CN104312237B - A kind of pottery is with containing carboxy acrylic ester toner coating - Google Patents
A kind of pottery is with containing carboxy acrylic ester toner coating Download PDFInfo
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- CN104312237B CN104312237B CN201410542607.2A CN201410542607A CN104312237B CN 104312237 B CN104312237 B CN 104312237B CN 201410542607 A CN201410542607 A CN 201410542607A CN 104312237 B CN104312237 B CN 104312237B
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- butyl
- acrylic ester
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- 239000011248 coating agent Substances 0.000 title claims abstract description 27
- 238000000576 coating method Methods 0.000 title claims abstract description 27
- -1 carboxy acrylic ester Chemical class 0.000 title claims abstract description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 21
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000003999 initiator Substances 0.000 claims abstract description 9
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 7
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002160 Celluloid Polymers 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 7
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 7
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 7
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims abstract description 7
- 235000010215 titanium dioxide Nutrition 0.000 claims abstract description 7
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000004640 Melamine resin Substances 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000005187 foaming Methods 0.000 abstract description 10
- 241000406668 Loxodonta cyclotis Species 0.000 abstract description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000003973 paint Substances 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- 239000004927 clay Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009413 insulation Methods 0.000 description 4
- 238000005524 ceramic coating Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001354 calcination Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- MRBBLYNDWDOXQB-UHFFFAOYSA-N 2,2-dicyanopentanoic acid Chemical compound CCCC(C#N)(C#N)C(O)=O MRBBLYNDWDOXQB-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- KJCLYACXIWMFCC-UHFFFAOYSA-M sodium;5-benzoyl-4-hydroxy-2-methoxybenzenesulfonate Chemical group [Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 KJCLYACXIWMFCC-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
The invention discloses a kind of pottery with containing carboxy acrylic ester toner coating, raw material is: methyl methacrylate, N,N-DMAA, butyl methacrylate, celluloid, 2-methyl propionitrile, p-methyl benzenesulfonic acid, initiator, butyl acetate, toluene, Ketohexamethylene, levelling agent, butyl glycol ether, tetrabutyl ammonium bromide, titanium white and butyl polyacrylate；Product density 135-145g/cm3, glossiness 120%-140%, shore hardness 45-65H；Hot strength 20-30MPa, percentage elongation 200-300%, drying time, 20-30min, soaked 30-40d without foaming, obscission in 5% hydrochloric acid solution；Adhesive force 1-2 level, impact strength 500-550N/cm, soaks in saturated calcium hydroxide that 25-35d is non-foaming, elephant skin；Scrub resistance 800-1200 time.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery with containing carboxy acrylic ester toner coating.
Background technology
Coating, is be applied to body surface to form a class I liquid I of the solid-state film with protection, decoration or property (such as insulation, anticorrosion, mark etc.) or the general name of solid material, including oil (property) paint, water paint, powdery paints.Paint is flowable liquid coating, including oil (property) paint and water paint.Paint is with organic solvent for medium or high solid, solvent-free oil paint.Water paint is that available water is dissolved or with the scattered coating of water.Coating, as one of the main material of house decoration, the large percentage accounted in decorations, buys the whether qualified environment directly influencing overall finishing effect and room of coating, sometimes even the healthy of human body can be produced harm greatly.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.According to the classification of the chemical products that the modern times pass through, coating belongs to fine chemical product.Modern coating is progressively becoming a polyfunctional engineering material of class, is an important industry in chemical industry.
Pottery is the various goods of the material prepared for primary raw material through mixing, the molding of pulverizing and calcining with natural clay and various natural minerals.People were called pottery the article of high-temperature firing in special kiln being fabricated to potter's clay in the past, and pottery is the general name of pottery and porcelain.The traditional concept of pottery refers to all artificial industrial products being raw material with Inorganic nonmetal mineral such as clays.It include by clay or containing the mixture of clay through mixing, shape, calcining and the various goods made.Broadly fall into its scope to the finest fine pottery and porcelain by the most coarse earthenware.Primary raw material for it is the silicate mineral (such as clay, quartz etc.) taking from nature, therefore with industry such as glass, cement, enamel, refractory materials, belongs to the category of " silicate industry ".Reform and open up to the outside world over 30 years, Chinese pottery industrial boom, nowadays become in the world genuine Production of Ceramics big country, consumption big country.The domestic ceramics yield of domestic product accounts for global about 70%, and display art ceramic yield is the 65% of the whole world, and architectural pottery yield also accounts for Gross World Product half of the country.China industry occupies very important status in world's building material industry.
Ceramic industry is very fast in China's development, and selling market turns to rise gradually.China is a Production of Ceramics big country, and the demand of pottery is also increasing.From domestic market situation, in recent years having a gratifying situation, supply falls short of demand for new, special products of famous brands, of extra fine quality ceramic product, and high-grade ceramic and medium-to-high grade sanitary ceramics are very in great demand, and the measured traditional product of matter continues to be in great demand, unsalable simply ropy product.Ceramic coating weatherability and processing characteristics are excellent, bear dirty and resistant to damage.Although conventional ceramic coating resistant to damage, but if the parts after application are curved processing, it is easy to crack, and fluorine resin paints and organic coating, it is easy to damaged by sandstone, dust etc..Therefore, the appearance of ceramic coating, receive the favor of ceramic industry the infiltration of forward other industry, promise well.And popularizing along with humanity concept, and the composition of novel harmonious society, design the pottery that a kind of adhesive force is good, corrosion-resistant, hardness tolerant is high and impact strength is good and be very important with the ester toner coating containing carboxy acrylic.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of pottery with containing carboxy acrylic ester toner coating, the technical problem such as solve that existing pottery ester toner paint adhesion containing carboxy acrylic is low, not shock-resistant, not corrosion-resistant and hardness is low.
Technical scheme:
A kind of pottery is with containing carboxy acrylic ester toner coating, and described pottery is as follows by the raw materials by weight portion proportioning containing carboxy acrylic ester toner coating: methyl methacrylate 100 parts；N, N-DMAA 15-25 part；Butyl methacrylate 35-45 part；Celluloid 35-45 part；2-methyl propionitrile 1-10 part；P-methyl benzenesulfonic acid 2-8 part；Initiator 5-15 part；Butyl acetate 6-8 part；Toluene 80-90 part；Ketohexamethylene 3-7 part；Levelling agent 1-10 part；Butyl glycol ether 4-8 part；Tetrabutyl ammonium bromide 0.2-0.8 part；Titanium white 30-40 part；Butyl polyacrylate 0.5-1.5 part.
As a preferred technical solution of the present invention: described pottery is as follows by the raw materials by weight portion proportioning containing carboxy acrylic ester toner coating: methyl methacrylate 100 parts；N, N-DMAA 20 parts；Butyl methacrylate 40 parts；40 parts of celluloid；2-methyl propionitrile 5 parts；P-methyl benzenesulfonic acid 5 parts；Initiator 10 parts；Butyl acetate 7 parts；Toluene 85 parts；Ketohexamethylene 5 parts；Levelling agent 5 parts；Butyl glycol ether 6 parts；Tetrabutyl ammonium bromide 0.5 part；Titanium white 35 parts；Butyl polyacrylate 1 part.
As a preferred technical solution of the present invention: described initiator adopts azo dicyano valeric acid initiator or benzophenone.
As a preferred technical solution of the present invention: described levelling agent adopts polydimethylsiloxane or melamine resin.
Beneficial effect:
A kind of pottery of the present invention adopts above technical scheme compared with prior art with containing carboxy acrylic ester toner coating, has following technical effect that 1, product density 135-145g/cm3, glossiness 120%-140%, shore hardness 45-65H；2, hot strength 20-30MPa, percentage elongation 200-300%, drying time, 20-30min, soaked 30-40d without foaming, obscission in 5% hydrochloric acid solution；3, adhesive force 1-2 level, impact strength 500-550N/cm, soaks in saturated calcium hydroxide that 25-35d is non-foaming, elephant skin；4, product scrub resistance 800-1200 time, it is possible to current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Embodiment 1:
A kind of pottery is with containing carboxy acrylic ester toner coating, and its raw materials by weight portion proportioning is as follows: methyl methacrylate 100 parts；N, N-DMAA 15 parts；Butyl methacrylate 35 parts；35 parts of celluloid；2-methyl propionitrile 1 part；P-methyl benzenesulfonic acid 2 parts；Benzophenone 5 parts；Butyl acetate 6 parts；Toluene 80 parts；Ketohexamethylene 3 parts；Polydimethylsiloxane 1 part；Butyl glycol ether 4 parts；Tetrabutyl ammonium bromide 0.2 part；Titanium white 30 parts；Butyl polyacrylate 0.5 part.
Above-mentioned raw materials is added in reactor, be warmed up to 90 DEG C, insulation reaction 3h mix homogeneously, pulverize with pulverizer after cooling, with the sieved sieve of 120mg, prepare coating.
Density 135g/cm3, glossiness 120%, shore hardness 45H；Hot strength 20MPa, percentage elongation 200%, drying time, 30min, soaked 30d without foaming, obscission in 5% hydrochloric acid solution；Adhesive force 2 grades, impact strength 500N/cm, soaks in saturated calcium hydroxide that 25d is non-foaming, elephant skin, scrub resistance 800 times.
Embodiment 2:
A kind of pottery is with containing carboxy acrylic ester toner coating, and its raw materials by weight portion proportioning is as follows: methyl methacrylate 100 parts；N, N-DMAA 25 parts；Butyl methacrylate 45 parts；45 parts of celluloid；2-methyl propionitrile 10 parts；P-methyl benzenesulfonic acid 8 parts；Benzophenone 15 parts；Butyl acetate 8 parts；Toluene 90 parts；Ketohexamethylene 7 parts；Melamine resin 10 parts；Butyl glycol ether 8 parts；Tetrabutyl ammonium bromide 0.8 part；Titanium white 40 parts；Butyl polyacrylate 1.5 parts.
Above-mentioned raw materials is added in reactor, be warmed up to 110 DEG C, insulation reaction 5h mix homogeneously, pulverize with pulverizer after cooling, with the sieved sieve of 140mg, prepare coating.
Density 140g/cm3, glossiness 130%, shore hardness 55H；Hot strength 25MPa, percentage elongation 250%, drying time, 25min, soaked 35d without foaming, obscission in 5% hydrochloric acid solution；Adhesion 1 grade, impact strength 525N/cm, soaks in saturated calcium hydroxide that 30d is non-foaming, elephant skin, film scrub resistance 1000 times.
Embodiment 3:
A kind of pottery is with containing carboxy acrylic ester toner coating, and its raw materials by weight portion proportioning is as follows: methyl methacrylate 100 parts；N, N-DMAA 20 parts；Butyl methacrylate 40 parts；40 parts of celluloid；2-methyl propionitrile 5 parts；P-methyl benzenesulfonic acid 5 parts；Azo dicyano valeric acid initiator 10 parts；Butyl acetate 7 parts；Toluene 85 parts；Ketohexamethylene 5 parts；Melamine resin 5 parts；Butyl glycol ether 6 parts；Tetrabutyl ammonium bromide 0.5 part；Titanium white 35 parts；Butyl polyacrylate 1 part.
Above-mentioned raw materials is added in reactor, be warmed up to 100 DEG C, insulation reaction 4h mix homogeneously, pulverize with pulverizer after cooling, with the sieved sieve of 130mg, prepare coating.
Density 145g/cm3, glossiness 140%, shore hardness 65H；Hot strength 30MPa, percentage elongation 300%, drying time, 20min, soaked 40d without foaming, obscission in 5% hydrochloric acid solution；Adhesion 1 grade, impact strength 550N/cm, soaks in saturated calcium hydroxide that 35d is non-foaming, elephant skin, film scrub resistance 1200 times.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to present disclosure is illustrated, rather than restriction, and the therefore any change in the implication suitable with claims of the present invention and scope, all it is believed that be included in the scope of claims.
Claims (1)
1. a pottery is with containing carboxy acrylic ester toner coating, it is characterised in that described pottery is as follows by the raw materials by weight portion proportioning containing carboxy acrylic ester toner coating: methyl methacrylate 100 parts；N, N-DMAA 20 parts；Butyl methacrylate 40 parts；40 parts of celluloid；2-methyl propionitrile 5 parts；P-methyl benzenesulfonic acid 5 parts；Initiator 10 parts；Butyl acetate 7 parts；Toluene 85 parts；Ketohexamethylene 5 parts；Levelling agent 5 parts；Butyl glycol ether 6 parts；Tetrabutyl ammonium bromide 0.5 part；Titanium white 35 parts；Butyl polyacrylate 1 part；
Described initiator adopts azo dicyano valeric acid initiator or benzophenone；
Described levelling agent adopts polydimethylsiloxane or melamine resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410542607.2A CN104312237B (en) | 2014-10-14 | 2014-10-14 | A kind of pottery is with containing carboxy acrylic ester toner coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410542607.2A CN104312237B (en) | 2014-10-14 | 2014-10-14 | A kind of pottery is with containing carboxy acrylic ester toner coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104312237A CN104312237A (en) | 2015-01-28 |
| CN104312237B true CN104312237B (en) | 2016-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410542607.2A Active CN104312237B (en) | 2014-10-14 | 2014-10-14 | A kind of pottery is with containing carboxy acrylic ester toner coating |
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Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004269620A (en) * | 2003-03-06 | 2004-09-30 | Mitsubishi Gas Chem Co Inc | Powder coating material |
| CN101921357B (en) * | 2010-08-17 | 2012-08-29 | 江门市制漆厂有限公司 | High-solid low-viscosity hydroxy acrylic resin and preparation process thereof |
| CN102766238B (en) * | 2012-08-13 | 2013-10-30 | 佛山市高明同德化工有限公司 | High-adhesion thermoset acrylic resin and preparation method thereof |
| CN103130944B (en) * | 2013-02-21 | 2015-07-01 | 西安交通大学 | Preparation method of high-reaction-activity hydroxyl acrylic resin |
| CN103613698B (en) * | 2013-11-26 | 2016-08-10 | 阜阳市诗雅涤新材料科技有限公司 | A kind of thermosetting acrylic resin used for powder coating and preparation method and use thereof |
| CN103665271A (en) * | 2013-12-06 | 2014-03-26 | 江苏柏鹤涂料有限公司 | Acrylic acid-epoxy ester hybrid resin and coatings thereof |
| CN103864998B (en) * | 2014-03-12 | 2017-03-22 | 江门市三木化工有限公司 | Acrylic resin and preparation method thereof |
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2014
- 2014-10-14 CN CN201410542607.2A patent/CN104312237B/en active Active
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Effective date of registration: 20191204 Address after: 311300 457-459, Jintian Road, Jinnan street, Lin'an District, Hangzhou City, Zhejiang Province Patentee after: Hangzhou Lin'an Huaxin Plastic powder material Co.,Ltd. Address before: Zhujiang Road Wuzhong District Mudu town of Suzhou city in Jiangsu Province Tianlong 215101 No. 378 building room 4722 Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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Denomination of invention: A carboxylic acrylic resin powder coating for ceramics Effective date of registration: 20231010 Granted publication date: 20160629 Pledgee: Postal Savings Bank of China Co.,Ltd. Hangzhou Lin'an District Sub branch Pledgor: Hangzhou Lin'an Huaxin Plastic powder material Co.,Ltd. Registration number: Y2023330002280 |