CN104151895B - A kind of pottery polyacrylate coating - Google Patents
A kind of pottery polyacrylate coating Download PDFInfo
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- CN104151895B CN104151895B CN201410430865.1A CN201410430865A CN104151895B CN 104151895 B CN104151895 B CN 104151895B CN 201410430865 A CN201410430865 A CN 201410430865A CN 104151895 B CN104151895 B CN 104151895B
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Abstract
The present invention discloses a kind of pottery polyacrylate coating, and raw material is: Hydroxyethyl acrylate, titanium dioxide, Resorcinol, wilkinite, toluene, polyvinyl alcohol, photosensitizers, zinc sulfide white, tosic acid, light calcium carbonate, catalyzer, talcum powder, 5% sodium hydroxide, carboxymethyl cellulose and anhydrous magnesium sulfate; Product glossiness 120%-140%, hardness 4-7H, shock strength 5-6MPa; Time of drying, 10-15s, soaked 24-48h without exception in 5% hydrochloric acid soln; Water soaks 5-10d without foaming, obscission, in saturated calcium hydroxide, soak that 3-6d is non-foaming, elephant skin; Product snappiness 4-5mm, resistance to 130-150 DEG C of high temperature.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery polyacrylate coating.
Background technology
Reform and open up to the outside world over 30 years, Chinese pottery industrial boom, nowadays become qualified in the world Production of Ceramics big country, consumption big country. The domestic ceramics output of domestic product accounts for about the 70% of the whole world, and display art ceramic yield is the 65% of the whole world, and architectural pottery output also accounts for Gross World Product half of the country. China industry occupies very important status in world's building material industry. All belong to its scope to the meticulousst fine pottery and porcelain by the most coarse native device. Main raw material for it is the silicate minerals (such as clay, quartz etc.) taking from nature, therefore with industry such as glass, toluene mud, enamel, refractory materialss, belongs to the category of " silicate industry ". Up to now, pottery define like can be described as follows with summarizing: pottery is main raw material with aluminium silicate mineral or some oxide compound etc., the technique rock with a shaping type at high temperature made with certain temperature and atmosphere by specific physical and chemical process according to the intention of people. Surface can glazing or not glazing, some porcelain matter also has translucency in various degree, entire body by one or more crystal or with amorphous cementing matter and pore or form with microtextures such as grog inclusions.
Coating (paint), our usual said paint is one wherein. Refer to coat body surface to form film under certain conditions and play protection, the class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material. It is main raw material mainly with vegetables oil greatly because of early stage coating, therefore also known as painting. Instead of vegetables oil at synthetic resins, therefore it is called coating. Founding of New, over 60 years, with the development of national economy every profession and trade, progressively develops into the essential important industry in each field of national economy as its supporting coatings industry from an extremely unobtrusive little industry. Through the struggling hard of several generations, pioneering and keeping forging ahead, China has become second-biggest-in-the-world coating material production state and consumption state, enters into the main flow of world's coating industry development.
Ceramic coating is that one can make organism and inorganics react, thus has had both the novel ceramic coating of both advantages. The hardness of the ceramic coating of a new generation can reach more than 6H. High temperature resistant 400 degree, not sticky effect, color is multiple. And toluene ceramic coating can be made. Ceramic coating weathering resistance and processing characteristics are excellent, resistance to dirty and resistant to damage. Although conventional ceramic coating resistant to damage, but if the parts after application are carried out bending machining, it is easy to produce crackle, and fluorine resin paints and organic coating, it is easy to damaged by sandstone, dust etc. Therefore, the appearance of ceramic coating, receives the favor of ceramic industry, and just to other industry infiltration, prospect is had an optimistic view of. And popularizing along with humanity concept, and the formation of novel harmonious society, the pottery polyacrylate coating designing a kind of Heat stability is good, shock strength height, solvent resistant and snappiness good is very important.
Summary of the invention
The technical problem solved:
The application is for above-mentioned technical problem, it is provided that a kind of pottery polyacrylate coating, solves that existing pottery polyacrylate coating thermostability, hardness are low, not solvent resistant and the technical problem such as snappiness is poor.
Technical scheme:
A kind of pottery polyacrylate coating, the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 25-35 part; Resorcinol 5-15 part; Wilkinite 35-45 part; Toluene 80-100 part; Polyvinyl alcohol 15-25 part; Photosensitizers 1-10 part; Zinc sulfide white 10-30 part; Tosic acid 10-20 part; Light calcium carbonate 25-35 part; Catalyzer 3-5 part; Talcum powder 10-20 part; 5% sodium hydroxide 20-30 part; Carboxymethyl cellulose 2-8 part; Anhydrous magnesium sulfate 1-3 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 30 parts; Resorcinol 10 parts; Wilkinite 40 parts; Toluene 90 parts; Polyvinyl alcohol 20 parts; Photosensitizers 5 parts; 20 parts, zinc sulfide white; Tosic acid 15 parts; Light calcium carbonate 30 parts; Catalyzer 4 parts; Talcum powder 15 parts; 5% 25 parts, sodium hydroxide; Carboxymethyl cellulose 5 parts; Anhydrous magnesium sulfate 2 parts.
As a preferred technical solution of the present invention: described photosensitizers adopts Benzoin ethyl ether or benzophenone.
As a preferred technical solution of the present invention: described catalyzer adopts quarternary ammonium salt.
Useful effect:
A kind of pottery polyacrylate coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product glossiness 120%-140%, hardness 4-7H, shock strength 5-6MPa; 2,10-15s time of drying, soaks 24-48h without exception in 5% hydrochloric acid soln; 3, water soak 5-10d without foaming, obscission, in saturated calcium hydroxide, soak that 3-6d is non-foaming, elephant skin; 4, product snappiness 4-5mm, resistance to 130-150 DEG C of high temperature, it is possible to the widespread production not division of history into periods is for current material.
Embodiment
Embodiment 1:
A kind of pottery polyacrylate coating, its raw materials by weight portion proportioning is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 25 parts; Resorcinol 5 parts; Wilkinite 35 parts; Toluene 80 parts; Polyvinyl alcohol 15 parts; Benzoin ethyl ether 1 part; 10 parts, zinc sulfide white; Tosic acid 10 parts; Light calcium carbonate 25 parts;Quarternary ammonium salt 3 parts; Talcum powder 10 parts; 5% 20 parts, sodium hydroxide; Carboxymethyl cellulose 2 parts; Anhydrous magnesium sulfate 1 part.
After above-mentioned raw materials is mixed 2h in a kettle., it is coated on pottery, film uviolizing.
Product glossiness 120%, hardness 4H, shock strength 5MPa; Time of drying, 15s, soaked 24h without exception in 5% hydrochloric acid soln; Water soaks 5d without foaming, obscission, in saturated calcium hydroxide, soak that 3d is non-foaming, elephant skin; Product snappiness 4mm, resistance to 130 DEG C of high temperature.
Embodiment 2:
A kind of pottery polyacrylate coating, its raw materials by weight portion proportioning is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 35 parts; Resorcinol 15 parts; Wilkinite 45 parts; Toluene 100 parts; Polyvinyl alcohol 25 parts; Benzophenone 10 parts; 30 parts, zinc sulfide white; Tosic acid 20 parts; Light calcium carbonate 35 parts; Quarternary ammonium salt 5 parts; Talcum powder 20 parts; 5% 30 parts, sodium hydroxide; Carboxymethyl cellulose 8 parts; Anhydrous magnesium sulfate 3 parts.
After above-mentioned raw materials is mixed 4h in a kettle., it is coated on pottery, film uviolizing.
Product glossiness 130%, hardness 6H, shock strength 5MPa; Time of drying, 12s, soaked 36h without exception in 5% hydrochloric acid soln; Water soaks 8d without foaming, obscission, in saturated calcium hydroxide, soak that 4d is non-foaming, elephant skin; Product snappiness 4mm, resistance to 140 DEG C of high temperature.
Embodiment 3:
A kind of pottery polyacrylate coating, its raw materials by weight portion proportioning is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 30 parts; Resorcinol 10 parts; Wilkinite 40 parts; Toluene 90 parts; Polyvinyl alcohol 20 parts; Benzophenone 5 parts; 20 parts, zinc sulfide white; Tosic acid 15 parts; Light calcium carbonate 30 parts; Quarternary ammonium salt 4 parts; Talcum powder 15 parts; 5% 25 parts, sodium hydroxide; Carboxymethyl cellulose 5 parts; Anhydrous magnesium sulfate 2 parts.
After above-mentioned raw materials is mixed 3h in a kettle., it is coated on pottery, film uviolizing.
Product glossiness 140%, hardness 7H, shock strength 6MPa; Time of drying, 10s, soaked 48h without exception in 5% hydrochloric acid soln; Water soaks 10d without foaming, obscission, in saturated calcium hydroxide, soak that 6d is non-foaming, elephant skin; Product snappiness 5mm, resistance to 150 DEG C of high temperature.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth the content of the present invention, instead of restriction, and the therefore any change in the implication suitable with the claim book of the present invention and scope, all it is believed that be included in the scope of claim book.
Claims (4)
1. a pottery polyacrylate coating, it is characterised in that the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts; Titanium dioxide 25-35 part; Resorcinol 5-15 part; Wilkinite 35-45 part; Toluene 80-100 part; Polyvinyl alcohol 15-25 part; Photosensitizers 1-10 part; Zinc sulfide white 10-30 part; Tosic acid 10-20 part; Light calcium carbonate 25-35 part; Catalyzer 3-5 part; Talcum powder 10-20 part; 5% sodium hydroxide 20-30 part; Carboxymethyl cellulose 2-8 part; Anhydrous magnesium sulfate 1-3 part.
2. a kind of pottery polyacrylate coating according to claim 1, it is characterised in that the raw materials by weight portion proportioning of described pottery polyacrylate coating is as follows: Hydroxyethyl acrylate 100 parts;Titanium dioxide 30 parts; Resorcinol 10 parts; Wilkinite 40 parts; Toluene 90 parts; Polyvinyl alcohol 20 parts; Photosensitizers 5 parts; 20 parts, zinc sulfide white; Tosic acid 15 parts; Light calcium carbonate 30 parts; Catalyzer 4 parts; Talcum powder 15 parts; 5% 25 parts, sodium hydroxide; Carboxymethyl cellulose 5 parts; Anhydrous magnesium sulfate 2 parts.
3. a kind of pottery polyacrylate coating according to claim 1, it is characterised in that: described photosensitizers adopts Benzoin ethyl ether or benzophenone.
4. a kind of pottery polyacrylate coating according to claim 1, it is characterised in that: described catalyzer adopts quarternary ammonium salt.
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CN201410430865.1A CN104151895B (en) | 2014-08-28 | 2014-08-28 | A kind of pottery polyacrylate coating |
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CN201410430865.1A CN104151895B (en) | 2014-08-28 | 2014-08-28 | A kind of pottery polyacrylate coating |
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CN104151895B true CN104151895B (en) | 2016-06-15 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63265980A (en) * | 1987-04-22 | 1988-11-02 | Toyobo Co Ltd | Ultraviolet-curable ink composition |
CN1486960A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet light cured ceramic paint |
CN103305116A (en) * | 2013-06-17 | 2013-09-18 | 武汉绿凯科技有限公司 | Photo-curing transparency-increased film coating solution as well as preparation method and application thereof |
CN103396689A (en) * | 2013-08-01 | 2013-11-20 | 苏州市明大高分子科技材料有限公司 | LED-UV light source curable coating and preparation method |
CN103937377A (en) * | 2013-01-21 | 2014-07-23 | 上海参爱贸易有限公司 | Low gloss ultraviolet curing coating |
-
2014
- 2014-08-28 CN CN201410430865.1A patent/CN104151895B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63265980A (en) * | 1987-04-22 | 1988-11-02 | Toyobo Co Ltd | Ultraviolet-curable ink composition |
CN1486960A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet light cured ceramic paint |
CN103937377A (en) * | 2013-01-21 | 2014-07-23 | 上海参爱贸易有限公司 | Low gloss ultraviolet curing coating |
CN103305116A (en) * | 2013-06-17 | 2013-09-18 | 武汉绿凯科技有限公司 | Photo-curing transparency-increased film coating solution as well as preparation method and application thereof |
CN103396689A (en) * | 2013-08-01 | 2013-11-20 | 苏州市明大高分子科技材料有限公司 | LED-UV light source curable coating and preparation method |
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Effective date of registration: 20201222 Address after: 224006 room 109, no.1572, Luming Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province Patentee after: Yancheng Yanlong water Co., Ltd Address before: Room 4722, Tianlong building, no.378, Zhujiang South Road, Mudu Town, Wuzhong District, Suzhou City, Jiangsu Province Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |