WO2009038234A1 - Feuille d'étiquettes autocollantes et son procédé de production - Google Patents

Feuille d'étiquettes autocollantes et son procédé de production Download PDF

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Publication number
WO2009038234A1
WO2009038234A1 PCT/JP2008/067582 JP2008067582W WO2009038234A1 WO 2009038234 A1 WO2009038234 A1 WO 2009038234A1 JP 2008067582 W JP2008067582 W JP 2008067582W WO 2009038234 A1 WO2009038234 A1 WO 2009038234A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
adhesive label
sheet
label sheet
pressure
Prior art date
Application number
PCT/JP2008/067582
Other languages
English (en)
Japanese (ja)
Inventor
Yoshiyuki Tanaka
Kenji Harada
Kazuki Nakamura
Original Assignee
Lintec Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lintec Corporation filed Critical Lintec Corporation
Priority to JP2009533220A priority Critical patent/JP5214618B2/ja
Publication of WO2009038234A1 publication Critical patent/WO2009038234A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31D—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
    • B31D1/00—Multiple-step processes for making flat articles ; Making flat articles
    • B31D1/02—Multiple-step processes for making flat articles ; Making flat articles the articles being labels or tags
    • B31D1/026—Cutting or perforating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31D—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
    • B31D1/00—Multiple-step processes for making flat articles ; Making flat articles
    • B31D1/02—Multiple-step processes for making flat articles ; Making flat articles the articles being labels or tags
    • B31D1/021—Making adhesive labels having a multilayered structure, e.g. provided on carrier webs
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer

Definitions

  • the present invention relates to an adhesive label sheet and its removal.
  • the present invention provides an adhesive label sheet that does not peel off the image ⁇ , is easily positioned in a sheet, and has a small amount of air [, and can be efficiently used. It is about the male. Background
  • small-sized labels include anti-tampering labeno label and 10 words away.
  • sealing labels are often ffled for purposes such as virginity certification for products.
  • Large-size labels include so-called stick power, such as a vehicle's container or striped sticker for signage, signboards, advertising boards, etc.
  • stickers for displaying each S3 ⁇ 4 such as signs, information boards, risk predictions, and product marks.
  • posters and presentation materials can be easily printed using printers and other materials and images created by computers.
  • Examples include dot impact printers, laser printers, direct thermal printers, thermal transfer printers, or ink jet printers.
  • ink jet printers have less power during printout, and full power error.
  • Can print It is widely used because it has advantages such as low running costs associated with printout.
  • Dye-based inks have poor weather resistance.
  • the parent ink-based ink strength S is usually used.
  • the new material-based inks should be appreciated. 3 ⁇ 43 ⁇ 4rf, because they adhere to the surface, they have the disadvantage of being peeled off by rubbing with your hands.
  • the leakage retaining liquid having resin emulsion, lubricant component, and 3 ⁇ 4 ⁇
  • an image protection sheet formed by forming the protection S is disclosed (for example, see Patent Document 1). According to this dislike, the formation of the image and the formation of the protective film can be performed with one apparatus, so that the process can be reduced.
  • an image creation and clipping device in which an inkjet head and a cutting head are mounted on a single guide rail and controlled by a single 13] device to eliminate cutting line misalignment (for example, Reference 2).
  • the notch is formed in the retaining S; ⁇ , the notch formed from the surface of the image ⁇ S to the release sheet is formed, and the scrap is raised or separated from the release sheet.
  • Adhesive label / resiate that can be easily done is a traditional les, known so far.
  • the I «S is not peeled off under such circumstances, and it is possible to cut off the f-cut (f is easy to set up and can be made with a small amount of Adhesive label sheets that can be easily peeled off, and those that cost $ 3 ⁇ 4t efficiently;
  • the present invention is based on the knowledge gained.
  • the adhesive label sheet of ⁇ is a layer formed by applying a coating solution made of resin emulsion
  • the Hi ⁇ is not peeled off, and the half force ( ⁇ is easy to set up, can be put together with a small amount of detail, and the adhesive label from the waste sheet Adhesive label sheet that can be easily peeled off, and this product can be efficiently removed for $ 3 ⁇ 4t.
  • F i g .: ⁇ ⁇ ⁇ : of the invention (a cross-sectional view of an example of the structure of a 3 ⁇ 4-wearing labenore sheet, F i g.2 shows the state after the residue of the adhesive label sheet shown in FIG.
  • reference numerals 1 and la are Xie layers
  • 2 and 2 a are drawing cranes
  • 3 and 3 a are cover 4 and 4attf occupancy
  • 5 is a peel sheet
  • 10 is adhesive.
  • Label sheet, 20 represents a semi-occupied rabenole
  • P represents a rabeno-cutting incision BEST MODE FOR CARRYING OUT THE INVENTION
  • the pressure-sensitive adhesive label sheet of the present invention is a pressure-sensitive adhesive label sheet having a structure of a protective layer, a Z layer, a pressure-sensitive adhesive layer, and a release sheet. The tip of the sheet is formed on the release sheet; Next, the configuration of the pressure-sensitive adhesive label sheet of the present invention will be described with reference to the drawings.
  • F i g. 1 is a cross-sectional view of a different example of the pressure-sensitive adhesive label sheet of the present invention.
  • the occupying labenore sheet 10 includes image layers 2 and It has a structure that is attached to the release sheet 5 through the adhesive layer 4 through the adhesive layer 4, and from the surface of the kneading 2 the rabeno punching cut P is formed in a predetermined shape.
  • the tip is formed on the peeling sheet 5 to be ⁇ "T.
  • F i g. 2 is a plan view showing the state after the occupancy of the rice occupying labenore sheet 10 shown in the above F i g.
  • the layer 1a which is cut out in the shape of a sheet, is affixed onto the release sheet 5 via the adhesive layer 4a, The As shown in Fig. 1, a notch is formed in the rotation 3 and the lame force leakage 3 is easily raised at the position of the notch in the lower layer when raising the residue. Can do.
  • the label can be peeled off from the release sheet without scraping.
  • This: ⁇ also allows Horan 3 to easily peel off the label of a predetermined shape from the release sheet by placing the cut portion in the lower layer 3 ⁇ 4S b.
  • plastic plastics include polyethylene resins such as polyethylene, polypropylene, and various polyolefin resins, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, polystyrene resins, and polyvinyl chloride. Trees, fluoric resins such as acrylic resins, polyurethane resins, polycarbonate resins, polyamide resins, polytetrafluoroethylene, etc. it can.
  • Xie is the age of plastic film, good 3D curved surface follow-up ability, good image acceptability, etc.
  • the composition by ink jet ⁇ polychlorinated bur resin film and polyurethane resin film force S is preferable .
  • the images made by the photocopy are acrylic resin film and polyurethane resin film cartridge 1.
  • these plastic films may be subjected to surface treatment such as oxidation / depression to improve adhesion to the adhesive layer formed on the plastic film and the image receiving layer such as the image receiving layer. Can do.
  • oxidation method examples include corona treatment, chrome treatment (humidity, flame treatment, thermal JE ⁇ treatment, ozone, ultraviolet irradiation treatment, etc., and unevenness treatment methods include, for example, sand plast method, reverse treatment, etc.
  • chrome treatment humidity, flame treatment, thermal JE ⁇ treatment, ozone, ultraviolet irradiation treatment, etc.
  • unevenness treatment methods include, for example, sand plast method, reverse treatment, etc.
  • surface treatment methods are suitable depending on the view of the film, but in general, the corona ⁇ method is preferably used from the standpoint of effectiveness and effectiveness etc.
  • a primer for forming a primer layer Processing can also be applied.
  • the thickness is not particularly limited, but usually
  • the application to the pressure-sensitive adhesive label sheet of the present invention improves the image acceptability, it may have an image receiving layer on the surface side of the substrate.
  • This image-receiving layer usually has a binder resin.
  • resin examples include polyester resin, polyureta: / fat, polyacryl shelves, poly; ⁇ "" resin, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl chloride resin, polyimide resin. It is done.
  • This binder resin may be used alone or in combination of two or more.
  • the inorganic power include particle power S such as silica, clay, talc, kaolin, diatomaceous earth, aluminum hydroxide, magnesium hydroxide, anolemina, charcoal 7 lucium, ⁇ barium, titanium oxide, and zeolite.
  • particle power S such as silica, clay, talc, kaolin, diatomaceous earth, aluminum hydroxide, magnesium hydroxide, anolemina, charcoal 7 lucium, ⁇ barium, titanium oxide, and zeolite.
  • «5 ⁇ Xie include Tetsuko Kizuki such as ion 3 ⁇ 4 « f fat, urea resin, polystyrene resin, acrylic resin and the like.
  • ⁇ is not particularly limited, but is usually 0 ⁇ 0 0 1 ⁇ 2 O / zm ⁇ , preferably 0.0 1 ⁇ 1.
  • the content of the knot-inder resin and ⁇ is not particularly limited, but is usually 1 0 0: 1-1 0 0: 1 0 0 0 0 in mass ratio, preferably 1 0 0: 1 0 to 1 0 0: 5 0 0.
  • the image receiving layer can be provided with a fixing agent, an engraving agent, a leveling agent, an antioxidant, an ultraviolet absorber, a lubricant, a reversal, and the like.
  • a binder resin, a filler, and various additives used as desired [ ⁇ are dissolved or dispersed in an appropriate soot such as water, which is suitable for coating.
  • an appropriate soot such as water
  • this coating liquid is applied to one side of the gravel: Direct gravure, Gravure reverse, Micro gravure, Meyer bar, Air knife, Blade, Die, Rono Knife, Reno sous, Curtain coat, etc. ⁇ , Flexo, Letter It can be opened by printing on presses, screens, etc .;
  • the thickness of the image receiving layer is usually from 0.:! To 1 ⁇ ⁇ ⁇ ⁇ , preferably from 1 to 20 / z m.
  • the pressure-sensitive adhesive that forms the pressure-sensitive adhesive layer formed on the side of the surface is not particularly limited. Any suitable! SS can be used.
  • acrylic adhesives, rubber adhesives, silicone adhesives, polyurethane adhesives, and polyester adhesives can be used. Among these, acrylics are used from the viewpoint of weather resistance.
  • Adhesive strength S is preferably used.
  • acryloester examples include (meth) acrylobutyl ester, (meth) acrylonyl ester, (meth) acrylo 1 ⁇ hexyl ester, (meth) acrylo! ⁇ Putyl ester, (meth) acrylooctyl ester, (meth) acrylo!
  • Nonyl ester (meth) acryloyl ester, and the like.
  • (meta) Hydroxyl group-containing monomers such as clino hydroxyethinoreester, (meth) atalino hydroxypropyl ester, amide group-containing monomers such as (meth) acrylamide and dimethyl (meth) acrylamide, and carboxyls such as (meth) atari ⁇ And soot-containing monomers.
  • amide group-containing monomers such as (meth) acrylamide and dimethyl (meth) acrylamide
  • carboxyls such as (meth) atari ⁇ And soot-containing monomers.
  • other monomers that can be copolymerized with the above-described acryloester such as vinyl, styrene, and atalononitrile, may be copolymerized according to the above requirements.
  • This pressure-sensitive adhesive is mixed with a tackifier, ⁇ k filling i, etc. as desired.
  • the given pressure-sensitive adhesive like e.g. rosin resin, ceiling ⁇ such polyterpene resins, C 5 based, C 9 type, DC PD petroleum Tanamune, coumarone-indene resins, such as synthetic resin such as xylene resin It is
  • 3 ⁇ 43 ⁇ 4 ⁇ IJ includes polyisocyanate conversion)), epoxy, fat, melamine fat, urea resin, chelation ⁇ ), salt, and the like.
  • charge i ⁇ include ffif ports, titanium oxide, siri force, and calcium carbonate.
  • the above-mentioned pressure-sensitive adhesive may be applied using the force method applied to the back surface of the substrate.
  • the above-mentioned occupant is applied to the release surface of the release sheet.
  • the release sheet is used as it is.
  • a release sheet is attached to the pressure-sensitive adhesive layer.
  • Examples of the release sheet in the pressure-sensitive adhesive label sheet of the present invention include, for example, Mr. Kamijo, 3 ⁇ 4 SW such as glassine paper and coated paper, laminated paper laminated with a thermoplastic resin such as polyethylene, polyethylene terephthalate, and polybutylene Polyester films such as terephthalate and polyethylene naphthalate, polypropylene and polyethylene ⁇ ⁇ ⁇ ⁇ ⁇ IJ are applied to form a struggle layer.
  • the thickness of the release sheet is not particularly limited, but is usually 30 to: I 50 ⁇ .
  • the pressure-sensitive adhesive label sheet of the present invention is suitable for printing on demand; ⁇ :, printing; W is a method advantageous for on-demand ⁇ :, for example, B3 ⁇ 4 copying method, inkjet method, electronic photography ⁇ ; Etc., but especially ⁇ copy; ⁇ 3 ⁇ 4inkjet ⁇ ; is ®.
  • each individual label is labeled with a predetermined shape from the surface of the image S.
  • a notch for punching out is formed with a blade, for example, so that the other end is formed on the release sheet. This printing can be done by operating a computer.
  • the operation to form tiiiER printing and cutting may be performed using a device equipped with both a mark and a cutting roller, or a device equipped with a mark and a device equipped with a cutting rod. It is possible to do this, but it is preferable to use a device equipped with both the former seal notification I and cutting leakage, hugging the formation of the image and the cut.
  • a device equipped with both the former seal notification I and cutting leakage hugging the formation of the image and the cut.
  • the tiff self-cutting force S is formed on the formed image 3 ⁇ 4) 1
  • the tone is transparent, and the adhesive label is peeled off from the waste sheet ii. It is important to have a property that makes it easy to raise the scrap and to remove the pressure-sensitive adhesive label from the release sheet by placing the cut portion in the lower layer.
  • Such a protective film can be formed by applying a coating solution made of resin emulsification onto the tilt self-portrait ⁇ .
  • a coating solution made of resin emulsification made of resin emulsification onto the tilt self-portrait ⁇ .
  • Kisatsu Chirono is a good choice for small amounts of adhesive labels.
  • the ftitSi fat emulsion is not particularly limited as long as it is capable of forming the protective material S having a habit property, and various resin emulsions can be used.
  • resin E Marushon for example solid concentration 5-6 0 weight 0/0, preferably from 2 0-5 0 quality »% polyurethane resin aqueous emulsion is preferred.
  • the attalinole-modified polyurethane resin aqueous emulsion is prepared by, for example, (1) preparing a water-soluble polyurethane, adding an acryl group-containing monomer in the next layer and polymerizing it in-situ, and (2) forming a butyl group.
  • An acrylic group-containing monomer is copolymerized in a polyurethane thread containing polyurethane yarn as: ⁇ , (3) Acrylic resin formed as water and polyurethane as water It can be obtained, for example, by polymerizing an acryl-based monomer to produce an aqueous product.
  • an epoxy-modified polyurethane resin aqueous emulsion can be obtained by, for example, epoxidizing an aqueous polyurethane resin having a carboxyl group with two or more epoxy groups in one molecule.
  • the thickness of the protective layer S is preferably 1 to 6 O / m, from the viewpoint of balance such as image protection 13 ⁇ 43 ⁇ 4 and scum rise ⁇ , ease of adhesive label peeling from the release sheet, and 10 to 4 ⁇ ⁇ ⁇ is more preferred.
  • the present invention also refers to a male who uses the adhesive label sheet of the present invention described above.
  • the method of the present invention comprises the steps of: (a) forming a layer on the surface of the printing layer having the structure of a layer of the Z layer, an adhesive layer, and a Z release sheet; (A) from the surface of the image formed in the process ⁇ , a cut-off process for forming a predetermined shape of Raveno ⁇ ] so that the tip reaches the release sheet; and (c) tfffS It is assumed that a coating step of coating a coating solution comprising shelf emulsification is formed on the screen to form a coating S.
  • the coating liquid used is made of resin emulsion.
  • resin emulsion polyurethane resin water is used.
  • Emulsions, especially Akurinore male poly Uretan resin aqueous emulsion Ya epoxy-modified Poriuretan resin aqueous emulsion is preferred.
  • the image forming process and the half-cut process are performed, and then the resin emulsion is used.
  • a coating solution that is used it is easy to position the first cut, and the adhesive label sheet can be attached with a small amount of processing.
  • Adhesive label sheets can be easily lifted or peeled off from the release sheet.
  • a printing axe made by sequentially laminating an acrylic adhesive layer and a release sheet with a thickness of 20 / zm on a white acrylic resin with a thickness of 80 / m [LA g SSJ -AWj]: ⁇ is the same as in Example 1 and is shown in Fig. 1. “Fit adhesive label sheet”
  • the pressure-sensitive adhesive label sheet of the present invention is easy for anyone to set up and cut the sheet, and can be stored with a small amount of light, and the pressure-sensitive adhesive label can be easily peeled off from the waste release sheet.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Adhesive Tapes (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Making Paper Articles (AREA)
  • Wrappers (AREA)

Abstract

L'invention concerne une feuille d'étiquettes autocollantes (10) présentant une structure comprenant une couche de protection (3, 3a)/couche d'image (2, 2a)/couche de base (1, 1a)/couche autocollante (4, 4a)/feuille de détachement (5), caractérisée en ce que des incisions (P) pour découper une étiquette d'une forme donnée ont été formées de façon à ce que les incisions (P) s'étendent depuis la surface de la couche d'image (2, 2a) et que les extrémités de celle-ci atteignent la feuille détachement (5). L'invention concerne également un procédé de production de la feuille d'étiquettes. Cette feuille d'étiquettes autocollantes est caractérisée en ce que la couche d'image ne se décolle pas, que le positionnement dans un état de demi-incision est simple, en ce que la feuille d'étiquettes autocollantes peut être produite par un nombre réduit d'étapes, et en ce que le retrait des parties inutiles ainsi que le décollement de l'étiquette autocollante sur la feuille de détachement sont simples.
PCT/JP2008/067582 2007-09-20 2008-09-19 Feuille d'étiquettes autocollantes et son procédé de production WO2009038234A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009533220A JP5214618B2 (ja) 2007-09-20 2008-09-19 粘着ラベルシート及びその製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007244126 2007-09-20
JP2007-244126 2007-09-20

Publications (1)

Publication Number Publication Date
WO2009038234A1 true WO2009038234A1 (fr) 2009-03-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/067582 WO2009038234A1 (fr) 2007-09-20 2008-09-19 Feuille d'étiquettes autocollantes et son procédé de production

Country Status (2)

Country Link
JP (1) JP5214618B2 (fr)
WO (1) WO2009038234A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013028147A (ja) * 2011-07-29 2013-02-07 Dainippon Printing Co Ltd 熱転写受像シートおよびそれを用いた遊戯カード
CN104240596A (zh) * 2014-09-30 2014-12-24 李峰 一种新型防伪结构及其生产方法
JP2016172330A (ja) * 2015-03-16 2016-09-29 リンテック株式会社 再使用防止粘着シート
US11996013B2 (en) 2019-05-02 2024-05-28 Pilot Italia S.P.A. Label and manufacturing method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1076621A (ja) * 1996-07-12 1998-03-24 Konica Corp 情報記録材料
JP2003251718A (ja) * 2002-03-04 2003-09-09 Olympus Optical Co Ltd ラベル作成方法
JP2004001446A (ja) * 2002-03-28 2004-01-08 Seiko Epson Corp 画像保護シート、画像保護液、インクジェット記録物とその製造方法
JP2007001110A (ja) * 2005-06-23 2007-01-11 Toppan Printing Co Ltd 紙部材の製造方法及び紙部材並びに紙容器

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3097779U (ja) * 2003-05-14 2004-02-05 株式会社　ジャパンプランニングセンター ステッカー
JP4110555B2 (ja) * 2004-07-28 2008-07-02 ヤマックス株式会社 封印体及び封印シート

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1076621A (ja) * 1996-07-12 1998-03-24 Konica Corp 情報記録材料
JP2003251718A (ja) * 2002-03-04 2003-09-09 Olympus Optical Co Ltd ラベル作成方法
JP2004001446A (ja) * 2002-03-28 2004-01-08 Seiko Epson Corp 画像保護シート、画像保護液、インクジェット記録物とその製造方法
JP2007001110A (ja) * 2005-06-23 2007-01-11 Toppan Printing Co Ltd 紙部材の製造方法及び紙部材並びに紙容器

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013028147A (ja) * 2011-07-29 2013-02-07 Dainippon Printing Co Ltd 熱転写受像シートおよびそれを用いた遊戯カード
CN104240596A (zh) * 2014-09-30 2014-12-24 李峰 一种新型防伪结构及其生产方法
JP2016172330A (ja) * 2015-03-16 2016-09-29 リンテック株式会社 再使用防止粘着シート
US11996013B2 (en) 2019-05-02 2024-05-28 Pilot Italia S.P.A. Label and manufacturing method

Also Published As

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JPWO2009038234A1 (ja) 2011-01-13
JP5214618B2 (ja) 2013-06-19

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