WO2022196392A1 - Composition de résine pour substrat de film de découpage en dés, substrat de film de découpage en dés et film de découpage en dés - Google Patents
Composition de résine pour substrat de film de découpage en dés, substrat de film de découpage en dés et film de découpage en dés Download PDFInfo
- Publication number
- WO2022196392A1 WO2022196392A1 PCT/JP2022/009398 JP2022009398W WO2022196392A1 WO 2022196392 A1 WO2022196392 A1 WO 2022196392A1 JP 2022009398 W JP2022009398 W JP 2022009398W WO 2022196392 A1 WO2022196392 A1 WO 2022196392A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dicing film
- resin composition
- film substrate
- styrene
- unsaturated carboxylic
- Prior art date
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 107
- 239000000758 substrate Substances 0.000 title claims abstract description 97
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 138
- 229920005989 resin Polymers 0.000 claims abstract description 61
- 239000011347 resin Substances 0.000 claims abstract description 61
- 229920001577 copolymer Polymers 0.000 claims abstract description 59
- 229920000554 ionomer Polymers 0.000 claims abstract description 59
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000005977 Ethylene Substances 0.000 claims abstract description 58
- 239000004952 Polyamide Substances 0.000 claims abstract description 41
- 229920002647 polyamide Polymers 0.000 claims abstract description 41
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 32
- 239000010410 layer Substances 0.000 claims description 53
- 229920001971 elastomer Polymers 0.000 claims description 27
- 239000000806 elastomer Substances 0.000 claims description 23
- 239000012790 adhesive layer Substances 0.000 claims description 17
- 238000006386 neutralization reaction Methods 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 7
- 239000000470 constituent Substances 0.000 claims description 4
- -1 primary amine compounds Chemical class 0.000 description 29
- 239000000463 material Substances 0.000 description 26
- 239000002585 base Substances 0.000 description 21
- 238000000034 method Methods 0.000 description 21
- 229920005604 random copolymer Polymers 0.000 description 20
- 239000000853 adhesive Substances 0.000 description 19
- 230000001070 adhesive effect Effects 0.000 description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 16
- 239000000178 monomer Substances 0.000 description 14
- 239000002253 acid Substances 0.000 description 12
- 229920001400 block copolymer Polymers 0.000 description 12
- 229920006132 styrene block copolymer Polymers 0.000 description 11
- 125000002947 alkylene group Chemical group 0.000 description 8
- 239000002216 antistatic agent Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- 150000003440 styrenes Chemical class 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 150000001733 carboxylic acid esters Chemical class 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 229920001890 Novodur Polymers 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 3
- 229920000305 Nylon 6,10 Polymers 0.000 description 3
- 229920000572 Nylon 6/12 Polymers 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 150000002148 esters Chemical group 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- 229920003189 Nylon 4,6 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- ZMUCVNSKULGPQG-UHFFFAOYSA-N dodecanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCCCC(O)=O ZMUCVNSKULGPQG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
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- GJZFGDYLJLCGHT-UHFFFAOYSA-N 1,2-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=C(CC)C(CC)=CC=C3SC2=C1 GJZFGDYLJLCGHT-UHFFFAOYSA-N 0.000 description 1
- UYEDESPZQLZMCL-UHFFFAOYSA-N 1,2-dimethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=C(C)C(C)=CC=C3SC2=C1 UYEDESPZQLZMCL-UHFFFAOYSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
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- CTOHEPRICOKHIV-UHFFFAOYSA-N 1-dodecylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCCCCCCCCCCC CTOHEPRICOKHIV-UHFFFAOYSA-N 0.000 description 1
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- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
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- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- HSOOVEKLGOIEFF-UHFFFAOYSA-N ethenyl nitrate Chemical compound [O-][N+](=O)OC=C HSOOVEKLGOIEFF-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- VEWLDLAARDMXSB-UHFFFAOYSA-N ethenyl sulfate;hydron Chemical compound OS(=O)(=O)OC=C VEWLDLAARDMXSB-UHFFFAOYSA-N 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 229920005674 ethylene-propylene random copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical class FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 1
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical compound NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 description 1
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229910001419 rubidium ion Inorganic materials 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0869—Acids or derivatives thereof
- C09J123/0876—Neutralised polymers, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
Definitions
- the present invention relates to a resin composition for a dicing film substrate, a dicing film substrate, and a dicing film.
- Patent Literature 1 describes a radiation-curable adhesive tape for wafer processing containing an antistatic resin containing a polyether component and the ionomer.
- Patent Document 2 describes a resin composition for a dicing film substrate containing the ionomer, ethylene, (meth)acrylic acid, and a copolymer of (meth)acrylic acid alkyl ester.
- the dicing film around the chips stretches sufficiently (hereinafter also referred to as "normal temperature elongation"). If the dicing film is not stretched sufficiently and a plurality of chips are pushed up by the fine pins, a phenomenon may occur in which chips that are not to be picked up are separated from the dicing film. In addition, if the dicing film has low elongation at room temperature, stress may be applied to the chip during the pick-up process, which may cause breakage within the chip. When these problems occur, the product yield decreases and product defects increase.
- a resin composition containing an ionomer (A), a polyamide (B), and a styrenic resin (C) has good compatibility, and the characteristics of each material can be improved without reducing the homogeneity. It is possible to maintain Each component contained in the resin composition will be described below, and then the physical properties of the resin composition will be described.
- the ionomer (A) of the ethylene/unsaturated carboxylic acid copolymer (hereinafter also simply referred to as "ionomer (A)" is an ethylene/unsaturated carboxylic acid copolymer in which part or all of the acid is a metal ion and has a structure in which a plurality of ethylene-unsaturated carboxylic acid copolymers are crosslinked.
- the resin composition may contain only one ionomer (A), or may contain two or more kinds of ionomers (A). You can stay.
- the ethylene/unsaturated carboxylic acid-based copolymer may be a block copolymer or a random copolymer.
- the ethylene/unsaturated carboxylic acid-based copolymer may also be a graft copolymer obtained by graft-polymerizing a known compound to a random polymer or block polymer.
- unsaturated carboxylic acid esters include unsaturated carboxylic acid alkyl esters having an alkyl group having 1 to 12 carbon atoms in the ester moiety. The number of carbon atoms in the alkyl group is more preferably 1-8, more preferably 1-4.
- alkyl groups include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, 2-ethylhexyl, isooctyl groups and the like.
- ethylene/unsaturated carboxylic acid copolymer examples include binary copolymers such as ethylene/acrylic acid copolymer and ethylene/methacrylic acid copolymer; ethylene/methacrylic acid/acrylic acid Terpolymers such as n-butyl copolymers and ethylene/methacrylic acid/isobutyl acrylate copolymers;
- the ionomer (A) of the present invention is obtained by cross-linking (neutralizing) the carboxyl groups contained in the ethylene/unsaturated carboxylic acid copolymer with metal ions at an arbitrary ratio.
- the amount of structural units derived from other monomers is preferably 1% by mass or more and 20% by mass or less, more preferably 5% by mass or more and 15% by mass or less, relative to all the structural units of the unsaturated carboxylic acid-based copolymer.
- the amount of structural units derived from other monomers is 1% by mass or more, elongation when the resin composition is used as a base material for a dicing film tends to be good.
- the amount of structural units derived from other monomers is 20% by mass or less
- the base material is difficult to block, and fusion and the like are also likely to occur. Hard to come by.
- the content of the ionomer (A) in the resin composition is 30 parts by mass with respect to a total of 100 parts by mass of the ionomer (A), the polyamide (B) described later, and the styrene resin (C) described later.
- 95 mass parts or less is preferable, 40 mass parts or more and 90 mass parts or less are preferable, and 45 mass parts or more and 90 mass parts or less are more preferable.
- the amount of the ionomer (A) is 30 parts by mass or more, the elongation at room temperature and the elongation at low temperature of the substrate obtained from the resin composition are improved.
- the amount of the ionomer (A) is 95 parts by mass or less, the amounts of the polyamide (B) and the styrene resin (C) are relatively large enough, and the substrate obtained from the resin composition And the modulus strength at low temperature and the elongation at normal temperature and low temperature are improved.
- Polyamide (B) may be a resin containing two or more amide groups.
- the ionomer (A) described above tends to have a low melting point and low heat resistance. The heat resistance of the substrate for the dicing film becomes very good. Further, when the ionomer (A) and the polyamide (B) are combined, good modulus strength and severability can be obtained when the resin composition is used as a base material for a dicing film.
- the melting point of the polyamide (B) is preferably 160°C or higher and 250°C or lower, more preferably 170°C or higher and 240°C or lower, and even more preferably 180°C or higher and 235°C or lower.
- the melting point of the polyamide (B) is measured, for example, by a differential scanning calorimeter (DSC) or the like.
- styrene-based elastomers examples include block copolymers containing a hard segment composed of a styrene block (styrene polymer) and a soft segment composed of an alkylene block, or hydrogenated products thereof; random copolymers of styrene and alkylene; A polymer or a hydrogenated product thereof; or an acid-modified styrene-based elastomer obtained by acid-modifying the styrene-based elastomer.
- styrene-based elastomers include block copolymers containing a hard segment composed of a styrene block (styrene polymer) and a soft segment composed of an alkylene block, or hydrogenated products thereof; random copolymers of styrene and alkylene; A polymer or a hydrogenated product thereof; or an acid-modified styrene-based elastomer obtained by acid-modifying the st
- examples of styrene-based elastomers include random copolymers of styrene and alkylene. Examples include styrene-butadiene random copolymers, styrene-isoprene random copolymers, styrene-ethylene-butylene random copolymers, styrene-ethylene-propylene random copolymers, styrene-isobutylene random copolymers, styrene - including ethylene-isoprene random copolymers.
- the acid-modified styrene-based elastomer can be obtained by graft-polymerizing the block copolymer, random copolymer, or the like with an unsaturated carboxylic acid or a derivative thereof in the presence of a radical initiator.
- a radical initiator Any known radical initiator can be used as long as it is used for the graft reaction of polyolefins.
- UV absorbers examples include benzophenone-based, benzoate-based, benzotriazole-based, cyanoacrylate-based, hindered amine-based, and the like.
- additives are appropriately selected according to their type.
- the melt flow rate of the resin composition measured at 230°C and a load of 2160 g is 0.1 g/10 min or more and 30 g/10 min or less. is preferred, 0.2 g/10 min or more and 15 g/10 min or less is more preferred, 0.5 g/10 min or more and 10 g/10 min or less is even more preferred, and 1.0 g/10 min or more and 7 g/10 min or less is even more preferred.
- the melt flow rate of the resin composition is within this range, the modulus strength at room temperature and low temperature and the elongation at room temperature and low temperature of the substrate obtained from the resin composition tend to be good.
- the average value of the 25% modulus in the MD direction (machine direction) and the 25% modulus in the TD direction (transverse direction) measured at 23°C of the layer containing the resin composition is preferably 7 MPa or more and 13 MPa or less, and 8 MPa or more and 12 MPa. The following are more preferred.
- the dicing film substrate tends to have good elongation at room temperature.
- the above 25% modulus is obtained by preparing a film having a thickness of 100 ⁇ m, a length in the TD direction of 10 mm, and a length in the MD direction of 180 mm, which has the same composition as the layer containing the resin composition. -3: Equivalent to 1995), and is a value measured by a Shimadzu desk-top precision universal testing machine AG-X, which is a measuring device.
- the test speed shall be 300 mm/min.
- ethylene/unsaturated carboxylic acid/unsaturated carboxylic acid alkyl ester terpolymer or its ionomer ethylene/unsaturated carboxylic acid alkyl ester copolymer, ethylene/vinyl ester copolymer, ethylene/unsaturated carboxylic acid alkyl ester Layers containing ester-carbon monoxide copolymers, unsaturated carboxylic acid grafts thereof, polyvinyl chloride and the like are included.
- the other resin layer may contain only one type of the above resin, or may contain two or more types thereof.
- the thickness of the other resin layer is not particularly limited, it is preferably 10 ⁇ m or more and 100 ⁇ m or less, more preferably 15 ⁇ m or more and 80 ⁇ m or less, from the viewpoint of not impairing the modulus strength and elongation of the layer containing the resin composition.
- the thickness of the entire dicing film substrate is preferably 50 ⁇ m or more from the viewpoint of frame retention during dicing, and 200 ⁇ m or less from the viewpoint of extensibility (expandability), considering that it is used as a constituent member of the dicing film.
- the dicing film substrate is a laminate of a layer containing the above resin composition and another resin layer
- either one of the layer containing the above resin composition and the other resin layer is Alternatively, one layer may be formed first, and the other layer may be formed on the one layer by using a T-die film forming machine, an extrusion coating forming machine, or the like, and laminated.
- the dicing film of the present invention only needs to comprise the above-described dicing film substrate and an adhesive layer laminated on at least one surface thereof, and may contain other configurations as necessary. .
- the dicing film substrate is composed of multiple layers, it is preferable that the layer containing the resin composition in the dicing film substrate and the adhesive layer are laminated.
- the adhesive that constitutes the adhesive layer can be the adhesive for the adhesive layer of a general dicing film.
- adhesives include rubber-based, acrylic-based, silicone-based, and polyvinyl ether-based adhesives; radiation-curable adhesives; heat-foaming adhesives, and the like.
- the adhesive layer preferably contains a radiation-curable adhesive, and more preferably contains an ultraviolet-curable adhesive.
- UV-curable adhesives usually contain a radically polymerizable compound (which may be a monomer, an oligomer, or a polymer) and a photopolymerization initiator, and optionally a crosslinking agent, a tackifier, and a filler. agents, anti-aging agents, and additives such as coloring agents.
- radically polymerizable compounds include methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, octyl (meth)acrylate, (meth)acrylic Monomers or oligomers of (meth)acrylic acid alkyl esters such as isononyl acid; (meth)acrylate hydroxyalkyl esters such as hydroxyethyl (meth)acrylate, hydroxybutyl (meth)acrylate, and hydroxyhexyl (meth)acrylate Monomers or oligomers; the above (meth)acrylic acid alkyl esters and/or (meth)acrylic acid hydroxyalkyl esters and other monomers such as (meth)acrylic acid, itaconic acid, maleic anhydride, (meth)acrylic acid amide, (meth)acrylic acid N-hydroxymethylamide, (meth)acrylic acid alkyl
- cross-linking agents examples include polyisocyanate compounds, melamine resins, urea resins, polyamines, and carboxyl group-containing polymers.
- the thickness of the adhesive layer is appropriately selected according to the type of adhesive, preferably 3 to 100 ⁇ m, more preferably 3 to 50 ⁇ m.
- the adhesive layer of the dicing film may be protected by a separator.
- the surface of the adhesive layer can be kept smooth.
- the dicing film can be easily handled and transported, and a label can be processed on the separator. The separator is peeled off when using the dicing film.
- the method for producing the dicing film is not particularly limited, and for example, it may be produced by applying an adhesive to the above-mentioned dicing base material by a known method.
- the adhesive can be applied by a gravure roll coater, a reverse roll coater, a kiss roll coater, a dip roll coater, a bar coater, a knife coater, a spray coater, or the like.
- an adhesive layer may be formed by applying an adhesive onto a release sheet, and the adhesive layer may be transferred to the dicing film substrate to laminate the dicing film substrate and the adhesive layer.
- the dicing film base material and the adhesive layer may be formed at the same time by co-extrusion or the like.
- Styrene resin 1 SEBS (styrene-ethylene-butylene-styrene block copolymer (manufactured by Asahi Kasei Chemicals, SOE S1611 (trade name), JIS K 7210: 1999 (equivalent to ISO 1133: 1997) , MFR measured at 230 ° C., 2160 g load: 12.0 g / 10 minutes, Tan ⁇ peak temperature: 9 ° C.)
- Styrene resin 2 HSBR (hydrogenated styrene-butadiene random copolymer (manufactured by JSR, DYNARON 1320P (trade name), JIS K 7210: 1999 (equivalent to ISO 1133: 1997), 230 ° C.
- Styrene resin 3 SEBS (styrene-ethylene-butylene-styrene block copolymer (manufactured by Asahi Kasei Chemicals, Tuftec H1041 (trade name), JIS K 7210: 1999 (equivalent to ISO 1133: 1997), 230 ° C., MFR measured at 2160 g load: 5.0 g/10 min, Tan ⁇ peak temperature: -45 ° C.)
- Styrene resin 4 acid-modified SEBS (maleic anhydride-modified styrene-ethylene-butylene-styrene block copolymer (manufactured by Asahi Kasei Chemicals, Tuftec M1913 (trade name), acid value: 10 mg CH 3 ONa/g, JIS K 7210 : 1999 (equivalent to ISO 1133:1997), MFR
- EMAA ethylene/methacrylic acid copolymer (content of structural units derived from ethylene: 91% by mass, content of structural units derived from methacrylic acid: 9% by mass, JIS K 7210: 1999 (ISO 1133: 1997), MFR measured at 190 ° C., 2160 g load: 3 g / 10 minutes)
- TPU Thermoplastic polyurethane elastomer (manufactured by Tosoh Corporation, Miractran P485RSUI (trade name))
- Example 1 An ethylene/unsaturated carboxylic acid copolymer ionomer (A), a polyamide (B), and a styrene resin (C) were dry-blended at the ratios (mass ratios) shown in Table 1.
- the dry-blended mixture was put into the resin inlet of a 30 mm ⁇ twin-screw extruder and melt-kneaded at a die temperature of 230° C. to obtain a resin composition for a dicing film substrate.
- the obtained resin composition for a dicing film substrate was measured for MFR at 230° C. (190° C. only in Comparative Example 1) under a load of 2160 g in accordance with JIS K 7210:1999 (corresponding to ISO 1133:1997). Table 1 shows the results.
- the obtained resin composition for a dicing film substrate was molded at a processing temperature of 230° C. using a 40 mm ⁇ T die film molding machine to prepare a T die film having a thickness of 100 ⁇ m.
- the resulting T-die film was used as a dicing film substrate and evaluated by the following methods. Table 1 shows the results.
- the 25% modulus in the MD direction and the 25% modulus in the TD direction obtained by the above tests were averaged, and the room temperature modulus strength of the dicing film substrate was evaluated according to the following criteria.
- the dicing film substrate was cut into strips of 10 mm width ⁇ 180 mm length.
- JIS K 7127: 1999 (equivalent to ISO 527-3: 1995)
- the 10% modulus was measured at -15°C.
- the chuck-to-chuck distance was 100 mm, and the test speed was 500 mm/min.
- the 10% modulus in the MD direction and the 10% modulus in the TD direction obtained by the above tests were averaged, and the low-temperature modulus strength of the dicing film substrate was evaluated according to the following criteria.
- the room-temperature elongation of the dicing film substrate was evaluated according to the following criteria.
- the low-temperature elongation of the dicing film substrate was evaluated according to the following criteria.
- the dicing film substrate using the resin composition for material was excellent in room-temperature modulus strength, low-temperature modulus strength, room-temperature elongation, and low-temperature elongation.
- Comparative Example 1 which does not contain polyamide (B) and styrene-based resin (C)
- Comparative Example 2 which did not contain polyamide (B)
- the low-temperature modulus strength was low.
- Comparative Example 3 which does not contain the styrene-based resin (C)
- both room-temperature elongation and low-temperature elongation were low.
- Comparative Examples 4 to 7 which did not contain the ionomer (A) of the ethylene/unsaturated carboxylic acid copolymer, both the normal temperature elongation and the low temperature elongation were low.
- the resin composition for a dicing film substrate of the present invention can realize a dicing film substrate excellent in room-temperature modulus strength, low-temperature modulus strength, room-temperature elongation, and low-temperature elongation. .
- a dicing film substrate having excellent elongation at room temperature and low temperature and also excellent modulus strength at room temperature and low temperature is realized. Therefore, it is very useful in the field of manufacturing semiconductor devices.
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- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
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Abstract
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CN202280021186.1A CN117063262A (zh) | 2021-03-18 | 2022-03-04 | 切割膜基材用树脂组合物、切割膜基材、及切割膜 |
JP2023506968A JPWO2022196392A1 (fr) | 2021-03-18 | 2022-03-04 | |
KR1020237030144A KR20230138017A (ko) | 2021-03-18 | 2022-03-04 | 다이싱 필름 기재용 수지 조성물, 다이싱 필름 기재, 및 다이싱 필름 |
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JP2017098369A (ja) * | 2015-11-20 | 2017-06-01 | 三井・デュポンポリケミカル株式会社 | ダイシングフィルム基材用樹脂組成物、ダイシングフィルム基材およびダイシングフィルム |
WO2018123804A1 (fr) * | 2016-12-27 | 2018-07-05 | 三井・デュポンポリケミカル株式会社 | Base de film de découpage en dés et film de découpage en dés |
WO2020031928A1 (fr) * | 2018-08-08 | 2020-02-13 | 三井・ダウポリケミカル株式会社 | Composition de résine pour substrat de film de découpage en dés, substrat de film de découpage en dés et film de découpage en dés |
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JP2011210887A (ja) | 2010-03-29 | 2011-10-20 | Furukawa Electric Co Ltd:The | 放射線硬化型ウエハ加工用粘着テープ |
JP5666875B2 (ja) | 2010-10-21 | 2015-02-12 | アキレス株式会社 | 半導体製造工程用テープの基材フィルム |
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- 2022-03-04 WO PCT/JP2022/009398 patent/WO2022196392A1/fr active Application Filing
- 2022-03-04 JP JP2023506968A patent/JPWO2022196392A1/ja active Pending
- 2022-03-04 CN CN202280021186.1A patent/CN117063262A/zh active Pending
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JP2017098369A (ja) * | 2015-11-20 | 2017-06-01 | 三井・デュポンポリケミカル株式会社 | ダイシングフィルム基材用樹脂組成物、ダイシングフィルム基材およびダイシングフィルム |
WO2018123804A1 (fr) * | 2016-12-27 | 2018-07-05 | 三井・デュポンポリケミカル株式会社 | Base de film de découpage en dés et film de découpage en dés |
WO2020031928A1 (fr) * | 2018-08-08 | 2020-02-13 | 三井・ダウポリケミカル株式会社 | Composition de résine pour substrat de film de découpage en dés, substrat de film de découpage en dés et film de découpage en dés |
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CN117063262A (zh) | 2023-11-14 |
JPWO2022196392A1 (fr) | 2022-09-22 |
TW202302747A (zh) | 2023-01-16 |
KR20230138017A (ko) | 2023-10-05 |
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