CN105462489B - Peelable blue glue and its preparation technology - Google Patents
Peelable blue glue and its preparation technology Download PDFInfo
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- CN105462489B CN105462489B CN201610038600.6A CN201610038600A CN105462489B CN 105462489 B CN105462489 B CN 105462489B CN 201610038600 A CN201610038600 A CN 201610038600A CN 105462489 B CN105462489 B CN 105462489B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses the peelable blue glue of one kind and its preparation technology.Described peelable blue glue, calculate, be made up of 50 80 parts of UV solidified resins A, 50 80 parts of UV solidified resins B, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer, 1 10 parts of blueness UV mill bases, 35 parts of light trigger A and 35 parts of photoinitiator b by weight.After the peelable blue glue film can the UV light irradiation rapid curings through 365nm, hardening time be 1~10s.Adhesion is good, and non-scale is come off, peeled off easily, completely, and residual stain is not flowed；It can be applied to the insulating of the materials such as PET, ITO conducting film, ito glass, mobile phone glass, strengthened glass form, moistureproof, anti-pollution and scratch resistant protection.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of peelable blue glue and its preparation technology, this can
Peel off blue glue and be particularly suitable for use in the irradiation solidification of 365nm UV-LED light sources.
Background technology
In recent years, the fast development of digital product has driven the fast development of touch-screen industry.High performance touch-screen system
Standby technique needs to lose the ink of function with resistance or metal surface is processed " peelable blue gel ", " surface protective glue " of protection.
When manufacturing printed board, some parts will often be covered using adhesive on plate, in order to avoid poured during scolding tin by tin, such as golden hand
Finger, interface card, the plate face of carbonaceous conductive button and larger area, these are required for optionally scolding tin and multiple continuously scolding tin,
Such as SMD hybrid precast, Reflow Soldering craft and automatic and other soldering tin techniques etc..Peelable blue gel is used for reference in PCB industry printed boards
Protected mode in technique, avoids touch-screen from sustaining damage in the mill using printing peelable glue, improves production efficiency and production
Product quality.Generally, peelable glue is a kind of one pack system touch-screen special isolation protection pliability ink, and color is sticky for blueness
Shape liquid, is more prone to peel off, toughness can also be strengthened, and hand can be used after application by the peelable gel coating after high temperature resistant
Or instrument is easily peeled off, without having residue in material surface or contaminated materials, it is not necessary to secondary cleaning, with attachment
Power is good, not cull, endurance (acid-base property) it is excellent, smooth light is easy-peel, the advantages of easy to operate.It is mainly used in touch-screen thoroughly
Bright ITO electro-conductive glass, ito thin film, the insulation plated film flow of PET film, can be dried by being screen printed onto on PET film and glass
Be roasted into after film and play a part of preventing material contaminated in process of production or scratch, on the touchscreen, lower circuit bonding before,
It can be taken off, and be once stripped clean with simple and easy method.
General heated more than 100 DEG C of current peelable blue glue is solidified, and solidification temperature is high, and typically peelable
Blue glue is same there is also the time is long, stripping process there are problems that it is cumbersome, have.
The content of the invention
, can fast curing-formed, adhesion it is an object of the invention to provide one kind in order to overcome the deficiencies in the prior art
Good peelable blue glue and its preparation technology.The preparation technology of the invention is simple, and obtained peelable blue glue peeling effect is good.
Technical scheme is specifically described as follows.
The present invention provides a kind of peelable blue glue, calculates by weight, and its raw material composition and content are as follows：
Wherein described UV solidified resins A structural formula is as follows：
Wherein：M is the integer in the range of 1-50；N is the integer in the range of 1-50；
Described UV solidified resins B is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran
Acrylate, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid
Ester, three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris propylene
Acid esters, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, three
Cyclodecane Dimethanol Diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane trimethacrylate,
Hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester list
One or more in acrylate, epoxy silicone monomer, silicone acrylate and vinyl ethers monomer；
Described light trigger A be selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO,
Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular light
One or more in initiator Esacure KIP 150；
Described photoinitiator b be selected from BASF BASF light triggers Irgacure 2959, IRGACURE500 or
It is one or more of in IRGACURE819DW.
In the present invention, described UV solidified resins A is calculated by weight, and its raw material composition and content are as follows：
Described UV solidified resins A is carried out as follows：
Methyl and phenyl hydrogen-containing silicon oil and trimethylolpropane trimethacrylate are proportionally added into reaction vessel, then added
Enter polymerization inhibitor, be passed through protective gas, stir and heat, be warming up to 60~80 DEG C, add catalyst, the lower 3~5h of constant temperature of stirring stops
Only heat, treat that temperature drops to room temperature, produce UV solidified resins A.
In the present invention, described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510,
One or more in BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348；Described wetting agent is
The NP-100 of LG-DOW company；Described defoamer is selected from Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-
037th, the one or more in BYK-038, BYK-044.
The useful achievement of the present invention is as follows：
A kind of peelable blue glue of the present invention, it is real under 365nmUV-LED irradiations containing numerous crosslink propylene acrylate structures
Rapid curing is showed.
The peelable blue glue of the present invention, the NDJ-1 rotation viscometers provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai,
By GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, carried out under conditions of 25 DEG C of room temperature
Detection, its viscosity is 30000~40000mPa.s.
The peelable blue glue of the present invention, by GB/T 6753.1-2007 standards " colored paint, varnish and printing-ink fineness of grind
Measure " carry out the fineness test of peelable blue glue, measuring fineness is：≤5μm.
Further, the load glass of peelable blue glue is precoated after the peelable blue glue film obtained by the present invention through UV nail polish light irradiation
The surface of piece, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as completely
The standard of solidification, the shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention can
The hardening time for peeling off blue glue is 1-5s.
Further, a kind of peelable blue glue of the invention, be as the UV solidified resin A molecular structures of main film forming substance
Organosilicon structures, with very low surface energy, reduce the interaction between film and base material, are allowed to embody preferably from stripping
Property, it is not required to add stripping auxiliary agent again, the problem of effectively overcoming residual stain after stripping.Peel strength newly thinks carefully company using Shenzhen
CMT5104 electronic tension testers at room temperature press GB/T2790-1995 standards " 180 ° of peeling strength test sides of adhesive
Method " carries out 180 ° of peel test, draw speed 50mm/min；Peel strength is measured for 0.21~0.25kN/m；
In summary, a kind of peelable blue glue of the invention, has higher hardness of film, gloss after film.And its
Preparation method is simple due to technique, easy to control, thus with technology maturation, it is quick, efficient the features such as, and suitable for industrial metaplasia
Production.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai；
The hard instrument QHQ of film Pencil scratch, the production of Tianjin Material Testing Machine factory；
Praise the production of mapping test instrument Co., Ltd in the portable mirror luster meters of WGG-60, Shanghai.
Embodiment 1
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A is calculated by weight, and it is constituted and content is as follows：
Described UV solidified resins A is carried out as follows：By 10 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of trihydroxy methyls
Propane triacrylate is added in 500ml three-necked flask, is added 0.01 part of polymerization inhibitor MEHQ, is passed through guarantor
Gas is protected, stirs and heats, 60 DEG C are warming up to, 0.03 part of catalyst chloroplatinic acid/aqueous isopropanol is added, constant temperature 3h under stirring,
Stop heating, treat that flask temperature drops to room temperature, produce UV solidified resins A.
Described UV solidified resins B be double pentaerythritol methacrylate, (2) ethoxylated bisphenol A dimethylacrylates,
Tricyclodecane Dimethanol diacrylate in mass ratio 2：1：1 mixture；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is Germany BYK-035, BYK-037 in mass ratio 1：1 mixture；
The violet 3D blueness UV mill bases that described blue UV mill bases provide for Guangzhou Xin Bo pigment Science and Technology Ltd.；
Described light trigger A is BASF BASF light trigger Irgacure1173, Irgacure TPO, Irgacure
907 in mass ratio 1:1:The mixture of 1 composition；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
1:The mixture of 1 composition；
In the present embodiment, a kind of preparation technology of peelable blue glue specifically includes following steps：
According to formula, in control rotating speed 300r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 1 part of wetting agent of middle addition, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of blueness UV mill base, through under 600r/min rotating speeds
Rotating speed is down to 300r/min after scattered 15min, 50 parts of UV solidified resins A, 50 parts of UV solidified resins B, 3 parts of light triggers are added
A and 3 part of photoinitiator b, continues scattered 30min, is well mixed, that is, obtains peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai is rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 40000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness for 5 μM.
After peelable blue glue film obtained by the present embodiment peelable blue glue is precoated through the UV-LED light irradiations through 365nm
The surface of slide, according to fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using it is tack-free as
The standard being fully cured, the shortest time used characterizes when being fully cured with peelable blue glue), after testing, of the invention is fast
The hardening time for doing peelable blue glue is 5s.
Further, a kind of peelable blue glue of the present embodiment, is used as the UV solidified resin A molecular structures of main film forming substance
For organosilicon structures, with very low surface can, reduce the interaction between film and base material, be allowed to embody preferably peelable
From property, peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790-1995 using Shenzhen
Standard " 180 ° of peeling strength test methods of adhesive " carries out 180 ° of peel test, draw speed 50mm/min；Measure stripping
Intensity is 0.25kN/m；
There is faster curing rate, easily peelable, noresidue after the peelable blue glue film of the gained of above example 1.
Embodiment 2
A kind of peelable blue glue, is calculated by weight, and its raw material composition and content are as follows：
Wherein：Described UV solidified resins A is calculated by weight, and it is constituted and content is as follows：
Described UV solidified resins A is carried out as follows：By 20 parts of methyl and phenyl hydrogen-containing silicon oils and 40 parts of trihydroxy methyls
Propane triacrylate is added in 500ml three-necked flask, adds 0.02 part of polymerization inhibitor, is passed through protective gas, stirring
And heat, 80 DEG C are warming up to, 0.05 part of catalyst is added, the lower constant temperature 5h of stirring stops heating, treats that flask temperature drops to room temperature,
Produce UV solidified resins A.
Described UV solidified resins B is double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate press 2：2：The mixture of 1 composition；
Described levelling agent is Germany BYK-345, BYK-346 in mass ratio 1：The mixture of 1 composition；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is that German BYK Bi Ke BYK-024, BYK-025, BYK-035 are 1 in mass ratio：1：1 composition
Mixture；
The sapphire blue three-dimensional 3D bluenesss UV colors that described blue UV mill bases provide for Guangzhou Xin Bo pigment Science and Technology Ltd.
Slurry；
Described light trigger A is BASF BASF light triggers Irgacure TPO, Irgacure 369, Irgacure
819 in mass ratio 2:1:The mixture of 1 composition；
Described photoinitiator b be BASF BASF light triggers Irgacure 2959, IRGACURE500 in mass ratio
2:The mixture of 1 composition；
In the present embodiment, a kind of preparation technology of peelable blue glue specifically includes following steps：
According to formula, in control rotating speed 400r/min GFJ-0.4 types high speed dispersor, (the new promise instrument and equipment in Shanghai is limited
Company) 10 parts of wetting agents of middle addition, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of blueness UV mill bases, through under 800r/min rotating speeds
Rotating speed is down to 300r/min after scattered 20min, 80 parts of UV solidified resins A, 80 parts of UV solidified resins B, 5 parts of light triggers are added
A and 5 part of photoinitiator b, continues scattered 100min, is well mixed, that is, obtains peelable blue glue.
Peelable blue glue obtained by the present embodiment, the NDJ-1 provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai is rotated
Viscosimeter, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of bar of room temperature
Detected under part, its viscosity is 30000mPa.s.
Peelable blue glue obtained by the present embodiment, by GB/T 6753.1-2007 standards, " colored paint, varnish and printing-ink are ground
The measure of grinding rate " carries out the fineness test of peelable blue glue, measures fineness for 4 μm.
The UV-LED light irradiations through 365nm precoat the load of peelable blue glue after peelable blue glue film obtained by the present embodiment
The surface of slide, according to the fingers-touch method (surface of the peelable blue glue for the cured a period of time that press...withes one's finger, using tack-free as complete
The standard of all solidstate, shortest time used characterizes when being fully cured with peelable blue glue), after testing, quick-drying of the invention
The hardening time of peelable blue glue is 1s.
Peel strength newly thinks carefully the CMT5104 electronic tension testers of company at room temperature by GB/T2790- using Shenzhen
1995 standards " 180 ° of peeling strength test methods of adhesive " carry out 180 ° of peel test, draw speed 50mm/min；Measure
Peel strength is 0.21kN/m；
There is faster curing rate, easily peelable, noresidue after the peelable blue glue film of the gained of above example 2.
In summary, numerous cross-linked structures are contained after a kind of peelable blue glue curing of coating of the invention, are on the one hand realized
Rapid curing, UV high speed curable improves its curing rate, only 1-5s；It is used as the UV solidified resins of main film forming substance
A molecular structures are organosilicon structures, with very low surface energy, reduce the interaction between film and base material, are allowed to embody
Go out preferably from fissility, be not required to add stripping auxiliary agent again, the problem of effectively overcoming residual stain after stripping, peel strength is 0.21
~0.25kN/m；There are quick setting capabilities after the peelable blue glue film of the high temperature resistant after 365nmUV-LED light irradiations, with reference to
The good non-scale of power is come off, peeled off easily, completely, and residual stain is not flowed.
Above said content is only the basic explanation under present inventive concept, and according to appointing that technical scheme is made
What equivalent transformation, all should belong to protection scope of the present invention.
Claims (4)
1. a kind of peelable blue glue, it is characterised in that calculate by weight, its raw material composition and content are as follows：
Wherein described UV solidified resins A structural formula is as follows：
Wherein：M is the integer in the range of 1-50；N is the integer in the range of 1-50；
Described UV solidified resins B is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran propylene
Acid esters, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra-acrylate,
Three (2- ethoxys) isocyanuric acid triacrylates, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris acrylic acid
Ester, the third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, three rings
Decane Dimethanol Diacrylate, the third oxidation neopentylglycol diacrylate, hyperbranched polyester acrylic ester, alkoxypropan olefin(e) acid
Ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone propylene
One or more in acid esters and vinyl ethers monomer；
Described light trigger A is selected from BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure
369th, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular photoinitiator
One or more in Esacure KIP 150；
Described photoinitiator b be selected from BASF BASF light triggers Irgacure 2959, IRGACURE500 or
It is one or more of in IRGACURE819DW.
2. peelable blue glue according to claim 1, it is characterised in that viscosity at its 25 DEG C for 30000~
40000mPa.s, fineness≤5 μm, hardening time is 1-5s, the peel strength under draw speed 50mm/min be 0.21~
0.25kN/m。
3. peelable blue glue according to claim 1, it is characterised in that described UV solidified resins A is counted by weight
Calculate, its raw material composition and content are as follows：
Described UV solidified resins A is prepared as follows：
Methyl and phenyl hydrogen-containing silicon oil and trimethylolpropane trimethacrylate are proportionally added into reaction vessel, resistance is added
Poly- agent, is passed through protective gas, stirs and heats, and is warming up to 60~80 DEG C, adds catalyst, and stirring 3~5h of lower constant temperature stops adding
Heat, treats that temperature drops to room temperature, produces UV solidified resins A.
4. peelable blue glue according to claim 1, it is characterised in that described levelling agent is selected from the high Tego Glide of enlightening
410th, in Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348
One or more；Described wetting agent is the NP-100 of LG-DOW company；Described defoamer is selected from Germany BYK Bi Ke
One or more in BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038600.6A CN105462489B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and its preparation technology |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038600.6A CN105462489B (en) | 2016-01-20 | 2016-01-20 | Peelable blue glue and its preparation technology |
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| CN105462489B true CN105462489B (en) | 2017-10-17 |
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| CN103031053B (en) * | 2013-01-06 | 2015-07-29 | 北京海斯迪克新材料有限公司 | Touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof |
| CN103627313B (en) * | 2013-11-29 | 2016-08-17 | 广州机械科学研究院有限公司 | A kind of peelable protection material of ultraviolet light polymerization and its preparation method and application |
| CN104745068A (en) * | 2013-12-30 | 2015-07-01 | 比亚迪股份有限公司 | Modified UV paint and preparation method thereof |
| CN105131779B (en) * | 2015-09-14 | 2018-06-29 | 上海应用技术学院 | A kind of ultraviolet curing organic silicon mould release and preparation method thereof |
| CN105219252A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of UV solidifies strippable water-based paint and preparation method thereof |
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