CN104151894B - Ultraviolet light polymerization polyacrylate coating used by a kind of pottery - Google Patents
Ultraviolet light polymerization polyacrylate coating used by a kind of pottery Download PDFInfo
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- CN104151894B CN104151894B CN201410430864.7A CN201410430864A CN104151894B CN 104151894 B CN104151894 B CN 104151894B CN 201410430864 A CN201410430864 A CN 201410430864A CN 104151894 B CN104151894 B CN 104151894B
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- pottery
- ultraviolet light
- light polymerization
- acid
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- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 18
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 33
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 11
- KRPAJLYSLFNDOA-UHFFFAOYSA-N mephenesin carbamate Chemical compound CC1=CC=CC=C1OCC(O)COC(N)=O KRPAJLYSLFNDOA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229950006838 mephenesin carbamate Drugs 0.000 claims abstract description 10
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims abstract description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 9
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 239000001361 adipic acid Substances 0.000 claims abstract description 8
- 235000011037 adipic acid Nutrition 0.000 claims abstract description 8
- 239000012948 isocyanate Substances 0.000 claims abstract description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 8
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 8
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000003504 photosensitizing agent Substances 0.000 claims abstract description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000012975 dibutyltin dilaurate Substances 0.000 claims abstract description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005711 Benzoic acid Substances 0.000 claims abstract description 3
- 235000010233 benzoic acid Nutrition 0.000 claims abstract description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- RZGSPMLEQHFAHD-UHFFFAOYSA-N benzoic acid;toluene Chemical compound CC1=CC=CC=C1.OC(=O)C1=CC=CC=C1 RZGSPMLEQHFAHD-UHFFFAOYSA-N 0.000 claims description 5
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 claims description 4
- 229910052573 porcelain Inorganic materials 0.000 claims description 4
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- -1 ammonia Formic acid esters acrylate Chemical class 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- NNNLYDWXTKOQQX-UHFFFAOYSA-N 1,1-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OC(CC)(OC(=O)C=C)OC(=O)C=C NNNLYDWXTKOQQX-UHFFFAOYSA-N 0.000 claims 1
- 235000013847 iso-butane Nutrition 0.000 claims 1
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000005187 foaming Methods 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 241000406668 Loxodonta cyclotis Species 0.000 abstract description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 5
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000005587 bubbling Effects 0.000 abstract description 2
- 239000000919 ceramic Substances 0.000 description 7
- 239000003973 paint Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 239000004927 clay Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- ZSDJVGXBJDDOCD-UHFFFAOYSA-N benzene dioctyl benzene-1,2-dicarboxylate Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1=CC=CC=C1 ZSDJVGXBJDDOCD-UHFFFAOYSA-N 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- WCRDXYSYPCEIAK-UHFFFAOYSA-N dibutylstannane Chemical compound CCCC[SnH2]CCCC WCRDXYSYPCEIAK-UHFFFAOYSA-N 0.000 description 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of pottery ultraviolet light polymerization polyacrylate coating, raw material is: oligomerisation mephenesin Carbamate acrylate, ethylene glycol, Glycerin triacrylate, neopentyl glycol, ethyl acrylate, trimethylolpropane, photosensitizer, benzoic acid, toluene di-isocyanate(TDI), p-phthalic acid, cross-linking agent, adipic acid, dibutyl tin dilaurate, M-phthalic acid and Polyethylene Glycol；Product glossiness 130% 140%, hardness 4 6H, after 5% hydrochloric acid solution soaks 24 48h without bubbling, obscission；Water soaks at 25 DEG C 10 20d not elephant skin, foaming, saturated calcium hydroxide soaks 2 6d without exception；Adhesive force 12 grades, impact strength 5 10MPa；Product scrub resistance 1,800 2000 times, pliability 3 5mm, can be with the widespread production not division of history into periods for current material.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery ultraviolet light polymerization polyacrylic acid
Ester paint.
Background technology
Pottery be with natural clay and various natural minerals for primary raw material through pulverizing mixing,
The various goods of the material that molding and calcining prepare.In the past people be fabricated to potter's clay specially
In the kiln of door, the article of high-temperature firing are referred to as pottery, and pottery is the general name of pottery and porcelain.Pottery
The traditional concept of porcelain refers to all artificial industry with Inorganic nonmetal mineral such as clays as raw material
Product.It include by clay or containing the mixture of clay through mixing, shape, calcining and make
Various goods.Broadly fall into its model to the finest fine pottery and porcelain by the most coarse earthenware
Enclose.Development due to ceramic science technology.And the demand day that market is to pottery new product
Benefit increases, and forces Ceramics Enterprises to want development new product, and must consider the variation of product
Problem that rationalization's production process is brought by this factor and the impact of generation.Suitable in order to strengthen
Ying Xing, Ceramics Enterprises not only needs to improve science and technology application level and the research of new product energetically
Ability, constantly makes model change, it is necessary to use program evaluation and review technique, GT and many
The production organization method that kind mixes line production etc. are advanced, use adaptable machinery equipment and
Flexible production manufactures system, to adapt to produce the needs of variation.
Coating (paint), our the most described paint is one therein.Finger is coated
Body surface can form thin film under certain conditions and play protection, decoration or other specific functions
One class I liquid I of (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of painting in early days
Material is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Instead of at synthetic resin and planted
Thing oil, therefore referred to as coating.Coating non-liquid, powdery paints is the big class of coating variety one.?
National economy and people's lives play an important role.Using coating content per capita year is that a country is raw
The important indicator that running water is flat.
Ceramic industry is very fast in China's development, and selling market gradually turns to rise.China is a pottery
Big producing country, the most increasing to the demand of pottery.In terms of the situation of domestic market, shape in recent years
Gesture is gratifying, and supply falls short of demand for new, special products of famous brands, of extra fine quality ceramic product, high-grade ceramic and medium-to-high grade sanitary ceramics ten
Dividing grappling, the measured traditional product of matter continues to be in great demand, unsalable simply ropy product.Newly
China set up over 60 years, along with the development of national economy every profession and trade, as the painting that it is supporting
Material industry progressively develops into all fields of national economy from a little industry the most unobtrusive
Requisite important industry.Through the struggling hard of several generations, pioneering and keeping forging ahead, China becomes
For second-biggest-in-the-world coating material production state and country of consumption, enter into the master of world's coating industry development
Stream.And popularizing along with humanity concept, and the composition of novel harmonious society, a kind of light of design
The pottery ultraviolet light polymerization polypropylene that pool degree is good, hardness is high, resistance to water and impact strength are excellent
Acid esters coating is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that ultraviolet light polymerization polyacrylic acid used by a kind of pottery
Ester paint, solves existing pottery ultraviolet light polymerization polyacrylate coating glossiness and hardness
Low, resistance to water and pliability difference and the technical problem such as impact strength is low.
Technical scheme:
A kind of pottery uses ultraviolet light polymerization polyacrylate coating, described pottery ultraviolet light polymerization
The raw materials by weight portion proportioning of polyacrylate coating is as follows: oligomerisation mephenesin Carbamate acrylate
100 parts；Ethylene glycol 20-30 part；Glycerin triacrylate 30-40 part；New penta 2
Alcohol 15-25 part；Ethyl acrylate 40-60 part；Trimethylolpropane 15-25 part；Photosensitizer
10-20 part；Benzoic acid 25-35 part；Toluene di-isocyanate(TDI) 20-40 part；P-phthalic acid
5-25 part；Cross-linking agent 1-10 part；Adipic acid 15-35 part；Dibutyl tin dilaurate 10-30
Part；M-phthalic acid 5-15 part；Polyethylene Glycol 25-45 part.
As a preferred technical solution of the present invention: described pottery ultraviolet light polymerization polypropylene
The raw materials by weight portion proportioning of acid esters coating is as follows: oligomerisation mephenesin Carbamate acrylate 100
Part；Ethylene glycol 25 parts；Glycerin triacrylate 35 parts；Neopentyl glycol 20 parts；
Ethyl acrylate 50 parts；Trimethylolpropane 20 parts；Photosensitizer 15 parts；30 parts of benzoic acid；
Toluene di-isocyanate(TDI) 30 parts；P-phthalic acid 15 parts；Cross-linking agent 5 parts；Adipic acid 25
Part；Dibutyl tin dilaurate 20 parts；M-phthalic acid 10 parts；Polyethylene Glycol 35 parts.
As a preferred technical solution of the present invention: described photosensitizer use benzoin ethyl ether or
Benzophenone.
As a preferred technical solution of the present invention: described cross-linking agent uses hexakis-methoxy methyl three
Poly cyanamid or styrene.
Beneficial effect:
A kind of pottery ultraviolet light polymerization polyacrylate coating of the present invention uses above skill
Art scheme compared with prior art, has following technical effect that 1, product glossiness
130%-140%, hardness 4-6H, without bubbling, taking off in 5% hydrochloric acid solution after soaking 24-48h
Fall phenomenon；2, water soaks 10-20d not elephant skin, foaming at 25 DEG C, at saturated calcium hydroxide
Middle immersion 2-6d is without exception；3, adhesive force 1-2 level, impact strength 5-10MPa；4, produce
Product scrub resistance 1800-2000 time, pliability 3-5mm, can replace with the widespread production not division of history into periods
Current material.
Detailed description of the invention
Embodiment 1:
Ultraviolet light polymerization polyacrylate coating used by a kind of pottery, its raw materials by weight portion proportioning
As follows: oligomerisation mephenesin Carbamate acrylate 100 parts；Ethylene glycol 20 parts；Glycerin three
Acrylate 30 parts；Neopentyl glycol 15 parts；Ethyl acrylate 40 parts；Trimethylolpropane
15 parts；Benzoin ethyl ether 10 parts；25 parts of benzoic acid；Toluene di-isocyanate(TDI) 20 parts；Right
Phthalic acid 5 parts；Styrene 1 part；Adipic acid 15 parts；Dibutyl tin dilaurate 10 parts；
M-phthalic acid 5 parts；Polyethylene Glycol 25 parts.
Weigh oligomerisation mephenesin Carbamate acrylate, ethylene glycol, Glycerin triacrylate and
Neopentyl glycol puts in reactor, is warming up to 50 DEG C, stirs 15min, adds surplus stock,
Be warming up to 70 DEG C, stir 2h, be coated on pottery, with ultra violet lamp, lamp away from 20cm,
Irradiate 10s.
Product glossiness 130%, hardness 4H, nothing foaming after immersion 24h in 5% hydrochloric acid solution,
Obscission；Water soaks at 25 DEG C 10d not elephant skin, foaming, soaks in saturated calcium hydroxide
2d is without exception for bubble；Adhesive force 2 grades, impact strength 5MPa；Product scrub resistance 1800 times,
Pliability 3mm.
Embodiment 2:
Ultraviolet light polymerization polyacrylate coating used by a kind of pottery, its raw materials by weight portion proportioning
As follows: oligomerisation mephenesin Carbamate acrylate 100 parts；Ethylene glycol 30 parts；Glycerin three
Acrylate 40 parts；Neopentyl glycol 25 parts；Ethyl acrylate 60 parts；Trimethylolpropane
25 parts；Benzoin ethyl ether 20 parts；35 parts of benzoic acid；Toluene di-isocyanate(TDI) 40 parts；Right
Phthalic acid 25 parts；Hexamethoxymethyl melamine 10 parts；Adipic acid 35 parts；Dibutyl
30 parts of tin dilaurate stannum；M-phthalic acid 15 parts；Polyethylene Glycol 45 parts.
Weigh oligomerisation mephenesin Carbamate acrylate, ethylene glycol, Glycerin triacrylate and
Neopentyl glycol puts in reactor, is warming up to 50 DEG C, stirs 20min, adds surplus stock,
Be warming up to 70 DEG C, stir 3h, be coated on pottery, with ultra violet lamp, lamp away from 20cm,
Irradiate 15s.
Product glossiness 135%, hardness 5H, nothing foaming after immersion 36h in 5% hydrochloric acid solution,
Obscission；Water soaks at 25 DEG C 15d not elephant skin, foaming, soaks in saturated calcium hydroxide
4d is without exception for bubble；Adhesion 1 grade, impact strength 8MPa；Product scrub resistance 1900 times,
Pliability 4mm.
Embodiment 3:
Ultraviolet light polymerization polyacrylate coating used by a kind of pottery, its raw materials by weight portion proportioning
As follows: oligomerisation mephenesin Carbamate acrylate 100 parts；Ethylene glycol 25 parts；Glycerin three
Acrylate 35 parts；Neopentyl glycol 20 parts；Ethyl acrylate 50 parts；Trimethylolpropane
20 parts；Benzophenone 15 parts；30 parts of benzoic acid；Toluene di-isocyanate(TDI) 30 parts；To benzene
Dioctyl phthalate 15 parts；Hexamethoxymethyl melamine 5 parts；Adipic acid 25 parts；Dibutyl tin
20 parts of cinnamic acid stannum；M-phthalic acid 10 parts；Polyethylene Glycol 35 parts.
Weigh oligomerisation mephenesin Carbamate acrylate, ethylene glycol, Glycerin triacrylate and
Neopentyl glycol puts in reactor, is warming up to 50 DEG C, stirs 18min, adds surplus stock,
Be warming up to 70 DEG C, stir 2.5h, be coated on pottery, with ultra violet lamp, lamp away from 20cm,
Irradiate 12s.
Product glossiness 140%, hardness 6H, nothing foaming after immersion 48h in 5% hydrochloric acid solution,
Obscission；Water soaks at 25 DEG C 20d not elephant skin, foaming, soaks in saturated calcium hydroxide
6d is without exception for bubble；Adhesion 1 grade, impact strength 10MPa；Product scrub resistance 2000 times,
Pliability 5mm.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of
This any change in the implication suitable with claims of the present invention and scope, all should
It is considered to be included within the scope of the claims.
Claims (2)
1. ultraviolet light polymerization polyacrylate coating used by a pottery, it is characterised in that described pottery
The raw materials by weight portion proportioning of porcelain ultraviolet light polymerization polyacrylate coating is as follows: oligomerisation ammonia
Formic acid esters acrylate 100 parts；Ethylene glycol 20-30 part；Glycerin triacrylate
30-40 part；Neopentyl glycol 15-25 part；Ethyl acrylate 40-60 part；Trimethylolpropane
15-25 part；Photosensitizer 10-20 part；Benzoic acid 25-35 part；Toluene di-isocyanate(TDI) 20-40
Part；P-phthalic acid 5-25 part；Cross-linking agent 1-10 part；Adipic acid 15-35 part；Dibutyl
Tin dilaurate stannum 10-30 part；M-phthalic acid 5-15 part；Polyethylene Glycol 25-45 part；
Described photosensitizer uses benzoin ethyl ether or benzophenone；
Described cross-linking agent uses hexamethoxymethyl melamine or styrene.
A kind of pottery ultraviolet light polymerization polyacrylate the most according to claim 1 is coated with
Material, it is characterised in that the raw material of described pottery ultraviolet light polymerization polyacrylate coating is by weight
Number proportioning is as follows: oligomerisation mephenesin Carbamate acrylate 100 parts；Ethylene glycol 25 parts；Three hydroxyls
Base propane triacrylate 35 parts；Neopentyl glycol 20 parts；Ethyl acrylate 50 parts；Three hydroxyls
Methylpropane 20 parts；Photosensitizer 15 parts；30 parts of benzoic acid；Toluene di-isocyanate(TDI) 30 parts；
P-phthalic acid 15 parts；Cross-linking agent 5 parts；Adipic acid 25 parts；Dibutyl tin dilaurate
20 parts；M-phthalic acid 10 parts；Polyethylene Glycol 35 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430864.7A CN104151894B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet light polymerization polyacrylate coating used by a kind of pottery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430864.7A CN104151894B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet light polymerization polyacrylate coating used by a kind of pottery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104151894A CN104151894A (en) | 2014-11-19 |
| CN104151894B true CN104151894B (en) | 2016-11-30 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104693936A (en) * | 2015-03-12 | 2015-06-10 | 湖州中辰建设有限公司 | Alkali-resistant acrylic resin powder paint for new ceramics |
| CN107069600A (en) * | 2017-04-25 | 2017-08-18 | 瞿慧 | A kind of building pipe |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6974850B2 (en) * | 2003-05-30 | 2005-12-13 | 3M Innovative Properties Company | Outdoor weatherable photopolymerizable coatings |
| US7807488B2 (en) * | 2004-09-27 | 2010-10-05 | Qualcomm Mems Technologies, Inc. | Display element having filter material diffused in a substrate of the display element |
| CN103059713A (en) * | 2011-10-20 | 2013-04-24 | 珠海东诚光固化材料有限公司 | Ultraviolet light-cured self-cleaning coating, and preparation method and application thereof |
| JP6222559B2 (en) * | 2012-11-08 | 2017-11-01 | 日油株式会社 | Urethane (meth) acrylate mixture and urethane (meth) acrylate composition |
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2014
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