WO2009069483A1 - 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 - Google Patents

固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 Download PDF

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Publication number
WO2009069483A1
WO2009069483A1 PCT/JP2008/070781 JP2008070781W WO2009069483A1 WO 2009069483 A1 WO2009069483 A1 WO 2009069483A1 JP 2008070781 W JP2008070781 W JP 2008070781W WO 2009069483 A1 WO2009069483 A1 WO 2009069483A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
olefin
solid titanium
ingredient
olefin polymerization
Prior art date
Application number
PCT/JP2008/070781
Other languages
English (en)
French (fr)
Inventor
Kazuhisa Matsunaga
Kazutaka Tsuru
Kazumitsu Kawakita
Tetsunori Shinozaki
Original Assignee
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals, Inc. filed Critical Mitsui Chemicals, Inc.
Priority to KR1020127024634A priority Critical patent/KR20120120467A/ko
Priority to EP08853456.5A priority patent/EP2221320B1/en
Priority to JP2009543756A priority patent/JP5306225B2/ja
Priority to US12/744,760 priority patent/US8742040B2/en
Priority to BRPI0819666-4A priority patent/BRPI0819666B1/pt
Priority to KR1020107012185A priority patent/KR101228202B1/ko
Priority to CN2008801177533A priority patent/CN101874046B/zh
Priority to ES08853456.5T priority patent/ES2629993T3/es
Publication of WO2009069483A1 publication Critical patent/WO2009069483A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

[解決手段]　チタン、マグネシウム、ハロゲンおよび特定の環状エステル化合物（ａ）と環状エステル化合物（ｂ）とを含む固体状チタン触媒成分（Ｉ）、この触媒成分（Ｉ）を含むオレフィン重合用触媒、およびこのオレフィン重合用触媒を用いたオレフィン重合方法。 [効果]　本発明の固体状チタン触媒成分、オレフィン重合用触媒、およびオレフィンの重合体の製造方法によれば、立体規則性が高く、広い分子量分布を有するオレフィン重合体を、高活性で製造でき、また、たとえば高速延伸性、高速成形性などの成形性に加え、剛性にも優れたオレフィン重合体が製造可能になり、さらに製造コストを低減することができる。
PCT/JP2008/070781 2007-11-27 2008-11-14 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 WO2009069483A1 (ja)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1020127024634A KR20120120467A (ko) 2007-11-27 2008-11-14 고체상 타이타늄 촉매 성분, 올레핀 중합용 촉매 및 올레핀의 중합 방법
EP08853456.5A EP2221320B1 (en) 2007-11-27 2008-11-14 Solid titanium catalyst ingredient, catalyst for olefin polymerization, and method of polymerizing olefin
JP2009543756A JP5306225B2 (ja) 2007-11-27 2008-11-14 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
US12/744,760 US8742040B2 (en) 2007-11-27 2008-11-14 Solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
BRPI0819666-4A BRPI0819666B1 (pt) 2007-11-27 2008-11-14 Componente catalisador de titânio sólido, catalisador de polimerização de olefina e processo de polimerização de olefina
KR1020107012185A KR101228202B1 (ko) 2007-11-27 2008-11-14 고체상 타이타늄 촉매 성분, 올레핀 중합용 촉매 및 올레핀의 중합 방법
CN2008801177533A CN101874046B (zh) 2007-11-27 2008-11-14 固态钛催化剂成分、烯烃聚合用催化剂以及烯烃聚合方法
ES08853456.5T ES2629993T3 (es) 2007-11-27 2008-11-14 Ingrediente de catalizador de titanio sólido, catalizador para polimerización de olefinas, método para polimerizar olefinas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007306332 2007-11-27
JP2007-306332 2007-11-27

Publications (1)

Publication Number Publication Date
WO2009069483A1 true WO2009069483A1 (ja) 2009-06-04

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PCT/JP2008/070781 WO2009069483A1 (ja) 2007-11-27 2008-11-14 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法

Country Status (14)

Country Link
US (1) US8742040B2 (ja)
EP (1) EP2221320B1 (ja)
JP (1) JP5306225B2 (ja)
KR (2) KR101228202B1 (ja)
CN (1) CN101874046B (ja)
BR (1) BRPI0819666B1 (ja)
ES (1) ES2629993T3 (ja)
HU (1) HUE035826T2 (ja)
MY (1) MY155648A (ja)
RU (1) RU2443715C1 (ja)
SA (1) SA08290734B1 (ja)
SG (1) SG194361A1 (ja)
TW (1) TWI421127B (ja)
WO (1) WO2009069483A1 (ja)

Cited By (15)

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JP2011132294A (ja) * 2009-12-22 2011-07-07 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011184620A (ja) * 2010-03-10 2011-09-22 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011190408A (ja) * 2010-03-16 2011-09-29 Mitsui Chemicals Inc プロピレン系ブロック共重合体およびこれらから得られる成形体
JP2011190407A (ja) * 2010-03-16 2011-09-29 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011195662A (ja) * 2010-03-18 2011-10-06 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011195661A (ja) * 2010-03-18 2011-10-06 Mitsui Chemicals Inc プロピレン系ブロック共重合体およびこれから得られるプロピレン系樹脂組成物およびこれらから得られる成形体
JPWO2010032793A1 (ja) * 2008-09-22 2012-02-16 三井化学株式会社 プロピレン系ブロック共重合体、該共重合体を含む組成物およびこれらから得られる成形体
WO2014054673A1 (ja) 2012-10-03 2014-04-10 サンアロマー株式会社 レトルトフィルム用プロピレン樹脂組成物
JP2014181317A (ja) * 2013-03-21 2014-09-29 Prime Polymer Co Ltd プロピレン系重合体および該プロピレン系重合体を含むプロピレン系樹脂組成物
WO2015012310A1 (ja) * 2013-07-23 2015-01-29 東洋紡株式会社 空洞含有ポリプロピレンフィルム
WO2018117271A1 (en) 2016-12-20 2018-06-28 Sunallomer Ltd. Masterbatch composition
WO2019177179A1 (en) 2018-03-16 2019-09-19 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article
WO2019177180A1 (en) 2018-03-16 2019-09-19 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article
WO2019245058A1 (en) 2018-06-19 2019-12-26 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article
WO2020080555A1 (en) 2018-10-18 2020-04-23 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article

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US9593184B2 (en) 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
CN105504110A (zh) * 2015-12-30 2016-04-20 神华集团有限责任公司 烯烃聚合用催化剂固体组分的制备方法
BR112018013487B1 (pt) 2015-12-31 2022-08-30 Braskem America, Inc. Sistema catalisador isento de ftalato para polimerização de olefina, e, processo para preparação de uma poliolefina
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
US9815920B1 (en) 2016-10-14 2017-11-14 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US10124324B1 (en) 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US10822438B2 (en) 2017-05-09 2020-11-03 Formosa Plastics Corporation Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
US11401356B2 (en) * 2017-07-19 2022-08-02 China Petroleum & Chemical Corporation Olefin polymerization catalyst comprising cyclotriveratrylene and derivatives thereof
JP7466661B2 (ja) * 2020-08-26 2024-04-12 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒、オレフィンの重合方法およびプロピレン重合体

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JPS5763310A (en) 1980-08-13 1982-04-16 Montedison Spa Ingredient and catalyst for olefin polymerization
JPS58138715A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd オレフイン類の重合方法
US4442276A (en) * 1982-02-12 1984-04-10 Mitsui Petrochemical Industries, Ltd. Process for polymerizing or copolymerizing olefins
JPS59207904A (ja) * 1983-05-11 1984-11-26 Mitsui Petrochem Ind Ltd オレフイン重合体の製造方法
JPH037703A (ja) 1989-03-02 1991-01-14 Mitsui Petrochem Ind Ltd オレフィンの重合方法およびオレフィン重合用触媒
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Cited By (18)

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US8729189B2 (en) 2008-09-22 2014-05-20 Mitsui Chemicals, Inc. Propylene-based block copolymer, composition containing the copolymer, and molded products obtained therefrom
JPWO2010032793A1 (ja) * 2008-09-22 2012-02-16 三井化学株式会社 プロピレン系ブロック共重合体、該共重合体を含む組成物およびこれらから得られる成形体
JP5441909B2 (ja) * 2008-09-22 2014-03-12 三井化学株式会社 プロピレン系ブロック共重合体、該共重合体を含む組成物およびこれらから得られる成形体
JP2011132294A (ja) * 2009-12-22 2011-07-07 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011184620A (ja) * 2010-03-10 2011-09-22 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011190408A (ja) * 2010-03-16 2011-09-29 Mitsui Chemicals Inc プロピレン系ブロック共重合体およびこれらから得られる成形体
JP2011190407A (ja) * 2010-03-16 2011-09-29 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011195662A (ja) * 2010-03-18 2011-10-06 Mitsui Chemicals Inc プロピレン系樹脂組成物およびこれらから得られる成形体
JP2011195661A (ja) * 2010-03-18 2011-10-06 Mitsui Chemicals Inc プロピレン系ブロック共重合体およびこれから得られるプロピレン系樹脂組成物およびこれらから得られる成形体
WO2014054673A1 (ja) 2012-10-03 2014-04-10 サンアロマー株式会社 レトルトフィルム用プロピレン樹脂組成物
JP2014181317A (ja) * 2013-03-21 2014-09-29 Prime Polymer Co Ltd プロピレン系重合体および該プロピレン系重合体を含むプロピレン系樹脂組成物
WO2015012310A1 (ja) * 2013-07-23 2015-01-29 東洋紡株式会社 空洞含有ポリプロピレンフィルム
JPWO2015012310A1 (ja) * 2013-07-23 2017-03-02 東洋紡株式会社 空洞含有ポリプロピレンフィルム
WO2018117271A1 (en) 2016-12-20 2018-06-28 Sunallomer Ltd. Masterbatch composition
WO2019177179A1 (en) 2018-03-16 2019-09-19 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article
WO2019177180A1 (en) 2018-03-16 2019-09-19 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article
WO2019245058A1 (en) 2018-06-19 2019-12-26 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article
WO2020080555A1 (en) 2018-10-18 2020-04-23 Basell Poliolefine Italia S.R.L. Polypropylene composition and molded article

Also Published As

Publication number Publication date
CN101874046A (zh) 2010-10-27
BRPI0819666B1 (pt) 2018-07-10
KR20120120467A (ko) 2012-11-01
US20100305285A1 (en) 2010-12-02
ES2629993T3 (es) 2017-08-17
HUE035826T2 (hu) 2018-08-28
EP2221320A1 (en) 2010-08-25
KR20100072370A (ko) 2010-06-30
TWI421127B (zh) 2014-01-01
EP2221320A4 (en) 2013-10-09
KR101228202B1 (ko) 2013-01-30
EP2221320B1 (en) 2017-06-21
RU2010125768A (ru) 2012-01-10
SA08290734B1 (ar) 2011-09-18
RU2443715C1 (ru) 2012-02-27
US8742040B2 (en) 2014-06-03
BRPI0819666A2 (pt) 2015-05-26
JPWO2009069483A1 (ja) 2011-04-14
TW200932353A (en) 2009-08-01
SG194361A1 (en) 2013-11-29
MY155648A (en) 2015-11-13
JP5306225B2 (ja) 2013-10-02
CN101874046B (zh) 2013-03-20

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