CN106349934B - High hardness nanocomposite ceramic resin - Google Patents
High hardness nanocomposite ceramic resin Download PDFInfo
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- CN106349934B CN106349934B CN201610737370.2A CN201610737370A CN106349934B CN 106349934 B CN106349934 B CN 106349934B CN 201610737370 A CN201610737370 A CN 201610737370A CN 106349934 B CN106349934 B CN 106349934B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of high hardness nanocomposite ceramic resin, is made of component A and B component, component A includes following raw material：95-100 parts of nano ceramics resin, 4-10 parts of nano-titanium dioxide, 4-5 parts of nano silicon dioxide, 10-12 parts of pigment, 0.8-1 parts of BYK-320,1.2-1.5 parts of BYK-161, B component include following raw material：25-30 parts of CeRam HD 1001B, 2-3 parts of blanc fixe.High hardness nanocomposite ceramic resin prepared by the present invention, environmentally protective nontoxic, environmentally safe, the two-component nano ceramics resin with excellent surface property high rigidity, high tenacity envelope, extremely excellent weatherability, the performances such as high temperature resistant, cold resistance is good.
Description
Technical field
The invention belongs to paint fields, and in particular to a kind of high hardness nanocomposite ceramic resin.
Background technology
Coating is to be coated in the body surface protected or decorated, and can form the continuous of firm attachment with coated article
Film coating, because coating is exposed in air, the effects that cold and hot variation, air oxidation, coating easily occur cracking, dusting, peeling,
Phenomena such as discoloration is that coating loses original decoration defencive function.This problem can all to the resident to live to cause to perplex, so
Collection decoration, weatherability, the multi-functional nano ceramics cold coating product in one of high temperature resistant, cold resistance should be developed.
Invention content
The purpose of the present invention is to provide a kind of high hardness nanocomposite ceramic resins, solve nano ceramics cold coating and are easy
The problem of cracking, dusting, peeling, discoloration.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of high hardness nanocomposite ceramic resin, is made of component A and B component, and component A includes following raw material：It receives
95-100 parts of ceramic resin of rice, 4-10 parts of nano-titanium dioxide, 4-5 parts of nano silicon dioxide, 10-12 parts of pigment, BYK-320
0.8-1 parts, 1.2-1.5 parts of BYK-161, B component include following raw material：25-30 parts of CeRam HD 1001B, precipitation
The weight ratio of 2-3 parts of barium sulfate, component A and B component is 9:1.
Preferably, a kind of high hardness nanocomposite ceramic resin is made of component A and B component, and component A includes that following parts by weight are former
Material：97 parts of nano ceramics resin, 7 parts of nano-titanium dioxide, 5 parts of nano silicon dioxide, 11 parts of pigment, 0.9 part of BYK-320,
1.3 parts of BYK-161, B component include following raw material：27 parts of CeRam HD 1001B, 3 parts of blanc fixe.
The advantage of the invention is that：High hardness nanocomposite ceramic resin prepared by the present invention, it is environmentally protective nontoxic, to environment without
Pollution, the two-component nano ceramics resin with excellent surface property high rigidity, high tenacity envelope, extremely excellent weatherability,
The performances such as high temperature resistant, cold resistance is good.
Specific implementation mode
Embodiment 1
A kind of high hardness nanocomposite ceramic resin, is made of component A and B component, and component A includes following raw material：It receives
97 parts of ceramic resin of rice, 7 parts of nano-titanium dioxide, 5 parts of nano silicon dioxide, 11 parts of pigment, 0.9 part of BYK-320, BYK-161
1.3 parts, B component includes following raw material：27 parts of CeRam HD 1001B, 3 parts of blanc fixe.Component A and B component
Weight ratio be 9:1.It prepares according to a conventional method.
Hardness is 6H after the resin solidification of the present invention, and adhesive force experiment is 0 grade, wearability experiment（0.5g/r）/mg：
5.0, shock resistance experiment：50cm, water resistance experiment（600h）：It is without exception, resistance to boiling water experiment（100℃≥ 24h）：Not loss of gloss, no
Blistering allows slight change, resilient, alcohol resistance experiment（Soaked in absolute ethyl alcohol is for 24 hours）：It is without exception, salt fog resistance experiment
（12h）：It is unchanged, artificial ageing resistance experiment：3000h is not blistering, does not peel off, flawless.
Embodiment 2
A kind of high hardness nanocomposite ceramic resin, is made of component A and B component, and component A includes following raw material：It receives
95 parts of ceramic resin of rice, 4 parts of nano-titanium dioxide, 4 parts of nano silicon dioxide, 10 parts of pigment, 0.8 part of BYK-320, BYK-161
1.2 parts, B component includes following raw material：25 parts of CeRam HD 1001B, 2 parts of blanc fixe, component A and B component
Weight ratio be 9:1.It prepares according to a conventional method.
Hardness is 5H after the resin solidification of the present invention, and adhesive force experiment is 0 grade, wearability experiment（0.5g/r）/mg：
5.0, shock resistance experiment：50cm, water resistance experiment（600h）：It is without exception, resistance to boiling water experiment（100℃≥ 24h）：Not loss of gloss, no
Blistering allows slight change, resilient, alcohol resistance experiment（Soaked in absolute ethyl alcohol is for 24 hours）：It is without exception, salt fog resistance experiment
（12h）：It is unchanged, artificial ageing resistance experiment：2900h is not blistering, does not peel off, flawless.
Embodiment 3
A kind of high hardness nanocomposite ceramic resin, is made of component A and B component, and component A includes following raw material：It receives
100 parts of ceramic resin of rice, 10 parts of nano-titanium dioxide, 5 parts of nano silicon dioxide, 12 parts of pigment, 1 part of BYK-320, BYK-161
1.5 parts, B component includes following raw material：30 parts of CeRam HD 1001B, 3 parts of blanc fixe, component A and B component
Weight ratio be 9:1.It prepares according to a conventional method.
Hardness is 5H after the resin solidification of the present invention, and adhesive force experiment is 0 grade, wearability experiment（0.5g/r）/mg：
5.0, shock resistance experiment：50cm, water resistance experiment（600h）：It is without exception, resistance to boiling water experiment（100℃≥ 24h）：Not loss of gloss, no
Blistering allows slight change, resilient, alcohol resistance experiment（Soaked in absolute ethyl alcohol is for 24 hours）：It is without exception, salt fog resistance experiment
（12h）：It is unchanged, artificial ageing resistance experiment：2900h is not blistering, does not peel off, flawless.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification should all belong to the covering scope of the present invention.
Claims (2)
1. a kind of high hardness nanocomposite ceramic resin, it is characterised in that：It is made of component A and B component, component A includes following weight
Part raw material：95-100 parts of nano ceramics resin, 4-10 parts of nano-titanium dioxide, 4-5 parts of nano silicon dioxide, 10-12 parts of pigment,
0.8-1 parts of BYK-320,1.2-1.5 parts of BYK-161, B component include following raw material：CeRam HD 1001B 25-
The weight ratio of 30 parts, 2-3 parts of blanc fixe, component A and B component is 9:1.
2. a kind of high hardness nanocomposite ceramic resin according to claim 1, it is characterised in that：By component A and B component group
At component A includes following raw material：97 parts of nano ceramics resin, 7 parts of nano-titanium dioxide, 5 parts of nano silicon dioxide,
11 parts of pigment, 0.9 part of BYK-320,1.3 parts of BYK-161, B component include following raw material：CeRam HD 1001B
27 parts, 3 parts of blanc fixe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737370.2A CN106349934B (en) | 2016-08-29 | 2016-08-29 | High hardness nanocomposite ceramic resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737370.2A CN106349934B (en) | 2016-08-29 | 2016-08-29 | High hardness nanocomposite ceramic resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106349934A CN106349934A (en) | 2017-01-25 |
| CN106349934B true CN106349934B (en) | 2018-10-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610737370.2A Active CN106349934B (en) | 2016-08-29 | 2016-08-29 | High hardness nanocomposite ceramic resin |
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| CN (1) | CN106349934B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286811A (en) * | 2017-08-01 | 2017-10-24 | 福州皇家地坪有限公司 | Pseudo-classic terrace |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4117570B2 (en) * | 2005-01-28 | 2008-07-16 | 東洋紡績株式会社 | Optically easy-adhesive polyester film and optical laminated polyester film |
| CN104356826A (en) * | 2014-11-14 | 2015-02-18 | 珠海市澜诺新材料科技有限公司 | Surface self-cleaning coating and preparation method thereof |
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2016
- 2016-08-29 CN CN201610737370.2A patent/CN106349934B/en active Active
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| Publication number | Publication date |
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| CN106349934A (en) | 2017-01-25 |
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| CB03 | Change of inventor or designer information |
Inventor after: Chen Zunhou Inventor after: Chen Liang Inventor after: Xie Guixiu Inventor after: Miao Jiancheng Inventor before: Chen Zhoufei Inventor before: Zheng Hongfang Inventor before: Miao Jiancheng Inventor before: Xie Guixiu |
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Effective date of registration: 20200518 Address after: 710000 Standard Factory Building No. 1, Incubator No. 5, Lantian Road, Xi'an Airline Base, Shaanxi Province-2 Patentee after: XI'AN RUISEN NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: Fuqing City, Fuzhou City, Fujian Province, Yang Dang street 350300 No. 2 bucket Patentee before: FUZHOU ROYAL FLOOR Co.,Ltd. |