CN104312235B - A kind of ceramic with corrosion-resistant acrylic acid epoxy resin powdery paints - Google Patents
A kind of ceramic with corrosion-resistant acrylic acid epoxy resin powdery paints Download PDFInfo
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- CN104312235B CN104312235B CN201410541689.9A CN201410541689A CN104312235B CN 104312235 B CN104312235 B CN 104312235B CN 201410541689 A CN201410541689 A CN 201410541689A CN 104312235 B CN104312235 B CN 104312235B
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- epoxy resin
- corrosion
- acrylic acid
- powdery paints
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- 239000003822 epoxy resin Substances 0.000 title claims abstract description 19
- 239000003973 paint Substances 0.000 title claims abstract description 19
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 19
- 238000005260 corrosion Methods 0.000 title claims abstract description 17
- 230000007797 corrosion Effects 0.000 title claims abstract description 17
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 239000000919 ceramic Substances 0.000 title description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- -1 monoacid Chemical compound 0.000 claims abstract description 9
- 239000003999 initiator Substances 0.000 claims abstract description 8
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims abstract description 7
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical compound NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940123208 Biguanide Drugs 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims abstract description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims abstract description 4
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 10
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 10
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000001035 drying Methods 0.000 abstract description 6
- 241000406668 Loxodonta cyclotis Species 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 5
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 abstract 1
- 125000003944 tolyl group Chemical group 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 239000004593 Epoxy Substances 0.000 description 4
- 238000005524 ceramic coating Methods 0.000 description 4
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- DGXRZJSPDXZJFG-UHFFFAOYSA-N docosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCCC(O)=O DGXRZJSPDXZJFG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- MRBBLYNDWDOXQB-UHFFFAOYSA-N 2,2-dicyanopentanoic acid Chemical compound CCCC(C#N)(C#N)C(O)=O MRBBLYNDWDOXQB-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- KJCLYACXIWMFCC-UHFFFAOYSA-M sodium;5-benzoyl-4-hydroxy-2-methoxybenzenesulfonate Chemical group [Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 KJCLYACXIWMFCC-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses the corrosion-resistant acrylic acid epoxy resin powdery paints of a kind of pottery, raw material is: glycidyl methacrylate, polyhydric alcohol, azodiisobutyronitrile, monoacid, di-tert-butyl peroxide, dicyclopentadiene, initiator, maleic anhydride, epoxy resin, zinc oxide, levelling agent, 1 adjacent toluene biguanide, dodecanedioic acid, 2 mercaptobenzothiazolers and titanium dioxide；Product fusing point 200 220 DEG C, density 135 145g/cm3, 5% hydrochloric acid solution soaks 20 30d without exception；Glossiness 140% 150%, after artificial accelerated aging 500h, protects light rate 94 98%；Shore hardness 50 70H, drying time 20,30min, soaked in saturated calcium hydroxide that 15 35d are non-foaming, elephant skin, scrub resistance 1,800 2200 times.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of ceramic with corrosion-resistant acrylic acid epoxy tree
Fat powdery paints.
Background technology
Ceramic industry is very fast in China's development, and selling market gradually turns to rise.China is a pottery
Big producing country, the most increasing to the demand of pottery.In terms of the situation of domestic market, shape in recent years
Gesture is gratifying, and supply falls short of demand for new, special products of famous brands, of extra fine quality ceramic product, high-grade ceramic and medium-to-high grade sanitary ceramics ten
Dividing grappling, the measured traditional product of matter continues to be in great demand, unsalable simply ropy product.So far
Till the present, defining like can briefly be described as follows of pottery: pottery is to use aluminium silicate mineral
Or some oxide etc. is primary raw material, according to the intention of people by specific physical and chemical process
The technique rock with a shaping type at high temperature made with certain temperature and atmosphere.Surface
Can glazing or not glazing, some porcelains also have translucence in various degree, and entire body is by one
Kind or multiple crystal or with amorphous cement and pore or with the microstructure such as grog inclusion enclave
Composition.
Founding of New, over 60 years, along with the development of national economy every profession and trade, is joined as it
The coatings industry of set progressively develops into national economy from a little industry the most unobtrusive
The requisite important industry in each field.Through the struggling hard of several generations, pioneer and keep forging ahead, I
State has become second-biggest-in-the-world coating material production state and country of consumption, enters into world's coating industry development
Main flow.Coating (paint), our the most described paint is one therein.Refer to be coated with
It is distributed in body surface to form thin film under certain conditions and play protection, decoration or other are special
One class I liquid I of function (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of in early days
Coating mostly with vegetable oil as primary raw material, therefore also referred to as paint.Replace at synthetic resin
Vegetable oil, therefore referred to as coating.Coating non-liquid, powdery paints is the big class of coating variety one.
Pottery is the general name of pottery and porcelain.People was as far back as the most B.C. 8000 the front Neolithic Age
Just invent pottery.Ceramic material is oxide, nitride, boride and carbide etc. mostly.
Common ceramic material has clay, aluminium oxide, Kaolin etc..The general hardness of ceramic material is higher,
But plasticity is poor.Except feeder, decoration use on, science, technology development in
Also play an important role.Ceramic Material is the earth original ample resources clay through quenching take and
Become.And the character tool toughness of clay, it is plastic that room temperature meets water, micro-dry can carve, and absolutely dry grinds；Burn
Pottery can be become to fill water to 700 degree；Burn to 1230 degree of then porcelain, can not absorb water
And corrosion-and high-temp-resistant.The elasticity of its usage, has answering of various intention in culture today science and technology
With.Ceramic coating is that one can make Organic substance react with inorganic matter, thus has had both both
The novel ceramic coating of advantage.The hardness of the ceramic coating of a new generation can reach more than 6H.
High temperature resistant 400 degree, not gluing effect, color is multiple.And di-tert-butyl peroxide can be made
Physical property ceramic coating.And popularizing along with humanity concept, and the composition of novel harmonious society,
Design that a kind of resistance to soiling is good, corrosion-resistant, fast drying and the high corrosion-resistant acrylic acid of pottery of hardness
Epoxy powder coating is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of ceramic with corrosion-resistant acrylic acid epoxy tree
Fat powdery paints, solves the corrosion-resistant acrylic acid epoxy resin powdery paints resistance to soiling of existing pottery
Difference, it is weak to burn into and is dried the technical problems such as slow and hardness is low.
Technical scheme:
A kind of pottery is with corrosion-resistant acrylic acid epoxy resin powdery paints, described ceramic with corrosion-resistant
The raw materials by weight portion proportioning of acrylic acid epoxy resin powdery paints is as follows: methacrylic acid contracts
Water glyceride 100 parts；Polyhydric alcohol 30-40 part；Azodiisobutyronitrile 5-15 part；Monoacid
15-25 part；Di-tert-butyl peroxide 1-10 part；Dicyclopentadiene 5-15 part；Initiator
5-15 part；Maleic anhydride 5-25 part；Epoxy resin 10-30 part；Zinc oxide 5-15
Part；Levelling agent 1-10 part；1-neighbour's toluene biguanide 1-10 part；Dodecanedioic acid 15-35 part；
2-mercaptobenzothiazole 1-5 part；Titanium dioxide 45-55 part.
As a preferred technical solution of the present invention: the described corrosion-resistant acrylic acid epoxy of pottery
The raw materials by weight portion proportioning of toner coating is as follows: glycidyl methacrylate
100 parts；Polyhydric alcohol 35 parts；Azodiisobutyronitrile 10 parts；20 parts of monoacid；Two tertiary fourths
Base peroxide 5 parts；Dicyclopentadiene 10 parts；Initiator 10 parts；Maleic anhydride
15 parts；Epoxy resin 20 parts；Zinc oxide 10 parts；Levelling agent 5 parts；1-neighbour's toluene biguanide 5
Part；Dodecanedioic acid 25 parts；2-mercaptobenzothiazole 3 parts；Titanium dioxide 50 parts.
As a preferred technical solution of the present invention: described initiator uses azo dicyano penta
Acid initiator or benzophenone.
As a preferred technical solution of the present invention: described levelling agent uses polydimethylsiloxanes
Alkane or polyether polyester modified organic silicon oxygen alkane.
Beneficial effect:
A kind of pottery of the present invention with the employing of corrosion-resistant acrylic acid epoxy resin powdery paints with
Upper technical scheme compared with prior art, has following technical effect that 1, product fusing point
200-220 DEG C, density 135-145g/cm3, 5% hydrochloric acid solution soaks 20-30d without exception；
2, glossiness 140%-150%, after artificial accelerated aging 500h, protects light rate 94-98%；3、
Shore hardness 50-70H, drying time, 20-30min, soaked 15-35d in saturated calcium hydroxide
Non-foaming, elephant skin；4, product scrub resistance 1800-2200 time, can with widespread production not
Current material is replaced in the division of history into periods.
Detailed description of the invention
Embodiment 1:
A kind of pottery corrosion-resistant acrylic acid epoxy resin powdery paints, its raw materials by weight portion
Proportioning is as follows: glycidyl methacrylate 100 parts；Polyhydric alcohol 30 parts；Azo two is different
Butyronitrile 5 parts；15 parts of monoacid；Di-tert-butyl peroxide 1 part；Dicyclopentadiene 5 parts；
Benzophenone 5 parts；Maleic anhydride 5 parts；Epoxy resin 10 parts；Zinc oxide 5 parts；
Polydimethylsiloxane 1 part；1-neighbour's toluene biguanide 1 part；Dodecanedioic acid 15 parts；2-mercapto
Base benzothiazole 1 part；Titanium dioxide 45 parts.
Being added by above-mentioned raw materials in reactor, be warmed up to 140 DEG C, the mixing of insulation reaction 6h is all
Even, pulverize with pulverizer after cooling, be sieved through sieve with 150mg, prepare coating.
Product fusing point 200 DEG C, density 135g/cm3, 5% hydrochloric acid solution soaks 20d and is as good as
Often；Glossiness 140%, after artificial accelerated aging 500h, protects light rate 94%；Shore hardness 50H,
Drying time, 30min, soaked in saturated calcium hydroxide that 15d is non-foaming, elephant skin, resistance to shampooing
Property 1800 times.
Embodiment 2:
A kind of pottery corrosion-resistant acrylic acid epoxy resin powdery paints, its raw materials by weight portion
Proportioning is as follows: glycidyl methacrylate 100 parts；Polyhydric alcohol 40 parts；Azo two is different
Butyronitrile 15 parts；25 parts of monoacid；Di-tert-butyl peroxide 10 parts；Dicyclopentadiene 15
Part；Benzophenone 15 parts；Maleic anhydride 25 parts；Epoxy resin 30 parts；Zinc oxide
15 parts；10 parts of polyether polyester modified organic silicon oxygen alkane；1-neighbour's toluene biguanide 10 parts；12
Docosandioic acid 35 parts；2-mercaptobenzothiazole 5 parts；Titanium dioxide 55 parts.
Being added by above-mentioned raw materials in reactor, be warmed up to 180 DEG C, the mixing of insulation reaction 10h is all
Even, pulverize with pulverizer after cooling, be sieved through sieve with 150mg, prepare coating.
Product fusing point 210 DEG C, density 140g/cm3, 5% hydrochloric acid solution soaks 25d and is as good as
Often；Glossiness 145%, after artificial accelerated aging 500h, protects light rate 96%；Shore hardness 60H,
Drying time, 25min, soaked in saturated calcium hydroxide that 25d is non-foaming, elephant skin, resistance to shampooing
Property 2000 times.
Embodiment 3:
A kind of pottery corrosion-resistant acrylic acid epoxy resin powdery paints, its raw materials by weight portion
Proportioning is as follows: glycidyl methacrylate 100 parts；Polyhydric alcohol 35 parts；Azo two is different
Butyronitrile 10 parts；20 parts of monoacid；Di-tert-butyl peroxide 5 parts；Dicyclopentadiene 10
Part；Azo dicyano valeric acid initiator 10 parts；Maleic anhydride 15 parts；Epoxy resin
20 parts；Zinc oxide 10 parts；5 parts of polyether polyester modified organic silicon oxygen alkane；1-neighbour's toluene biguanide
5 parts；Dodecanedioic acid 25 parts；2-mercaptobenzothiazole 3 parts；Titanium dioxide 50 parts.
Being added by above-mentioned raw materials in reactor, be warmed up to 160 DEG C, the mixing of insulation reaction 8h is all
Even, pulverize with pulverizer after cooling, be sieved through sieve with 150mg, prepare coating.
Product fusing point 220 DEG C, density 145g/cm3, 5% hydrochloric acid solution soaks 30d and is as good as
Often；Glossiness 150%, after artificial accelerated aging 500h, protects light rate 98%；Shore hardness 70H,
Drying time, 20min, soaked in saturated calcium hydroxide that 35d is non-foaming, elephant skin, resistance to shampooing
Property 2200 times.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of
This any change in the implication suitable with claims of the present invention and scope, all should
It is considered to be included within the scope of the claims.
Claims (1)
1. a pottery is with corrosion-resistant acrylic acid epoxy resin powdery paints, it is characterised in that institute
State pottery by the raw materials by weight portion proportioning of corrosion-resistant acrylic acid epoxy resin powdery paints such as
Under: glycidyl methacrylate 100 parts；Polyhydric alcohol 35 parts；Azodiisobutyronitrile 10
Part；20 parts of monoacid；Di-tert-butyl peroxide 5 parts；Dicyclopentadiene 10 parts；Cause
Agent 10 parts；Maleic anhydride 15 parts；Epoxy resin 20 parts；Zinc oxide 10 parts；Levelling
Agent 5 parts；1-neighbour's toluene biguanide 5 parts；Dodecanedioic acid 25 parts；2-mercaptobenzothiazole 3
Part；Titanium dioxide 50 parts；
Described initiator uses azo dicyano valeric acid initiator or benzophenone；
Described levelling agent uses polydimethylsiloxane or polyether polyester modified organic silicon oxygen alkane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410541689.9A CN104312235B (en) | 2014-10-14 | 2014-10-14 | A kind of ceramic with corrosion-resistant acrylic acid epoxy resin powdery paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410541689.9A CN104312235B (en) | 2014-10-14 | 2014-10-14 | A kind of ceramic with corrosion-resistant acrylic acid epoxy resin powdery paints |
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| CN104312235A CN104312235A (en) | 2015-01-28 |
| CN104312235B true CN104312235B (en) | 2016-08-24 |
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| CN201410541689.9A Expired - Fee Related CN104312235B (en) | 2014-10-14 | 2014-10-14 | A kind of ceramic with corrosion-resistant acrylic acid epoxy resin powdery paints |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104673041A (en) * | 2015-03-12 | 2015-06-03 | 湖州中辰建设有限公司 | Novel acrylate resin powder coating for ceramics |
| CN104673040A (en) * | 2015-03-12 | 2015-06-03 | 湖州中辰建设有限公司 | Novel acrylic ester powder coating for ceramics |
| SG11202106051QA (en) * | 2018-12-13 | 2021-07-29 | Materia Inc | Coating compositions |
| CN113831505B (en) * | 2021-11-02 | 2024-02-06 | 黄山新佳精细材料有限公司 | High-gloss self-curing epoxy resin and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004269620A (en) * | 2003-03-06 | 2004-09-30 | Mitsubishi Gas Chem Co Inc | Powder coating material |
| CN101921357B (en) * | 2010-08-17 | 2012-08-29 | 江门市制漆厂有限公司 | High-solid low-viscosity hydroxy acrylic resin and preparation process thereof |
| CN102766238B (en) * | 2012-08-13 | 2013-10-30 | 佛山市高明同德化工有限公司 | High-adhesion thermoset acrylic resin and preparation method thereof |
| CN103130944B (en) * | 2013-02-21 | 2015-07-01 | 西安交通大学 | Preparation method of high-reaction-activity hydroxyl acrylic resin |
| CN103613698B (en) * | 2013-11-26 | 2016-08-10 | 阜阳市诗雅涤新材料科技有限公司 | A kind of thermosetting acrylic resin used for powder coating and preparation method and use thereof |
| CN103665271A (en) * | 2013-12-06 | 2014-03-26 | 江苏柏鹤涂料有限公司 | Acrylic acid-epoxy ester hybrid resin and coatings thereof |
| CN103864998B (en) * | 2014-03-12 | 2017-03-22 | 江门市三木化工有限公司 | Acrylic resin and preparation method thereof |
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