CN105560082B - Improved strippable property nail polish glue and preparation method thereof - Google Patents
Improved strippable property nail polish glue and preparation method thereof Download PDFInfo
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- CN105560082B CN105560082B CN201610099313.6A CN201610099313A CN105560082B CN 105560082 B CN105560082 B CN 105560082B CN 201610099313 A CN201610099313 A CN 201610099313A CN 105560082 B CN105560082 B CN 105560082B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/95—Involves in-situ formation or cross-linking of polymers
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Abstract
A kind of improved strippable property nail polish glue of the present invention, in parts by weight, it is made of reactive diluent, 0.05-0.1 parts of levelling agents, 1-10 parts of wetting agent, 0.2-1 parts of defoaming agent, 1-10 parts of mill bases and 3-5 parts of the photoinitiator of UV solidified resin B, 50-80 part of 50-80 parts of UV solidified resin A, 50-80 part.Additionally provide the preparation method of above-mentioned strippable property nail polish glue, wetting agent, levelling agent, defoaming agent and mill base are added in high speed disperser, UV solidified resin A, UV solidified resin B, reactive diluent, thickener and photoinitiator are added after dispersion, continue to disperse, it is uniformly mixed to get improved strippable property nail polish glue is arrived.There are after 395nmUV-LED light irradiation quick setting capabilities after strippable property nail polish glue film of the invention, the technical fields such as the manicure of various people can be widely used.
Description
Technical field
The invention belongs to polymeric material fields, are related to a kind of nail polish glue, specifically a kind of improved strippable property first
Factice and preparation method thereof.
Background technique
Ms likes having deep love for derived from one kind to manicure.Nail polish glue using when with tool be applied to nail, by common UV light
Crosslink polymerization reaction after the light source treatment with irradiation of source, the nail polish adhesive curing object of generation is beautiful in colour, glittering and translucent full, change
It is infinite, it is the favorite of ladies.Compared with common UV light source curing mode, UV-LED light source is high with luminous efficiency, the service life is long,
Many advantages, such as reaction speed is fast, heat release is few, energy-saving and environmental protection has gradually substituted common UV light source.With enriching for city life
With the quickening of rhythm of life transformation, ladies have liked the nail of allegro transformation oneself.Peelable nail polish glue is easy to use,
Do not have to whole of cleaner energy when needing to remove to peel off, easily, is particularly suitable for child and uses.But current peelable nail polish glue one
As peelable component is added in the formula of nail polish glue, make troubles to the production and use of nail polish glue.
Based on background above, need to develop one kind can rapid curing, have from removing component and meanwhile have decorative effect,
The good improved strippable property nail polish glue and preparation method thereof of peeling effect.
Summary of the invention
For above-mentioned technical problem in the prior art, the present invention provides a kind of improved strippable property nail polish glue and its systems
Preparation Method, described this improved strippable property nail polish glue and preparation method thereof will solve peelable nail polish glue one in the prior art
As peelable component is added in the formula of nail polish glue, the technical issues of production and use to nail polish glue are made troubles.
The present invention provides a kind of improved strippable property nail polish glue, and in parts by weight, raw material composition and content are such as
Under:
The chemical structure of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；
The preparation method of the UV solidified resin A includes the following steps:
1) following component in parts by weight, is weighed:
2) above-mentioned gained methyl and phenyl hydrogen-containing silicon oil and double pentaerythritol methacrylate are added to a reaction vessel
In, polymerization inhibitor is then added, is passed through protective gas, stirs and heats, is warming up to 60~80 DEG C, catalyst is added, stirs lower perseverance
3~5h of temperature stops heating, drops to room temperature to temperature to get UV solidified resin A；
The UV solidified resin B is hyperbranched UV solidified resin；
The levelling agent is Digao Tego Glide 410, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-
344, any one in BYK-345, BYK-346, BYK-347 or BYK-348 or two or more mixtures；
The UV wetting agent is one of NP-100 or Germany's 333 levelling agent of BYK of Dow company or two
Kind mixture；
The defoaming agent is Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-
Any one in 044 or BYK-038 or two or more mixtures；
The photoinitiator A be BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular light
Any one in initiator Esacure KIP 150 or two or more mixtures；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 or
Any one in IRGACURE819DW or two or more mixtures.
Further, above-mentioned a kind of improved strippable property nail polish glue, in parts by weight, raw material composition and content
It is as follows:
Wherein, the UV solidified resin A's the preparation method comprises the following steps:
20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of double pentaerythritol methacrylates are added in a reaction vessel,
Then 0.005 part of polymerization inhibitor is added, is passed through protective gas, stirs and heat, be warming up to 60 DEG C, 0.03 part of catalyst is added,
Lower constant temperature 3h is stirred, stops heating, drops to room temperature to temperature to get UV solidified resin A；
The UV solidified resin C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
The mixture of olefin(e) acid ester 1:1:1 in mass ratio composition；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than the mixture of 1:1:1 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:1 composition.
Further, above-mentioned a kind of improved strippable property nail polish glue, in parts by weight, raw material composition and content
It is as follows:
Wherein, the UV solidified resin A's the preparation method comprises the following steps:
Above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of double pentaerythritol methacrylates are added to a reaction to hold
In device, 0.01 part of polymerization inhibitor is added, protective gas is passed through, stirred and heat, be warming up to 60 DEG C, 0.05 part of catalysis is added
Agent stirs lower constant temperature 5h, stops heating, drop to room temperature to temperature to get UV solidified resin A；
The UV solidified resin C is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
The mixture of olefin(e) acid ester 2:1:1 in mass ratio composition；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Mixture is planted than 1:1:1 more；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 2:1 composition.
The present invention also provides a kind of preparation methods of above-mentioned improved strippable property nail polish glue, include the following steps:
1) UV solidified resin A, UV solidified resin B is weighed according to parts by weight, reactive diluent, levelling agent, wetting agent, is disappeared
Infusion, mill base and photoinitiator；
2) wetting agent, levelling agent, defoaming agent and mill base are added in the high speed disperser of control revolving speed 300-400r/min,
Revolving speed is down to 250~350r/min after dispersing 15-20min under 600-800r/min revolving speed, UV solidified resin A, UV is added
Solidified resin B and photoinitiator A, photoinitiator b continue to disperse 5-10min, are uniformly mixed to get improved strippable property first is arrived
Factice.
The reaction equation of above-mentioned UV solidified resin A is as follows:
The present invention is due to using the UV solidified resin A of multi-functional acrylate and with the over-expense of dissaving structure
Change UV solidified resin, makes it have the rapid shaping ability at 395nmUV-LED, lamp source irradiation.The resulting improvement of the present invention
Strippable property nail polish glue film after precoated through UV nail polish light irradiation improved strippable property nail polish glue glass slide surface, according to finger
Touching method (the surface of the improved strippable property nail polish glue for the cured a period of time that press...withes one's finger, using tack-free as being fully cured
Standard, shortest time used characterizes when being fully cured with improved strippable property nail polish glue), through detecting, quick-drying of the invention
The curing time of improved strippable property nail polish glue is 1-7s.UV solidified resin A molecule as main film forming substance of the invention
Structure is organosilicon structures, with very low surface energy, reduces the interaction between film and substrate, is allowed to embody preferably
Rippability, peel strength newly think carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, and tensile speed 50mm/min is measured
Peel strength is 0.21~0.25kN/m.The chameleon pigment of the resulting improved strippable property nail polish glue addition of the present invention is to improvement
Strippable property nail polish glue bring ever-changing color.
The present invention is compared with prior art, and technological progress is significant.The present invention has to be shone in 395nmUV-LED lamp source
Quick setting capabilities under penetrating, have the characteristics that cover with paint, lacquer, colour wash, etc. convenient and efficient, color it is bright it is changeable, strippable property is good, while there is bloom
The peelable effect that remover can be achieved with is not added in pool.Moreover, preparation method of the invention is due to simple process, it is easy to control, because
This has the characteristics that technology maturation, quick, efficient, and is suitable for industrialized production.The beauty of various people can be widely used in the present invention
First-class technical field.
Specific embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment and the information of manufacturer used in the present invention are as follows:
GFJ-0.4 type high speed disperser, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of improved strippable property nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows:
Above-mentioned 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of double pentaerythritol methacrylates are added to three mouthfuls of 500ml
In flask, 0.005 part of polymerization inhibitor is added, protective gas is passed through, stirred and heat, be warming up to 60 DEG C, is added 0.03 part and urge
Agent stirs lower constant temperature 3h, stops heating, drop to room temperature to flask temperature to get UV solidified resin A.
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is that BASF Irgacure1173, Irgacure 184D, Irgacure TPO press quality
Than the mixture of 1:1:1 composition；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 1:1 composition；
A kind of preparation method of above-mentioned improved strippable property nail polish glue, specifically comprises the following steps:
(1), the preparation of improved strippable property nail polish glue
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 300r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoaming agent and 1 part of mill base, through dispersing under 600r/min revolving speed
Revolving speed is down to 300r/min after 15min, be added 50 parts of UV solidified resin A, 50 parts of UV solidified resin B, 50 portions of reactive diluents,
3 parts of photoinitiator A and 3 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get improved strippable property nail polish glue is arrived.
UV-LED light irradiation precoating after the resulting improved strippable property nail polish glue film of the present invention through 395nm is improved can
The surface of the glass slide of stripping property nail polish glue, according to fingers-touch method (the improved strippable property nail polish for the cured a period of time that press...withes one's finger
The surface of glue, it is used most short when being fully cured with improved strippable property nail polish glue using tack-free as the standard being fully cured
Time characterizes), through detecting, the curing time of the improved strippable property nail polish glue of quick-drying of the invention is 1s.
Peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.25kN/m；Therefore, higher curing rate after the resulting improved strippable property nail polish glue film of the present invention, easily
Removing.
Embodiment 2
A kind of improved strippable property nail polish glue, in parts by weight, raw material composition and content are as follows:
Wherein in parts by weight, composition and content are as follows by the UV solidified resin A:
The UV solidified resin A is prepared as follows:
60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of double pentaerythritol methacrylates are added to the three-necked flask of 500ml
In, 0.01 part of polymerization inhibitor is added, protective gas is passed through, stirs and heats, is warming up to 80 DEG C, 0.05 part of catalyst is added,
Lower constant temperature 5h is stirred, stops heating, drops to room temperature to flask temperature to get UV solidified resin A.
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 press quality
Mixture is planted than 1:1:1 more；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 in mass ratio
The mixture of 2:1 composition；
A kind of preparation method of above-mentioned improved strippable property nail polish glue, specifically comprises the following steps:
According to formula, in the GFJ-0.4 type high speed disperser for controlling revolving speed 400r/min, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoaming agent and 10 parts of mill bases, through dispersing under 800r/min revolving speed
Revolving speed is down to 300r/min after 20min, be added 80 parts of UV solidified resin A, 80 parts of UV solidified resin B, 80 portions of reactive diluents,
5 parts of photoinitiator A and 5 parts of photoinitiator bs continue to disperse 10min, are uniformly mixed to get improved strippable property nail polish glue is arrived.
UV-LED light irradiation precoating after the resulting improved strippable property nail polish glue film of the present invention through 395nm is improved can
The surface of the glass slide of stripping property nail polish glue, according to fingers-touch method (the improved strippable property nail polish for the cured a period of time that press...withes one's finger
The surface of glue, it is used most short when being fully cured with improved strippable property nail polish glue using tack-free as the standard being fully cured
Time characterizes), through detecting, the curing time of the improved strippable property nail polish glue of quick-drying of the invention is 7s.It presents and becomes after solidification
Color effect.
Peel strength newly thinks carefully the CMT5104 electronic tension tester of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, tensile speed 50mm/min；It measures
Peel strength is 0.21kN/m；Therefore, higher curing rate after the resulting improved strippable property nail polish glue film of the present invention, easily
Removing.
In conclusion improved strippable property nail polish glue of the invention is using UV curing formula, the high speed curable of UV is mentioned
Its curing rate, only 1~7s are risen；Addition has toughening effect UV solidified resin C, has improved strippable property nail polish glue
There is certain toughness.UV solidified resin A molecular structure as main film forming substance is organosilicon structures, has very low surface
Can, the interaction between film and substrate is reduced, is allowed to embody preferable rippability peel strength to be 0.21~0.25kN/
m。
The content is only the basic explanation under present inventive concept, and any etc. made by technical solution according to the present invention
Effect transformation, is within the scope of protection of the invention.
Claims (4)
1. a kind of improved strippable property nail polish glue, it is characterised in that in parts by weight, raw material composition and content are as follows:
The chemical structure of the UV solidified resin A is as follows:
Wherein: m is the integer within the scope of 1-30；The preparation method of the UV solidified resin A includes the following steps:
1) following component in parts by weight, is weighed:
2) above-mentioned gained methyl and phenyl hydrogen-containing silicon oil and double pentaerythritol methacrylate are added in a reaction vessel, so
After polymerization inhibitor is added, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, catalyst is added, stir lower constant temperature 3~
5h stops heating, drops to room temperature to temperature to get UV solidified resin A；
The UV solidified resin B is hyperbranched UV solidified resin；
The levelling agent be Digao Tego Glide 410, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344,
Any one in BYK-345, BYK-346, BYK-347 or BYK-348 or two or more mixtures；
The wetting agent is the mixing of one or both of NP-100 or Germany's 333 levelling agent of BYK of Dow company
Object；
The defoaming agent is Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-044 or BYK-
Any one in 038 or two or more mixtures；
The photoinitiator A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure
369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular photoinitiator
Any one in Esacure KIP 150 or two or more mixtures；
The photoinitiator b be BASF BASF photoinitiator Irgacure 2959, IRGACURE500 or
Any one in IRGACURE819DW or two or more mixtures.
2. a kind of improved strippable property nail polish glue according to claim 1, it is characterised in that in parts by weight, former
Material composition and content are as follows:
Wherein, the UV solidified resin A's the preparation method comprises the following steps:
20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of double pentaerythritol methacrylates are added in a reaction vessel, then
0.005 part of polymerization inhibitor is added, is passed through protective gas, stirs and heat, be warming up to 60 DEG C, 0.03 part of catalyst is added, stirs
Lower constant temperature 3h stops heating, drops to room temperature to temperature to get UV solidified resin A；
The reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
The mixture of ester 1:1:1 in mass ratio composition；
The levelling agent is Digao Tego Glide 410；
The wetting agent is the NP-100 of Dow company；
The defoaming agent is Germany BYK-035, BYK-037 mixture of 1:1 in mass ratio；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure1173, Irgacure 184D, Irgacure TPO in mass ratio 1:
The mixture of 1:1 composition；
The photoinitiator b is BASF BASF photoinitiator Irgacure 2959, IRGACURE500 1:1 group in mass ratio
At mixture.
3. a kind of improved strippable property nail polish glue according to claim 1, it is characterised in that in parts by weight, former
Material composition and content are as follows:
Wherein, the UV solidified resin A's the preparation method comprises the following steps:
Above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of double pentaerythritol methacrylates are added in a reaction vessel,
The polymerization inhibitor for adding 0.01 part, is passed through protective gas, stirs and heats, and is warming up to 60 DEG C, and 0.05 part of catalyst is added, stirring
Lower constant temperature 5h stops heating, drops to room temperature to temperature to get UV solidified resin A；
The reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran acrylic acid
The mixture of ester 2:1:1 in mass ratio composition；
The levelling agent is the mixture of Germany BYK-345, BYK-346 1:1 in mass ratio composition；
The wetting agent is Germany BYK 333；
The defoaming agent is the mixture of Germany BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition；
The mill base is a kind of temperature sensing color changing mill base of changeable colour；
The photoinitiator A is BASF Irgacure 184D, Irgacure TPO, Irgacure 369 in mass ratio 1:
More kinds of mixtures of 1:1；
The photoinitiator b is BASF BASF photoinitiator Irgacure 2959, IRGACURE500 2:1 group in mass ratio
At mixture.
4. the preparation method of improved strippable property nail polish glue described in any one in claims 1 to 3, it is characterised in that packet
Include following steps:
1) UV solidified resin A, UV solidified resin B, reactive diluent, levelling agent, wetting agent, defoaming are weighed according to parts by weight
Agent, mill base and photoinitiator；Parts by weight are as follows:
2) wetting agent, levelling agent, defoaming agent and mill base, warp are added in the high speed disperser of control revolving speed 300-400r/min
Disperse after 15-20min revolving speed being down to 250~350r/min under 600-800r/min revolving speed, it is solid that UV solidified resin A, UV is added
Change resin B, reactive diluent and photoinitiator A, photoinitiator b, continue to disperse 5-10min, is uniformly mixed improved to get arriving
Strippable property nail polish glue.
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| CN107281010A (en) * | 2017-06-23 | 2017-10-24 | 梁萍 | A kind of nail polish glue containing plants essential oil and preparation method thereof |
| CN108586754A (en) * | 2018-05-14 | 2018-09-28 | 中科广化（重庆）新材料研究院有限公司 | A kind of hyperbranched silicone acrylic resin and the preparation method and application thereof |
| CN110204726B (en) * | 2019-06-11 | 2022-02-11 | 上海本诺电子材料有限公司 | Preparation method of organic silicon modified acrylic resin |
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| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
| CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
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|---|---|---|---|---|
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
| CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
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| CN105560082A (en) | 2016-05-11 |
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