASF Irgacure1173, Irgacure 184D, Irgacure
TPO, Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular
One or more of photoinitiator Esacure KIP 150；The photoinitiator b is selected from photoinitiator sulfosalt Easepi
6992, one or more of salt compounded of iodine Easepi820 or Irgacure 250.
In the present invention, in parts by weight, raw material composition and content are as follows by the UV solidified resins A：
The UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil, 4 vinyl epoxy cyclohexane and trimethylolpropane trimethacrylate are added in proportion
Enter into reaction vessel, add polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, catalysis is added
Agent stirs lower 3~5h of constant temperature, stops heating, wait for that temperature drops to room temperature to get UV solidified resins A.
The present invention also provides a kind of preparation processes of peelable nail polish glue, are as follows：
According to formula, wetting agent, levelling agent, antifoaming agent are added in the high speed dispersor of control rotating speed 300-400r/min
With UV mill bases, rotating speed is down to 300r/min after disperseing 15-20min under 600-800r/min rotating speeds, UV solidified resins are added
A, UV solidified resins B and photoinitiator A, photoinitiator b continue to disperse 5-10min, be uniformly mixed to get to peelable nail polish
Glue.
The useful achievement of the present invention is as follows：
A kind of peelable nail polish glue of the present invention, containing numerous crosslink propylene acrylate structures, under 365nmUV-LED irradiations
Realize rapid curing.After the peelable nail polish glue film of gained of the invention peelable nail polish glue is precoated through UV nail polish light irradiations
The surface of glass slide, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free work
For the standard being fully cured, when being fully cured with peelable nail polish glue the shortest time used characterize), after testing, the present invention
The peelable nail polish glue of quick-drying hardening time be 1-5s.
Further, a kind of peelable nail polish glue of the invention, the UV solidified resin A molecular structures as main film forming substance
For organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, is allowed to embody preferably from stripping
From property, it is not required to add stripping auxiliary agent again.Peel strength newly thinks carefully the CMT5104 electronic tension testers of company in room using Shenzhen
The lower peel test that 180 ° are carried out by GB/T2790-1995 standards " 180 ° of peeling strength test methods of adhesive " of temperature, stretches speed
Spend 50mm/min；It is 0.21~0.25kN/m to measure peel strength；
In conclusion a kind of peelable nail polish glue of the present invention, has higher hardness of film, gloss after film.And
Preparation method is easy to control due to simple for process, therefore has the characteristics that technology maturation, quick, efficient, and suitable for industrial metaplasia
Production.
Specific implementation mode
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of peelable nail polish glue, in parts by weight, raw material composition and content are as follows：
Wherein：In parts by weight, composition and content are as follows by the UV solidified resins A：
The UV solidified resins A is carried out as follows：By 10 parts of methyl and phenyl hydrogen-containing silicon oils, 5 parts of 4- ethylene basic rings
Oxygen hexamethylene and 10 parts of trimethylolpropane trimethacrylates are added in the three-necked flask of 500ml, add 0.01 part of resistance
Poly- agent, is passed through protective gas, stirs and heats, and is warming up to 60 DEG C, and 0.03 part of catalyst is added, and stirs lower constant temperature 3h, stops adding
Heat waits for that flask temperature drops to room temperature to get UV solidified resins A.
UV solidified resins B is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, pentaerythritol tetraacrylate in mass ratio 1：1：1：The mixture of 1 composition；
The levelling agent is the high Tego Glide of enlightening 410；
The wetting agent is the NP-100 of Dow company；
The antifoaming agent is Germany BYK-035, BYK-037 in mass ratio 1：1 mixture；
The UV mill bases are one in mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010, Huang F512
Kind or a variety of mixtures；
The photoinitiator A is BASF BASF photoinitiator Irgacure1173, Irgacure TPO, Irgacure
907 in mass ratio 1:1:The mixture of 1 composition；
The photoinitiator b is photoinitiator sulfosalt Easepi 6992, the iodine that the easy chemical company of upper sea light provides
Salt Easepi 820 in mass ratio 1:The mixture of 1 composition；
In the present embodiment, a kind of preparation process of peelable nail polish glue specifically comprises the following steps：
According to formula, in the GFJ-0.4 types high speed dispersor for controlling rotating speed 300r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of antifoaming agent and 1 part of UV mill base, through disperseing under 600r/min rotating speeds
Rotating speed is down to 300r/min after 15min, 50 parts of UV solidified resins A, 50 parts of UV solidified resins B, 3 parts of photoinitiator A and 3 are added
Part photoinitiator b continues to disperse 5min, is uniformly mixed to get to peelable nail polish glue.
After peelable nail polish glue film obtained by the present embodiment peelable nail polish is precoated through the UV-LED light irradiations through 365nm
The surface of the glass slide of glue, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, not glue
Hand as the standard being fully cured, when being fully cured with peelable nail polish glue the shortest time used characterize), after testing, this
The hardening time of the peelable nail polish glue of quick-drying of invention is 5s.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.25kN/m；
There is faster curing rate after the peelable nail polish glue film of 1 gained of embodiment, it is easily peelable.
Embodiment 2
A kind of peelable nail polish glue, in parts by weight, composition and content are as follows：
Wherein：In parts by weight, composition and content are as follows by the UV solidified resins A：
The UV solidified resins A is carried out as follows：By 20 parts of methyl and phenyl hydrogen-containing silicon oils, 10 parts of 4- ethylene basic rings
Oxygen hexamethylene and 40 parts of trimethylolpropane trimethacrylates are added in the three-necked flask of 500ml, add 0.02 part of resistance
Poly- agent, is passed through protective gas, stirs and heats, and is warming up to 80 DEG C, and 0.05 part of catalyst is added, and stirs lower constant temperature 5h, stops adding
Heat waits for that flask temperature drops to room temperature to get UV solidified resins A.
UV solidified resins B is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, pentaerythritol tetraacrylate in mass ratio 2：2：1：The mixture of 1 composition；
The levelling agent is Germany BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
The wetting agent is the NP-100 of Dow company；
The antifoaming agent is German BYK Bi Ke BYK-024, BYK-025, BYK-035 are 1 in mass ratio：1：1 composition
Mixture；
The UV mill bases are one in mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010, Huang F512
Kind or a variety of mixtures；
The photoinitiator A is BASF BASF photoinitiators Irgacure TPO, 369 Irgacure, Irgacure
819 in mass ratio 2:1:The mixture of 1 composition；
The photoinitiator b is photoinitiator sulfosalt Easepi 6992, the iodine that the easy chemical company of upper sea light provides
Salt Easepi 820 in mass ratio 2:The mixture of 1 composition；
In the present embodiment, a kind of preparation process of peelable nail polish glue specifically comprises the following steps：
According to formula, in the GFJ-0.4 types high speed dispersor for controlling rotating speed 400r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of antifoaming agent and 10 parts of UV mill bases, through disperseing under 800r/min rotating speeds
Rotating speed is down to 300r/min after 20min, 80 parts of UV solidified resins A, 80 parts of UV solidified resins B, 5 parts of photoinitiator A and 5 are added
Part photoinitiator b continues to disperse 10min, is uniformly mixed to get to peelable nail polish glue.
The UV-LED light irradiations through 365nm precoat peelable nail polish glue after peelable nail polish glue film obtained by the present embodiment
Glass slide surface, according to the fingers-touch method (surface of the peelable nail polish glue for the cured a period of time that press...withes one's finger, with tack-free
As the standard being fully cured, when being fully cured with peelable nail polish glue the shortest time used characterize), after testing, this hair
The hardening time of the peelable nail polish glue of bright quick-drying is 1s.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.21kN/m；Noresidue after stripping.
There is faster curing rate after peelable nail polish glue film obtained by 2 invention of embodiment, it is easily peelable.
In conclusion contain numerous cross-linked structures after a kind of peelable nail polish glue curing of coating of the present invention, it is on the one hand real
Rapid curing is showed, the high speed curable of UV improves its curing rate, only 1-5s；A kind of peelable nail polish glue of the present invention,
UV solidified resin A molecular structures as main film forming substance are organosilicon structures, have very low surface energy, reduce film
Interaction between base material is allowed to embody preferable rippability, and peel strength newly thinks carefully the CMT5104 of company using Shenzhen
Electronic tension tester presses GB/T2790-1995 standards " 180 ° of peeling strength test methods of adhesive " and carries out 180 ° at room temperature
Peel test, tensile speed 50mm/min；It is 0.21~0.25kN/m to measure peel strength.Noresidue after stripping, under being convenient for
Secondary gluing.
Above said content is only the basic explanation under present inventive concept, and is appointed made by technical solution according to the present invention
What equivalent transformation, is within the scope of protection of the invention.
Claims (6)
1. a kind of peelable nail polish glue, which is characterized in that in parts by weight, raw material composition and content are as follows：
Wherein：The chemical constitution of the UV solidified resins A is as follows：
Wherein：M is the integer within the scope of 1-30；N is the integer within the scope of 1-30；
The UV solidified resins B is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
Ester, pentaerythritol tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra-acrylates, three
(2- ethoxys) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Third oxidation trimethylolpropane trimethacrylate, ethoxyquin pentaerythritol tetraacrylate, isobornyl acrylate, tristane
It is Dimethanol Diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate, hyperbranched
Polyester acrylate, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list acrylic acid
One or more of ester, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer；
The one kind of the UV mill bases in mill base indigo plant F4049, purple F612, red F3087, red F3095, orange F8010, Huang F512
Or it is several；
The wetting agent is the NP-100 of Dow company.
2. peelable nail polish glue according to claim 1, which is characterized in that the antifoaming agent is selected from Germany BYK Bi Ke
One or more of BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044, BYK-038；Described
Levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345,
One or more of BYK-346, BYK-347 or BYK-348.
3. peelable nail polish glue according to claim 1, which is characterized in that the photoinitiator A is selected from BASF
Irgacure1173、Irgacure 184D、Irgacure TPO、Irgacure 369、Irgacure 651、Irgacure
379, one or more of Irgacure 819, Irgacure 907 or macromolecular photoinitiator Esacure KIP 150；Institute
The photoinitiator b stated is in photoinitiator sulfosalt Easepi 6992, salt compounded of iodine Easepi 820 or Irgacure 250
One or more.
4. peelable nail polish glue according to claim 1, which is characterized in that the UV solidified resins A is in parts by weight
It calculates, raw material composition and content are as follows：
The UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil, 4 vinyl epoxy cyclohexane and trimethylolpropane trimethacrylate are proportionally added into
In reaction vessel, polymerization inhibitor is added, is passed through protective gas, stir and is heated, is warming up to 60~80 DEG C, catalyst is added, stirs
Lower 3~5h of constant temperature is mixed, stops heating, waits for that temperature drops to room temperature to get UV solidified resins A.
5. the peelable nail polish glue according to one of claim 1-4, which is characterized in that hardening time 1-5s is being stretched
The peel strength measured when speed 50mm/min is 0.21~0.25kN/m.
6. a kind of preparation process of peelable nail polish glue as described in claim 1, which is characterized in that be as follows：
According to formula, wetting agent, levelling agent, antifoaming agent and UV are added in the high speed dispersor of control rotating speed 300-400r/min
Rotating speed is down to 300r/min by mill base after disperseing 15-20min under 600-800r/min rotating speeds, and UV solidified resins A, UV are added
Solidified resin B and photoinitiator A, photoinitiator b continue to disperse 5-10min, be uniformly mixed to get to peelable nail polish glue.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610038373.7A CN105534742B (en) | 2016-01-20 | 2016-01-20 | A kind of peelable nail polish glue and preparation process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038373.7A CN105534742B (en) | 2016-01-20 | 2016-01-20 | A kind of peelable nail polish glue and preparation process |
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| CN105534742B true CN105534742B (en) | 2018-10-23 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0597630A (en) * | 1991-10-11 | 1993-04-20 | Kao Corp | Water-based nail enamel |
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN104434568A (en) * | 2014-11-27 | 2015-03-25 | 毛红兵 | Strippable water-based non-irritation nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
-
2016
- 2016-01-20 CN CN201610038373.7A patent/CN105534742B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0597630A (en) * | 1991-10-11 | 1993-04-20 | Kao Corp | Water-based nail enamel |
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN104434568A (en) * | 2014-11-27 | 2015-03-25 | 毛红兵 | Strippable water-based non-irritation nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
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| CN105534742A (en) | 2016-05-04 |
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