CN102446728A - 绝缘膜的改性方法 - Google Patents
绝缘膜的改性方法 Download PDFInfo
- Publication number
- CN102446728A CN102446728A CN2011103036957A CN201110303695A CN102446728A CN 102446728 A CN102446728 A CN 102446728A CN 2011103036957 A CN2011103036957 A CN 2011103036957A CN 201110303695 A CN201110303695 A CN 201110303695A CN 102446728 A CN102446728 A CN 102446728A
- Authority
- CN
- China
- Prior art keywords
- plasma
- film
- silicon nitride
- modifying
- oxidized silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 214
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 243
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 150
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 150
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 124
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 90
- 230000003647 oxidation Effects 0.000 claims abstract description 88
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims description 167
- 238000012545 processing Methods 0.000 claims description 124
- 239000007789 gas Substances 0.000 claims description 119
- 238000000137 annealing Methods 0.000 claims description 96
- 230000001590 oxidative effect Effects 0.000 claims description 55
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 32
- 239000001301 oxygen Substances 0.000 claims description 32
- 230000008676 import Effects 0.000 claims description 11
- 230000009467 reduction Effects 0.000 abstract description 3
- 235000012431 wafers Nutrition 0.000 description 109
- 230000004048 modification Effects 0.000 description 28
- 238000012986 modification Methods 0.000 description 28
- 238000010438 heat treatment Methods 0.000 description 21
- 238000010586 diagram Methods 0.000 description 18
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 15
- 230000005855 radiation Effects 0.000 description 15
- 229910052710 silicon Inorganic materials 0.000 description 15
- 239000010703 silicon Substances 0.000 description 15
- 239000000758 substrate Substances 0.000 description 13
- 238000002834 transmittance Methods 0.000 description 13
- 229910052721 tungsten Inorganic materials 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 11
- 239000010937 tungsten Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 239000010453 quartz Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 description 9
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 9
- 229910007991 Si-N Inorganic materials 0.000 description 8
- 229910006294 Si—N Inorganic materials 0.000 description 8
- 239000004065 semiconductor Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 229910018557 Si O Inorganic materials 0.000 description 6
- 230000033228 biological regulation Effects 0.000 description 6
- 238000010304 firing Methods 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 125000004430 oxygen atom Chemical group O* 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000010718 Oxidation Activity Effects 0.000 description 1
- 229920006361 Polyflon Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 230000028016 temperature homeostasis Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02318—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment
- H01L21/02321—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer
- H01L21/02329—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer introduction of nitrogen
- H01L21/02332—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer introduction of nitrogen into an oxide layer, e.g. changing SiO to SiON
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02318—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment
- H01L21/02337—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment treatment by exposure to a gas or vapour
- H01L21/0234—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment treatment by exposure to a gas or vapour treatment by exposure to a plasma
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
- H01L21/28167—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation
- H01L21/28202—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation in a nitrogen-containing ambient, e.g. nitride deposition, growth, oxynitridation, NH3 nitridation, N2O oxidation, thermal nitridation, RTN, plasma nitridation, RPN
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Plasma & Fusion (AREA)
- Formation Of Insulating Films (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010-221269 | 2010-09-30 | ||
JP2010221269A JP2012079785A (ja) | 2010-09-30 | 2010-09-30 | 絶縁膜の改質方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN102446728A true CN102446728A (zh) | 2012-05-09 |
Family
ID=46009127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2011103036957A Pending CN102446728A (zh) | 2010-09-30 | 2011-09-29 | 绝缘膜的改性方法 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP2012079785A (ko) |
KR (1) | KR101270875B1 (ko) |
CN (1) | CN102446728A (ko) |
TW (1) | TW201234480A (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109690268A (zh) * | 2016-09-08 | 2019-04-26 | 庄信万丰股份有限公司 | 方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6040609B2 (ja) * | 2012-07-20 | 2016-12-07 | 東京エレクトロン株式会社 | 成膜装置及び成膜方法 |
US11450578B2 (en) * | 2018-04-27 | 2022-09-20 | Tokyo Electron Limited | Substrate processing system and substrate processing method |
EP3832697B1 (en) * | 2018-08-02 | 2023-06-07 | Fuji Corporation | Atmospheric-pressure plasma generator |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040185676A1 (en) * | 2003-01-31 | 2004-09-23 | Nec Electronics Corporation | Semiconductor device and method of manufacturing semiconductor device |
JP2005235792A (ja) * | 2002-02-27 | 2005-09-02 | Tokyo Electron Ltd | 基板処理方法 |
US20080000551A1 (en) * | 2004-11-04 | 2008-01-03 | Tokyo Electron Limited | Insulating Film Forming Method and Substrate Processing Method |
US20080233692A1 (en) * | 2007-03-22 | 2008-09-25 | Semiconductor Manufacturing International (Shanghai) Corporation | Method and System for Forming a Controllable Gate Oxide |
US20090053905A1 (en) * | 2007-08-20 | 2009-02-26 | Hynix Semiconductor Inc. | Method of forming dielectric layer of semiconductor memory device |
CN101416286A (zh) * | 2006-04-03 | 2009-04-22 | 应用材料股份有限公司 | 以多退火步骤形成氮氧化硅栅极介电层的方法 |
JP2010021378A (ja) * | 2008-07-11 | 2010-01-28 | Tokyo Electron Ltd | シリコン酸窒化膜の形成方法および形成装置 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7501352B2 (en) * | 2005-03-30 | 2009-03-10 | Tokyo Electron, Ltd. | Method and system for forming an oxynitride layer |
US7429538B2 (en) * | 2005-06-27 | 2008-09-30 | Applied Materials, Inc. | Manufacturing method for two-step post nitridation annealing of plasma nitrided gate dielectric |
WO2008081724A1 (ja) * | 2006-12-28 | 2008-07-10 | Tokyo Electron Limited | 絶縁膜の形成方法および半導体装置の製造方法 |
JP5425404B2 (ja) * | 2008-01-18 | 2014-02-26 | 東京エレクトロン株式会社 | アモルファスカーボン膜の処理方法およびそれを用いた半導体装置の製造方法 |
KR20090080606A (ko) * | 2008-01-22 | 2009-07-27 | 주식회사 하이닉스반도체 | 플래시 메모리 소자의 제조 방법 |
KR20100012482A (ko) * | 2008-07-29 | 2010-02-08 | 주식회사 하이닉스반도체 | 플래시 메모리 소자의 터널 절연막 형성 방법 |
-
2010
- 2010-09-30 JP JP2010221269A patent/JP2012079785A/ja active Pending
-
2011
- 2011-09-28 TW TW100135001A patent/TW201234480A/zh unknown
- 2011-09-29 CN CN2011103036957A patent/CN102446728A/zh active Pending
- 2011-09-29 KR KR1020110098798A patent/KR101270875B1/ko not_active IP Right Cessation
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005235792A (ja) * | 2002-02-27 | 2005-09-02 | Tokyo Electron Ltd | 基板処理方法 |
US20040185676A1 (en) * | 2003-01-31 | 2004-09-23 | Nec Electronics Corporation | Semiconductor device and method of manufacturing semiconductor device |
US20080000551A1 (en) * | 2004-11-04 | 2008-01-03 | Tokyo Electron Limited | Insulating Film Forming Method and Substrate Processing Method |
CN101416286A (zh) * | 2006-04-03 | 2009-04-22 | 应用材料股份有限公司 | 以多退火步骤形成氮氧化硅栅极介电层的方法 |
US20080233692A1 (en) * | 2007-03-22 | 2008-09-25 | Semiconductor Manufacturing International (Shanghai) Corporation | Method and System for Forming a Controllable Gate Oxide |
US20090053905A1 (en) * | 2007-08-20 | 2009-02-26 | Hynix Semiconductor Inc. | Method of forming dielectric layer of semiconductor memory device |
JP2010021378A (ja) * | 2008-07-11 | 2010-01-28 | Tokyo Electron Ltd | シリコン酸窒化膜の形成方法および形成装置 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109690268A (zh) * | 2016-09-08 | 2019-04-26 | 庄信万丰股份有限公司 | 方法 |
Also Published As
Publication number | Publication date |
---|---|
KR20120034016A (ko) | 2012-04-09 |
JP2012079785A (ja) | 2012-04-19 |
TW201234480A (en) | 2012-08-16 |
KR101270875B1 (ko) | 2013-06-05 |
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Application publication date: 20120509 |