WO2008126743A1 - 触媒前駆体物質及びそれを用いた触媒 - Google Patents

触媒前駆体物質及びそれを用いた触媒 Download PDF

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Publication number
WO2008126743A1
WO2008126743A1 PCT/JP2008/056588 JP2008056588W WO2008126743A1 WO 2008126743 A1 WO2008126743 A1 WO 2008126743A1 JP 2008056588 W JP2008056588 W JP 2008056588W WO 2008126743 A1 WO2008126743 A1 WO 2008126743A1
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Prior art keywords
catalyst
precursor substance
fuel cell
water
gas shift
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PCT/JP2008/056588
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English (en)
French (fr)
Inventor
Kozo Takatsu
Yoshimi Kawashima
Satoshi Nakai
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Idemitsu Kosan Co., Ltd.
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Priority to CN2008800112599A priority Critical patent/CN101652176B/zh
Priority to EP08739699.0A priority patent/EP2135673A4/en
Priority to KR1020097020951A priority patent/KR101484793B1/ko
Priority to JP2009509278A priority patent/JP5421770B2/ja
Priority to CA2681411A priority patent/CA2681411C/en
Priority to US12/594,983 priority patent/US8088708B2/en
Publication of WO2008126743A1 publication Critical patent/WO2008126743A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
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    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
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    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
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    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
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    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

　本発明は、銅、亜鉛およびアルミニウムを含み、特定の格子面間隔ｄ（Å）にブロードなX線回折ピークを示す触媒前駆体物質及び銅塩、亜鉛塩及びアルミニウム塩を含有する溶液とアルカリ金属又はアルカリ土類金属水酸化物を含有する溶液を混合して沈殿させることによる該触媒前駆体物質を製造し、該触媒前駆体を焼成して触媒を調製し、該触媒を水性ガスシフト反応用触媒とし、該触媒を用いて一酸化炭素を変成し、該変成方法により得られた水素を用いて燃料電池システムとすることにより、活性及び耐久性が高く、燃料電池に適用しても活性の低下が少なく、長期間使用できる水性ガスシフト反応用として有用な触媒及び該触媒を用いた一酸化炭素変成方法並びに該変成方法により得られた水素を用いる燃料電池システムを提供する。
PCT/JP2008/056588 2007-04-10 2008-04-02 触媒前駆体物質及びそれを用いた触媒 WO2008126743A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN2008800112599A CN101652176B (zh) 2007-04-10 2008-04-02 催化剂前体物质及使用该催化剂前体物质的催化剂
EP08739699.0A EP2135673A4 (en) 2007-04-10 2008-04-02 CATALYST PREPARATION MATERIAL AND THIS USING CATALYST
KR1020097020951A KR101484793B1 (ko) 2007-04-10 2008-04-02 촉매 전구체 물질 및 그것을 이용한 촉매
JP2009509278A JP5421770B2 (ja) 2007-04-10 2008-04-02 触媒前駆体物質及びそれを用いた触媒
CA2681411A CA2681411C (en) 2007-04-10 2008-04-02 Catalyst precursor substance, and catalyst using the same
US12/594,983 US8088708B2 (en) 2007-04-10 2008-04-02 Catalyst precursor substance, and catalyst using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007102898 2007-04-10
JP2007-102898 2007-04-10

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WO2008126743A1 true WO2008126743A1 (ja) 2008-10-23

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PCT/JP2008/056588 WO2008126743A1 (ja) 2007-04-10 2008-04-02 触媒前駆体物質及びそれを用いた触媒

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US (1) US8088708B2 (ja)
EP (1) EP2135673A4 (ja)
JP (1) JP5421770B2 (ja)
KR (1) KR101484793B1 (ja)
CN (1) CN101652176B (ja)
CA (1) CA2681411C (ja)
TW (1) TWI433723B (ja)
WO (1) WO2008126743A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011048976A1 (ja) * 2009-10-23 2011-04-28 三菱瓦斯化学株式会社 メタノール合成触媒
JP2011194362A (ja) * 2010-03-23 2011-10-06 Idemitsu Kosan Co Ltd 一酸化炭素転換用触媒の製造方法
JP2012139637A (ja) * 2010-12-28 2012-07-26 Idemitsu Kosan Co Ltd 銅−亜鉛−アルミニウム触媒、その製造方法、一酸化炭素変成方法、及び水素製造方法
JP2014524836A (ja) * 2011-07-27 2014-09-25 サウジ アラビアン オイル カンパニー 気体炭化水素から硫黄化合物を除去するのに有用な触媒組成物、その製造方法およびその使用
JP2015505799A (ja) * 2011-12-02 2015-02-26 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード 中温で作用する水性ガスシフト触媒およびその調製のための方法

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CA2666204C (en) * 2006-10-13 2015-09-22 Idemitsu Kosan Co., Ltd. Catalyst for carbon monoxide conversion and method of carbon monoxide modification with the same
WO2011132957A2 (ko) * 2010-04-21 2011-10-27 에스케이이노베이션주식회사 나노미터 크기의 구리계 촉매, 그 제조 방법 및 이를 이용한 카르복시산의 직접수소화를 통한 알코올 제조방법
CA2815124C (en) * 2010-11-19 2016-04-19 Rentech, Inc. Stable slurry bed fischer-tropsch catalyst with high surface area and activity
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US20130217568A1 (en) * 2012-02-20 2013-08-22 Saudi Basic Industries Corporation Oxidative dehydrogenation of olefins catalyst and methods of making and using the same
TWI612031B (zh) * 2012-09-18 2018-01-21 China Petrochemical Technology Co Ltd 一種聯產環己醇和鏈烷醇的方法和裝置
US9889429B2 (en) 2012-10-16 2018-02-13 Bill W. Helton Hydrogen production catalysts and associated systems and methods
US8920635B2 (en) * 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
CN105408006B (zh) * 2013-07-31 2019-11-01 国际壳牌研究有限公司 氧化亚氮分解催化剂
CN104560251B (zh) * 2013-10-28 2017-04-19 中国石油化工股份有限公司 净化剂及其用途
AR107702A1 (es) 2016-02-29 2018-05-23 Haldor Topsoe As Renovación con baja cantidad de vapor / carbono
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WO2018015824A1 (en) * 2016-07-18 2018-01-25 Sabic Global Technologies B.V. Process for high-pressure hydrogenation of carbon dioxide to syngas in the presence of a copper/zinc/zirconium mixed metal oxide catalyst
EP3305404A1 (en) * 2016-10-10 2018-04-11 National Petrochemical Company Copper/zinc/aluminium catalyst for the methanol synthesis prepared from a binary zinc-aluminium precursor solution
US10814312B2 (en) * 2017-05-25 2020-10-27 Osaka Gas Co., Ltd. Desulfurizing agent for gases and gas desulfurization method
CN108435182B (zh) * 2017-08-16 2021-01-15 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
KR102233613B1 (ko) * 2018-10-15 2021-03-30 재단법인 포항산업과학연구원 중온용 수성가스 전환 반응 촉매, 이의 제조방법, 및 이를 이용한 수소 제조방법
KR102199485B1 (ko) * 2018-10-18 2021-01-06 연세대학교 원주산학협력단 일단 수성가스 전이 반응을 위한 촉매의 제조 방법
CN112206763A (zh) * 2019-07-12 2021-01-12 中石化南京化工研究院有限公司 一种铜系低温变换催化剂及其制备方法
CN112473667B (zh) * 2020-11-24 2022-11-29 西安理工大学 不同形貌和表面Cu+含量的CuO催化剂的制备方法
CN114762826A (zh) * 2021-07-21 2022-07-19 天津科技大学 高指数晶面Cu2O光催化剂的制备方法及其应用

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