CN105434189A - Strippable nail polish gel and preparation method thereof - Google Patents
Strippable nail polish gel and preparation method thereof Download PDFInfo
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- CN105434189A CN105434189A CN201610038374.1A CN201610038374A CN105434189A CN 105434189 A CN105434189 A CN 105434189A CN 201610038374 A CN201610038374 A CN 201610038374A CN 105434189 A CN105434189 A CN 105434189A
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- nail polish
- cured resin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/544—Dendrimers, Hyperbranched polymers
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- Chemical & Material Sciences (AREA)
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- Epidemiology (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses strippable nail polish gel and a preparation method thereof. The strippable nail polish gel is prepared from by weight, 50-80 parts of UV curing resin A, 50-80 parts of UV curing resin B, 50-80 parts of reactive diluents, 0.05-1 part of leveling agent, 1-10 parts of wetting agent, 0.2-1 part of antifoaming agent, 1-10 parts of UV color paste, 3-5 parts of photoinitiator A and 3-5 parts of photoinitiator B. The strippable nail polish gel has rapid curing capacity after being irradiated through 365 nm UV-LED lamps and can be widely applied to the technical field of nail care of various users.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of peelable nail polish glue and preparation method thereof, this peelable nail polish glue is specially adapted to the UV-LED light source irradiation solidification of 365nm.
Background technology
Ms to manicure like come from one and have deep love for.Nail polish glue is applied to fingernail with instrument when using, and after common UV light source light source treatment with irradiation, cross-linking polymerization occurs, the nail polish adhesive curing thing of generation beautiful in colour, glittering and translucent full, change irregularly infinite, be the favorite of ladies.Compared with the light source curing mode of common UV, UV-LED light source has the plurality of advantages such as luminous efficiency is high, the life-span is long, response speed is fast, heat release is few, energy-saving and environmental protection, substitutes common UV light source gradually.Along with the quickening that the abundant of city life and rhythm of life convert, ladies have liked the fingernail of allegro conversion oneself.Peelable nail polish glue is easy to use, peels off when needing to take off without cleaner with regard to whole of energy, easily, is particularly suitable for child and uses.But current peelable nail polish glue is generally aqueous, transparent water of need arranging in pairs or groups or sealing water use; Not as oiliness nail polish glue in persistence, drying is comparatively slow, and peelable nail polish glue generally with the addition of peelable component in the formula of nail polish glue, makes troubles to the production of nail polish glue and use.
Based on above background, need to develop a kind of can fast setting, there is decorative effect simultaneously, having from peeling off component, peelable nail polish glue that peeling effect is good and preparation method thereof.
Summary of the invention
One of the object of the invention provide a kind of can with UV-LED light source energy fast setting, simultaneously have high glaze, do not add the peelable effective peelable nail polish glue that remover just can realize.
Two of the object of the invention provides the preparation method of above-mentioned a kind of peelable nail polish glue.
Technical scheme of the present invention is specifically described as follows.
The invention provides a kind of peelable nail polish glue, calculate by weight, its raw material composition and content as follows:
Wherein: the chemical constitution of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-30; N is the integer within the scope of 1-30;
Described UV cured resin B is hyperbranched UV cured resin;
Described reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolane acrylate, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetra-acrylate, three (2-ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane triacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate, and one or more in vinyl ethers monomer,
Described UV mill base is selected from one or more in mill base blue F4049, purple F612, red F3087, red F3095, orange F8010 or yellow F512.
In the present invention, described levelling agent is selected from one or more in enlightening height TegoGlide410, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348; Described wetting agent is one or both in the NP-100 of LG-DOW company or German BYK333 levelling agent; Described defoamer is one or more in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044, BYK-038.
In the present invention, described light trigger A is one or more in BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369, Irgacure651, Irgacure379, Irgacure819, Irgacure907 or macromolecular photoinitiator EsacureKIP150; Described photoinitiator b is selected from one or more in BASF BASF light trigger Irgacure2959, IRGACURE500 or IRGACURE819DW.
In the present invention, described UV cured resin A calculates by weight, its raw material composition and content as follows:
Described UV cured resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and pentaerythritol triacrylate are joined in reaction vessel in proportion; add polymerization inhibitor again; pass into protective gas; stir and heat, being warming up to 60 ~ 80 DEG C, adding catalyst; stir lower constant temperature 3 ~ 5h; stop heating, treat that temperature drops to room temperature, obtain UV cured resin A.
The present invention also provides a kind of preparation method of peelable nail polish glue, and concrete steps are as follows:
According to formula, wetting agent, levelling agent, defoamer and UV mill base is added in the high speed dispersor controlling rotating speed 300-400r/min, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resin A, UV cured resin B, reactive diluent and light trigger A, photoinitiator b, continue dispersion 5-30min, mix homogeneously, namely obtains peelable nail polish glue.
Useful achievement of the present invention is as follows:
The peelable nail polish glue of one of the present invention, because the UV cured resin A that have employed multi-functional acrylate and the hyperbranched UV cured resin B with dissaving structure makes it have the fast setting respond under 365nmUV-LED lamp source is irradiated.Have and cover with paint, lacquer, colour wash, etc. bright changeable, the peelable feature such as good of convenient and swift, color.
Further, through the surface of the microscope slide of the peelable nail polish glue of UV nail polish light irradiation precoating after peelable nail polish glue film of the present invention, according to the fingers-touch method (surface of the peelable nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable nail polish glue, the shortest time used characterizes), after testing, the hardening time of quick-drying peelable nail polish glue of the present invention is 1-7s.
Further, peelable nail polish glue of the present invention, the UV cured resin A molecular structure as main film forming substance is organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, make it to embody better from fissility, do not need to add stripping auxiliary agent again.The CMT5104 electronic tension tester that peel strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " adhesive 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording peel strength is 0.21 ~ 0.25kN/m;
Further, the UV cured resin B with the dissaving structure of toughening effect of interpolation, makes peelable nail polish glue have certain toughness.
In sum, the peelable nail polish glue of one of the present invention, have the quick setting capabilities under 365nmUV-LED lamp source is irradiated, it has higher toughness, gloss and color capability after film.And its preparation method due to technique simple, easy to control, the maturation that therefore possesses skills, the feature such as quick, efficient, and be suitable for suitability for industrialized production.
Detailed description of the invention
Below by embodiment, the present invention is described in further detail, but do not limit the present invention.
In the raw material that various embodiments of the present invention are used except the special producer that shows and specification, other raw materials are commercially available, and specification is chemical pure.
The model of the various equipment that the present invention is used and the information of manufacturer as follows:
GFJ-0.4 type high speed dispersor, Shanghai Xin Nuo instrument and equipment company limited produces.
Embodiment 1
A kind of peelable nail polish glue, calculates by weight, its raw material composition and content as follows:
Wherein said UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A is prepared as follows: join in the there-necked flask of 500ml by 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of pentaerythritol triacrylates; add the polymerization inhibitor MEHQ of 0.005 part again; pass into protective gas; stir and heat, being warming up to 60 DEG C, adding 0.03 part of catalyst chloroplatinic acid/vinyl double-seal head complex; stir lower constant temperature 3h; stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
Described UV cured resin B is hyperbranched polyester acrylic ester prepolymer;
Described reactive diluent be diethylene glycol diacrylate, isobornyl acrylate, hyperbranched polyester acrylic ester in mass ratio 1:1:1 composition mixture.
Described levelling agent is enlightening height TegoGlide410;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the mixture of German BYK-035, BYK-037 1:1 in mass ratio;
Described UV mill base is purple F612;
Described light trigger A be BASF Irgacure1173, Irgacure184D, IrgacureTPO in mass ratio 1:1:1 composition mixture;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratio 1:1 composition mixture;
In the present embodiment, a kind of preparation method of peelable nail polish glue, specifically comprises the steps:
According to formula, 1 part of wetting agent, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of UV mill base is added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo instrument and equipment company limited) controlling rotating speed 300r/min, after disperseing 15min under 600r/min rotating speed, rotating speed is down to 300r/min, add 50 parts of UV cured resin A, 50 parts of UV cured resin B, 50 parts of reactive diluents, 3 parts of light trigger A and 3 part photoinitiator bs, continue dispersion 50min, mix homogeneously, namely obtains peelable nail polish glue.
Through the surface of the microscope slide of the peelable nail polish glue of UV-LED light irradiation precoating of 365nm after the peelable nail polish glue film of the present embodiment, according to the fingers-touch method (surface of the peelable nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable nail polish glue, the shortest time used characterizes), after testing, the hardening time of quick-drying peelable nail polish glue of the present invention is 1s.After solidification, film presents purple effect.
The CMT5104 electronic tension tester that peel strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " adhesive 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording peel strength is 0.25kN/m;
Curing rate higher after the peelable nail polish glue film of the present embodiment in sum, easily peels off, has good color effect simultaneously.
Embodiment 2
A kind of peelable nail polish glue, calculates by weight, its raw material composition and content as follows:
Wherein said UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A is prepared as follows: join in the there-necked flask of 500ml by 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of pentaerythritol triacrylates; add the hydroquinone of polymerization retarder of 0.01 part again; pass into protective gas; stir and heat, being warming up to 80 DEG C, adding 0.05 part of catalyst chloroplatinic acid/aqueous isopropanol; stir lower constant temperature 5h; stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
Described UV cured resin B is hyperbranched polyester acrylic ester prepolymer;
Described reactive diluent be diethylene glycol diacrylate, isobornyl acrylate, hyperbranched polyester acrylic ester in mass ratio 1:2:1 composition mixture.
Described levelling agent be German BYK-345, BYK-346 in mass ratio 1:1 composition mixture;
Described wetting agent is German BYK333;
Described defoamer be German BYK Bi Ke BYK-024, BYK-025 in mass ratio 1:1 composition mixture;
Described UV mill base is the blue F4049 of mill base;
Described light trigger A is BASF Irgacure184D, IrgacureTPO, Irgacure369 1:1:1 many kinds of mixture in mass ratio;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratio 2:1 composition mixture;
In the present embodiment, a kind of preparation method of peelable nail polish glue, specifically comprises the steps:
According to formula, 10 parts of wetting agent, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of UV mill bases are added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo instrument and equipment company limited) controlling rotating speed 400r/min, after disperseing 20min under 800r/min rotating speed, rotating speed is down to 300r/min, add 80 parts of UV cured resin A, 80 parts of UV cured resin B, 80 parts of reactive diluents, 5 parts of light trigger A and 5 part photoinitiator bs, continue dispersion 30min, mix homogeneously, namely obtains peelable nail polish glue.
Through the surface of the microscope slide of the peelable nail polish glue of UV-LED light irradiation precoating of 365nm after the peelable nail polish glue film of the present embodiment, according to the fingers-touch method (surface of the peelable nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable nail polish glue, the shortest time used characterizes), after testing, the hardening time of quick-drying peelable nail polish glue of the present invention is 7s.Blue color effect is presented after solidification.
The CMT5104 electronic tension tester that peel strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " adhesive 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording peel strength is 0.21kN/m;
Curing rate higher after the peelable nail polish glue film of the present embodiment in sum, easily peels off, has good color effect simultaneously.
In sum, what the peelable nail polish glue of the present embodiment adopted is UV curing formula, and the high speed curable of UV improves its curing rate, only has 1 ~ 7s; Easy stripping, peel strength is 0.21 ~ 0.25kN/m; The UV mill base that peelable nail polish glue of the present invention adds brings Protean color to peelable nail polish glue, interpolation there is toughening effect UV cured resin B, make peelable nail polish glue have certain toughness.
Above said content be only the present invention conceive under basic explanation, and according to any equivalent transformation that technical scheme of the present invention is done, all should protection scope of the present invention be belonged to.
Claims (6)
1. a peelable nail polish glue, is characterized in that, calculate by weight, its raw material composition and content as follows:
Wherein: the chemical constitution of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-30; N is the integer within the scope of 1-30;
Described UV cured resin B is hyperbranched UV cured resin;
Described reactive diluent is double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolane acrylate, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetra-acrylate, three (2-ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane triacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate, and one or more in vinyl ethers monomer,
Described UV mill base is selected from one or more in mill base blue F4049, purple F612, red F3087, red F3095, orange F8010 or yellow F512.
2. peelable nail polish glue according to claim 1, it is characterized in that, described levelling agent is selected from one or more in enlightening height TegoGlide410, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348; Described wetting agent is one or both in the NP-100 of LG-DOW company or German BYK333 levelling agent; Described defoamer is one or more in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044, BYK-038.
3. peelable nail polish glue according to claim 1, it is characterized in that, described light trigger A is one or more in BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369, Irgacure651, Irgacure379, Irgacure819, Irgacure907 or macromolecular photoinitiator EsacureKIP150; Described photoinitiator b is selected from one or more in BASF BASF light trigger Irgacure2959, IRGACURE500 or IRGACURE819DW.
4. peelable nail polish glue according to claim 1, is characterized in that, described UV cured resin A calculates by weight, its raw material composition and content as follows:
Described UV cured resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and pentaerythritol triacrylate are joined in reaction vessel in proportion; add polymerization inhibitor again; pass into protective gas; stir and heat, being warming up to 60 ~ 80 DEG C, adding catalyst; stir lower constant temperature 3 ~ 5h; stop heating, treat that temperature drops to room temperature, obtain UV cured resin A.
5. according to the peelable nail polish glue one of claim 1-4 Suo Shu, it is characterized in that, hardening time is 1-7s, and the peel strength recorded when draw speed 50mm/min is 0.21 ~ 0.25kN/m.
6. a preparation method for peelable nail polish glue, it is characterized in that, concrete steps are as follows:
According to formula, wetting agent, levelling agent, defoamer and UV mill base is added in the high speed dispersor controlling rotating speed 300-400r/min, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resin A, UV cured resin B, reactive diluent and light trigger A, photoinitiator b, continue dispersion 5-30min, mix homogeneously, namely obtains peelable nail polish glue.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107556964A (en) * | 2017-09-22 | 2018-01-09 | 深圳市联灏新材料技术开发有限公司 | A kind of quanta point material sealant composition of radiation-hardenable |
CN107898697A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田环保节能科技有限公司 | A kind of Environmental-friendnail nail enamel |
CN111110588A (en) * | 2020-01-16 | 2020-05-08 | 佛山市蓝狐生物科技有限公司 | Peelable base glue and preparation method thereof |
CN113667358A (en) * | 2021-08-30 | 2021-11-19 | 广东蓝天优创美化妆品有限公司 | Color paste for low-odor UV (ultraviolet) nail polish gel and preparation method thereof |
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JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
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2016
- 2016-01-20 CN CN201610038374.1A patent/CN105434189B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107556964A (en) * | 2017-09-22 | 2018-01-09 | 深圳市联灏新材料技术开发有限公司 | A kind of quanta point material sealant composition of radiation-hardenable |
CN107556964B (en) * | 2017-09-22 | 2021-01-26 | 东莞市联灏新材料技术开发有限公司 | Radiation-curable quantum dot material sealant composition |
CN107898697A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田环保节能科技有限公司 | A kind of Environmental-friendnail nail enamel |
CN111110588A (en) * | 2020-01-16 | 2020-05-08 | 佛山市蓝狐生物科技有限公司 | Peelable base glue and preparation method thereof |
CN113667358A (en) * | 2021-08-30 | 2021-11-19 | 广东蓝天优创美化妆品有限公司 | Color paste for low-odor UV (ultraviolet) nail polish gel and preparation method thereof |
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